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Volume 46
Main Index

Issue 1


X-ray Absorption Spectroscopic Characterization of the Molybdenum Site of Escherichia coli Dimethyl Sulfoxide Reductase
Graham N. George, Christian J. Doonan, Richard A. Rothery, Nasim Boroumand, and Joel H. Weiner
pp 2 - 4; DOI:
10.1021/ic061695t
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Influence of Electron-Attractor Substituents on the Magnetic Properties of Ni(II) String Complexes
Xavier López, Marc Bénard, and Marie-Madeleine Rohmer
pp 5 - 7; DOI:
10.1021/ic061705q
PDF
Base-Stabilized Amidodiarsenes: Synthesis, Structure, and Theoretical Studies
Shaun P. Green, Cameron Jones, Guoxia Jin, and Andreas Stasch
pp 8 - 10; DOI:
10.1021/ic062163f
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Homo- and Heteroleptic Complexes of Four-Membered Group 13 Metal(I) N-Heterocyclic Carbene Analogues with Group 10 Metal(0) Fragments
Shaun P. Green, Cameron Jones, and Andreas Stasch
pp 11 - 13; DOI:
10.1021/ic062057d
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Synthesis and Characterization of Cationic Tungsten(V) Methylidynes
Edwin F. van der Eide, Warren E. Piers, Masood Parvez, and Robert McDonald
pp 14 - 21; DOI:
10.1021/ic0611342
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Cyanide-Bridged Mn(III)-Fe(III) Bimetallic Complexes Based on the Pentacyano(1-methylimidazole)ferrate(III) Building Block: Structure and Magnetic Characterizations
Wei-Wei Ni, Zhong-Hai Ni, Ai-Li Cui, Xin Liang, and Hui-Zhong Kou
pp 22 - 33; DOI:
10.1021/ic060575i
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Speciation of the Catalytic Oxygen Evolution System: [MnIII/IV2(-O)2(terpy)2(H2O)2](NO3)3 + HSO5-
Hongyu Chen, Ranitendranath Tagore, Gerard Olack, John S. Vrettos, Tsu-Chien Weng, James Penner-Hahn, Robert H. Crabtree, and Gary W. Brudvig
pp 34 - 43; DOI:
10.1021/ic060499j
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Structural Characterization of Al10O6iBu16(-H)2, a High Aluminum Content Cluster: Further Studies of Methylaluminoxane (MAO) and Related Aluminum Complexes
Feng-Jung Wu, Larry S. Simeral, Anthony A. Mrse, Jan L. Eilertsen, Lacramioara Negureanu, Zhehong Gan, Frank R. Fronczek, Randall W. Hall, and Leslie G. Butler
pp 44 - 47; DOI:
10.1021/ic060291y
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Weak-Field Anions Displace the Histidine Ligand in a Synthetic Heme Peptide but Not in N-Acetylmicroperoxidase-8: Possible Role of Heme Geometry Differences
Aaron B. Cowley and David R. Benson
pp 48 - 59; DOI:
10.1021/ic060682c
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Quantitative Geometric Descriptions of the Belt Iron Atoms of the Iron-Molybdenum Cofactor of Nitrogenase and Synthetic Iron(II) Model Complexes
Javier Vela, Jordi Cirera, Jeremy M. Smith, Rene J. Lachicotte, Christine J. Flaschenriem, Santiago Alvarez, and Patrick L. Holland
pp 60 - 71; DOI:
10.1021/ic0609148
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Design of Molecular Scaffolds Based on Unusual Geometries for Magnetic Modulation of Spin-Diverse Complexes with Selective Redox Response
Maurício Lanznaster, Mary Jane Heeg, Gordon T. Yee, Bruce R. McGarvey, and Claudio N. Verani
pp 72 - 78; DOI:
10.1021/ic060944a
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fac-{Ru(CO)3}2+-Core Complexes and Design of Metal-Based Drugs. Synthesis, Structure, and Reactivity of Ru-Thiazole Derivative with Serum Proteins and Absorption-Release Studies with Acryloyl and Silica Hydrogels as Carriers in Physiological Media
Renzo Cini, Sandra Defazio, Gabriella Tamasi, Mario Casolaro, Luigi Messori, Angela Casini, Margherita Morpurgo, and Michael Hursthouse
pp 79 - 92; DOI:
10.1021/ic060755s
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Synthesis and Characterization of Silyldichloramines, Their Reactions with F- Ions, Instability of N2Cl2 and NCl2-, and Formation of NCl3
Stefan Schneider, Michael Gerken, Ralf Haiges, Thorsten Schroer, Jerry A. Boatz, David A. Dixon, Daniel J. Grant, and Karl O. Christe
pp 93 - 102; DOI:
10.1021/ic0609103
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Control of Two-Electron Four-Center (2e-/4c) C-C Bond Formation Observed for Tetracyanoethenide Dimerization, [TCNE]22-
Juan N. Novoa, Jordi Ribas-Ariño, William W. Shum, and Joel S. Miller
pp 103 - 107; DOI:
10.1021/ic0611037
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Insights into the Mechanism of Electrocatalytic Hydrogen Evolution Mediated by Fe2(S2C3H6)(CO)6: The Simplest Functional Model of the Fe-Hydrogenase Active Site
Claudio Greco, Giuseppe Zampella, Luca Bertini, Maurizio Bruschi, Piercarlo Fantucci, and Luca De Gioia
pp 108 - 116; DOI:
10.1021/ic061168+
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A Density Functional Theory Study of the Electronic Properties of Os(II) and Os(III) Complexes Immobilized on Au(111)
Noel M. O'Boyle, Tim Albrecht, Daniel H. Murgida, Lynda Cassidy, Jens Ulstrup, and Johannes G. Vos
pp 117 - 124; DOI:
10.1021/ic060903e
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Modulation of the Singlet-Singlet Through-Space Energy Transfer Rates in Cofacial Bisporphyrin and Porphyrin-Corrole Dyads
Claude P. Gros, Frédéric Brisach, Anastasia Meristoudi, Enrique Espinosa, Roger Guilard, and Pierre D. Harvey
pp 125 - 135; DOI:
10.1021/ic0613558
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Synthesis and Characterization of a New Layered Fluoroaluminophosphate (C4H11NOH)3.5[Al4(PO4)5F]·0.5H3O with Extra-Large 16-Rings
Min Zhang, Dan Zhou, Jiyang Li, Jihong Yu, Jun Xu, Feng Deng, Guanghua Li, and Ruren Xu
pp 136 - 140; DOI:
10.1021/ic061362w
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Syntheses of Mixed-Ligand Tetranuclear Gold(I)-Nitrogen Clusters by Ligand Exchange Reactions with the Dinuclear Gold(I) Formamidinate Complex Au2(2,6-Me2Ph-form)2
Hanan E. Abdou, Ahmed A. Mohamed, and John P. Fackler, Jr.
pp 141 - 146; DOI:
10.1021/ic0612449
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Syntheses and Structures of Asymmetric Bis(silyl) Niobocene Hydrides
Konstantin Yu. Dorogov, Muhammed Yousufuddin, Nam-Nhat Ho, Andrei V. Churakov, Lyudmila G. Kuzmina, Arthur J. Schultz, Sax A. Mason, Judith A. K. Howard, Dmitry A. Lemenovskii, Robert Bau, and Georgii I. Nikonov
pp 147 - 160; DOI:
10.1021/ic061314b
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Static Magnetization of V15 Cluster at Ultra-Low Temperatures: Precise Estimation of Antisymmetric Exchange
Alex Tarantul, Boris Tsukerblat, and Achim Müller
pp 161 - 169; DOI:
10.1021/ic061394j
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Assignment of the Ferriheme Resonances of the High-Spin Forms of Nitrophorins 1 and 4 by 1H NMR Spectroscopy: Comparison to Structural Data Obtained from X-ray Crystallography
Tatiana Kh. Shokhireva, Kevin M. Smith, Robert E. Berry, Nikolai V. Shokhirev, Celia A. Balfour, Hongjun Zhang, and F. Ann Walker
pp 170 - 178; DOI:
10.1021/ic061407t
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Control of S-Based Aggregation: Designed Synthesis of NiM2 and Ni2M Trinuclear Complexes
Stephen P. Jeffery, Michael L. Singleton, Joseph H. Reibenspies, and Marcetta Y. Darensbourg
pp 179 - 185; DOI:
10.1021/ic061475f
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Crystal-Engineering Studies of Coordination Polymers and a Molecular-Looped Complex Containing Dipyridyl-Amide Ligands
Biing-Chiau Tzeng, Yung-Chi Huang, Bo-So Chen, Wan-Min Wu, Shih-Yang Lee, Gene-Hsiang Lee, and Shie-Ming Peng
pp 186 - 195; DOI:
10.1021/ic061528t
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Glycine- and Sarcosine-Based Models of Vanadate-Dependent Haloperoxidases in Sulfoxygenation Reactions
Cornelia Wikete, Pingsong Wu, Giuseppe Zampella, Luca De Gioia, Giulia Licini, and Dieter Rehder
pp 196 - 207; DOI:
10.1021/ic061534p
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Synthesis, Crystal Structure, and Optical Properties of LiGd5P2O13, a Layered Lithium Gadolinium Phosphate Containing One-Dimensional Li Chains
Jing Zhu, Wen-Dan Cheng, Dong-Sheng Wu, Hao Zhang, Ya-Jing Gong, Hua-Nan Tong, and Dan Zhao
pp 208 - 212; DOI:
10.1021/ic061536+
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Characterization of the Crystal and Magnetic Structures of the Mixed-Anion Coordination Polymer Cu(HCO2)(NO3)(pyz) {pyz = Pyrazine} by X-ray Diffraction, ac Magnetic Susceptibility, dc Magnetization, Muon-Spin Relaxation, and Spin Dimer Analysis
J. L. Manson, T. Lancaster, J. A. Schlueter, S. J. Blundell, M. L. Brooks, F. L. Pratt, C. L. Nygren, H.-J. Koo, D. Dai, and M.-H. Whangbo
pp 213 - 220; DOI:
10.1021/ic061590q
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Supramolecular Assemblies of Trinuclear Triangular Copper(II) Secondary Building Units through Hydrogen Bonds. Generation of Different Metal-Organic Frameworks, Valuable Catalysts for Peroxidative Oxidation of Alkanes
Corrado Di Nicola, Yauhen Yu. Karabach, Alexander M. Kirillov, Magda Monari, Luciano Pandolfo, Claudio Pettinari, and Armando J. L. Pombeiro
pp 221 - 230; DOI:
10.1021/ic061595n
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Two Organically Templated Niobium and Zinconiobium Fluorophosphates: Low Temperature Hydrothermal Syntheses of NbOF(PO4)2(C2H10N2)2 and Zn3(NbOF)(PO4)4(C2H10N2)2
Guang-Zhen Liu, Shou-Tian Zheng, and Guo-Yu Yang
pp 231 - 237; DOI:
10.1021/ic061752i
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Dinuclear Complexes Formed with the Triazacyclononane Derivative ENOTA4-: High-Pressure 17O NMR Evidence of an Associative Water Exchange on [MnII2(ENOTA)(H2O)2]
Edina Balogh, Zhenjie He, Wenyuan Hsieh, Shuang Liu, and Éva Tóth
pp 238 - 250; DOI:
10.1021/ic0616582
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Atomic Distributions in the -Brass Structure of the Cu-Zn System: A Structural and Theoretical Study
Olivier Gourdon, Delphine Gout, Darrick J. Williams, Thomas Proffen, Sara Hobbs, and Gordon J. Miller
pp 251 - 260; DOI:
10.1021/ic0616380
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Anion Partitioning and Ion-Pairing Behavior of Anions in the Extraction of Cesium Salts by 4,5' '-Bis(tert-octylbenzo)dibenzo-24-crown-8 in 1,2-Dichloroethane
Tatiana G. Levitskaia, Leon Maya, Gary J. Van Berkel, and Bruce A. Moyer
pp 261 - 272; DOI:
10.1021/ic061605k
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Substituent Effects on Exchange Coupling: 5-Aryl-Substituted Semiquinones and Their Complexes with MnII and CuII
David A. Shultz, Joseph C. Sloop, Tashni-Ann Coote, Mithra Beikmohammadi, Jeff Kampf, and Paul D. Boyle
pp 273 - 277; DOI:
10.1021/ic061807g
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Inorganic-Organic Framework Structures; M(II) Ethylenediphosphonates (M = Co, Ni, Mn) and a Mn(II) Ethylenediphosphonato-phenanthroline
Crystal A. Merrill and Anthony K. Cheetham
pp 278 - 284; DOI:
10.1021/ic0618302
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Kinetics and Mechanism of the Comproportionation of Hypothiocyanous Acid and Thiocyanate to Give Thiocyanogen in Acidic Aqueous Solution
Péter Nagy, Kelemu Lemma, and Michael T. Ashby
pp 285 - 292; DOI:
10.1021/ic061470i
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Oxidative N-Dealkylation Reactions by Oxoiron(IV) Complexes of Nonheme and Heme Ligands
Kasi Nehru, Mi Sook Seo, Jinheung Kim, and Wonwoo Nam
pp 293 - 298; DOI:
10.1021/ic0614014
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Syntheses, Structures, Spectroscopy, and Chromotropism of New Complexes Arising from the Reaction of Nickel(II) Nitrate with Diphenyl(dipyrazolyl)methane
Natalie Baho and Davit Zargarian
pp 299 - 308; DOI:
10.1021/ic061311z
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Modulating the M-M Distance in Dinuclear Complexes. New Ligand with a 2,2'-Biphenol Fragment as Key Unit: Synthesis, Coordination Behavior, and Crystal Structures of Cu(II) and Zn(II) Dinuclear Complexes
Gianluca Ambrosi, Mauro Formica, Vieri Fusi, Luca Giorgi, Annalisa Guerri, Mauro Micheloni, Paola Paoli, Roberto Pontellini, and Patrizia Rossi
pp 309 - 320; DOI:
10.1021/ic061474n
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Facile Construction of Lanthanide Metallomacrocycles with the Bridging Imidazolate and Triazolate Ligands and Their Ring Expansions
Jie Zhang, Ruifang Cai, Zhenxia Chen, and Xigeng Zhou
pp 321 - 327; DOI:
10.1021/ic061722f
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Aluminum and Zinc Complexes Based on an Amino-Bis(pyrazolyl) Ligand: Synthesis, Structures, and Use in MMA and Lactide Polymerization
Bing Lian, Christophe M. Thomas, Osvaldo L. Casagrande Jr., Christian W. Lehmann, Thierry Roisnel, and Jean-François Carpentier
pp 328 - 340; DOI:
10.1021/ic061749z
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Negative Differential Resistance and Memory Effect in Diodes Based on 1,4-Dibenzyl C60 and Zinc Phthalocyanine Doped Polystyrene Hybrid Material
Jian Lin, Min Zheng, Jiangshan Chen, Xiang Gao, and Dongge Ma
pp 341 - 344; DOI:
10.1021/ic061851w
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Issue 2


Intercalation of Iodic Acid into the Layered Uranyl Iodate, UO2(IO3)2(H2O)
Jie Ling and Thomas E. Albrecht-Schmitt
pp 346 - 347; DOI:
10.1021/ic062072i
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Catalytic Promiscuity in Biomimetic Systems: Catecholase-like Activity, Phosphatase-like Activity, and Hydrolytic DNA Cleavage Promoted by a New Dicopper(II) Hydroxo-Bridged Complex
Nicolás A. Rey, Ademir Neves, Adailton J. Bortoluzzi, Claus T. Pich, and Hernán Terenzi
pp 348 - 350; DOI:
10.1021/ic0613107
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1,2-HOIQO-a Highly Versatile 1,2-HOPO Analogue
Michael Seitz, Michael D. Pluth, and Kenneth N. Raymond
pp 351 - 353; DOI:
10.1021/ic0614869
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Which Is Reactive in Alkaline Solution, Boronate Ion or Boronic Acid? Kinetic Evidence for Reactive Trigonal Boronic Acid in an Alkaline Solution
Satoshi Iwatsuki, Shihoko Nakajima, Masahiko Inamo, Hideo D. Takagi, and Koji Ishihara
pp 354 - 356; DOI:
10.1021/ic0615372
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Reaction of the Mo3S4 Cluster with Dimethylacetylenedicarboxylate: An ESR-Active Cluster and an Organometallic Cluster Formed by ,-Conjugate Addition
Yasuhiro Ide and Takashi Shibahara
pp 357 - 359; DOI:
10.1021/ic0617285
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Sterically Bulky Tris(triazolyl)borate Ligands as Water-Soluble Analogues of Tris(pyrazolyl)borate
Finith E. Jernigan, III, Nathan A. Sieracki, Michael T. Taylor, Aaron S. Jenkins, Sharon E. Engel, Brittany W. Rowe, Fernando A. Jové, Glenn P. A. Yap, Elizabeth T. Papish, and Gregory M. Ferrence
pp 360 - 362; DOI:
10.1021/ic061828a
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Supramolecular Rotor: Adamantylammonium([18]crown-6) in [Ni(dmit)2]- Salt
Daisuke Sato, Tomoyuki Akutagawa, Sadamu Takeda, Shin-ichiro Noro, and Takayoshi Nakamura
pp 363 - 365; DOI:
10.1021/ic061831u
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Chelating or Bridging? Halide-Controlled Binding Mode of Diamido Donor Ligands in Iron(III) Complexes
Anjan Kumar Das, Zohreh Moatazedi, Garry Mund, Andrew J. Bennet, Raymond J. Batchelor, and Daniel B. Leznoff
pp 366 - 368; DOI:
10.1021/ic061832m
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Formation of Hollow Ni2P Nanoparticles Based on the Nanoscale Kirkendall Effect
Ray-Kuang Chiang and Ray-Tung Chiang
pp 369 - 371; DOI:
10.1021/ic061846s
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One-Dimensional Metal-Organic Framework with Unprecedented Heptanuclear Copper Units
Sacramento Ferrer, Elena Aznar, Francesc Lloret, Alfonso Castiñeiras, Malva Liu-González, and Joaquín Borrás
pp 372 - 374; DOI:
10.1021/ic0619106
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First Insights into the Electronic Properties of a Cu(II) Center Embedded in the PN3 Cap of a Calix[6]arene-Based Ligand
G. Izzet, X. Zeng, D. Over, B. Douziech, J. Zeitouny, M. Giorgi, I. Jabin, Y. Le Mest, and O. Reinaud
pp 375 - 377; DOI:
10.1021/ic0620384
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Investigation on the Influence of Particular Structure Parameters on the Anisotropic Spin-Exchange Interactions in the Distorted Wolframite-Type Oxides Cu(MoxW1-x)O4
Björn C. Schwarz, Helmut Ehrenberg, Hans Weitzel, and Hartmut Fuess
pp 378 - 380; DOI:
10.1021/ic061944d
PDF
Synthesis of Functionalized Carboranes as Potential Anticancer and BNCT Agents
Venkata Jaganmohan Reddy, Matthew M. Roforth, Chalet Tan, and M. Venkat Ram Reddy
pp 381 - 383; DOI:
10.1021/ic061948i
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Assignment of Molecular Structures to the Electrochemical Reduction Products of Diiron Compounds Related to [Fe-Fe] Hydrogenase: A Combined Experimental and Density Functional Theory Study
Stacey J. Borg, Jesse W. Tye, Michael B. Hall, and Stephen P. Best
pp 384 - 394; DOI:
10.1021/ic061211t
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Single- and Two-Photon Properties of a Dye-Derivatized Roussin's Red Salt Ester (Fe2(-RS)2(NO)4) with a Large TPA Cross Section1
Stephen R. Wecksler, Alexander Mikhailovsky, Dmitry Korystov, Fabian Buller, Ramamurthi Kannan, Loon-Seng Tan, and Peter C. Ford
pp 395 - 402; DOI:
10.1021/ic0607336
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A Metallacage Encapsulating Chloride as a Probe for a Solvation Scale in Ionic Liquids
Corinne Daguenet and Paul J. Dyson
pp 403 - 408; DOI:
10.1021/ic060631f
PDF
Electrochemical and Photophysical Properties of DNA Metallo-intercalators Containing the Ruthenium(II) Tris(1-pyrazolyl)methane Unit
Simon P. Foxon, Clive Metcalfe, Harry Adams, Michelle Webb, and Jim A. Thomas
pp 409 - 416; DOI:
10.1021/ic0607134
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Theoretical Determination of the Excited States and of g-Factors of the Creutz-Taube Ion, [(NH3)5-Ru-pyrazine-Ru-(NH3)5]5+
Hélène Bolvin
pp 417 - 427; DOI:
10.1021/ic060816m
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Metal Phosphonates Based on Bis(benzimidazol-2-ylmethyl)imino Methylenephosphonate: From Discrete Dimer to Two-Dimensional Network Containing Metallomacrocycles
Deng-Ke Cao, Jing Xiao, Jian-Wei Tong, Yi-Zhi Li, and Li-Min Zheng
pp 428 - 436; DOI:
10.1021/ic060990a
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Occurrence of a Rare 49·66 Structural Topology, Chirality, and Weak Ferromagnetism in the [NH4][MII(HCOO)3] (M = Mn, Co, Ni) Frameworks
Zheming Wang, Bin Zhang, Katsuya Inoue, Hideki Fujiwara, Takeo Otsuka, Hayao Kobayashi, and Mohamedally Kurmoo
pp 437 - 445; DOI:
10.1021/ic0610031
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Phase Transition in Tl2TeO3: Influence and Origin of the Thallium Lone Pair Distortion
Franziska Rieger and Anja-Verena Mudring
pp 446 - 452; DOI:
10.1021/ic061273j
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Selection and Discovery of Polymorphs of Platinum Complexes Facilitated by Polymer-Induced Heteronucleation
Adam L. Grzesiak and Adam J. Matzger
pp 453 - 457; DOI:
10.1021/ic061323k
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Stability Constants: A New Twist in Transition Metal Bispidine Chemistry
Karin Born, Peter Comba, Rosana Ferrari, Geoffrey A. Lawrance, and Hubert Wadepohl
pp 458 - 464; DOI:
10.1021/ic061501+
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Functionalized Bis(thiosemicarbazonato) Complexes of Zinc and Copper: Synthetic Platforms Toward Site-Specific Radiopharmaceuticals
Jason P. Holland, Franklin I. Aigbirhio, Helen M. Betts, Paul D. Bonnitcha, Paul Burke, Martin Christlieb, Grant C. Churchill, Andrew R. Cowley, Jonathan R. Dilworth, Paul S. Donnelly, Jennifer C. Green, Josephine M. Peach, Sridhar R. Vasudevan, and John E. Warren
pp 465 - 485; DOI:
10.1021/ic0615628
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Ligand Structural Effects on Cu2S2 Bonding and Reactivity in Side-On Disulfido-Bridged Dicopper Complexes
Eric C. Brown, Itsik Bar-Nahum, John T. York, Nermeen W. Aboelella, and William B. Tolman
pp 486 - 496; DOI:
10.1021/ic061589r
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{[Cu(mtz)]3(CuI)}n: An Unprecedented Non-interpenetrated (123)(122·14)3 Network with Triple-Stranded Helices
Xi-He Huang, Tian-Lu Sheng, Sheng-Chang Xiang, Rui-Biao Fu, Sheng-Min Hu, Ya-Min Li, and Xin-Tao Wu
pp 497 - 500; DOI:
10.1021/ic0617341
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Electron-Sponge Behavior and Electronic Structures in Cobalt-Centered Pentagonal Prismatic Co11Te7(CO)10 and Co11Te5(CO)15 Cluster Anions
Olivier Cador, Hélène Cattey, Jean-François Halet, Walter Meier, Yves Mugnier, Joachim Wachter, Jean-Yves Saillard, Bachir Zouchoune, and Manfred Zabel
pp 501 - 509; DOI:
10.1021/ic061904+
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Stabilization of Reduced Molybdenum-Iron-Sulfur Single- and Double-Cubane Clusters by Cyanide Ligation
Russell P. Pesavento, Curtis P. Berlinguette, and R. H. Holm
pp 510 - 516; DOI:
10.1021/ic061704y
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Synthesis and Characterization of a New Ternary Imide-Li2Ca(NH)2
Guotao Wu, Zhitao Xiong, Tao Liu, Yongfeng Liu, Jianjiang Hu, Ping Chen, Yuanping Feng, and Andrew T. S. Wee
pp 517 - 521; DOI:
10.1021/ic060769y
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Electronic Structure of Nitric Oxide Adducts of Bis(diaryl-1,2-dithiolene)iron Compounds: Four-Membered Electron-Transfer Series [Fe(NO)(L)2]z (z = 1+, 0, 1-, 2-)
Prasanta Ghosh, Keira Stobie, Eckhard Bill, Eberhard Bothe, Thomas Weyhermüller, Michael D. Ward, Jon A. McCleverty, and Karl Wieghardt
pp 522 - 532; DOI:
10.1021/ic061874a
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Multiple Additions of Phenylgermanium Ligands to Tetraruthenium and Tetraosmium Carbonyl Cluster Complexes
Richard D. Adams, Erin M. Boswell, Burjor Captain, and Mitul A. Patel
pp 533 - 540; DOI:
10.1021/ic062039w
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63Cu NMR Spectroscopy of Copper(I) Complexes with Various Tridentate Ligands: CO as a Useful 63Cu NMR Probe for Sharpening 63Cu NMR Signals and Analyzing the Electronic Donor Effect of a Ligand
Masato Kujime, Takuya Kurahashi, Masaaki Tomura, and Hiroshi Fujii
pp 541 - 551; DOI:
10.1021/ic060745r
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Mixed Co-Rh Nitrido-Encapsulated Carbonyl Clusters. Synthesis, Solid-State Structure, and Electrochemical/EPR Characterization of the Anions [Co10Rh(N)2(CO)21]3-, [Co10Rh2(N)2(CO)24]2-, and [Co11Rh(N)2(CO)24]2-
Michela Costa, Roberto Della Pergola, Alessandro Fumagalli, Franco Laschi, Serena Losi, Piero Macchi, Angelo Sironi, and Piero Zanello
pp 552 - 560; DOI:
10.1021/ic0608288
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Temperature-Dependent Coordination of Phosphine to Five-Coordinate Alkenylruthenium Complexes
Sripriya K. Seetharaman, Min-Chul Chung, Ulrich Englich, Karin Ruhlandt-Senge, and Michael B. Sponsler
pp 561 - 567; DOI:
10.1021/ic061389f
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1H NMR Direct Observation of Enantiomeric Exchange in Palladium(II) and Platinum(II) Complexes Containing N,N' Bidentate Aryl-pyridin-2-ylmethyl-amine Ligands
Virginia Diez, José V. Cuevas, Gabriel García-Herbosa, Gabriel Aullón, Jonathan P. H. Charmant, Arancha Carbayo, and Asunción Muñoz
pp 568 - 577; DOI:
10.1021/ic061060u
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ESR, Zero-Field Splitting, and Magnetic Exchange of Exchange-Coupled Copper(II)-Copper(II) Pairs in Copper(II) Tetraphenylporphyrin N-Oxide
Fuh-An Yang, Chih-Wei Guo, Yao-Jung Chen, Jyh-Horung Chen, Shin-Shin Wang, Jo-Yu Tung, Lian-Pin Hwang, and Shanmugam Elango
pp 578 - 585; DOI:
10.1021/ic0611802
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Syntheses and Characterizations of Bismuth Nanofilms and Nanorhombuses by the Structure-Controlling Solventless Method
Jing Chen, Li-Ming Wu, and Ling Chen
pp 586 - 591; DOI:
10.1021/ic0615067
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Mechanism and Driving Force of NO Transfer from S-Nitrosothiol to Cobalt(II) Porphyrin: A Detailed Thermodynamic and Kinetic Study
Xiao-Qing Zhu, Jian-Yu Zhang, and Jin-Pei Cheng
pp 592 - 600; DOI:
10.1021/ic061427v
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Hydrothermal Synthesis and Structural Characterizations of Two New Germanates with a Novel Topological Framework and Unusual Ge4(OH)4 Cubane
Yan Xu, Liying Cheng, and Wansheng You:
pp 601 - 601; DOI:
10.1021/ic0622656
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Redox-Controlled Molecular Flipper Based on a Chiral Cu Complex
Anna Company, Mireia Güell, Dana Popa, JordiBenet-Buchholz,, Teodor Parella, Xavier Fontrodona, AntoniLlobet, Miquel Solà, Xavi Ribasm, Josep M. Luis, and MiquelCostas:
pp 602 - 602; DOI:
10.1021/ic062266y
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Issue 3


Zeolite-like Copper Iodide Framework with New 66 Topology
Minghui Bi, Guanghua Li, Yongchun Zou, Zhan Shi, and Shouhua Feng
pp 604 - 606; DOI:
10.1021/ic061163c
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Ground- and Excited-State Reactivity of Iron Porphyrinogens
Julien Bachmann, Justin M. Hodgkiss, Elizabeth R. Young, and Daniel G. Nocera
pp 607 - 609; DOI:
10.1021/ic0616636
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Cyanide-Bridged Fe(III)-Mn(III) Chain with Metamagnetic Properties and Significant Magnetic Anisotropy
Shi Wang, Marilena Ferbinteanu, and Masahiro Yamashita
pp 610 - 612; DOI:
10.1021/ic061681n
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Insights into the Mechanism of N2O Reduction by Reductively Activated N2O Reductase from Kinetics and Spectroscopic Studies of pH Effects
Koyu Fujita and David M. Dooley
pp 613 - 615; DOI:
10.1021/ic061843f
PDF
Novel Copper-Complex-Substituted Tungstogermanates
Chun-Mei Wang, Shou-Tian Zheng, and Guo-Yu Yang
pp 616 - 618; DOI:
10.1021/ic0618605
PDF
Four-Coordinate Iron(II) Porphyrinates: Electronic Configuration Change by Intermolecular Interaction
Chuanjiang Hu, Bruce C. Noll, Charles E. Schulz, and W. Robert Scheidt
pp 619 - 621; DOI:
10.1021/ic0620182
PDF
{[Nd4(ox)4(NO3)2(OH)2(H2O)2]·5H2O}n: A Porous 3D Lanthanide-Based Coordination Polymer with a Special Luminescent Property
Li-Zhi Zhang, Wen Gu, Bing Li, Xin Liu, and Dai-Zheng Liao
pp 622 - 624; DOI:
10.1021/ic061635n
PDF
Selective Self-Assembly of Hexameric Homo- and Heteropolymetallic Lanthanide Wheels: Synthesis, Structure, and Photophysical Studies
Xiao-Yan Chen, Yann Bretonnière, Jacques Pécaut, Daniel Imbert, Jean-Claude Bünzli, and Marinella Mazzanti
pp 625 - 637; DOI:
10.1021/ic061806o
PDF
Synthesis and Electron Transfer Studies of Ruthenium-Terpyridine-Based Dyads Attached to Nanostructured TiO2
Henriette Wolpher, Subrata Sinha, Jingxi Pan, Anh Johansson, Maria J. Lundqvist, Petter Persson, Reiner Lomoth, Jonas Bergquist, Licheng Sun, Villy Sundström, Björn Åkermark, and Tomás Polívka
pp 638 - 651; DOI:
10.1021/ic060858a
PDF
Synthesis, Structure, and Thermochemistry of the Formation of the Metal-Metal Bonded Dimers [Mo(-TeAr)(CO)3(PiP3)]2 (Ar = Phenyl, Naphthyl) by Phosphine Elimination from Mo(TePh)(CO)3(PiPr3)2
John J. Weir, James E. McDonough, George Fortman, Derek Isrow, Carl D. Hoff, Brian Scott, and Gregory J. Kubas
pp 652 - 659; DOI:
10.1021/ic061654x
PDF
Spin Coupling in the Supramolecular Structure of a New Tetra(Quinoline-TEMPO)Yttrium(III) Complex
Luca Maretti, Marilena Ferbinteanu, Fanica Cimpoesu, Saiful S. M. Islam, Yasunori Ohba, Takashi Kajiwara, Masahiro Yamashita, and Seigo Yamauchi
pp 660 - 669; DOI:
10.1021/ic0610841
PDF
Structural Studies and Photochromism of Mercury(II)-Iodo Complexes of (Arylazo)imidazoles
K. K. Sarker, B. G. Chand, K. Suwa, J. Cheng, T.-H. Lu, J. Otsuki, and C. Sinha
pp 670 - 680; DOI:
10.1021/ic061221u
PDF
Accounting for the Differences in the Structures and Relative Energies of the Highly Homoatomic np-np (n 3)-Bonded S2I42+, the Se-I -Bonded Se2I42+, and Their Higher-Energy Isomers by AIM, MO, NBO, and VB Methodologies
Scott Brownridge, Margaret-Jane Crawford, Hongbin Du, Richard D. Harcourt, Carsten Knapp, Risto S. Laitinen, Jack Passmore, J. Mikko Rautiainen, Reijo J. Suontamo, and Jussi Valkonen
pp 681 - 699; DOI:
10.1021/ic061523w
PDF
Cyclometalated Iridium(III) Diimine Bis(biotin) Complexes as the First Luminescent Biotin-Based Cross-Linkers for Avidin
Kenneth Kam-Wing Lo and Jason Shing-Yip Lau
pp 700 - 709; DOI:
10.1021/ic0612202
PDF
The Copper(II) Adduct of the Unstructured Region of the Amyloidogenic Fragment Derived from the Human Prion Protein is Redox-Active at Physiological pH
Jason Shearer and Pamela Soh
pp 710 - 719; DOI:
10.1021/ic061236s
PDF
Synthesis, Structure, Photophysics, Electrochemistry, and Ion-Binding Studies of Ruthenium(II) 1,10-Phenanthroline Complexes Containing Thia-, Selena-, and Aza-Crown Pendants
Mei-Jin Li, Ben Wai-Kin Chu, Nianyong Zhu, and Vivian Wing-Wah Yam
pp 720 - 733; DOI:
10.1021/ic061507z
PDF
Synthesis, Structure, and Activity of Supramolecular Mimics for the Active Site and Arg141 Residue of Copper, Zinc-Superoxide Dismutase
Ying-Hua Zhou, Heng Fu, Wei-Xi Zhao, Wei-Lin Chen, Cheng-Yong Su, Hongzhe Sun, Liang-Nian Ji, and Zong-Wan Mao
pp 734 - 739; DOI:
10.1021/ic061541d
PDF
DNA Binding and Cytotoxicity of Ruthenium(II) and Rhenium(I) Complexes of 2-Amino-4-phenylamino-6-(2-pyridyl)-1,3,5-triazine
Dik-Lung Ma, Chi-Ming Che, Fung-Ming Siu, Mengsu Yang, and Kwok-Yin Wong
pp 740 - 749; DOI:
10.1021/ic061518s
PDF
Amido/Amine Triazacyclononane-Based Zirconium Complexes: Syntheses, Reactivity, and Structures
Humberto Ferreira, Alberto R. Dias, M. Teresa Duarte, José R. Ascenso, and Ana M. Martins
pp 750 - 755; DOI:
10.1021/ic061588z
PDF
Odd-Numbered FeIII Complexes: Synthesis, Molecular Structure, Reactivity, and Magnetic Properties
Ayuk M. Ako, Oliver Waldmann, Valeriu Mereacre, Frederik Klöwer, Ian J. Hewitt, Christopher E. Anson, Hans U. Güdel, and Annie K. Powell
pp 756 - 766; DOI:
10.1021/ic061650s
PDF
Antimony-121 Mössbauer Spectral Study of -Zn4Sb3
Raphaël P. Hermann, Fernande Grandjean, Tsi-Chi Chen, Dennis E. Brown, C. E. Johnson, G. Jeffrey Snyder, and Gary J. Long
pp 767 - 770; DOI:
10.1021/ic061533x
PDF
New Stannide ScAgSn: Determination of the Superstructure via Two-Dimensional 45Sc Solid State NMR
C. Peter Sebastian, Long Zhang, Constanze Fehse, Rolf-Dieter Hoffmann, Hellmut Eckert, and Rainer Pöttgen
pp 771 - 779; DOI:
10.1021/ic061691o
PDF
Unusual Polybrominated Polypyrazolylborates and Their Copper(I) Complexes: Synthesis, Characterization, and Catalytic Activity
Glen P. A. Yap, Fernando Jove, Juan Urbano, Eleuterio Alvarez, Swiatoslaw Trofimenko, M. Mar Díaz-Requejo, and Pedro J. Pérez
pp 780 - 787; DOI:
10.1021/ic061714z
PDF
Ni1-xPtx (x = 0-0.12) Hollow Spheres as Catalysts for Hydrogen Generation from Ammonia Borane
Fangyi Cheng, Hua Ma, Yueming Li, and Jun Chen
pp 788 - 794; DOI:
10.1021/ic061712e
PDF
New In Situ Cleavage of Both S-S and S-C(sp2) Bonds and Rearrangement Reactions toward the Construction of Copper(I) Cluster-Based Coordination Networks
Jing Wang, Shao-Liang Zheng, Sheng Hu, Yue-Hua Zhang, and Ming-Liang Tong
pp 795 - 800; DOI:
10.1021/ic0616028
PDF
Single-Crystal Growth and Characterization of Disilver(I) Monofluorophosphate(V), Ag2PO3F: Crystal Structure, Thermal Behavior, Vibrational Spectroscopy, and Solid-State 19F, 31P, and 109Ag MAS NMR Spectroscopy
Matthias Weil, Michael Puchberger, Ekkehard Füglein, Enrique J. Baran, Julia Vannahme, Hans J. Jakobsen, and Jrgen Skibsted
pp 801 - 808; DOI:
10.1021/ic061765w
PDF
Ruthenium(II) Complexes Containing Bis(2-(diphenylphosphino)phenyl) Ether and Their Catalytic Activity in Hydrogenation Reactions
Ramalingam Venkateswaran, Joel T. Mague, and Maravanji S. Balakrishna
pp 809 - 817; DOI:
10.1021/ic061782l
PDF
Coordination of Biologically Important -Amino Acids to Calcium(II) at High pH: Insights from Crystal Structures of Calcium -Aminocarboxylates
Stefan Fox, Insa Büsching, Walter Barklage, and Henry Strasdeit
pp 818 - 824; DOI:
10.1021/ic061838b
PDF
Electroactive Thiazole Derivatives Capped with Ferrocenyl Units Showing Charge-Transfer Transition and Selective Ion-Sensing Properties: A Combined Experimental and Theoretical Study
Antonio Caballero, Vega Lloveras, David Curiel, Alberto Tárraga, Arturo Espinosa, Rafaela García, José Vidal-Gancedo, Concepció Rovira, Klaus Wurst, Pedro Molina, and Jaume Veciana
pp 825 - 838; DOI:
10.1021/ic061803b
PDF
Spectroscopic and Redox Properties of Novel d6-Complexes Engineered from All Z-Ethenylthiophene-bipyridine Ligands
Abdelhalim Belbakra, Sébastien Goeb, Antoinette De Nicola, Raymond Ziessel, Cristiana Sabatini, Andrea Barbieri, and Francesco Barigelletti
pp 839 - 847; DOI:
10.1021/ic061825y
PDF
Di- and Tetranuclear Copper(I) Complexes Containing Phenylaminobis(phosphonite), PhN{P(OC6H4OMe-o)2}2, and Their Reactivity toward Bipyridyl Ligands
Chelladurai Ganesamoorthy, Maravanji S. Balakrishna, Paulose P. George, and Joel T. Mague
pp 848 - 858; DOI:
10.1021/ic061883j
PDF
Stacking Design of Inverse Perovskites: The Systems (Sr3-xBaxN)E, E = Bi, Sb
Frank Gäbler and Rainer Niewa
pp 859 - 865; DOI:
10.1021/ic061863h
PDF
Syntheses, Structures, and Electrochemical Properties of Platinum(II) Complexes Containing Di-tert-butylbipyridine and Crown Ether Annelated Dithiolate Ligands
Yong Ji, Rui Zhang, Yu-Jia Li, Yi-Zhi Li, Jing-Lin Zuo, and Xiao-Zeng You
pp 866 - 873; DOI:
10.1021/ic061882r
PDF
Diverse Polyanions Based on MnBi4 and MnSb4 Tetrahedra: Polymorphism, Structure, and Bonding in Ca21Mn4Bi18 and Ca21Mn4Sb18
Sheng-qing Xia and Svilen Bobev
pp 874 - 883; DOI:
10.1021/ic061958j
PDF
Structural, Spectral, Electric-Field-Induced Second Harmonic, and Theoretical Study of Ni(II), Cu(II), Zn(II), and VO(II) Complexes with [N2O2] Unsymmetrical Schiff Bases of S-Methylisothiosemicarbazide Derivatives
Julieta Gradinaru, Alessandra Forni, Vadim Druta, Francesca Tessore, Sandro Zecchin, Silvio Quici, and Nicolae Garbalau
pp 884 - 895; DOI:
10.1021/ic062035r
PDF
Synthesis, Reactivity, Spectroscopic Characterization, X-ray Structures, PGSE, and NOE NMR Studies of (5-C5Me5)-Rhodium and -Iridium Derivatives Containing Bis(pyrazolyl)alkane Ligands
Claudio Pettinari, Riccardo Pettinari, Fabio Marchetti, Alceo Macchioni, Daniele Zuccaccia, Brian W. Skelton, and Allan H. White
pp 896 - 906; DOI:
10.1021/ic061928g
PDF
Crystal Structure and Chemical Bonding of the High-Temperature Phase of AgN3
Carsten L. Schmidt, Robert Dinnebier, Ulrich Wedig, and Martin Jansen
pp 907 - 916; DOI:
10.1021/ic061963n
PDF
Cyanide-Promoted Demetalation of TrpyNiNCO: A Route to Sensitive Metallotripyrrins of CoII, FeII, and MnII
Martin Bröring, Serguei Prikhodovski, Carsten D. Brandt, Esther Cónsul Tejero, Silke Köhler, and Clemens Pietzonka
pp 917 - 925; DOI:
10.1021/ic062009t
PDF
N4H9Cu7S4: A Hydrazinium-Based Salt with a Layered Cu7S4- Framework
David B. Mitzi
pp 926 - 931; DOI:
10.1021/ic0621291
PDF
Heterocyclic-Based Nitrodicyanomethanide and Dinitrocyanomethanide Salts: A Family of New Energetic Ionic Liquids
Ruihu Wang, Haixiang Gao, Chengfeng Ye, Brendan Twamley, and Jean'ne M. Shreeve
pp 932 - 938; DOI:
10.1021/ic0619198
PDF
Synthesis, Characterization, and Biomimetic Chemistry of cis-Oxosulfidomolybdenum(VI) Complexes Stabilized by an Intramolecular Mo(O)=S···S Interaction
Les J. Laughlin, Aston A. Eagle, Graham N. George, Edward R. T. Tiekink, and Charles G. Young
pp 939 - 948; DOI:
10.1021/ic061213d
PDF
X-ray-Excited Optical Luminescence (XEOL) and X-ray Absorption Fine Structures (XAFS) Studies of Gold(I) Complexes with Diphosphine and Bipyridine Ligands
Pil-Sook G. Kim, Yongfeng Hu, Marie-C. Brandys, Tara J. Burchell, Richard J. Puddephatt, and Tsun K. Sham
pp 949 - 957; DOI:
10.1021/ic0609352
PDF
Ytterbium(II) Complex Bearing a Diaminobis(phenolate) Ligand: Synthesis, Structure, and One-Electron-Transfer and -Caprolactone Polymerization Reactions
Hui Zhou, Huadong Guo, Yingming Yao, Liying Zhou, Hongmei Sun, Hongting Sheng, Yong Zhang, and Qi Shen
pp 958 - 964; DOI:
10.1021/ic061805w
PDF
Redox Behavior of Phenyl-Terpyridine-Substituted Artificial Oligopeptides Cross-Linked by Co and Fe
Kristi Ohr, Rebekah L. McLaughlin, and Mary Elizabeth Williams
pp 965 - 974; DOI:
10.1021/ic0612101
PDF
Replacement of Chlorides with Dicarboxylate Ligands in Anticancer Active Ru(II)-DMSO Compounds: A New Strategy That Might Lead to Improved Activity
Ioannis Bratsos, Barbara Serli, Ennio Zangrando, Nikos Katsaros, and Enzo Alessio
pp 975 - 992; DOI:
10.1021/ic0613964
PDF
Synthesis of Zirconium, Hafnium, and Tantalum Complexes with Sterically Demanding Hydrazide Ligands
Jean-Sébastien M. Lehn, Saba Javed, and David M. Hoffman
pp 993 - 1000; DOI:
10.1021/ic061483w
PDF
Half-Sandwich Hydride Complexes of Ruthenium with Bidentate Phosphinoamine Ligands: Proton-Transfer Reactions to [(C5R5)RuH(L)] [R = H, Me; L = dippae, (R,R)-dippach]
Manuel Jiménez-Tenorio, M. Dolores Palacios, M. Carmen Puerta, and Pedro Valerga
pp 1001 - 1012; DOI:
10.1021/ic061745u
PDF
Deposition of CuInS2 Thin Films Using Copper- and Indium/Sulfide-Containing Precursors through a Two-Stage MOCVD Method
Seung Soo Lee, Kook Won Seo, Jong Pil Park, Sin Kyu Kim, and Il-Wun Shim
pp 1013 - 1017; DOI:
10.1021/ic061445c
PDF
Complexation of Pu(IV) with the Natural Siderophore Desferrioxamine B and the Redox Properties of Pu(IV)(siderophore) Complexes
Hakim Boukhalfa, Sean D. Reilly, and Mary. P. Neu
pp 1018 - 1026; DOI:
10.1021/ic061544q
PDF
Study of the Replacement of Weak Ligands on Square-Planar Organometallic Nickel(II) Complexes. Organo-Nickel Aquacomplexes
Juan A. Casares, Pablo Espinet, Jesús M. Martínez-Ilarduya, Jesús J. Mucientes, and Gorka Salas
pp 1027 - 1032; DOI:
10.1021/ic061933k
PDF

Issue 4


Assembling the Cage-Based Metal-Organic Network from a Cubic Metalloligand
Ai-Ling Cheng, Na Liu, Jian-Yong Zhang, and En-Qing Gao
pp 1034 - 1035; DOI:
10.1021/ic061943l
PDF
[Ni5Sb17]4- Transition-Metal Zintl Ion Complex: Crossing the Zintl Border in Molecular Intermetalloid Clusters
Melanie J. Moses, James C. Fettinger, and Bryan W. Eichhorn
pp 1036 - 1038; DOI:
10.1021/ic0616535
PDF
Reverse Photochromic Behavior of an Iron-Magnesium Complex
Minoru Kobayashi, Akito Takashima, Tomohiko Ishii, Hiroshi Naka, Masanobu Uchiyama,and, and Kentaro Yamaguchi
pp 1039 - 1041; DOI:
10.1021/ic0616986
PDF
Silver Iodobismuthates: Syntheses, Structures, Properties, and Theoretical Studies of [Bi2Ag2I102-]n and [Bi4Ag2I162-]n
Wen-Xiang Chai, Li-Ming Wu, Jun-Qian Li, and Ling Chen
pp 1042 - 1044; DOI:
10.1021/ic062091s
PDF
Synthesis and Reactivity of a Bis(disulfide)-Bridged RuMo3S4 Double-Cubane Cluster: A New Family of Nona- or Decanuclear Mixed-Metal Sulfide Clusters with Two RuMo3S4 Units
Izuru Takei, Koji Kobayashi, Keita Dohki, and Masanobu Hidai
pp 1045 - 1047; DOI:
10.1021/ic0621953
PDF
Room-Temperature Spin Crossover Observed for [(TPyA)FeII(DBQ2-)FeII(TPyA)]2+ [TPyA = Tris(2-pyridylmethyl)amine; DBQ2- = 2,5-Di-tert-butyl-3,6-dihydroxy-1,4-benzoquinonate]
Kil Sik Min, Antonio DiPasquale, Arnold L. Rheingold, and Joel S. Miller
pp 1048 - 1050; DOI:
10.1021/ic062400e
PDF
Double-Bridge Bonding of Aluminium and Hydrogen in the Crystal Structure of -AlH3
Volodymyr A. Yartys, Roman V. Denys, Jan Petter Maehlen, Christoph Frommen, Maximilian Fichtner, Boris M. Bulychev, and Hermann Emerich
pp 1051 - 1055; DOI:
10.1021/ic0617487
PDF
Synthesis, Structural Characterization, Catalytic Properties, and Theoretical Study of Compounds Containing an Al-O-M (M = Ti, Hf) Core
Prabhuodeyara M. Gurubasavaraj, Swadhin K. Mandal, Herbert W. Roesky, Rainer B. Oswald, Aritra Pal, and Mathias Noltemeyer
pp 1056 - 1061; DOI:
10.1021/ic060538r
PDF
Well-Defined Silica-Supported Rare-Earth Silylamides
Régis M. Gauvin, Laurent Delevoye, Rahma Ali Hassan, Jérôme Keldenich, and André Mortreux
pp 1062 - 1070; DOI:
10.1021/ic0610334
PDF
Synthesis and Elaboration of the Dinuclear Iron-Imide Cluster Core [Fe2(-NR)2]2+
Jeremiah S. Duncan, Michael J. Zdilla, and Sonny C. Lee
pp 1071 - 1080; DOI:
10.1021/ic061133+
PDF
Role of the Hydroxyl-Water Hydrogen-Bond Network in Structural Transitions and Selectivity toward Cesium in Cs0.38(D1.08H0.54)SiTi2O7·(D0.86H0.14)2O Crystalline Silicotitanate
Aaron J. Celestian, John B. Parise, Ronald I. Smith, Brian H. Toby, and Abraham Clearfield
pp 1081 - 1089; DOI:
10.1021/ic0611387
PDF
Neutron Diffraction and Theoretical DFT Studies of Two Dimensional Molecular-Based Magnet K2[Mn(H2O)2]3[Mo(CN)7]2·6H2O
Béatrice Gillon, Antoine Goujon, Stéphanie Willemin, Joulia Larionova, Cédric Desplanches, Eliseo Ruiz, Gilles André, John A. Stride, and Christian Guérin
pp 1090 - 1099; DOI:
10.1021/ic0611645
PDF
Molecular and Electronic Structure of Square-Planar Gold Complexes Containing Two 1,2-Di(4-tert-butylphenyl)ethylene-1,2-dithiolato Ligands: [Au(2L)2]1+/0/1-/2-. A Combined Experimental and Computational Study
Swarnalatha Kokatam, Kallol Ray, Joseph Pap, Eckhard Bill, William E. Geiger, Robert J. LeSuer, Philip H. Rieger, Thomas Weyhermüller, Frank Neese, and Karl Wieghardt
pp 1100 - 1111; DOI:
10.1021/ic061181u
PDF
Searching for Stable, Five-Coordinate Aquated Al(III) Species. Water Exchange Mechanism and Effect of pH
Hans Hanauer, Ralph Puchta, Timothy Clark, and Rudi van Eldik
pp 1112 - 1122; DOI:
10.1021/ic061284c
PDF
Iron-Molybdenum Charge-Transfer Hybrids Containing Organometallic and Inorganic Fragments Bridged by Aryldiazenido Ligands in a -6:1 Coordination Mode: Syntheses, Characterization, X-ray Structures, Electrochemistry, and Theoretical Investigation
Carolina Manzur, Lorena Millán, Mauricio Fuentealba, Jean-René Hamon, Loïc Toupet, Samia Kahlal, Jean-Yves Saillard, and David Carrillo
pp 1123 - 1134; DOI:
10.1021/ic0613098
PDF
In Situ Solvothermal Generation of 1,2,4-Triazolates and Related Compounds from Organonitrile and Hydrazine Hydrate: A Mechanism Study
Lin Cheng, Wei-Xiong Zhang, Bao-Hui Ye, Jian-Bin Lin, and Xiao-Ming Chen
pp 1135 - 1143; DOI:
10.1021/ic061303i
PDF
Syntheses, Luminescence Switching, and Electrochemical Studies of Photochromic Dithienyl-1,10-phenanthroline Zinc(II) Bis(thiolate) Complexes
Tung-Wan Ngan, Chi-Chiu Ko, Nianyong Zhu, and Vivian Wing-Wah Yam
pp 1144 - 1152; DOI:
10.1021/ic061359c
PDF
Theoretical Studies of [FeFe]-Hydrogenase: Infrared Fingerprints of the Dithiol-Bridging Ligand in the Active Site
Silviu Zilberman, Edward I. Stiefel, Morrel H. Cohen, and Roberto Car
pp 1153 - 1161; DOI:
10.1021/ic061432z
PDF
Syntheses and Unusual Segregated-Alternated Hybrid Stacking Structure of Hydrogen-Bonded Charge-Transfer Complexes Composed of Bis[2,3-pyridinedithiolate]metal Complexes
Sota Shibahara, Hiroshi Kitagawa, Yoshiki Ozawa, Koshiro Toriumi, Takashi Kubo, and Kazuhiro Nakasuji
pp 1162 - 1170; DOI:
10.1021/ic0615269
PDF
New Lanthanide Hybrid as Clustered Infinite Nanotunnel with 3D Ln-O-Ln Framework and (3,4)-Connected Net
You-gui Huang, Ben-lai Wu, Da-qiang Yuan, Yan-qing Xu, Fei-long Jiang, and Mao-chun Hong
pp 1171 - 1176; DOI:
10.1021/ic0615271
PDF
Determination of 77Se-77Se and 77Se-13C J-Coupling Parameters for the Clusters [Re5OsSe8(CN)6]3- and [Re4Os2Se8(CN)6]2-
Kannan Ramaswamy, Eric G. Tulsky, Jeffrey R. Long, Jeff L.-F. Kao, and Sophia E. Hayes
pp 1177 - 1186; DOI:
10.1021/ic061571g
PDF
Synthesis, Structural Characterization, and Biological Studies of Six- and Five-Coordinate Organotin(IV) Complexes with the Thioamides 2-Mercaptobenzothiazole, 5-Chloro-2-mercaptobenzothiazole, and 2-Mercaptobenzoxazole
Marianna N. Xanthopoulou, Sotiris K. Hadjikakou, Nick Hadjiliadis, Maciej Kubicki, Stavroula Skoulika, Thomas Bakas, Martin Baril, and Ian S. Butler
pp 1187 - 1195; DOI:
10.1021/ic061601f
PDF
Diastereoselective Oxidative Addition of Dihydrogen to IrI(CO)((R)-BINAP) and [Ir(CO)2((R)-BINAP)][SbF6]
Abdurrahman Ç. Atesin, Simon B. Duckett, Christine Flaschenriem, William W. Brennessel, and Richard Eisenberg
pp 1196 - 1204; DOI:
10.1021/ic061471a
PDF
Coordination Chemistry of H2 and N2 in Aqueous Solution. Reactivity and Mechanistic Studies Using trans-FeII(P2)2X2-Type Complexes (P2 = a Chelating, Water-Solubilizing Phosphine)
John D. Gilbertson, Nathaniel K. Szymczak, Justin L. Crossland, Warren K. Miller, David K. Lyon, Bruce M. Foxman, Joclyn Davis, and David R. Tyler
pp 1205 - 1214; DOI:
10.1021/ic061570o
PDF
Structures and Physical Properties of New Semiconducting Gold and Copper Polytellurides: Ba7Au2Te14 and Ba6.76Cu2.42Te14
Yanjie Cui, Abdeljalil Assoud, Jianxiao Xu, and Holger Kleinke
pp 1215 - 1221; DOI:
10.1021/ic061616d
PDF
Evidence for Strong Tantalum-to-Boron Dative Interactions in (silox)3Ta(BH3) and (silox)3Ta(2-B,Cl-BCl2Ph) (silox = tBu3SiO)1
Jeffrey B. Bonanno, Thomas P. Henry, Peter T. Wolczanski, Aaron W. Pierpont, and Thomas R. Cundari
pp 1222 - 1232; DOI:
10.1021/ic0616885
PDF
Rationally Designed Micropores within a Metal-Organic Framework for Selective Sorption of Gas Molecules
Banglin Chen, Shengqian Ma, Fatima Zapata, Frank R. Fronczek, Emil B. Lobkovsky, and Hong-Cai Zhou
pp 1233 - 1236; DOI:
10.1021/ic0616434
PDF
Tetrahydroxy-p-benzoquinone as a Source of Polydentate O-Donor Ligands. Synthesis, Crystal Structure, and Magnetic Properties of the [Cu(bpy)(dhmal)]2 Dimer and the Two-Dimensional [{SiW12O40}{Cu2(bpy)2(H2O)(ox)}2]·16H2O Inorganic-Metalorganic Hybrid
Santiago Reinoso, Pablo Vitoria, Leire San Felices, Ainara Montero, Luis Lezama, and Juan M. Gutiérrez-Zorrilla
pp 1237 - 1249; DOI:
10.1021/ic061671m
PDF
A New Series of Three-Dimensional Metal-Organic Framework, [M2(H2O)][C5N1H3(COO)2]3·2H2O, M = La, Pr, and Nd: Synthesis, Structure, and Properties
Partha Mahata and Srinivasan Natarajan
pp 1250 - 1258; DOI:
10.1021/ic0617644
PDF
Sulfur K-edge Spectroscopic Investigation of Second Coordination Sphere Effects in Oxomolybdenum-Thiolates: Relationship to Molybdenum-Cysteine Covalency and Electron Transfer in Sulfite Oxidase
Katrina Peariso, Matthew E. Helton, Eileen N. Duesler, Susan E. Shadle, and Martin L. Kirk
pp 1259 - 1267; DOI:
10.1021/ic061150z
PDF
Studies of Structural Effects on the Half-Wave Potentials of Mononuclear and Dinuclear Nickel(II) Diphosphine/Dithiolate Complexes
Kendra Redin, Aaron D. Wilson, Rachel Newell, M. Rakowski DuBois, and Daniel L. DuBois
pp 1268 - 1276; DOI:
10.1021/ic061740x
PDF
Novel Vanadium(IV) Oxyfluorides with 'Spin-Ladder'-Like Structures, and Their Relationship to (VO)2P2O7
David W. Aldous, Richard J. Goff, J. Paul Attfield, and Philip Lightfoot
pp 1277 - 1282; DOI:
10.1021/ic0617386
PDF
Copper(I)-Rhenate Hybrids: Syntheses, Structures, and Optical Properties
Haisheng Lin and Paul A. Maggard
pp 1283 - 1290; DOI:
10.1021/ic061767g
PDF
Interaction Mechanisms between Uranium(VI) and Rutile Titanium Dioxide: From Single Crystal to Powder
Johan Vandenborre, Romuald Drot, and Eric Simoni
pp 1291 - 1296; DOI:
10.1021/ic061783d
PDF
Heteronuclear Complexes of Macrocyclic Oxamide with Co-ligands: Syntheses, Crystal Structures, and Magnetic Properties
Li-Na Zhu, Na Xu, Wei Zhang, Dai-Zheng Liao, Kazuyoshi Yoshimura, Ko Mibu, Zong-Hui Jiang, Shi-Ping Yan, and Peng Cheng
pp 1297 - 1304; DOI:
10.1021/ic061792m
PDF
Intramolecular Chalcogen-Tin Interactions in (o-MeE-C6H4)CH2SnPh3-nCln (E = S, O; n = 0, 1, 2), Characterized by X-ray Diffraction and 119Sn Solution and Solid-State NMR
Teresita Munguia, Marcela López-Cardoso, Francisco Cervantes-Lee, and Keith H. Pannell
pp 1305 - 1314; DOI:
10.1021/ic061811s
PDF
Dinuclear Manganese Complexes Containing Chiral 1,4,7-Triazacyclononane-Derived Ligands and Their Catalytic Potential for the Oxidation of Olefins, Alkanes, and Alcohols
Vladimir B. Romakh, Bruno Therrien, Georg Süss-Fink, and Georgiy B. Shul'pin
pp 1315 - 1331; DOI:
10.1021/ic061950+
PDF
Mechanistic Studies on the Formation of Trifluoromethyl Sulfur Pentafluoride, SF5CF3-a Greenhouse Gas
William Carrier, Corey S. Jamieson, and Ralf I. Kaiser
pp 1332 - 1336; DOI:
10.1021/ic0618450
PDF
Two 3D Porous Lanthanide-Fumarate-Oxalate Frameworks Exhibiting Framework Dynamics and Luminescent Change upon Reversible De- and Rehydration
Wen-Hua Zhu, Zhe-Ming Wang, and Song Gao
pp 1337 - 1342; DOI:
10.1021/ic061833e
PDF
Controlled Binding of a L-Cysteinato Cobalt(III) Octahedron to a Cadmium(II) Center
Takashi Aridomi, Tatsuya Kawamoto, and Takumi Konno
pp 1343 - 1353; DOI:
10.1021/ic061868e
PDF
Synthesis and Characterization of High-Quality ZnS, ZnS:Mn2+, and ZnS:Mn2+/ZnS (Core/Shell) Luminescent Nanocrystals
Zewei Quan, Zhenling Wang, Piaoping Yang, Jun Lin, and Jiye Fang
pp 1354 - 1360; DOI:
10.1021/ic061917n
PDF
Amine-Amide Equilibrium in Gold(III) Complexes and a Gold(III)-Gold(I) Aurophilic Bond
Lingyun Cao, Michael C. Jennings, and Richard J. Puddephatt
pp 1361 - 1368; DOI:
10.1021/ic061911y
PDF
Synthesis of [F3SNXeF][AsF6] and Structural Study by Multi-NMR and Raman Spectroscopy, Electronic Structure Calculations, and X-ray Crystallography
Gregory L. Smith, Hélène P.A. Mercier, and Gary J. Schrobilgen
pp 1369 - 1378; DOI:
10.1021/ic061899+
PDF
Efficiency of the Refocused 31P-29Si MAS-J-INEPT NMR Experiment for the Characterization of Silicophosphate Crystalline Phases and Amorphous Gels
C. Coelho, T. Azaïs, L. Bonhomme-Coury, G. Laurent, and C. Bonhomme
pp 1379 - 1387; DOI:
10.1021/ic061964f
PDF
Enhancement of External Spin-Orbit Coupling Effects Caused by Metal-Metal Cooperativity
Charlotte N. Burress, Martha I. Bodine, Oussama Elbjeirami, Joseph H. Reibenspies, Mohammad A. Omary, and François P. Gabbaï
pp 1388 - 1395; DOI:
10.1021/ic061998n
PDF
Investigation into the Formation of Supramolecular Compounds from Mixed As/S-Ligand Complexes [(Cp*Mo)2As2S3] (Cp* = C5Me5) and Copper Halides
Michael Pronold, Manfred Scheer, Joachim Wachter, and Manfred Zabel
pp 1396 - 1400; DOI:
10.1021/ic062052g
PDF
Integrated Experimental-Theoretical Investigation of the Na-Li-Al-H System
Susanne M. Opalka, Ole M. Lvvik, Hendrik W. Brinks, Paul W. Saxe, and Bjrn C. Hauback
pp 1401 - 1409; DOI:
10.1021/ic062032e
PDF
Ta3AlC2 and Ta4AlC3 - Single-Crystal Investigations of Two New Ternary Carbides of Tantalum Synthesized by the Molten Metal Technique
Johannes Etzkorn, Martin Ade, and Harald Hillebrecht
pp 1410 - 1418; DOI:
10.1021/ic062231y
PDF
First Investigation at Elevated Pressures To Confirm the Exact Nature of the Gated Electron-Transfer Systems: Volume Profiles of the Gated Reduction Reaction and Nongated Reverse Oxidation Reaction Involving a [Cu(dmp)2(solvent)]2+/[Cu(dmp)2]+ Couple (dmp = 2,9-Dimethyl-1,10-phenanthroline)
Sumitaka Itoh, Kyoko Noda, Ryouhei Yamane, Nobuyuki Kishikawa, and Hideo D. Takagi
pp 1419 - 1425; DOI:
10.1021/ic061591i
PDF
One-Step Redox Route to N-Heterocyclic Phosphenium Ions
Gregor Reeske and Alan H. Cowley
pp 1426 - 1430; DOI:
10.1021/ic061956z
PDF
Synthesis of Nitrosylruthenium Complexes Containing 2,2':6',2' '-Terpyridine by Reactions of Alkoxo Complexes with Acids
Hirotaka Nagao, Keiji Enomoto, Yuuki Wakabayashi, Gen Komiya, Toshiyuki Hirano, and Takao Oi
pp 1431 - 1439; DOI:
10.1021/ic061644w
PDF
Synthetic and X-ray Structural and Reactivity Studies of Cp*RuIV Complexes Containing Bidentate Dithiocarbonate, Xanthate, Carbonate, and Phosphinate Ligands (Cp* = 5-C5Me5)
Elaine Phuay Leng Tay, Seah Ling Kuan, Weng Kee Leong, and Lai Yoong Goh
pp 1440 - 1450; DOI:
10.1021/ic061781t
PDF
Oxidation of Ferrocenes by Copper(II) in Aqueous Acetonitrile: Nitrate and Chloride Ion Effects
Japhet Irangu and Robert B. Jordan
pp 1451 - 1458; DOI:
10.1021/ic0618551
PDF
Crystal Structure, Electronic Structure, and Physical Properties of Ti1-Mo1+As4 and Ti1-Mo1+Sb4
Shahab Derakhshan, Abdeljalil Assoud, Katja M. Kleinke, and Holger Kleinke
pp 1459 - 1463; DOI:
10.1021/ic0619254
PDF
Protonation and Methylation of an Anderson-Type Polyoxoanion [IMo6O24]5-
Daisuke Honda, Shusaku Ikegami, Tomoaki Inoue, Tomoji Ozeki, and Atsushi Yagasaki
pp 1464 - 1470; DOI:
10.1021/ic061881z
PDF
Influence of the Chelate Ligand Structure on the Amide Methanolysis Reactivity of Mononuclear Zinc Complexes
Gajendrasingh K. Ingle, Magdalena M. Makowska-Grzyska, Ewa Szajna-Fuller, Indranil Sen, John C. Price, Atta M. Arif, and Lisa M. Berreau
pp 1471 - 1480; DOI:
10.1021/ic062020t
PDF
Tripodal Amido Boron and Aluminum Complexes
Hongping Zhu and Eugene Y.-X. Chen
pp 1481 - 1487; DOI:
10.1021/ic0620889
PDF
Structure and Bonding of Vanadium(V) Complexes with Hydroxyurea in Aqueous Solution: Density Functional Theory Investigations of Isomers and Intramolecular Rearrangements
Ivana Vinkovi Vrek, Mladen Biru, and Michael Bühl
pp 1488 - 1501; DOI:
10.1021/ic061699y
PDF
Syntheses and X-ray Diffraction, Photochemical, and Optical Characterization of Cu2SixSn1-xS3 (0.4 x 0.6) for Photovoltaic Applications
A. Lafond, J. A. Cody, M. Souilah, C. Guillot-Deudon, R. Kiebach, and W. Bensch
pp 1502 - 1506; DOI:
10.1021/ic0621087
PDF
Lanthanide Triple-Stranded Helicates: Controlling the Yield of the Heterobimetallic Species
Thomas B. Jensen, Rosario Scopelliti, and Jean-Claude G.Bünzli:
pp 1507 - 1507; DOI:
10.1021/ic062289c
PDF
Phenylazo-pyridine and Phenylazo-pyrazole chlorido Ruthenium(II) Arene Complexes: Arene Loss, Aquation, and Cancer Cell Cytotoxicity
Sarah J. Dougan, Michael Melchart, Abraha Habtemariam, Simon Parsons, and Peter J. Sadler:
pp 1508 - 1508; DOI:
10.1021/ic070028c
PDF

Issue 5


A Salute to the Founding Editor, Robert W. Parry (1917-2006)
Richard Eisenberg
pp 1509 - 1510; DOI:
10.1021/ic070021v
PDF
Homochiral Coordination Polymer with Infinite Double-Stranded Helices
Lei Han, Henry Valle, and Xianhui Bu
pp 1511 - 1513; DOI:
10.1021/ic062015p
PDF
Do Sitting-Atop Metalloporphyrin Complexes Exist? Observation of N-H- - - Bonding in Arene Solvates of a Diprotonated Porphyrin Dication
J. Luis Gárate-Morales, Fook S. Tham, and Christopher A. Reed
pp 1514 - 1516; DOI:
10.1021/ic062213g
PDF
Photochemical Production of a Highly Reactive Porphyrin-Iron-Oxo Species
Zhengzheng Pan, Rui Zhang, Leslie W.-M. Fung, and Martin Newcomb
pp 1517 - 1519; DOI:
10.1021/ic061972w
PDF
An Unusual 1D Manganese Azido Complex with Novel EO/EO/EO/EE Coordination Mode: Synthesis, Structure, and Magnetic Properties
Fu-Chen Liu, Yong-Fei Zeng, Jiong-Peng Zhao, Bo-Wen Hu, Xian-He Bu, Joan Ribas, and Joan Cano
pp 1520 - 1522; DOI:
10.1021/ic061892s
PDF
Lead Rare-Earth Oxyhalides: Syntheses and Characterization of Pb6LaO7X (X = Cl, Br)
Oleg I. Siidra, Sergey V. Krivovichev, Thomas Armbruster, and Wulf Depmeier
pp 1523 - 1525; DOI:
10.1021/ic062191y
PDF
Low-Temperature Spectral Observation of the First Six-Coordinate Nitrosyl Complexes of Cobalt(II) meso-Tetratolylporphyrin with Trans Nitrogen Base Ligands
Tigran S. Kurtikyan, Emil R. Markaryan, Artur N. Mardyukov, and John A. Goodwin
pp 1526 - 1528; DOI:
10.1021/ic062070y
PDF
Cyanide-Bridged WV-CoII Double-Zigzag Chain Based on an Octacoordinated W Precursor: Metamagnetism and Spin Canting
Jung Hee Yoon, Jeong Hak Lim, Seok Woo Choi, Hyoung Chan Kim, and Chang Seop Hong
pp 1529 - 1531; DOI:
10.1021/ic062143d
PDF
Deliberate Design of a 3D Homochiral CuII/L-met/AgI Coordination Network Based on the Distinct Soft-Hard Recognition Principle
Tzuoo-Tsair Luo, Liang-Yu Hsu, Chan-Cheng Su, Chuen-Her Ueng, Tseng-Chang Tsai, and Kuang-Lieh Lu
pp 1532 - 1534; DOI:
10.1021/ic062132k
PDF
Resolution of Enantiomers in Solution and Determination of the Chirality of Extended Metal Atom Chains
Daniel W. Armstrong, F. Albert Cotton, Ana G. Petrovic, Prasad L. Polavarapu, and Molly M. Warnke
pp 1535 - 1537; DOI:
10.1021/ic062263l
PDF
Highly Sensitive Fluorescent Probe for Selective Detection of Hg2+ in DMF Aqueous Media
Dayu Wu, Wei Huang, Chunying Duan, Zhihua Lin, and Qingjin Meng
pp 1538 - 1540; DOI:
10.1021/ic062274e
PDF
Synthesis of a Selenidostannate(IV), [Mn(tepa)·Sn3Se7]n, Demonstrating the Transformation from Achiral to Chiral and Dimeric to Polymeric Structure
Jian Zhou, Guo-Qing Bian, Jie Dai, Yong Zhang, Ai-bin Tang, and Qin-Yu Zhu
pp 1541 - 1543; DOI:
10.1021/ic062403r
PDF
Magnetic Properties of a Manganese(II) Trinuclear Complex Involving a Tridentate Schiff-Base Ligand
Radovan Herchel, Roman Boa, Milan Gembick, Karsten Falk, Hartmut Fuess, Wolfgang Haase, and Ingrid Svoboda
pp 1544 - 1546; DOI:
10.1021/ic061717b
PDF
Electronic Structure of Ferric Heme Nitrosyl Complexes with Thiolate Coordination
Florian Paulat and Nicolai Lehnert
pp 1547 - 1549; DOI:
10.1021/ic070023f
PDF
Structural Characterization and Reactivity of UO2(salophen)L and [UO2(salophen)]2: Dimerization of UO2(salophen) Fragments in Noncoordinating Solvents (salophen = N,N'-Disalicylidene-o-phenylenediaminate, L = N,N-Dimethylformamide, Dimethyl Sulfoxide)
Koichiro Takao and Yasuhisa Ikeda
pp 1550 - 1562; DOI:
10.1021/ic0611950
PDF
A Series of New Organic-Inorganic Molybdenum Arsenate Complexes Based on [(ZnO6)(As3O3)2Mo6O18]4- and [HxAs2Mo6O26](6-x)- Clusters as SBUs
Chunyan Sun, Yangguang Li, Enbo Wang, Dongrong Xiao, Haiyan An, and Lin Xu
pp 1563 - 1574; DOI:
10.1021/ic061227j
PDF
Structural and Spectroscopic Evidence for the Formation of Trinuclear and Tetranuclear Vanadium(III)/Carboxylate Complexes of Acetate and Related Derivatives in Aqueous Solution
Riya Mukherjee, Brenda A. Dougan, Fiona H. Fry, Scott D. Bunge, Christopher J. Ziegler, and Nicola E. Brasch
pp 1575 - 1585; DOI:
10.1021/ic0613210
PDF
Synthesis, Redox, and Magnetic Properties of a Neutral, Mixed-Valent Heptanuclear Manganese Wheel with S = 27/2 High-Spin Ground State
Rolf W. Saalfrank, Andreas Scheurer, Raju Prakash, Frank W. Heinemann, Takayuki Nakajima, Frank Hampel, Roland Leppin, Bernd Pilawa, Holger Rupp, and Paul Müller
pp 1586 - 1592; DOI:
10.1021/ic0614059
PDF
Three Guest-Including Coordination Solids from a Single Crystallization: A Discrete Cage and Open-Channel Networks from 1-D Ladders and 1-D Ribbons
Amir H. Mahmoudkhani and George K. H. Shimizu
pp 1593 - 1602; DOI:
10.1021/ic0615123
PDF
Blue Phosphorescence from Mixed Cyano-Isocyanide Cyclometalated Iridium(III) Complexes
Kenneth Dedeian, Jianmin Shi, Eric Forsythe, David C. Morton, and Peter Y. Zavalij
pp 1603 - 1611; DOI:
10.1021/ic061513v
PDF
CO2 Template Synthesis of Metal Formates with a ReO3 Net
Yun-Qi Tian, Yu-Ming Zhao, Hai-Jun Xu, and Cheng-Yu Chi
pp 1612 - 1616; DOI:
10.1021/ic0617240
PDF
Synthesis, Structure, and Redox Properties of N-Confused Bis(porphyrinatonickel(II)) Linked by o-Xylene
Piotr J. Chmielewski
pp 1617 - 1626; DOI:
10.1021/ic061793e
PDF
First-Row Transition-Metal Complexes Based on a Carboxylate Polychlorotriphenylmethyl Radical: Trends in Metal-Radical Exchange Interactions
Daniel Maspoch, Neus Domingo, Daniel Ruiz-Molina, Klaus Wurst, Joan Manel Hernández, Francesc Lloret, Javier Tejada, Concepció Rovira, and Jaume Veciana
pp 1627 - 1633; DOI:
10.1021/ic061815x
PDF
Structural Invariance in Silver(I) Coordination Networks Formed Using Flexible Four-Armed Thiopyridine Ligands
David B. Cordes and Lyall R. Hanton
pp 1634 - 1644; DOI:
10.1021/ic061867m
PDF
Characterization of Co-C Bonding in Dichlorovinylcobaloxime Complexes
Angela D. Follett, Katherine A. McNabb, Alicia A. Peterson, Joseph D. Scanlon, Christopher J. Cramer, and Kristopher McNeill
pp 1645 - 1654; DOI:
10.1021/ic0618293
PDF
Chelate Control of Diiron(I) Dithiolates Relevant to the [Fe-Fe]- Hydrogenase Active Site
Aaron K. Justice, Giuseppe Zampella, Luca De Gioia, Thomas B. Rauchfuss, Jarl Ivar van der Vlugt, and Scott R. Wilson
pp 1655 - 1664; DOI:
10.1021/ic0618706
PDF
Recognition of Thymine and Related Nucleosides by a ZnII-Cyclen Complex Bearing a Ferrocenyl Pendant
Gilles Gasser, Matthew J. Belousoff, Alan M. Bond, Zuzanna Kosowski, and Leone Spiccia
pp 1665 - 1674; DOI:
10.1021/ic061902p
PDF
Diazene Dehydrogenation Follows H2 Addition to Coordinated Dinitrogen in an ansa-Zirconocene Complex
Tamara E. Hanna, Ivan Keresztes, Emil Lobkovsky, and Paul J. Chirik
pp 1675 - 1683; DOI:
10.1021/ic0620539
PDF
PtII-Mediated Nitrile-Tetramethylguanidine Coupling as a Key Step for a Novel Synthesis of 1,6-Dihydro-1,3,5-triazines
Pavel V. Gushchin, Nadezhda A. Bokach, Konstantin V. Luzyanin, Alexey A. Nazarov, Matti Haukka, and Vadim Yu. Kukushkin
pp 1684 - 1693; DOI:
10.1021/ic061884b
PDF
Triferrocenes Built on a C3-Symmetric Ligand Platform: Entry to Redox-Active pseudo-Triphenylenes via Chelation-Driven Stereoselection of Triple Schiff Bases
Young-Kwan Lim, Scott Wallace, John C. Bollinger, Xufang Chen, and Dongwhan Lee
pp 1694 - 1703; DOI:
10.1021/ic062029v
PDF
The Ag2O-V2O5-HF(aq) System and Crystal Structure of -Ag3VO4
Thomas A. Albrecht, Charlotte L. Stern, and Kenneth R. Poeppelmeier
pp 1704 - 1708; DOI:
10.1021/ic062138+
PDF
Fe(II) Mononuclear Complexes with a New Aminopyridyl Ligand Bearing a Pivaloylamido Arm. Preparation and Spectroscopic Characterizations of a FeIII-Hydroperoxo Complex with Oxygen and Nitrogen Donors
Marlène Martinho, Frédéric Banse, Joëlle Sainton, Christian Philouze, Régis Guillot, Guillaume Blain, Pierre Dorlet, Sophie Lecomte, and Jean-Jacques Girerd
pp 1709 - 1717; DOI:
10.1021/ic0623415
PDF
Better Understanding of the Species with the Shortest Re26+ Bonds and Related Re27+ Species with Tetraguanidinate Paddlewheel Structures
F. Albert Cotton, Naresh S. Dalal, Penglin Huang, Sergey A. Ibragimov, Carlos A. Murillo, Paula M. B. Piccoli, Chris M. Ramsey, Arthur J. Schultz, Xiaoping Wang, and Qinliang Zhao
pp 1718 - 1726; DOI:
10.1021/ic062319b
PDF
Mechanism of [-H2SiV2W10O40]4--Catalyzed Epoxidation of Alkenes with Hydrogen Peroxide
Yoshinao Nakagawa and Noritaka Mizuno
pp 1727 - 1736; DOI:
10.1021/ic0623258
PDF
New Lanthanide-Containing Polytungstates Derived from the Cyclic P8W48 Anion: {Ln4(H2O)28[KP8W48O184(H4W4O12)2Ln2(H2O)10]13-}x, Ln = La, Ce, Pr, Nd
Matthias Zimmermann, Nebebech Belai, Raymond J. Butcher, Michael T. Pope, Elena V. Chubarova, Michael H. Dickman, and Ulrich Kortz
pp 1737 - 1740; DOI:
10.1021/ic0624423
PDF
Steps along the Path to Dihydrogen Activation at [FeFe] Hydrogenase Structural Models: Dependence of the Core Geometry on Electrocatalytic Proton Reduction
Mun Hon Cheah, Stacey J. Borg, and Stephen P. Best
pp 1741 - 1750; DOI:
10.1021/ic0623361
PDF
Synthesis and Characterization of Copper(II) Complexes of Nonfacially Coordinating Heteroscorpionate Ligands (4-Carboxyphenyl)bis(3,5-dimethylpyrazolyl)methane and (3-Carboxyphenyl)bis(3,5-dimethylpyrazolyl)methane
Guillermo A. Santillan and Carl J. Carrano
pp 1751 - 1759; DOI:
10.1021/ic062226u
PDF
Lithium, Titanium, and Zirconium Complexes with Novel Amidinate Scorpionate Ligands
Antonio Otero, Juan Fernández-Baeza, Antonio Antiñolo, Juan Tejeda, Agustín Lara-Sánchez, Luis F. Sánchez-Barba, Isabel López-Solera, and Ana M. Rodríguez
pp 1760 - 1770; DOI:
10.1021/ic062093c
PDF
Computational Studies of Structures and Properties of Metallaboranes. Part 3: Protonated Iron Bis(dicarbollide), [3-Fe-(1,2-C2B9H11)2H]-
Michael Bühl, Drahomír Hnyk, and Jan Macháek
pp 1771 - 1777; DOI:
10.1021/ic062096p
PDF
A Reductionist Biomimetic Model System That Demonstrates Highly Effective Zn(II)-Catalyzed Cleavage of an RNA Model
C. Tony Liu, Alexei A. Neverov, and R. Stan Brown
pp 1778 - 1788; DOI:
10.1021/ic062065u
PDF
Photoinduced Spin Transition for Iron(II) Compounds with Liquid-Crystal Properties
Shinya Hayami, Natsuko Motokawa, Aya Shuto, Naoji Masuhara, Takehiro Someya, Yoshihiro Ogawa, Katsuya Inoue, and Yonezo Maeda
pp 1789 - 1794; DOI:
10.1021/ic061646g
PDF
Nucleophilic Attack toward Group 4 Metal Complexes Bearing Reactive 1-Aza-1,3-butadienyl and Imido Moieties
Hirofumi Hamaki, Nobuhiro Takeda, and Norihiro Tokitoh
pp 1795 - 1802; DOI:
10.1021/ic0620844
PDF
Binuclear Vanadium Carbonyls: The Limits of the 18-Electron Rule
Zhaohui Liu, Qian-shu Li, Yaoming Xie, R. Bruce King, and Henry F. Schaefer III
pp 1803 - 1816; DOI:
10.1021/ic061499m
PDF
Cobaloximes as Functional Models for Hydrogenases. 2. Proton Electroreduction Catalyzed by Difluoroborylbis(dimethylglyoximato)cobalt(II) Complexes in Organic Media
Carole Baffert, Vincent Artero, and Marc Fontecave
pp 1817 - 1824; DOI:
10.1021/ic061625m
PDF
Controlled Synthesis of a Structurally Characterized Family of Sterically Constrained Heterocyclic Alkoxy-Modified Titanium Alkoxides
Timothy J. Boyle, Robin M. Sewell, Leigh Anna M. Ottley, Harry D. Pratt III, Christopher J. Quintana, and Scott D. Bunge
pp 1825 - 1835; DOI:
10.1021/ic0618798
PDF
Chromium Carbonyl Nitrosyls: Comparison with Isoelectronic Manganese Carbonyl Derivatives
Hongyan Wang, Yaoming Xie, Jun D. Zhang, R. Bruce King, and Henry F. Schaefer III
pp 1836 - 1846; DOI:
10.1021/ic0620541
PDF
Continuous-Wave and Pulse EPR Study of the Copper(II) Complex of N-Confused Tetraphenylporphyrin: Direct Observation of a Metal-Carbon Bond
Carlos Calle, Arthur Schweiger, and George Mitrikas
pp 1847 - 1855; DOI:
10.1021/ic0621852
PDF
Synthesis and Solid-State Structures of Pyrazolylmethane Complexes of the Rare Earths
Andrea Sella, Sarah E. Brown, Jonathan W. Steed, and Derek A. Tocher
pp 1856 - 1864; DOI:
10.1021/ic062370f
PDF

Issue 6


Mizoroki-Heck Coupling Using Immobilized Molecular Precatalysts: Leaching Active Species from Pd Pincers, Entrapped Pd Salts, and Pd NHC Complexes
Marcus Weck and Christopher W. Jones
pp 1865 - 1875; DOI:
10.1021/ic061898h
PDF
Genesis of Coordinatively Unsaturated Palladium Complexes Dissolved from Solid Precursors during Heck Coupling Reactions and Their Role as Catalytically Active Species
Klaus Köhler, Wolfgang Kleist, and Sandra S. Pröckl
pp 1876 - 1883; DOI:
10.1021/ic061907m
PDF
Palladium Nanoparticles as Efficient Green Homogeneous and Heterogeneous Carbon-Carbon Coupling Precatalysts: A Unifying View
Didier Astruc
pp 1884 - 1894; DOI:
10.1021/ic062183h
PDF
Homogeneous Nanosize Palladium Catalysts
Yasushi Tsuji and Tetsuaki Fujihara
pp 1895 - 1902; DOI:
10.1021/ic061872q
PDF
Recent Progress in Wacker Oxidations: Moving toward Molecular Oxygen as the Sole Oxidant
Candace N. Cornell and Matthew S. Sigman
pp 1903 - 1909; DOI:
10.1021/ic061858d
PDF
Palladium-Catalyzed Aerobic Oxidative Amination of Alkenes: Development of Intra- and Intermolecular Aza-Wacker Reactions
Vasily Kotov, Christopher C. Scarborough, and Shannon S. Stahl
pp 1910 - 1923; DOI:
10.1021/ic061997v
PDF
Reactions of Hypervalent Iodine Reagents with Palladium: Mechanisms and Applications in Organic Synthesis
Nicholas R. Deprez and Melanie S. Sanford
pp 1924 - 1935; DOI:
10.1021/ic0620337
PDF
Electronic Effects on Reductive Elimination To Form Carbon-Carbon and Carbon-Heteroatom Bonds from Palladium(II) Complexes
John F. Hartwig
pp 1936 - 1947; DOI:
10.1021/ic061926w
PDF
An Anomalous Spin-Polarization Mechanism in High-Spin Manganese(III) Porphyrin Complexes
Ru-Jen Cheng, Shu-Hao Chang, and Kuo-Cheng Hung
pp 1948 - 1950; DOI:
10.1021/ic0617238
PDF
Reactivity of MnII with Superoxide. Evidence for a [MnIIIOO]+ Unit by Low-Temperature Spectroscopies
Sihem Groni, Guillaume Blain, Régis Guillot, Clotilde Policar, and Elodie Anxolabéhère-Mallart
pp 1951 - 1953; DOI:
10.1021/ic062063+
PDF
Assessing the Slow Magnetic Relaxation Behavior of LnIII4MnIII6 Metallacrowns
Curtis M. Zaleski, Jeff W. Kampf, Talal Mallah, Martin L. Kirk, and Vincent L. Pecoraro
pp 1954 - 1956; DOI:
10.1021/ic0621648
PDF
On the Origin of a Band Gap in Compounds of Diamond-like Structures
Jürgen Köhler, Shuiquan Deng, Changhoon Lee, and Myung-Hwan Whangbo
pp 1957 - 1959; DOI:
10.1021/ic062256x
PDF
Structural Variations of Silver Ethylene Complexes Supported by Boron-Protected Fluorinated Scorpionates and the Isolation of a Ligand-Directed Silver Helix
H. V. Rasika Dias, Jiang Wu, Xiaoyu Wang, and Krishnan Rangan
pp 1960 - 1962; DOI:
10.1021/ic062293o
PDF
Synthesis and Characterization of a Novel Cobalt Carbonyl N-Heterocyclic Carbene Salt. Crystal Structure of [Co(CO)3(IMes)2]+[Co(CO)4]-
Hendrik van Rensburg, Robert P. Tooze, Douglas F. Foster, and Stefanus Otto
pp 1963 - 1965; DOI:
10.1021/ic062368o
PDF
Localization or Delocalization in the Electronic Structure of Creutz-Taube-Type Complexes in Aqueous Solution
Daisuke Yokogawa, Hirofumi Sato, Yoshihide Nakao, and Shigeyoshi Sakaki
pp 1966 - 1974; DOI:
10.1021/ic060173a
PDF
Cd, Hg, and Pb Compounds of Benzene-1,3-diamidoethanethiol (BDETH2)
K. M. Zaman, Lisa Y. Blue, F. E. Huggins, and D. A. Atwood
pp 1975 - 1980; DOI:
10.1021/ic0607639
PDF
Binuclear Iron-Sulfur Complexes with Bidentate Phosphine Ligands as Active Site Models of Fe-Hydrogenase and Their Catalytic Proton Reduction
Weiming Gao, Jesper Ekström, Jianhui Liu, Changneng Chen, Lars Eriksson, Linhong Weng, Björn Åkermark, and Licheng Sun
pp 1981 - 1991; DOI:
10.1021/ic0610278
PDF
Photophysical Properties of Highly Luminescent Copper(I) Halide Complexes Chelated with 1,2-Bis(diphenylphosphino)benzene
Akira Tsuboyama, Katsuaki Kuge, Manabu Furugori, Shinjiro Okada, Mikio Hoshino, and Kazunori Ueno
pp 1992 - 2001; DOI:
10.1021/ic0608086
PDF
Tuned Triazolatesilver(I) Luminescent Complexes from Zero- to Three-Dimensionality Based on Bi- to Tetratopic Bridged Ligands
Ying Wang, Bin Ding, Peng Cheng, Dai-Zheng Liao, and Shi-Ping Yan
pp 2002 - 2010; DOI:
10.1021/ic060855y
PDF
The Origin of Endocyclic Bond Length Variations in Disubstituted Cyclotriphosphazenes
Michael Calichman, Agnes Derecskei-Kovacs, and Christopher W. Allen
pp 2011 - 2016; DOI:
10.1021/ic060999c
PDF
Synthesis of a Family of Solids through the Building-Block Approach: A Case Study with Ag+ Substitution in the Ternary Na-Ge-Se System
Amitava Choudhury, Sabine Strobel, Benjamin R. Martin, Angela L. Karst, and Peter K. Dorhout
pp 2017 - 2027; DOI:
10.1021/ic061064z
PDF
Theoretical Studies of the [2 + 4] Diels-Alder Cycloaddition Reactions of Alkene Analogues of the Group 13 Elements with Toluene
Sing-Yi Gu, Jeng-Horng Sheu, and Ming-Der Su
pp 2028 - 2034; DOI:
10.1021/ic061100u
PDF
Genuine Examples of Tetrahedral Tetradentate Sulfide Ligand Bridging Four Pd Atoms: Controlled Formation of [(4-S){(2-X)Pd2(CN)2}2] (X = OH or Cl; HCN = p-C2H5OC6H4CH=NC6H4-p-C2H5) Complexes
Rut Benavente, Pablo Espinet, José M. Martín-Álvarez, Jesús A. Miguel, and Gabriel Aullón
pp 2035 - 2040; DOI:
10.1021/ic061367t
PDF
Assignment of the Ferriheme Resonances of the Low-Spin Complexes of Nitrophorins 1 and 4 by 1H and 13C NMR Spectroscopy: Comparison to Structural Data Obtained from X-ray Crystallography
Tatiana Kh. Shokhireva, Andrzej Weichsel, Kevin M. Smith, Robert E. Berry, Nikolai V. Shokhirev, Celia A. Balfour, Hongjun Zhang, William R. Montfort, and F. Ann Walker
pp 2041 - 2056; DOI:
10.1021/ic061408l
PDF
Second-Sphere Ligand-Field Effects in Solid Solutions of Anhydrous Transition-Metal Phosphates
H. Thauern and R. Glaum
pp 2057 - 2066; DOI:
10.1021/ic061481b
PDF
Experimental and Theoretical Methods to Investigate Extraframework Species in a Layered Material of Dodecaniobate Anions
May Nyman, James P. Larentzos, Edward J. Maginn, Margaret E. Welk, David Ingersoll, Hyunsoo Park, John B. Parise, Ivor Bull, and François Bonhomme
pp 2067 - 2079; DOI:
10.1021/ic061454l
PDF
Effects of Benzoannulation and -Octabutoxy Substitution on the Photophysical Behavior of Nickel Phthalocyanines: A Combined Experimental and DFT/TDDFT Study
Alexandra V. Soldatova, Junhwan Kim, Xinzhang Peng, Angela Rosa, Giampaolo Ricciardi, Malcolm E. Kenney, and Michael A. J. Rodgers
pp 2080 - 2093; DOI:
10.1021/ic061524o
PDF
Possible Biotransformation Reactions of Polynuclear Pt(II) Complexes
Nadine Summa, Joachim Maigut, Ralph Puchta, and Rudi van Eldik
pp 2094 - 2104; DOI:
10.1021/ic061990d
PDF
Self-Assembly and Characterization of Cyano-Bridged Bimetallic [Ln-Fe] and [Ln-Co] Complexes (Ln = La, Pr, Nd and Sm). Nature of the Magnetic Interactions between the Ln3+ and Fe3+ Ions
Wen-Tong Chen, Guo-Cong Guo, Ming-Sheng Wang, Gang Xu, Li-Zhen Cai, Takashiro Akitsu, Motoko Akita-Tanaka, Akiyuki Matsushita, and Jin-Shun Huang
pp 2105 - 2114; DOI:
10.1021/ic061609p
PDF
Triangular Oxalate Clusters [W3(3-S)(2-S2)3(C2O4)3]2- as Building Blocks for Coordination Polymers and Nanosized Complexes
Maxim N. Sokolov, Artem L. Gushchin, Konstantin A. Kovalenko, Eugenia V. Peresypkina, Alexander V. Virovets, Joaquin Sanchiz, and Vladimir P. Fedin
pp 2115 - 2123; DOI:
10.1021/ic061540l
PDF
Nanoblock Coupling Effect in Iodine Intercalated [Bi0.82CaO2]2[CoO2]1.69 Layered Cobaltite
E. Guilmeau, M. Pollet, D. Grebille, M. Hervieu, H. Muguerra, R. Cloots, M. Mikami, and R. Funahashi
pp 2124 - 2131; DOI:
10.1021/ic0616378
PDF
Ln14Na3Ru6O36 (Ln = Pr, Nd): Two New Complex Lanthanide-Containing Oxides of Ruthenium
William R. Gemmill, Mark D. Smith, and Hans-Conrad zur Loye
pp 2132 - 2138; DOI:
10.1021/ic0617083
PDF
Immobilized Tris(hydroxymethyl)aminomethane as a Scaffold for Ion-Selective Ligands: The Auxiliary Group Effect on Metal Ion Binding at the Phosphate Ligand
Spiro D. Alexandratos and Xiaoping Zhu
pp 2139 - 2147; DOI:
10.1021/ic061817h
PDF
Microwave-Assisted Synthesis of Tricarbonyl Rhenacarboranes: Steric and Electronic Effects on the 1,2 1,7 Carborane Cage Isomerization
Andrea F. Armstrong and John F. Valliant
pp 2148 - 2158; DOI:
10.1021/ic0617543
PDF
Combined Theoretical and Experimental Analysis of the Bonding in the Heterobimetallic Cubane-Type Mo3NiS4 and Mo3CuS4 Core Clusters
Juan Andrés, Marta Feliz, Jordi Fraxedas, Victor Hernández, Juan T. López-Navarrete, Rosa Llusar, Guillaume Sauthier, Fabricio R. Sensato, Bernard Silvi, Carles Boand, and Josep M. Campanera
pp 2159 - 2166; DOI:
10.1021/ic061853g
PDF
Theoretical Investigation of the Stepwise Hydrolysis of the [Re3(-Cl)3Cl9]3- Anion
Dimitrios G. Liakos, Emmanuel D. Simandiras, Nikolaos Psaroudakis, and Konstantinos Mertis
pp 2167 - 2172; DOI:
10.1021/ic061862p
PDF
Olefin Epoxidation by Alkyl Hydroperoxide with a Novel Cross-Bridged Cyclam Manganese Complex: Demonstration of Oxygenation by Two Distinct Reactive Intermediates
Guochuan Yin, Andrew M. Danby, David Kitko, John D. Carter, William M. Scheper, and Daryle H. Busch
pp 2173 - 2180; DOI:
10.1021/ic061957r
PDF
Syntheses, Structures, and Magnetic Properties of the Face-Centered Cubic Clusters [Tp8(H2O)12M6Fe8(CN)24]4+ (M = Co, Ni)
Long Jiang, Hye Jin Choi, Xiao-Long Feng, Tong-Bu Lu, and Jeffrey R. Long
pp 2181 - 2186; DOI:
10.1021/ic061924b
PDF
Rare-Earth Metal-Rich Antimonides: Syntheses, Structures, and Properties of Tm3Sb and Lu7Sb3
Shalabh Gupta, Ling Chen, Ashok K. Ganguli, and John D. Corbett
pp 2187 - 2192; DOI:
10.1021/ic0619409
PDF
Distinct Mechanisms of Bridging-Oxo Exchange in Di--O Dimanganese Complexes with and without Water-Binding Sites: Implications for Water Binding in the O2-Evolving Complex of Photosystem II
Ranitendranath Tagore, Robert H. Crabtree, and Gary W. Brudvig
pp 2193 - 2203; DOI:
10.1021/ic061968k
PDF
Synthesis, Crystal-Structure Determination and Magnetic Properties of Two New Transition-Metal Carbodiimides: CoNCN and NiNCN
Manuel Krott, Xiaohui Liu, Boniface P. T. Fokwa, Manfred Speldrich, Heiko Lueken, and Richard Dronskowski
pp 2204 - 2207; DOI:
10.1021/ic062051o
PDF
Iron Complexes of New Pentadentate Ligands Containing the 1,4,7-Triazacyclononane-1,4-diacetate Motif. Spectroscopic, Electro-, and Photochemical Studies
Yu-Fei Song, John F. Berry, Eckhard Bill, Eberhard Bothe, Thomas Weyhermüller, and Karl Wieghardt
pp 2208 - 2219; DOI:
10.1021/ic062001j
PDF
A New Synthetic Route to Mg2Na2NiH6 Where a [NiH4] Complex Is for the First Time Stabilized by Alkali Metal Counterions
Karim Kadir and Dag Noréus
pp 2220 - 2223; DOI:
10.1021/ic0620586
PDF
Functional Tetrametallic Linker Modules for Coordination Polymers and Metal-Organic Frameworks
Frank B. Johansson, Andrew D. Bond, and Christine J. McKenzie
pp 2224 - 2236; DOI:
10.1021/ic062131s
PDF
AeMg5In3 (Ae = Ba, Sr): New Intermetallic Compounds with Well-Differentiated Roles for the Normal Cation Types
Bin Li and John D. Corbett
pp 2237 - 2242; DOI:
10.1021/ic0621289
PDF
Multiple Photochemical Reaction Pathways in a Ni(II) Coordination Compound
Franklin P. Ow, Bryana L. Henderson, and Jeffrey I. Zink*
pp 2243 - 2248; DOI:
10.1021/ic061969c
PDF
Theoretical Investigations on Heteronuclear Chalcogen-Chalcogen Interactions: On the Nature of Weak Bonds between Chalcogen Centers
Christian Bleiholder, Rolf Gleiter, Daniel B. Werz, and Horst Köppel
pp 2249 - 2260; DOI:
10.1021/ic062110y
PDF
Formation of Antiferromagnetically Coupled C60- and Diamagnetic (C70-)2 Dimers in Ionic Complexes of Fullerenes with (MDABCO+)2·MIITPP (M = Zn, Co, Mn, and Fe) Assemblies
Dmitri V. Konarev, Salavat S. Khasanov, Akihiro Otsuka, Gunzi Saito, and Rimma N. Lyubovskaya
pp 2261 - 2271; DOI:
10.1021/ic0611138
PDF
Tuning of Ruthenium Complex Properties Using Pyrrole- and Pyrrolidine-Containing Polypyridine Ligands
David Martineau, Marc Beley, Philippe C. Gros, Silvia Cazzanti, Stefano Caramori, and Carlo A. Bignozzi
pp 2272 - 2277; DOI:
10.1021/ic062042f
PDF
Mechanistic Study of Iron(III) [Tetrakis(pentafluorophenyl)Porphyrin Triflate (F20TPP)Fe(OTf) Catalyzed Cyclooctene Epoxidation by Hydrogen Peroxide
Ned A. Stephenson and Alexis T. Bell
pp 2278 - 2285; DOI:
10.1021/ic060757c
PDF
New Insights on the Electronic and Molecular Structure of Cyanide-Ligated Iron(III) Porphyrinates
Jianfeng Li, Bruce C. Noll, Charles E. Schulz, and W. Robert Scheidt
pp 2286 - 2298; DOI:
10.1021/ic061463u
PDF
Phase Diagram of the TbBr3-RbBr Binary System: Thermodynamic and Transport Properties of the Rb3TbBr6 Compound
Leszek Rycerz and Marcelle Gaune-Escard
pp 2299 - 2306; DOI:
10.1021/ic0615978
PDF
Uranyl Ion Complexation by Citric and Citramalic Acids in the Presence of Diamines
Pierre Thuéry
pp 2307 - 2315; DOI:
10.1021/ic061772k
PDF
Copper(I) Complexes of Tripodal Tris(imidazolyl) Ligands: Potential Mimics of the Cu(A) Site of Hydroxylase Enzymes
Lei Zhou, Douglas Powell, and Kenneth M. Nicholas
pp 2316 - 2321; DOI:
10.1021/ic061985+
PDF
Kinetics of Oxidation of Nitroxyl Radicals with Superoxometal Complexes of Chromium and Rhodium
Michael J. Vasbinder and Andreja Bakac
pp 2322 - 2327; DOI:
10.1021/ic062010s
PDF
Ruthenium Nitrosyls Derived from Polypyridine Ligands with Carboxamide or Imine Nitrogen Donor(s): Isoelectronic Complexes with Different NO Photolability
Michael J. Rose, Apurba K. Patra, Eric A. Alcid, Marylin M. Olmstead, and Pradip K. Mascharak
pp 2328 - 2338; DOI:
10.1021/ic0620945
PDF
Control of Two-Electron Four-Center (2e-/4c) C-C Bond Formation Observed for Tetracyanoethenide Dimerization, [TCNE]22-
Juan N. Novoa,*, Jordi Ribas-Ariño,, William W. Shum, and Joel S. Miller*:
pp 2339 - 2339; DOI:
10.1021/ic070117p
PDF
Activation of Atmospheric Nitrogen and Azobenzene N=N Bond Cleavage by a Transient Nb(III) Complex
Uriah J. Kilgore, Xiaofan Yang, John Tomaszewski, John C. Huffman, and Daniel J. Mindiola
pp 2340 - 2340; DOI:
10.1021/ic0702062
PDF

Issue 7


MH2P2O7 (M = Co, Ni): Metamagnetic Interaction between the Zigzag Octahedral Chains
Tao Yang, Jing Ju, Guobao Li, Sihai Yang, Junliang Sun, Fuhui Liao, Jianhua Lin, Juns Sasaki, and Naoki Toyota
pp 2342 - 2344; DOI:
10.1021/ic061665q
PDF
From Encapsulation to Polypseudorotaxane: Unusual Anion Networks Driven by Predesigned Metal Bis(terpyridine) Complex Cations
Xiao-Ping Zhou, Wen-Xiu Ni, Shun-Ze Zhan, Jia Ni, Dan Li, and Ye-Gao Yin
pp 2345 - 2347; DOI:
10.1021/ic061927o
PDF
Self-assembly of a High-Nuclearity Chloride-Centered Copper(II) Cluster. Structure and Magnetic Properties of [Au(PPh3)2][trans-Cu6(-OH)6{-(3,5-CF3)2pz}6Cl]
Ahmed A. Mohamed, Alfredo Burini, Rossana Galassi, Daniele Paglialunga, José-Ramón Galán-Mascarós, Kim R. Dunbar, and John P. Fackler, Jr.
pp 2348 - 2349; DOI:
10.1021/ic062299d
PDF
Acetate/Di-2-pyridyl Ketone Oximate "Blend" as a Source of High-Nuclearity Nickel(II) Clusters: Dependence of the Nuclearity on the Nature of the Inorganic Anion Present
Theocharis C. Stamatatos, Eleanna Diamantopoulou, Catherine P. Raptopoulou, Vassilis Psycharis, Albert Escuer, and Spyros P. Perlepes
pp 2350 - 2352; DOI:
10.1021/ic062262t
PDF
Amide Hydrolysis Reactivity of a N4O-Ligated Zinc Complex: Comparison of Kinetic and Themodynamic Parameters with Those of the Corresponding Amide Methanolysis Reaction
Ewa Szajna-Fuller, Gajendrasingh K. Ingle, Rex W. Watkins, Atta M. Arif, and Lisa M. Berreau
pp 2353 - 2355; DOI:
10.1021/ic0622813
PDF
Mercury Bis(phenyltellurolate) as a Precursor for the Synthesis of Binary and Ternary Nanoclusters
Davi F. Back, Gelson N. M. de Oliveira, Robert A. Burrow, Ernesto E. Castellano, Ulrich Abram, and Ernesto S. Lang
pp 2356 - 2358; DOI:
10.1021/ic070006q
PDF
Dihydrogen and Silane Addition to Base-Free, Monomeric Bis(cyclopentadienyl)titanium Oxides
Tamara E. Hanna, Emil Lobkovsky, and Paul J. Chirik
pp 2359 - 2361; DOI:
10.1021/ic070205+
PDF
A RhII-AuII Bimetallic Core with a Direct Metal-Metal Bond
Arthur J. Esswein, Jillian L. Dempsey, and Daniel G. Nocera
pp 2362 - 2364; DOI:
10.1021/ic062203f
PDF
Addition of S-H Bonds across Electron-Deficient Olefins Catalyzed by Well-Defined Copper(I) Thiolate Complexes
Samuel A. Delp, Colleen Munro-Leighton, Laurel A. Goj, Magaly A. Ramírez, T. Brent Gunnoe, Jeffrey L. Petersen, and Paul D. Boyle
pp 2365 - 2367; DOI:
10.1021/ic070268s
PDF
Structures of Dimeric Hydrolysis Products of Thorium
Richard E. Wilson, S. Skanthakumar, Ginger Sigmon, Peter C. Burns, and L. Soderholm
pp 2368 - 2372; DOI:
10.1021/ic0617691
PDF
Synthesis, Structural Characterization, and Multifrequency Electron Paramagnetic Resonance Studies of Mononuclear Thiomolybdenyl Complexes
Simon C. Drew, Jason P. Hill, Ian Lane, Graeme R. Hanson, Robert W. Gable, and Charles G. Young
pp 2373 - 2387; DOI:
10.1021/ic060585j
PDF
A Density Functional Study of the Electronic Structure and Spin Hamiltonian Parameters of Mononuclear Thiomolybdenyl Complexes
Simon C. Drew, Charles G. Young, and Graeme R. Hanson
pp 2388 - 2397; DOI:
10.1021/ic060586b
PDF
Kinetic Analysis of the Conversion of Nonheme (Alkylperoxo)iron(III) Species to Iron(IV) Complexes
Michael P. Jensen, Antoni Mairata i Payeras, Adam T. Fiedler, Miquel Costas, József Kaizer, Audria Stubna, Eckard Münck, and Lawrence Que, Jr.
pp 2398 - 2408; DOI:
10.1021/ic0607787
PDF
The Vibrational Spectra of the Cyanide Ligand Revisited. Bridging Cyanides
Sidney F. A. Kettle, Eliano Diana, Enrico Boccaleri, and Pier Luigi Stanghellini
pp 2409 - 2416; DOI:
10.1021/ic0610482
PDF
Localization and Delocalization in a Mixed-Valence Dicopper Helicate
John C. Jeffery, Thomas Riis-Johannessen, Callum J. Anderson, Christopher J. Adams, Adam Robinson, Stephen P. Argent, Michael D. Ward, and Craig R. Rice
pp 2417 - 2426; DOI:
10.1021/ic061504m
PDF
Synthesis and Characterization of a New Tiara Pd(II) Thiolate Complex, [Pd(SC12H25)2]6, and Its Solution-Phase Thermolysis to Prepare Nearly Monodisperse Palladium Sulfide Nanoparticles
Zhiqiang Yang, Alexander B. Smetana, Christopher M. Sorensen, and Kenneth J. Klabunde
pp 2427 - 2431; DOI:
10.1021/ic061242o
PDF
Synthesis of Pd Complexes Combined with Photosensitizing of a Ruthenium(II) Polypyridyl Moiety through a Series of Substituted Bipyrimidine Bridges. Substituent Effect of the Bridging Ligand on the Photocatalytic Dimerization of -Methylstyrene
Akiko Inagaki, Shinichi Yatsuda, Shinichi Edure, Akiko Suzuki, Takeshi Takahashi, and Munetaka Akita
pp 2432 - 2445; DOI:
10.1021/ic0612909
PDF
Synthesis of CeO2 Nanorods via Ultrasonication Assisted by Polyethylene Glycol
Dengsong Zhang, Hongxia Fu, Liyi Shi, Chengsi Pan, Qiang Li, Yuliang Chu, and Weijun Yu
pp 2446 - 2451; DOI:
10.1021/ic061697d
PDF
The Monolanthanide-Containing Silicotungstates [Ln(2-SiW11O39)2]13- (Ln = La, Ce, Sm, Eu, Gd, Tb, Yb, Lu): A Synthetic and Structural Investigation
Bassem S. Bassil, Michael H. Dickman, Bernd von der Kammer, and Ulrich Kortz
pp 2452 - 2458; DOI:
10.1021/ic061737d
PDF
Water Exchange on Seven-Coordinate Mn(II) Complexes with Macrocyclic Pentadentate Ligands: Insight in the Mechanism of Mn(II) SOD Mimetics
Anne Dees, Achim Zahl, Ralph Puchta, Nico J. R. van Eikema Hommes, Frank W. Heinemann, and Ivana Ivanovi-Burmazovi
pp 2459 - 2470; DOI:
10.1021/ic061852o
PDF
Structural and Magnetic Properties of MCl2 (M = Fe, Mn, Co): Acetonitrile Solvates
Konstantin I. Pokhodnya, Michael Bonner, Antonio G. DiPasquale, Arnold L. Rheingold, Jae-Hyuk Her, Peter W. Stephens, Jong-Won Park, Bretni S. Kennon, Atta M. Arif, and Joel S. Miller
pp 2471 - 2477; DOI:
10.1021/ic061877n
PDF
New Copper and Silver Trimethylsilylchalcogenolates
Aneta Borecki and John F. Corrigan
pp 2478 - 2484; DOI:
10.1021/ic0618910
PDF
Toward Iron Sensors: Bioinspired Tripods Based on Fluorescent Phenol-oxazoline Coordination Sites
Raghavendra Kikkeri, Hassan Traboulsi, Nicolas Humbert, Elzbieta Gumienna-Kontecka, Rina Arad-Yellin, Galina Melman, Mourad Elhabiri, Anne-Marie Albrecht-Gary, and Abraham Shanzer
pp 2485 - 2497; DOI:
10.1021/ic061952u
PDF
On the Relevance of an Antiferromagnetic Dimer Model for the Spin-Gapped Magnetic Solids Cu(terpy)Mo2O7 and Cu(OH)(p-pyc)H2O
Hyun-Joo Koo, Changhoon Lee, Gareth B. Wilson-Short, Dadi Dai, and Myung-Hwan Whangbo
pp 2498 - 2502; DOI:
10.1021/ic061897p
PDF
Self-Assembled Cationic Heterochiral Honeycomb-Layered Metal Complexes with the in Situ Generated Pyrimidine-2-carboxylato Bisdidentate Ligand. Hydrothermal Synthesis, Crystal Structures, Magnetic Properties, and Theoretical Study of [M2(-pymca)3]OH·H2O (M = FeII, CoII)
Antonio Rodríguez-Diéguez, Joan Cano, Raikko Kivekäs, Abderrahmane Debdoubi, and Enrique Colacio
pp 2503 - 2510; DOI:
10.1021/ic061908e
PDF
Coordination Polymers and Hybrid Networks of Different Dimensionalities Formed by Metal Sulfites
K. Prabhakara Rao and C. N. R. Rao
pp 2511 - 2518; DOI:
10.1021/ic061988m
PDF
Novel Linear Transition Metal Clusters of a Heptadentate Bis--diketone Ligand
Guillem Aromí, Patrick Gamez, J. Krzystek, Huub Kooijman, Anthony L. Spek, Elizabeth J. MacLean, Simon J. Teat, and Harriott Nowell
pp 2519 - 2529; DOI:
10.1021/ic062075v
PDF
Synthesis and Voltammetry of [bmim]4[-S2W18O62] and Related Compounds: Rapid Precipitation and Dissolution of Reduced Surface Films
Andrew W. A. Mariotti, Jingli Xie, Brendan F. Abrahams, Alan M. Bond, and Anthony G. Wedd
pp 2530 - 2540; DOI:
10.1021/ic062022d
PDF
Spin Crossover in a Series of Iron(II) Complexes of 2-(2-Alkyl-2H-tetrazol-5-yl)-1,10-phenanthroline: Effects of Alkyl Side Chain, Solvent, and Anion
Wen Zhang, Fei Zhao, Tao Liu, Mei Yuan, Zhe-Ming Wang, and Song Gao
pp 2541 - 2555; DOI:
10.1021/ic062062h
PDF
Structure and Thermoelectric Characterization of AxBa8-xAl14Si31 (A = Sr, Eu) Single Crystals
Cathie L. Condron, Susan M. Kauzlarich, and G. S. Nolas
pp 2556 - 2562; DOI:
10.1021/ic062115v
PDF
Syntheses and Characterizations of Palladium-Based Molecular Triangle/Square Compounds and Hybrid Composites with Polyoxometalates
Kazuhiro Uehara, Ko Kasai, and Noritaka Mizuno
pp 2563 - 2570; DOI:
10.1021/ic062156r
PDF
Structure and Physical Properties of the Polar Oxysulfide CaZnOS
Timothy Sambrook, Catherine F. Smura, Simon J. Clarke, Kang Min Ok, and P. Shiv Halasyamani
pp 2571 - 2574; DOI:
10.1021/ic062120z
PDF
Conformational Flexibility in 2,2'-Dioxybiphenyl-chloro-cyclotetraphosphazenes and its Relevance to Polyphosphazene Analogues
Eric W. Ainscough, Andrew M. Brodie, Adrian B. Chaplin, Andreas Derwahl, John A. Harrison, and Carl A. Otter
pp 2575 - 2583; DOI:
10.1021/ic062141t
PDF
A Bridge to Coordination Isomer Selection in Lanthanide(III) DOTA-tetraamide Complexes
Jeff Vipond, Mark Woods, Piyu Zhao, Gyula Tircsó, Jimin Ren, Simon G. Bott, Doug Ogrin, Garry E. Kiefer, Zoltan Kovacs, and A. Dean Sherry
pp 2584 - 2595; DOI:
10.1021/ic062184+
PDF
Synthesis, Structure, and Properties of Low-Spin Manganese(III)-Poly(pyrazolyl)borate Complexes
Ferdaus Hossain, Matthew A. Rigsby, Cole T. Duncan, Paul L. Milligan, Jr., Richard L. Lord, Mu-Hyun Baik, and Franklin A. Schultz
pp 2596 - 2603; DOI:
10.1021/ic062224+
PDF
Electronic Localization versus Delocalization Determined by the Binding of the Linker in an Isomer Pair
F. Albert Cotton, Chun Y. Liu, Carlos A. Murillo, and Qinliang Zhao
pp 2604 - 2611; DOI:
10.1021/ic0622252
PDF
The Molecular and Electronic Structure of the Electron Transfer Series [Fe2(NO)2(S2C2R2)3]z (z = 0, -1, -2; R = phenyl, p-tolyl, p-tert-butylphenyl)
Prasanta Ghosh, Eckhard Bill, Thomas Weyhermüller, and Karl Wieghardt
pp 2612 - 2618; DOI:
10.1021/ic0622306
PDF
Determination of Equilibrium Constants and Computational Interaction Energies for Adducts of [Rh2(RCO2)4-n(PC)n] (n = 0-2) with Lewis Bases
Pipsa Hirva, Julio Esteban, Julio Lloret, Pascual Lahuerta, and Julia Pérez-Prieto
pp 2619 - 2626; DOI:
10.1021/ic062171w
PDF
New Bonding Modes for Boraamidinate Ligands in Heavy Group 15 Complexes: Fluxional Behavior of the 1:2 Complexes, LiM[PhB(NtBu)2]2 (M = As, Sb, Bi)
Jari Konu, Maravanji S. Balakrishna, Tristram Chivers, and Thomas W. Swaddle
pp 2627 - 2636; DOI:
10.1021/ic0622757
PDF
Interchain-Solvent-Induced Chirality Change of 1D Helical Chains: From Achiral to Chiral Crystallization
Long Jiang, Xiao-Long Feng, Cheng-Yong Su, Xiao-Ming Chen, and Tong-Bu Lu
pp 2637 - 2644; DOI:
10.1021/ic062272u
PDF
Steric and Electronic Effects Relating to the Cu2+ Jahn-Teller Distortion in Zn1-xCuxAl2O4 Spinels
A. Le Nestour, M. Gaudon, G. Villeneuve, R. Andriessen, and A. Demourgues
pp 2645 - 2658; DOI:
10.1021/ic062329c
PDF
Two-Photon Antenna Effect Induced in Octupolar Europium Complexes
Alexandre Picot, Floriane Malvolti, Boris Le Guennic, Patrice L. Baldeck, J. A. Gareth Williams, Chantal Andraud, and Olivier Maury
pp 2659 - 2665; DOI:
10.1021/ic062181x
PDF
Biphenolate Phosphine Complexes of Group 4 Metals
Lan-Chang Liang, Yu-Ning Chang, and Hon Man Lee
pp 2666 - 2673; DOI:
10.1021/ic062314e
PDF
Monodisperse and Core-Shell-Structured SiO2@YBO3:Eu3+ Spherical Particles: Synthesis and Characterization
Cuikun Lin, Deyan Kong, Xiaoming Liu, Huan Wang, Min Yu, and Jun Lin
pp 2674 - 2681; DOI:
10.1021/ic062318j
PDF
Effect of the Metal Environment on the Ferromagnetic Interaction in the Co-NC-W Pairs of Octacyanotungstate(V)-Cobalt(II) Three-Dimensional Networks
Sergiu Clima, Marc F. A. Hendrickx, Liviu F. Chibotaru, Alessandro Soncini, Vladimir Mironov, and Arnout Ceulemans
pp 2682 - 2690; DOI:
10.1021/ic062345+
PDF
Sulfur Ligand Substitution at the Nickel(II) Sites of Cubane-Type and Cubanoid NiFe3S4 Clusters Relevant to the C-Clusters of Carbon Monoxide Dehydrogenase
Jibin Sun, Christian Tessier, and R. H. Holm
pp 2691 - 2699; DOI:
10.1021/ic062362z
PDF
On the Existence of Molecular Palladium(VI) Compounds: Palladium Hexafluoride
Gabriel Aullón and Santiago Alvarez
pp 2700 - 2703; DOI:
10.1021/ic0623819
PDF
Alkylation of Deltahedral Zintl Clusters: Synthesis of [R-Ge9-Ge9-R]4- (R = tBu, sBu, nBu, tAm) and Structure of [tBu-Ge9-Ge9-tBu]4-
Michael W. Hull, Angel Ugrinov, Ivaylo Petrov, and Slavi C. Sevov
pp 2704 - 2708; DOI:
10.1021/ic0623314
PDF
Why [(5-C5MenH5-n)2Ti]2(2,2,2-N2) Can Not Add a H2 Molecule to the Side-On-Coordinated N2 while Its Zr and Hf Analogues Can? Insights from Computational Studies
Djamaladdin G. Musaev, Petia Bobadova-Parvanova, and Keiji Morokuma
pp 2709 - 2715; DOI:
10.1021/ic062405b
PDF
Synthesis, Structure, Reactivity, and Thermal Isomerization of Boron-Substituted 13-Vertex Cobaltacarboranes (5-Cp)Co(6-R2C2B10Me8H2) (R = H, Et)
Liang Deng, Hoi-Shan Chan, and Zuowei Xie
pp 2716 - 2724; DOI:
10.1021/ic062423t
PDF
Construction of Robust Open Metal-Organic Frameworks with Chiral Channels and Permanent Porosity
Daofeng Sun, Yanxiong Ke, David J. Collins, Gary A. Lorigan, and Hong-Cai Zhou
pp 2725 - 2734; DOI:
10.1021/ic0624773
PDF
Di(-oxo) Binuclear Manganese(III,IV) Poly(bipyridyl) Complexes Bearing Four Ruthenium(II) Photoactive Units: Synthesis, Characterization, and Photoinduced Electron-Transfer Properties
Sophie Romain, Jean-Claude Leprêtre, Jérôme Chauvin, Alain Deronzier, and Marie-Noëlle Collomb
pp 2735 - 2743; DOI:
10.1021/ic0624726
PDF
Synthesis, Crystal Structure, and Microstructure Analysis of Perovskite-Type Compounds LnCo0.95Ni0.05O3 (Ln = La, Pr, Nd, Sm, Gd, and Dy)
M. H. Aguirre, R. Robert, D. Logvinovich, and A. Weidenkaff
pp 2744 - 2750; DOI:
10.1021/ic0623821
PDF
Ionic Liquids from Car-Parrinello Simulations. 2. Structural Diffusion Leading to Large Anions in Chloraluminate Ionic Liquids
Barbara Kirchner and Ari P. Seitsonen
pp 2751 - 2754; DOI:
10.1021/ic0624874
PDF
Coordination Studies of a New Unsymmetrical 4-PNN'N' '-Tetradentate Ligand: Stepwise Formation and Structural Characterization
Sean E. Durran, Mark R. J. Elsegood, Shelly R. Hammond, and Martin B. Smith
pp 2755 - 2766; DOI:
10.1021/ic061196s
PDF
Nitrogen-Rich Carbon Nitride Network Materials via the Thermal Decomposition of 2,5,8-Triazido-s-Heptazine
Dale R. Miller, James R. Holst, and Edward G. Gillan
pp 2767 - 2774; DOI:
10.1021/ic061296y
PDF
Protonated Free-Base Corroles: Acidity, Electrochemistry, and Spectroelectrochemistry of [(Cor)H4]+, [(Cor)H5]2+, and [(Cor)H6]3+
Zhongping Ou, Jing Shen, Jianguo Shao, Wenbo E, Micha Gazowski, Daniel T. Gryko, and Karl M. Kadish
pp 2775 - 2786; DOI:
10.1021/ic0617893
PDF
Organometallic Fragments Coordinated to a Multiisocyanide Ligand and Their Physical Properties
Jong Hyub Paek, Kyu Ho Song, Il Jung, Sang Ook Kang, and Jaejung Ko
pp 2787 - 2796; DOI:
10.1021/ic0620900
PDF
A Series of [3 + 2] Cycloaddition Products from the Reaction of Rhenium Oxo Complexes with Diphenyl Ketene
Michael Middleditch, James C. Anderson, Alexander J. Blake, and Clare Wilson
pp 2797 - 2804; DOI:
10.1021/ic062290b
PDF
Optical and Redox Properties of Ruthenium Phthalocyanine Complexes Tuned with Axial Ligand Substituents
Tristan Rawling, Hong Xiao, Sang-Tae Lee, Stephen B. Colbran, and Andrew M. McDonagh
pp 2805 - 2813; DOI:
10.1021/ic061866u
PDF
Synthesis and Characterization of the Homoleptic Octahydrotriborate Complex Cr(B3H8)2 and Its Lewis Base Adducts
Dean M. Goedde, G. Kenneth Windler, and Gregory S. Girolami
pp 2814 - 2823; DOI:
10.1021/ic0621300
PDF
Synthesis, Characterization, and Photochromic Properties of Hybrid Organic-Inorganic Materials Based on Molybdate, DABCO, and Piperazine
Violaine Coué, Rémi Dessapt, Martine Bujoli-Doeuff, Michel Evain, and Stéphane Jobic
pp 2824 - 2835; DOI:
10.1021/ic0621502
PDF
Synthesis, Structure, and Reactivity of Mononuclear Re(I) Oximato Complexes
Luciano Cuesta, Miguel A. Huertos, Dolores Morales, Julio Pérez, Lucía Riera, Víctor Riera, Daniel Miguel, Amador Menéndez-Velázquez, and Santiago García-Granda
pp 2836 - 2845; DOI:
10.1021/ic062168c
PDF
Biimidazole and Bis(amide)bipyridine Molybdenum Carbonyl Complexes as Anions Receptors
Laura Ion, Dolores Morales, Sonia Nieto, Julio Pérez, Lucía Riera, Víctor Riera, Daniel Miguel, Richard A. Kowenicki, and Mary McPartlin
pp 2846 - 2853; DOI:
10.1021/ic0621650
PDF
Ruthenium(II) Complexes with Improved Photophysical Properties Based on Planar 4'-(2-Pyrimidinyl)-2,2':6',2' '-terpyridine Ligands
Yuan-Qing Fang, Nicholas J. Taylor, François Laverdière, Garry S. Hanan, Frédérique Loiseau, Francesco Nastasi, Sebastiano Campagna, Hélène Nierengarten, Emmanuelle Leize-Wagner, and Alain Van Dorsselaer
pp 2854 - 2863; DOI:
10.1021/ic0622609
PDF
Iodination of Stanna-closo-dodecaborate
Torben Gädt, Falko M. Schappacher, Rainer Pöttgen, and Lars Wesemann
pp 2864 - 2869; DOI:
10.1021/ic0622858
PDF
Complexation of UVI with 1-Hydroxyethane-1,1-diphosphonic Acid in Acidic to Basic Solutions
Wendy A. Reed, Linfeng Rao, PierLuigi Zanonato, Alexander Yu. Garnov, Brian A. Powell, and Kenneth L. Nash
pp 2870 - 2876; DOI:
10.1021/ic0621401
PDF
Ternary Zirconium Tin Antimonide ZrSn2-xSbx (0.2 < x < 0.8), Different from the Parent Binaries ZrSn2 and ZrSb2
Andriy V. Tkachuk, Davin G. Piercey, and Arthur Mar
pp 2877 - 2882; DOI:
10.1021/ic062277r
PDF
Carboranes and Baskets from Reaction of B4H10 with Allene
Hasan Sayin and Michael L. McKee
pp 2883 - 2891; DOI:
10.1021/ic070076x
PDF
Induced Currents and Electron Counting in Aromatic Boron Wheels: B82- and B9-
Patrick W. Fowler and Benjamin R. Gray
pp 2892 - 2897; DOI:
10.1021/ic062302t
PDF
Synthesis, Characterization, and Electrochemical Studies of ,'-Fused Metallocenoporphyrins
Hong J. H. Wang, Laurent Jaquinod, Marilyn M. Olmstead, M. Graça H. Vicente, Karl M. Kadish, Zhongping Ou, and Kevin M. Smith
pp 2898 - 2913; DOI:
10.1021/ic062303l
PDF
Tetrahedral D Atom Coordination of Nickel and Evidence for Anti-isostructural Phase Transition in Orthorhombic Ce2Ni7D~4
Yaroslav E. Filinchuk, Klaus Yvon, and Herman Emerich
pp 2914 - 2920; DOI:
10.1021/ic062312u
PDF
Hydrogen-Atom Transfer from Transition Metal Hydroperoxides, Hydrogen Peroxide, and Alkyl Hydroperoxides to Superoxo and Oxo Metal Complexes
Michael J. Vasbinder and Andreja Bakac
pp 2921 - 2928; DOI:
10.1021/ic070015z
PDF
Synthesis and Catalytic Properties in Olefin Epoxidation of Novel Iron(II) Complexes with Pyridine-Containing Macrocycles Bearing an Aminopropyl Pendant Arm
Sonia Taktak, Wanhua Ye, Aida M. Herrera, and Elena V. Rybak-Akimova
pp 2929 - 2942; DOI:
10.1021/ic070094e
PDF

Issue 8


Platinum Complex as a Nanomolar Protein Kinase Inhibitor
Douglas S. Williams, Patrick J. Carroll, and Eric Meggers
pp 2944 - 2946; DOI:
10.1021/ic062055t
PDF
Two Cu2 and Zn2 Metallamacrocycles Featuring a Novel Extended -Conjugated Carbazole Bridge
Alok Ranjan Paital, A-Qing Wu, Guo-Cong Guo, Guillem Aromí, Jordi Ribas-Ariño, and Debashis Ray
pp 2947 - 2949; DOI:
10.1021/ic062109z
PDF
N,N'-Dimethylformamide-Derived Products from Catalytic Oxidation of 3-Hydroxyflavone
Aramice Y. S. Malkhasian, Maila E. Finch, Borislava Nikolovski, Adarsh Menon, Benjamin E. Kucera, and Ferman A. Chavez
pp 2950 - 2952; DOI:
10.1021/ic062408o
PDF
Photophysical Studies and Excited-State Structure of a Blue Phosphorescent Gold-Thallium Complex
Eduardo J. Fernández, Antonio Laguna, José M. López-de-Luzuriaga, Miguel Monge, Manuel Montiel, and M. Elena Olmos
pp 2953 - 2955; DOI:
10.1021/ic062127g
PDF
Novel 3D LnIII-CuI Supramolecular Architecture Based on 2D MOFs with (6,3) Topology
Feng-Qin Wang, Xiang-Jun Zheng, Yong-Hong Wan, Chang-Yan Sun, Zhe-Ming Wang, Ke-Zhi Wang, and Lin-Pei Jin
pp 2956 - 2958; DOI:
10.1021/ic062236v
PDF
Core/Shell Oligometallic Template Synthesis of Macrocyclic Hexaoxime
Shigehisa Akine, Shuichi Sunaga, Takanori Taniguchi, Hayato Miyazaki, and Tatsuya Nabeshima
pp 2959 - 2961; DOI:
10.1021/ic062327s
PDF
Calculation of Water-Exchange Rates on Aqueous Polynuclear Clusters and at Oxide-Water Interfaces
Jianwei Wang, James R. Rustad, and William H. Casey
pp 2962 - 2964; DOI:
10.1021/ic070079+
PDF
K2[Ga(B5O10)]·4H2O: The First Chiral Zeolite-like Galloborate with Large Odd 11-Ring Channels
Zhi-Hong Liu, Ping Yang, and Ping Li
pp 2965 - 2967; DOI:
10.1021/ic070056v
PDF
Proton-Induced Cis-Trans Conversion of a Platinum(II) Center Coordinated by L-Cysteinatocobalt(III) Metalloligands
Zentaro Matsumoto, Takashi Aridomi, Asako Igashira-Kamiyama, Tatsuya Kawamoto, and Takumi Konno
pp 2968 - 2970; DOI:
10.1021/ic070265f
PDF
Boron-Pnictogen Multiple Bonds: Donor-Stabilized P=B and As=B Bonds and a Hindered Iminoborane with a B-N Triple Bond
Eric Rivard, W. Alexander Merrill, James C. Fettinger, Robert Wolf, Geoffrey H. Spikes, and Philip P. Power
pp 2971 - 2978; DOI:
10.1021/ic062076n
PDF
Trinuclear Silver(I) Complexes of Fluorinated Pyrazolates
H. V. Rasika Dias, Chammi S. Palehepitiya Gamage, Jeremy Keltner, Himashinie V. K. Diyabalanage, Ivan Omari, Yvonne Eyobo, Nadeeka R. Dias, Nathan Roehr, Lesly McKinney, and Theresa Poth
pp 2979 - 2987; DOI:
10.1021/ic062374k
PDF
Structural and Magnetic Properties of Layered Copper(II) Coordination Polymers Intercalating s and f Metal Ions
Jorge A. R. Navarro, Elisa Barea, Juan M. Salas, Norberto Masciocchi, Simona Galli, and Angelo Sironi
pp 2988 - 2997; DOI:
10.1021/ic061384i
PDF
pH-Specific Synthesis and Spectroscopic, Structural, and Magnetic Studies of a Chromium(III)-Citrate Species. Aqueous Solution Speciation of the Binary Chromium(III)-Citrate System
C. Gabriel, C. P. Raptopoulou, A. Terzis, V. Tangoulis, C. Mateescu, and A. Salifoglou
pp 2998 - 3009; DOI:
10.1021/ic061480j
PDF
Discovery of -LnNiSb3 (Ln = La, Ce): Crystal Growth, Structure, and Magnetic and Transport Behavior
Evan Lyle Thomas, Dixie P. Gautreaux, Han-Oh Lee, Zachary Fisk, and Julia Y. Chan
pp 3010 - 3016; DOI:
10.1021/ic0615832
PDF
Generation and Characterization of [(P)M-(X)-Co(TMPA)]n+ Assemblies; P = Porphyrinate, M = FeIII and CoIII, X = O2-, OH-, O22-, and TMPA = Tris(2-pyridylmethyl)amine
Eduardo E. Chufán, Claudio N. Verani, Simona C. Puiu, Eva Rentschler, Ulrich Schatzschneider, Christopher Incarvito, Arnold L. Rheingold, and Kenneth D. Karlin
pp 3017 - 3026; DOI:
10.1021/ic061686k
PDF
Syntheses and Characterization of Six Coordination Polymers of Zinc(II) and Cobalt(II) with 1,3,5-Benzenetricarboxylate Anion and Bis(imidazole) Ligands
Ying-Ying Liu, Jian-Fang Ma, Jin Yang, and Zhong-Min Su
pp 3027 - 3037; DOI:
10.1021/ic061575l
PDF
Excited-State Absorption Properties of Platinum(II) Terpyridyl Acetylides
Elena Shikhova, Evgeny O. Danilov, Solen Kinayyigit, Irina E. Pomestchenko, Alexander D. Tregubov, Frank Camerel, Pascal Retailleau, Raymond Ziessel, and Felix N. Castellano
pp 3038 - 3048; DOI:
10.1021/ic0618652
PDF
Antiferromagnetic or Canted Antiferromagnetic Orderings of Fe(III) d Spins of FeX4- Ions in BEDT-TTFVO(S)·FeX4 (X = Cl, Br) [BEDT-TTFVO(S) = Bis(ethylenedithio)tetrathiafulvalenoquinone(-thioquinone)-1,3-dithiolemethide]
Mingxing Wang, Xunwen Xiao, Hideki Fujiwara, Toyonari Sugimoto, Satoru Noguchi, Takekazu Ishida, Takehiko Mori, and Hiroko Aruga Katori
pp 3049 - 3056; DOI:
10.1021/ic0617700
PDF
Syntheses, Crystal Structures, and Magnetic Properties of Metal-Organic Hybrid Materials of Cu(II): Effect of a Long Chain Dicarboxylate Backbone, and Counteranion in Their Structural Diversity
A. K. Ghosh, D. Ghoshal, E. Zangrando, J. Ribas, and N. Ray Chaudhuri
pp 3057 - 3071; DOI:
10.1021/ic061720v
PDF
DNA Binding Studies of Novel Copper(II) Complexes Containing L-Tryptophan as Chiral Auxiliary: In Vitro Antitumor Activity of Cu-Sn2 Complex in Human Neuroblastoma Cells
Mala Chauhan, Kakoli Banerjee, and Farukh Arjmand
pp 3072 - 3082; DOI:
10.1021/ic061753a
PDF
Thermal and Electrochemically Assisted Pd-Cl Bond Cleavage in the d9-d9 Pd2(dppm)2Cl2 Complex by Pd3(dppm)3(CO)n+ Clusters (n = 2, 1, 0)
Cyril Cugnet, Yves Mugnier, Sophie Dal Molin, David Brevet, Dominique Lucas, and Pierre D. Harvey
pp 3083 - 3088; DOI:
10.1021/ic061777h
PDF
Synthesis, Structure, and Magnetic Properties of (A)[FeIII(oxalate)Cl2] (A = Alkyl Ammonium Cations) with Anionic 1D [FeIII(oxalate)Cl2]- Chains
Hong-Bin Xu, Zhe-Ming Wang, Tao Liu, and Song Gao
pp 3089 - 3096; DOI:
10.1021/ic0618854
PDF
Interaction of Product Analogues with the Active Site of Rhodobacter Sphaeroides Dimethyl Sulfoxide Reductase
Graham N. George, Kimberly Johnson Nelson, Hugh H. Harris, Christian J. Doonan, and K. V. Rajagopalan
pp 3097 - 3104; DOI:
10.1021/ic0619052
PDF
High-Nuclearity Ce/Mn and Th/Mn Cluster Chemistry: Preparation of Complexes with [Ce4Mn10O10(OMe)6]18+ and [Th6Mn10O22(OH)2]18+ Cores
Abhudaya Mishra, Anastasios J. Tasiopoulos, Wolfgang Wernsdorfer, Khalil A. Abboud, and George Christou
pp 3105 - 3115; DOI:
10.1021/ic061946y
PDF
Crystal Growth and Structural Characterization of the New Ordered Palladates LnKPdO3 (Ln = La, Pr, Nd, Sm-Gd) and the Isostructural, Partially Cu-Substituted Palladate PrK(Cu0.14Pd0.86)O3
Samuel J. Mugavero III, Mark D. Smith, and Hans-Conrad zur Loye
pp 3116 - 3122; DOI:
10.1021/ic062066m
PDF
Ditopic N-Crowned 4-(p-Aminophenyl)-2,6-diphenylpyridines: Implications of Macrocycle Topology on the Spectroscopic Properties, Cation Complexation, and Differential Anion Responses
Beatriz García-Acosta, Ramón Martínez-Máñez, Félix Sancenón, Juan Soto, Knut Rurack, Monika Spieles, Eduardo García-Breijo, and Luis Gil
pp 3123 - 3135; DOI:
10.1021/ic062069z
PDF
Two-Dimensional Iron(II) Spin Crossover Complex Constructed of Bifurcated NH···O- Hydrogen Bonds and - Interactions: [FeII(HLH,Me)2](ClO4)2·1.5MeCN (HLH,Me = Imidazol-4-yl-methylidene-8-amino-2-methylquinoline)
Hiroaki Hagiwara, Shingo Hashimoto, Naohide Matsumoto, and Seiichiro Iijima
pp 3136 - 3143; DOI:
10.1021/ic061960a
PDF
Copper Complexes of New Benzodioxotetraaza Macrocycles with Potential Applications in Nuclear Medicine
Patricia Antunes, Rita Delgado, Michael G. B. Drew, Vitor Félix, and Helmut Maecke
pp 3144 - 3153; DOI:
10.1021/ic062172o
PDF
Is the 3MLCT the Only Photoreactive State of Polypyridyl Complexes?
F. Alary, J.-L. Heully, L. Bijeire, and P. Vicendo
pp 3154 - 3165; DOI:
10.1021/ic062193i
PDF
Synthesis, Molecular Structure, and Catalytic Potential of the Tetrairon Complex [Fe4(N3O2-L)4(-O)2]4+ (L = 1-Carboxymethyl-4,7-dimethyl-1,4,7-triazacyclononane)
Vladimir B. Romakh, Bruno Therrien, Georg Süss-Fink, and Georgiy B. Shul'pin
pp 3166 - 3175; DOI:
10.1021/ic062207k
PDF
Large-Scale, Surfactant-Free, Hydrothermal Synthesis of Lithium Aluminate Nanorods: Optimization of Parameters and Investigation of Growth Mechanism
Upendra A. Joshi and Jae Sung Lee
pp 3176 - 3184; DOI:
10.1021/ic062227m
PDF
One-Dimensional Coordination Polymers Incorporating Silver(I) Perfluorocarboxylate Cuboctahedral Clusters and the Bis(methylthio)methane Ligand
Mohamed Osman Awaleh, Antonella Badia, and François Brisse
pp 3185 - 3191; DOI:
10.1021/ic062232q
PDF
Reaction of p-Toluenesulfonylamide and M(NMe2)4 (M = Ti, V): Generation of Electron-Deficient Imido Complexes of Early Transition Metals
Christian Lorber, Robert Choukroun, and Laure Vendier
pp 3192 - 3202; DOI:
10.1021/ic062404j
PDF
Luminescence Functionalization of SBA-15 by YVO4:Eu3+ as a Novel Drug Delivery System
Piaoping Yang, Shanshan Huang, Deyan Kong, Jun Lin, and Honggang Fu
pp 3203 - 3211; DOI:
10.1021/ic0622959
PDF
Surface Modification of High-Nuclearity Lanthanide Clusters: Two Tetramers Constructed by Cage-Shaped {Dy26} Clusters and Isonicotinate Linkers
Xiaojun Gu and Dongfeng Xue
pp 3212 - 3216; DOI:
10.1021/ic0623056
PDF
From Chain to Network: Design and Analysis of Novel Organic-Inorganic Assemblies from Organically Functionalized Zinc-Substituted Polyoxovanadates and Zinc Organoamine Subunits
Yanfei Qi, Yangguang Li, Chao Qin, Enbo Wang, Hua Jin, Dongrong Xiao, Xinglong Wang, and Song Chang
pp 3217 - 3230; DOI:
10.1021/ic062338l
PDF
New Layered Germanide Halides RE2GeX2 (RE = Y, Gd; X = Br, I)
Mar'yana Lukachuk, Reinhard K. Kremer, Hansjürgen Mattausch, and Arndt Simon
pp 3231 - 3235; DOI:
10.1021/ic062425d
PDF
Cyano-Bridged FeIII2CuII3 and FeIII4NiII4 Complexes: Syntheses, Structures, and Magnetic Properties
Zhi-Guo Gu, Wei Liu, Qiao-Fang Yang, Xin-Hui Zhou, Jing-Lin Zuo, and Xiao-Zeng You
pp 3236 - 3244; DOI:
10.1021/ic062267q
PDF
{}Crystal-to-Crystal Oxidative Deprotonation of a Di(-hydroxo) to a Di(-oxo) Dimer of Dimolybdenum Units
F. Albert Cotton, Zhong Li, Carlos A. Murillo, Xiaoping Wang, Rongmin Yu, and Qinliang Zhao
pp 3245 - 3250; DOI:
10.1021/ic062443v
PDF
Oxidation of Elemental Gold in Alcohol Solutions
Minna T. Räisänen, Marianna Kemell, Markku Leskelä, and Timo Repo
pp 3251 - 3256; DOI:
10.1021/ic0624468
PDF
Spin Exchange Effects on the Physicochemical Properties of Tetraoxolene-Bridged Bimetallic Complexes
Dong Guo and James K. McCusker
pp 3257 - 3274; DOI:
10.1021/ic070005y
PDF
Four Distinctively Different Decomposition Pathways of Metastable Supermesityltellurium(IV) Trichloride
Jens Beckmann, Stephan Heitz, and Malte Hesse
pp 3275 - 3282; DOI:
10.1021/ic062469m
PDF
Preparation and Isolation of Dithiolene Thiophosphoryl Molecules as Stable, Protected Forms of Dithiolene Ligands
Kuppuswamy Arumugam, James E. Bollinger, Mark Fink, and James P. Donahue
pp 3283 - 3288; DOI:
10.1021/ic0700203
PDF
Study of the Insertion/Deinsertion Mechanism of Sodium into Na0.44MnO2
F. Sauvage, L. Laffont, J.-M. Tarascon, and E. Baudrin
pp 3289 - 3294; DOI:
10.1021/ic0700250
PDF
Stabilization of Acepentalene by Coordination to Transition Metals: A DFT Investigation
Andrés Vega and Jean-Yves Saillard
pp 3295 - 3300; DOI:
10.1021/ic070083l
PDF
Flux Synthesis, Crystal Structures, and Solid-State NMR Spectroscopy of Two Indium Silicates Containing Varied In-O Coordination Geometries
Ling-I Hung, Sue-Lein Wang, Hsien-Ming Kao, and Kwang-Hwa Lii
pp 3301 - 3305; DOI:
10.1021/ic0700349
PDF
A Trinuclear Copper(II) Complex of 2,4,6-Tris(di-2-pyridylamine)-1,3,5-triazine Shows Prominent DNA Cleavage Activity
Jingwen Chen, Xiaoyong Wang, Ying Shao, Jianhui Zhu, Yangguang Zhu, Yizhi Li, Qiang Xu, and Zijian Guo
pp 3306 - 3312; DOI:
10.1021/ic0614162
PDF
Photochromism of Novel Metal Coordination Polymers with 1,2-Bis(2'-methyl-5'-(carboxylic acid)-3'-thienyl)perfluorocyclopentene in the Crystalline Phase
Jing Han, Masahiko Maekawa, Yusaku Suenaga, Hideaki Ebisu, Atsuhiro Nabei, Takayoshi Kuroda-Sowa, and Megumu Munakata
pp 3313 - 3321; DOI:
10.1021/ic0615168
PDF
Syntheses, Characterization, and Dioxygen Reactivities of Cu(I) Complexes with cis,cis-1,3,5-Triaminocyclohexane Derivatives: A Cu(III)2O2 Intermediate Exhibiting Higher C-H Activation
Yuji Kajita, Hidekazu Arii, Takahiro Saito, Yamato Saito, Shigenori Nagatomo, Teizo Kitagawa, Yasuhiro Funahashi, Tomohiro Ozawa, and Hideki Masuda
pp 3322 - 3335; DOI:
10.1021/ic062206s
PDF
Influence of an Extremely Negatively Charged Porphyrin on the Reversible Binding Kinetics of NO to Fe(III) and the Subsequent Reductive Nitrosylation
Joo-Eun Jee, Siegfried Eigler, Norbert Jux, Achim Zahl, and Rudi van Eldik
pp 3336 - 3352; DOI:
10.1021/ic061732g
PDF
Crystal Structure and Physical Properties of Conducting Molecular Antiferromagnets with a Halogen-Substituted Donor: (EDO-TTFBr2)2FeX4 (X = Cl, Br)
A. Miyazaki, H. Yamazaki, M. Aimatsu, T. Enoki, R. Watanabe, E. Ogura, Y. Kuwatani, and M. Iyoda
pp 3353 - 3366; DOI:
10.1021/ic061871y
PDF
A New Chiral N,N',O-Donor Heteroscorpionate Ligand. Structures of Ni2+, Cu2+, Zn2+ Complexes and Study of Solution Equilibria by Means of 1H NMR/UV-Vis Titrations and EXSY NMR Spectroscopy
Marcello Gennari, Matteo Tegoni, Maurizio Lanfranchi, Maria Angela Pellinghelli, and Luciano Marchiò
pp 3367 - 3377; DOI:
10.1021/ic062228e
PDF
Synthesis and Reactivity of Haloacetato Derivatives of Iron(II) Including the Crystal and the Molecular Structure of [Fe(CF3COOH)2(-CF3COO)2]n
Fabio Marchetti, Fabio Marchetti, Bernardo Melai, Guido Pampaloni, and Stefano Zacchini
pp 3378 - 3384; DOI:
10.1021/ic061903h
PDF
Rhenium Analogues of Promising Renal Imaging Agents with a {99mTc(CO)3}+ Core Bound to Cysteine-Derived Dipeptides, Including Lanthionine
Haiyang He, Malgorzata Lipowska, Xiaolong Xu, Andrew T. Taylor, and Luigi G. Marzilli
pp 3385 - 3394; DOI:
10.1021/ic0619299
PDF
Self-Assembly Reactions between the Cis-Protected Metal Corners (N-N)MII (N-N = Ethylenediamine, 4,4'-Substituted 2,2'-Bipyridine; M = Pd, Pt) and the Fluorinated Edge 1,4-Bis(4-pyridyl)tetrafluorobenzene
Montserrat Ferrer, Albert Gutiérrez, Mounia Mounir, Oriol Rossell, Eliseo Ruiz, Alexander Rang, and Marianne Engeser
pp 3395 - 3406; DOI:
10.1021/ic062373s
PDF
Pyrazole Complexes as Anion Receptors: Effects of Changing the Metal, the Pyrazole Substitution Pattern, and the Number of Pyrazole Ligands
Sonia Nieto, Julio Pérez, Lucía Riera, Víctor Riera, Daniel Miguel, James A. Golen, and Arnold L. Rheingold
pp 3407 - 3418; DOI:
10.1021/ic0700046
PDF

Issue 9


Preferential DNA Cleavage under Anaerobic Conditions by a DNA-Binding Ruthenium Dimer
Thamara K. Janaratne, Abhishek Yadav, Fiona Ongeri, and Frederick M. MacDonnell
pp 3420 - 3422; DOI:
10.1021/ic0619714
PDF
Structure and Magnetic Properties of a New Cobalt(II) Thiophenedicarboxylate Coordination Polymer Showing Unprecedented Coordination
Aude Demessence, Guillaume Rogez, Richard Welter, and Pierre Rabu
pp 3423 - 3425; DOI:
10.1021/ic070046u
PDF
Evidence for the Formation of Terminal Hydrides by Protonation of an Asymmetric Iron Hydrogenase Active Site Mimic
Salah Ezzaher, Jean-François Capon, Frédéric Gloaguen, François Y. Pétillon, Philippe Schollhammer, Jean Talarmin, Roger Pichon, and Nelly Kervarec
pp 3426 - 3428; DOI:
10.1021/ic0703124
PDF
Dendronized Diruthenium Compounds via the Copper(I)-Catalyzed Click Reaction
Wei-Zhong Chen, Phillip E. Fanwick, and Tong Ren
pp 3429 - 3431; DOI:
10.1021/ic0702623
PDF
Metal-Organic Framework Based on a Trinickel Secondary Building Unit Exhibiting Gas-Sorption Hysteresis
Shengqian Ma, Xi-Sen Wang, Erika S. Manis, Christopher D. Collier, and Hong-Cai Zhou
pp 3432 - 3434; DOI:
10.1021/ic070338v
PDF
The Importance of Questioning Scientific Assumptions: Some Lessons from f Element Chemistry
William J. Evans
pp 3435 - 3449; DOI:
10.1021/ic062011k
PDF
Two- and Three-Dimensional Lanthanide Complexes: Synthesis, Crystal Structures, and Properties
Jun Xia, Bin Zhao, Hong-Sheng Wang, Wei Shi, Yue Ma, Hai-Bin Song, Peng Cheng, Dai-Zheng Liao, and Shi-Ping Yan
pp 3450 - 3458; DOI:
10.1021/ic061620p
PDF
New Methacrylate-Functionalized Ba and Ba-Ti Oxoclusters as Potential Nanosized Building Blocks for Inorganic-Organic Hybrid Materials: Synthesis and Characterization
Alberto Albinati, Francesco Faccini, Silvia Gross, Guido Kickelbick, Silvia Rizzato, and Alfonso Venzo
pp 3459 - 3466; DOI:
10.1021/ic0615630
PDF
Crystal Structures of Incommensurately Modulated Ln(PO3)3 (Ln = Tb-Yb) and Commensurate Gd(PO3)3 and Lu(PO3)3
Henning A. Höppe and Stefan J. Sedlmaier
pp 3467 - 3474; DOI:
10.1021/ic0616030
PDF
Rare Earth Arenedisulfonate Metal-Organic Frameworks: An Approach toward Polyhedral Diversity and Variety of Functional Compounds
Felipe Gándara, Alberto García-Cortés, Concepción Cascales, Berta Gómez-Lor, Enrique Gutiérrez-Puebla, Marta Iglesias, Angeles Monge, and Natalia Snejko
pp 3475 - 3484; DOI:
10.1021/ic0617689
PDF
The Curium Aqua Ion
S. Skanthakumar, Mark R. Antonio, Richard E. Wilson, and L. Soderholm
pp 3485 - 3491; DOI:
10.1021/ic061798b
PDF
Series of Trinuclear NiIILnIIINiII Complexes Derived from 2,6-Di(acetoacetyl)pyridine: Synthesis, Structure, and Magnetism
Takuya Shiga, Nobuhiro Ito, Akiko Hidaka, Hisashi kawa, Susumu Kitagawa, and Masaaki Ohba
pp 3492 - 3501; DOI:
10.1021/ic0619153
PDF
Structural, Electrochemical, and Spectroscopic Characterization of a Redox Pair of Sulfite-Based Polyoxotungstates: -[W18O54(SO3)2]4- and -[W18O54(SO3)2]5-
Nigel Fay, Alan M. Bond, Carole Baffert, John F. Boas, John R. Pilbrow, De-Liang Long, and Leroy Cronin
pp 3502 - 3510; DOI:
10.1021/ic062067e
PDF
The Origin of the Surprising Stabilities of Highly Charged Self-Assembled Polymetallic Complexes in Solution
Gabriel Canard and Claude Piguet
pp 3511 - 3522; DOI:
10.1021/ic062126o
PDF
Heterotrimetallic Oxalato-Bridged ReIV2MII Complexes (M = Mn, Co, Ni, Cu): Synthesis, Crystal Structure, and Magnetic Properties
José Martínez-Lillo, Fernado S. Delgado, Catalina Ruiz-Pérez, Francesc Lloret, Miguel Julve, and Juan Faus
pp 3523 - 3530; DOI:
10.1021/ic0622095
PDF
Photochemical Ligand Substitution Reactions of fac-[Re(bpy)(CO)3Cl] and Derivatives
Shunsuke Sato, Akiko Sekine, Yuji Ohashi, Osamu Ishitani, Ana Maria Blanco-Rodríguez, Antonín Vlek, Jr., Taiju Unno, and Kazuhide Koike
pp 3531 - 3540; DOI:
10.1021/ic0621603
PDF
Organic-Inorganic Hybrids Constructed of Anderson-Type Polyoxoanions and Oxalato-Bridged Dinuclear Copper Complexes
Ruige Cao, Shuxia Liu, Linhua Xie, Yibing Pan, Jianfang Cao, Yuanhang Ren, and Lin Xu
pp 3541 - 3547; DOI:
10.1021/ic062208c
PDF
Distinct M and P Helical Complexes of H2O and Metal Ions NiII, CuII, and ZnII with Enantiomerically Pure Chiral Bis(pyrrol-2-ylmethyleneamine)cyclohexane Ligands: Crystal Structures and Circular Dichroism Properties
Yaobing Wang, Hongbing Fu, Fugang Shen, Xiaohai Sheng, Aidong Peng, Zhanjun Gu, Hongwei Ma, Jin Shi Ma, and Jiannian Yao
pp 3548 - 3556; DOI:
10.1021/ic062316z
PDF
Energy Decomposition Analysis of Metal-Metal Bonding in [M2X8]2- (X = Cl, Br) Complexes of 5f (U, Np, Pu), 5d (W, Re, Os), and 4d (Mo, Tc, Ru) Elements
Germán Cavigliasso and Nikolas Kaltsoyannis
pp 3557 - 3565; DOI:
10.1021/ic0623260
PDF
Electrolytes for Dye-Sensitized Solar Cells Based on Interhalogen Ionic Salts and Liquids
Mikhail Gorlov, Henrik Pettersson, Anders Hagfeldt, and Lars Kloo
pp 3566 - 3575; DOI:
10.1021/ic062244b
PDF
Protein Binding to Lanthanide(III) Complexes Can Reduce the Water Exchange Rate at the Lanthanide
Stephan G. Zech, Harriet B. Eldredge, Mark P. Lowe, and Peter Caravan
pp 3576 - 3584; DOI:
10.1021/ic070011u
PDF
Solid-State 129Xe and 131Xe NMR Study of the Perxenate Anion XeO64-
Michelle A. M. Forgeron, Roderick E. Wasylishen, Michael Gerken, and Gary J. Schrobilgen
pp 3585 - 3592; DOI:
10.1021/ic0624524
PDF
Molecular Recognition of Adeninium Cations on Anionic Metal-Oxalato Frameworks: An Experimental and Theoretical Analysis
Juan P. García-Terán, Oscar Castillo, Antonio Luque, Urko García-Couceiro, Garikoitz Beobide, and Pascual Román
pp 3593 - 3602; DOI:
10.1021/ic062448s
PDF
Synthesis and Spectroscopic Studies of Cyclometalated Pt(II) Complexes Containing a Functionalized Cyclometalating Ligand, 2-Phenyl-6-(1H-pyrazol-3-yl)-pyridine
Chi-Kin Koo, Yu-Man Ho, Cheuk-Fai Chow, Michael Hon-Wah Lam, Tai-Chu Lau, and Wai-Yeung Wong
pp 3603 - 3612; DOI:
10.1021/ic062439j
PDF
X-ray Structural Characterization of Imidazolylcobalamin and Histidinylcobalamin: Cobalamin Models for Aquacobalamin Bound to the B12 Transporter Protein Transcobalamin
Luciana Hannibal, Scott D. Bunge, Rudi van Eldik, Donald W. Jacobsen, Christoph Kratky, Karl Gruber, and Nicola E. Brasch
pp 3613 - 3618; DOI:
10.1021/ic070022n
PDF
Flux Synthesis, Crystal Structure, and Luminescence Properties of a New Europium Fluoride-Silicate: K5Eu2FSi4O13
Pei-Yun Chiang, Tsai-Wei Lin, Jian-Hung Dai, Bor-Chen Chang, and Kwang-Hwa Lii
pp 3619 - 3622; DOI:
10.1021/ic0700304
PDF
Boron and Aluminum Complexes of Sterically Demanding Phosphinimines and Phosphinimides
Silke Courtenay, Denise Walsh, Sarah Hawkeswood, Pingrong Wei, Anjan Kumar Das, and Douglas W. Stephan
pp 3623 - 3631; DOI:
10.1021/ic0700351
PDF
Wide Compositional and Structural Diversity in the System Tl/Bi/P/Q (Q = S, Se) and Observation of Vicinal P-Tl J Coupling in the Solid State
Matthew A. Gave, Christos D. Malliakas, David P. Weliky, and Mercouri G. Kanatzidis
pp 3632 - 3644; DOI:
10.1021/ic062465h
PDF
The First Ruthenium-Based Paullones: Syntheses, X-ray Diffraction Structures, and Spectroscopic and Antiproliferative Properties in Vitro
Wolfgang F. Schmid, Stefanie Zorbas-Seifried, Roland O. John, Vladimir B. Arion, Michael A. Jakupec, Alexander Roller, Markus Galanski, Ion Chiorescu, Haralabos Zorbas, and Bernhard K. Keppler
pp 3645 - 3656; DOI:
10.1021/ic070098j
PDF
Expanding the Crystal Chemistry of Uranyl Peroxides: Synthesis and Structures of Di- and Triperoxodioxouranium(VI) Complexes
Karrie-Ann Kubatko, Tori Z. Forbes, Amanda L. Klingensmith, and Peter C. Burns
pp 3657 - 3662; DOI:
10.1021/ic070118h
PDF
Critical Role of Water Content in the Formation and Reactivity of Uranium, Neptunium, and Plutonium Iodates under Hydrothermal Conditions: Implications for the Oxidative Dissolution of Spent Nuclear Fuel
Travis H. Bray, Jie Ling, Eun Sang Choi, James S. Brooks, James V. Beitz, Richard E. Sykora, Richard G. Haire, David M. Stanbury, and Thomas E. Albrecht-Schmitt
pp 3663 - 3668; DOI:
10.1021/ic070170d
PDF
Probing Anion- Interactions in 1-D Co(II), Ni(II), and Cd(II) Coordination Polymers Containing Flexible Pyrazine Ligands
Cory A. Black, Lyall R. Hanton, and Mark D. Spicer
pp 3669 - 3679; DOI:
10.1021/ic070194k
PDF
Thermodynamics and Kinetics of the Nickel(II)-Salicylhydroxamic Acid System. Phenol Rotation Induced by Metal Ion Binding
Begoña García, Sheila Gonzalez, Francisco J. Hoyuelos, Saturnino Ibeas, José M. Leal, María L. Senent, Tarita Biver, Fernando Secco, and Marcella Venturini
pp 3680 - 3687; DOI:
10.1021/ic0614061
PDF
95Mo and 17O NMR Studies of Aqueous Molybdate Solutions
Raisa I. Maksimovskaya and Gennady M. Maksimov
pp 3688 - 3695; DOI:
10.1021/ic061549n
PDF
Probing the Excited States of d6 Metal Complexes Containing the 2,2'-Bipyrimidine Ligand Using Time-Resolved Infrared Spectroscopy. 1. Mononuclear and Homodinuclear Systems
Wassim Z. Alsindi, Timothy L. Easun, X.-Z. Sun, Kate L. Ronayne, Michael Towrie, Juan-Manuel Herrera, Michael W. George, and Michael D. Ward
pp 3696 - 3704; DOI:
10.1021/ic0623112
PDF
Isostructural neo-Pentoxide Derivatives of Group 3 and the Lanthanide Series Metals for the Production of Ln2O3 Nanoparticles
Timothy J. Boyle, Leigh Anna M. Ottley, Sherrika D. Daniel-Taylor, Louis J. Tribby, Scott D. Bunge, Alison L. Costello, Todd M. Alam, John C. Gordon, and T. Mark McCleskey
pp 3705 - 3713; DOI:
10.1021/ic070253u
PDF
Relating Structural and Thermodynamic Effects of the Pb(II) Lone Pair: A New Picolinate Ligand Designed to Accommodate the Pb(II) Lone Pair Leads to High Stability and Selectivity
Aymeric Pellissier, Yann Bretonnière, Nicholas Chatterton, Jacques Pécaut, Pascale Delangle, and Marinella Mazzanti
pp 3714 - 3725; DOI:
10.1021/ic061823d
PDF
C-H Cleavage and Double Alkyl Additions to the Disulfido Ligand in Dicyanido-Bridged Ru2S2 Complexes
Sumito Ishizu, Hiroyasu Sugiyama, Brian K. Breedlove, and Kazuko Matsumoto
pp 3726 - 3735; DOI:
10.1021/ic062460k
PDF
Probing Mixed Valence in a New tppz-Bridged Diruthenium(III,II) Complex {(-tppz)[Ru(bik)Cl]2}3+ (tppz = 2,3,5,6-Tetrakis(2-pyridyl)pyrazine, bik = 2,2'-Bis(1-methylimidazolyl)ketone): EPR Silence, Intervalence Absorption, and CO Line Broadening
Moumita Koley, Biprajit Sarkar, Sandeep Ghumaan, Ece Bulak, Jan Fiedler, Wolfgang Kaim, and Goutam Kumar Lahiri
pp 3736 - 3742; DOI:
10.1021/ic0700102
PDF
Synthesis, Reactivity, and Structural Characterization of Sodium and Ytterbium Complexes Containing New Imidazolidine-Bridged Bis(phenolato) Ligands
Xiaoping Xu, Yingming Yao, Yong Zhang, and Qi Shen
pp 3743 - 3751; DOI:
10.1021/ic0701054
PDF
Ligand Topology Variations and the Importance of Ligand Field Strength in Non-Heme Iron Catalyzed Oxidations of Alkanes
Jason England, George J. P. Britovsek, Nitin Rabadia, and Andrew J. P. White
pp 3752 - 3767; DOI:
10.1021/ic070062r
PDF
-1:1-Peroxo-Bridged Dinuclear Peroxotungstate Catalytically Active for Epoxidation of Olefins
Keigo Kamata, Shinjiro Kuzuya, Kazuhiro Uehara, Syuhei Yamaguch, and Noritaka Mizuno
pp 3768 - 3774; DOI:
10.1021/ic0701211
PDF
Olefin Metathesis as an Inorganic Synthetic Tool: Cross and Ring Closing Metathesis Reactions of Diruthenium-Bound -Alkene--carboxylates
Wei-Zhong Chen, John D. Protasiewicz, Stephen A. Davis, James B. Updegraff, Li-Qing Ma, Phillip E. Fanwick, and Tong Ren
pp 3775 - 3782; DOI:
10.1021/ic070123l
PDF
Oxidative Addition Reactions of Alkyl Halides with the Group 13 Carbene Analogue [In{N(Dipp)C(Me)}2CH] (Dipp = 2,6-iPr2C6H3)
Michael S. Hill, Peter B. Hitchcock, and Ruti Pongtavornpinyo
pp 3783 - 3788; DOI:
10.1021/ic070183r
PDF

Issue 10


Magnesium Borohydride Complexed by Tetramethylethylenediamine
Grigorii L. Soloveichik, Matthew Andrus, and Emil B. Lobkovsky
pp 3790 - 3791; DOI:
10.1021/ic700376n
PDF
Oxidation of the Tris(carbene)borate Complex PhB(MeIm)3MnI(CO)3 to MnIV[PhB(MeIm)3]2(OTf)2
Adam P. Forshaw, Ranko P. Bontchev, and Jeremy M. Smith
pp 3792 - 3794; DOI:
10.1021/ic070187w
PDF
A Large [Mn10Na]4 Loop of Four Linked Mn10 Loops
Eleni E. Moushi, Christos Lampropoulos, Wolfgang Wernsdorfer, Vassilios Nastopoulos, George Christou, and Anastasios J. Tasiopoulos
pp 3795 - 3797; DOI:
10.1021/ic062454o
PDF
Optical Memory and Multistep Luminescence Thermochromism in Single Crystals of K2Na[Ag(CN)2]3
Mohammad A. Omary, Julie Clarissa F. Colis, C. L. Larochelle, and Howard H. Patterson
pp 3798 - 3800; DOI:
10.1021/ic070198p
PDF
An Unprecedented Polyborate Ester Anion: X-ray Diffraction Studies on [1,8-C10H6(NMe2)2H][B5O6(OMe)4]
Michael A. Beckett, Catherine C. Bland, Peter N. Horton, Michael B. Hursthouse, and K. Sukumar Varma
pp 3801 - 3803; DOI:
10.1021/ic700433e
PDF
[Mo(TmMe)(O)2Cl]: An Alternative Functional Model of Sulfite Oxidase
Dawn Wallace, Lorraine T. Gibson, John Reglinski, and Mark D. Spicer
pp 3804 - 3806; DOI:
10.1021/ic700468m
PDF
Preparation and Coordination Complex of the First Imine-Bridged Tetrathiafulvalene-Pyridine Donor Ligand
M'hamed Chahma, Nasser Hassan, Antonio Alberola, Helen Stoeckli-Evans, and Melanie Pilkington
pp 3807 - 3809; DOI:
10.1021/ic062257p
PDF
Manganese(III,IV) and Manganese(III) Oxide Clusters Trapped by Copper(II) Complexes
Satoshi Yamashita, Takuya Shiga, Masashi Kurashina, Masayuki Nihei, Hiroyuki Nojiri, Hiroshi Sawa, Toru Kakiuchi, and Hiroki Oshio
pp 3810 - 3812; DOI:
10.1021/ic062258h
PDF
Intermolecular Electron Transfer from Photogenerated Ru(bpy)3+ to [2Fe2S] Model Complexes of the Iron-Only Hydrogenase Active Site
Yong Na, Jingxi Pan, Mei Wang, and Licheng Sun
pp 3813 - 3815; DOI:
10.1021/ic070234k
PDF
Facile Oxidation-Based Synthesis of Sterically Encumbered Four-Coordinate Bis(2,9-di-tert-butyl-1,10-phenanthroline)copper(I) and Related Three-Coordinate Copper(I) Complexes
Bhavesh A. Gandhi, Omar Green, and Judith N. Burstyn
pp 3816 - 3825; DOI:
10.1021/ic0615224
PDF
A Density Functional Theory Study of the Reaction of the Biomimetic Iron(II) Complex of a Tetradentate Bispidine Ligand with H2O2
Peter Comba, Gopalan Rajaraman, and Heidi Rohwer
pp 3826 - 3838; DOI:
10.1021/ic061129y
PDF
Structure and Bonding in SnWO4, PbWO4, and BiVO4: Lone Pairs vs Inert Pairs
Matthew W. Stoltzfus, Patrick M. Woodward, Ram Seshadri, Jae-Hyun Klepeis, and Bruce Bursten
pp 3839 - 3850; DOI:
10.1021/ic061157g
PDF
Structure and Magnetic Properties of Pb2Cu3B4O11: a New Copper Borate Featuring [Cu3O8]10- Units
Shilie Pan, Byron Watkins, Jared P. Smit, Michael R. Marvel, Ian Saratovsky, and Kenneth R. Poeppelmeier
pp 3851 - 3855; DOI:
10.1021/ic0614824
PDF
Density Functional Study of Lithium Hexamethyldisilazide (LiHMDS) Complexes: Effects of Solvation and Aggregation
Svetlana Popenova, Robert C. Mawhinney, and Georg Schreckenbach
pp 3856 - 3864; DOI:
10.1021/ic061599s
PDF
Cyclometallated Iridium and Platinum Complexes with Noninnocent Ligands
Bhavna Hirani, Jian Li, Peter I. Djurovich, Muhammed Yousufuddin, Jonas Oxgaard, Petter Persson, Scott R. Wilson, Robert Bau, William A. Goddard III, and Mark E. Thompson
pp 3865 - 3875; DOI:
10.1021/ic061556b
PDF
Binding of Nitrate to a CuII-Cyclen Complex Bearing a Ferrocenyl Pendant: Synthesis, Solid-State X-ray Structure, and Solution-Phase Electrochemical and Spectrophotometric Studies
Gilles Gasser, Matthew J. Belousoff, Alan M. Bond, and Leone Spiccia
pp 3876 - 3888; DOI:
10.1021/ic061622+
PDF
Further Insights into the Spectroscopic Properties, Electronic Structure, and Kinetics of Formation of the Heme-Peroxo-Copper Complex [(F8TPP)FeIII-(O22-)-CuII(TMPA)]+
Reza A. Ghiladi, Eduardo E. Chufán, Diego del Río, Edward I. Solomon, Carsten Krebs, Boi Hanh Huynh, Hong-wei Huang, Pierre Moënne-Loccoz, Susan Kaderli, Marcus Honecker, Andreas D. Zuberbühler, Lisa Marzilli, Robert J. Cotter, and Kenneth D. Karlin
pp 3889 - 3902; DOI:
10.1021/ic061726k
PDF
Synthesis and Characterization of Vanadium(IV) Complexes with cis-Inositol in Aqueous Solution and in the Solid-State
Bernd Morgenstern, Barbara Kutzky, Christian Neis, Stefan Stucky, Kaspar Hegetschweiler, Eugenio Garribba, and Giovanni Micera
pp 3903 - 3915; DOI:
10.1021/ic0618504
PDF
Synthesis and Spectroscopic Characterization of Copper(II)-Nitrito Complexes with Hydrotris(pyrazolyl)borate and Related Coligands
Nicolai Lehnert, Ursula Cornelissen, Frank Neese, Tetsuya Ono, Yuki Noguchi, Ken-ichi Okamoto, and Kiyoshi Fujisawa
pp 3916 - 3933; DOI:
10.1021/ic0619355
PDF
Mn(II) and Cu(II) Complexes of a Dithiadiazolyl Radical Ligand: Monomer/Dimer Equilibria in Solution
James Britten, Nigel G. R. Hearns, Kathryn E. Preuss, John F. Richardson, and Sofi Bin-Salamon
pp 3934 - 3945; DOI:
10.1021/ic0619456
PDF
Hexaazamacrocyclic Nickel and Copper Complexes and their Reactivity with Tetracyanoquinodimethane
Loreto Ballester, Angel Gutiérrez, M. Felisa Perpiñán, Ana E. Sánchez, Marina Fonari, and Maria Gdaniec
pp 3946 - 3955; DOI:
10.1021/ic062016h
PDF
Nature of "Hydrogen Bond" in the Diborane-Benzene Complex: Covalent, Electrostatic, or Dispersive?
Hongzhi Li, Donghong Min, Sheldon G. Shore, William N. Lipscomb, and Wei Yang
pp 3956 - 3959; DOI:
10.1021/ic061857l
PDF
Exploring Lanthanide Luminescence in Metal-Organic Frameworks: Synthesis, Structure, and Guest-Sensitized Luminescence of a Mixed Europium/Terbium-Adipate Framework and a Terbium-Adipate Framework
Daniel T. de Lill, Ana de Bettencourt-Dias, and Christopher L. Cahill
pp 3960 - 3965; DOI:
10.1021/ic062019u
PDF
Facile and Efficient Synthesis of C-Hydroxycarboranes and C,C'-Dihydroxycarboranes
Kiminori Ohta, Tokuhito Goto, Hiroto Yamazaki, Fabio Pichierri, and Yasuyuki Endo
pp 3966 - 3970; DOI:
10.1021/ic062025q
PDF
Vanadium(V) Tartrato Complexes: Speciation in the H3O+(OH-)/H2VO4-/(2R,3R)-Tartrate System and X-ray Crystal Structures of Na4[V4O8(rac-tart)2]·12H2O and (NEt4)4[V4O8((R,R)-tart)2]·6H2O (tart = C4H2O64-)
Peter Schwendt, Alan S. Tracey, Jozef Tatiersky, Jana Gáliková, and Zdirad ák
pp 3971 - 3983; DOI:
10.1021/ic062223h
PDF
Molecular Tectonics of Mixed-Ligand Metal-Organic Frameworks: Positional Isomeric Effect, Metal-Directed Assembly, and Structural Diversification
Miao Du, Xiu-Juan Jiang, and Xiao-Jun Zhao
pp 3984 - 3995; DOI:
10.1021/ic062098+
PDF
Hydrothermal Vanadium Fluoride Chemistry: Four New V3+ Chain Structures
David W. Aldous, Nicholas F. Stephens, and Philip Lightfoot
pp 3996 - 4001; DOI:
10.1021/ic062061p
PDF
Complexation Kinetics of Copper(II) and Nickel(II) with Macrocycles: Identification of an Outer-Sphere Chelate Effect
Nichola McCann, Geoffrey A. Lawrance, Yorck-Michael Neuhold, and Marcel Maeder
pp 4002 - 4009; DOI:
10.1021/ic0621143
PDF
Coexistence of Five Different Copper(II)-Phenanthroline Species in the Crystal Packing of Inorganic-Metalorganic Hybrids Based on Keggin Polyoxometalates and Copper(II)-Phenanthroline-Oxalate Complexes
Santiago Reinoso, Pablo Vitoria, Juan M. Gutiérrez-Zorrilla, Luis Lezama, Juan M. Madariaga, Leire San Felices, and Amaia Iturrospe
pp 4010 - 4021; DOI:
10.1021/ic062367w
PDF
Density Functional Theory and ab Initio Study of Electronic and Electrochemistry Properties of the Tetranuclear Sandwich Complex [FeIII4(H2O)2(PW9O34)2]6-
Susanna Romo, Jorge A. Fernández, Joan Miquel Maestre, Bineta Keita, Louis Nadjo, Coen de Graaf, and Josep M. Poblet
pp 4022 - 4027; DOI:
10.1021/ic062030u
PDF
Au3SnP7@Black Phosphorus: An Easy Access to Black Phosphorus
Stefan Lange, Peer Schmidt, and Tom Nilges
pp 4028 - 4035; DOI:
10.1021/ic062192q
PDF
Varying Acidity of Aqua Ligands in Dependence on the Microenvironment in Mononucleobase (nb) Complexes of Type cis- and trans-[Pt(NH3)2(nb)(H2O)]n+
Patrick M. Lax, Marta Garijo Añorbe, Barbara Müller, Egla Yareth Bivián-Castro, and Bernhard Lippert
pp 4036 - 4043; DOI:
10.1021/ic062379h
PDF
In Search of Cyclohexane-like Sn612-: Synthesis of Li2Ln5Sn7 (Ln = Ce, Pr, Sm, Eu) with an Open-Chain Heptane-like Sn716- Instead
Iliya Todorov and Slavi C. Sevov
pp 4044 - 4048; DOI:
10.1021/ic062390h
PDF
Chloro Half-Sandwich Osmium(II) Complexes: Influence of Chelated N,N-Ligands on Hydrolysis, Guanine Binding, and Cytotoxicity
Anna F. A. Peacock, Abraha Habtemariam, Stephen A. Moggach, Alessandro Prescimone, Simon Parsons, and Peter J. Sadler
pp 4049 - 4059; DOI:
10.1021/ic062350d
PDF
Lanthanide Compounds with Fluorinated OC6F5 Ligands: Homo- and Heterovalent Complexes of Eu(II) and Eu(III)
Kieran Norton, Thomas J. Emge, and John G. Brennan
pp 4060 - 4066; DOI:
10.1021/ic062395e
PDF
Defects in Divided Zinc-Copper Aluminate Spinels: Structural Features and Optical Absorption Properties
Anne Le Nestour, Manuel Gaudon, Gérard Villeneuve, Marco Daturi, Ronn Andriessen, and Alain Demourgues
pp 4067 - 4078; DOI:
10.1021/ic0624064
PDF
Remarkable Steric Effects and Influence of Monodentate Axial Ligands L on the Spin-Crossover Properties of trans-[FeII(N4 ligand)L] Complexes
José Sánchez Costa, Kristian Lappalainen, Graham de Ruiter, Manuel Quesada, Jinkui Tang, Ilpo Mutikainen, Urho Turpeinen, C. Matthias Grunert, Philipp Gütlich, Hanane Zhor Lazar, Jean-François Létard, Patrick Gamez, and Jan Reedijk
pp 4079 - 4089; DOI:
10.1021/ic0624017
PDF
Synthesis and Structures of Bis(dithiolene)tungsten(IV,VI) Thiolate and Selenolate Complexes: Approaches to the Active Sites of Molybdenum and Tungsten Formate Dehydrogenases
Stanislav Groysman and R. H. Holm
pp 4090 - 4102; DOI:
10.1021/ic062441a
PDF
Nature of Cp*MoO2+ in Water and Intramolecular Proton-Transfer Mechanism by Stopped-Flow Kinetics and Density Functional Theory Calculations
Joo-Eun Jee, Aleix Comas-Vives, Chiara Dinoi, Gregori Ujaque, Rudi van Eldik, Agustí Lledós, and Rinaldo Poli
pp 4103 - 4113; DOI:
10.1021/ic062409g
PDF
Photomagnetic Properties of an Iron(II) Low-Spin Complex with an Unusually Long-Lived Metastable LIESST State
José Sánchez Costa, Cherif Balde, Chiara Carbonera, Dominique Denux, Alain Wattiaux, Cédric Desplanches, Jean-Pierre Ader, Philipp Gütlich, and Jean-François Létard
pp 4114 - 4119; DOI:
10.1021/ic062418p
PDF
Heterobimetallic Molecular Cages for the Deposition of Cu/Ti and Cu/Zn Mixed-Metal Oxides
Mazhar Hamid, Asif A. Tahir, Muhammad Mazhar, Matthias Zeller, and Allen D. Hunter
pp 4120 - 4127; DOI:
10.1021/ic0624470
PDF
Redox-Induced Solid-Solid Phase Transformation of TCNQ Microcrystals into Semiconducting Ni[TCNQ]2(H2O)2 Nanowire (Flowerlike) Architectures: A Combined Voltammetric, Spectroscopic, and Microscopic Study
Ayman Nafady and Alan M. Bond
pp 4128 - 4137; DOI:
10.1021/ic062470l
PDF
M2Ba2Sn6 (M =Yb, Ca): Metallic Zintl Phases with a Novel Tin Chain Substructure
Ming-Hui Ge and John D. Corbett
pp 4138 - 4144; DOI:
10.1021/ic070042p
PDF
Tetrakis(thiadiazole)porphyrazines. 5. Electrochemical and DFT/TDDFT Studies of the Free-Base Macrocycle and Its MgII, ZnII, and CuII Complexes
Maria Pia Donzello, Claudio Ercolani, Karl M. Kadish, Giampaolo Ricciardi, Angela Rosa, and Pavel A. Stuzhin
pp 4145 - 4157; DOI:
10.1021/ic070038d
PDF
Exceptional Self-Penetrating Networks Containing Unprecedented Quintuple-Stranded Molecular Braid, 9-Fold Meso Helices, and 17-Fold Interwoven Helices
Dong-Rong Xiao, Yang-Guang Li, En-Bo Wang, Lin-Lin Fan, Hai-Yan An, Zhong-Min Su, and Lin Xu
pp 4158 - 4166; DOI:
10.1021/ic070054a
PDF
Crystal Structures and in-Situ Formation Study of Mayenite Electrides
Luis Palacios, Ángeles G. De La Torre, Sebastián Bruque, Jose L. García-Muñoz, Santiago García-Granda, Denis Sheptyakov, and Miguel A. G. Aranda
pp 4167 - 4176; DOI:
10.1021/ic0700497
PDF
Three Novel Phases in the Sm-Co-Ga System. Syntheses, Crystal and Electronic Structures, and Electrical and Magnetic Properties
YongZhong Jia, Claude Belin, Monique Tillard, Laurence Lacroix-Orio, David Zitoun, and GuoHua Feng
pp 4177 - 4186; DOI:
10.1021/ic0700755
PDF
Dimerization Processes of Square Planar [PtII(tbpy)(dithiolato)]+ Radicals
József Sándor Pap, Flávio Luiz Benedito, Eberhard Bothe, Eckhard Bill, Serena DeBeer George, Thomas Weyhermüller, and Karl Wieghardt
pp 4187 - 4196; DOI:
10.1021/ic070130+
PDF
Iron(II) Complexes with Amide-Containing Macrocycles as Non-Heme Porphyrin Analogues
Ivan V. Korendovych, Olga P. Kryatova, William M. Reiff, and Elena V. Rybak-Akimova
pp 4197 - 4211; DOI:
10.1021/ic0701209
PDF
Comparative Study of Uranyl(VI) and -(V) Carbonato Complexes in an Aqueous Solution
Atsushi Ikeda, Christoph Hennig, Satoru Tsushima, Koichiro Takao, Yasuhisa Ikeda, Andreas C. Scheinost, and Gert Bernhard
pp 4212 - 4219; DOI:
10.1021/ic070051y
PDF
Modification of Spin Crossover Behavior through Solvent Assisted Formation and Solvent Inclusion in a Triply Interpenetrating Three-Dimensional Network
Matthias Bartel, Alina Absmeier, Guy N. L. Jameson, Franz Werner, Kenichi Kato, Masaki Takata, Roman Boca, Miki Hasegawa, Kurt Mereiter, Andrea Caneschi, and Wolfgang Linert
pp 4220 - 4229; DOI:
10.1021/ic070173q
PDF
Kinetics and Mechanism of the Photoinitiated Autoxidation of Sulfur(IV) in the Presence of Iodide Ion
Ildikó Kerezsi, Gábor Lente, and István Fábián
pp 4230 - 4238; DOI:
10.1021/ic061521b
PDF
Square-Planar N2S2NiII Complexes with an Extended -Conjugated System
Tatsuya Kawamoto, Kazunori Takeda, Masato Nishiwaki, Takashi Aridomi, and Takumi Konno
pp 4239 - 4247; DOI:
10.1021/ic0618246
PDF
Systematics and Anomalies in Rare Earth/Aluminum Bromide Vapor Complexes: Thermodynamic Properties of the Vapor Complexes LnAl3Br12 from Ln = Sc to Ln = Lu
Zhi-Chang Wang and Jin Yu
pp 4248 - 4255; DOI:
10.1021/ic061795z
PDF
Two-Dimensional Heisenberg Antiferromagnets: Syntheses, X-ray Structures, and Magnetic Behavior of [Cu(pz)2](ClO4)2, [Cu(pz)2](BF4)2, and [Cu(pz)2(NO3)](PF6)
F. Matthew Woodward, Pamela J. Gibson, Geoffrey B. Jameson, Christopher P. Landee, Mark M. Turnbull, and Roger D. Willett
pp 4256 - 4266; DOI:
10.1021/ic0621392
PDF
Phosphinic Platinum Complexes with 8-Thiotheophylline Derivatives: Synthesis, Characterization, and Antiproliferative Activity
P. Bergamini, V. Bertolasi, L. Marvelli, A. Canella, R. Gavioli, N. Mantovani, S. Mañas, and A. Romerosa
pp 4267 - 4276; DOI:
10.1021/ic062133c
PDF
Monocyclic Di- and Triphosphinophosphonium Cations: New Foundational Frameworks for catena-Phosphorus Chemistry
C. Adam Dyker, Neil Burford, Gabriel Menard, Michael D. Lumsden, and Andreas Decken
pp 4277 - 4285; DOI:
10.1021/ic0622499
PDF
Structural Study of Amorphous Tellurium(II) Halides TeCl2-xIx (x = 0.5, 0.1): X-ray Diffraction and Reverse Monte Carlo Simulations
Nikolay Zotov, Johannes Beck, Bärbel Knopp, and Armin Kirfel
pp 4286 - 4292; DOI:
10.1021/ic062307q
PDF
Oxygenation of Simple Zinc Alkyls: Surprising Dependence of Product Distributions on the Alkyl Substituents and the Presence of Water
Surajit Jana, Raphael J. F. Berger, Roland Fröhlich, Tania Pape, and Norbert W. Mitzel
pp 4293 - 4297; DOI:
10.1021/ic062438r
PDF
Oligonuclear Copper Complexes of a Bioinspired Pyrazolate-Bridging Ligand: Synthesis, Structures, and Equilibria in Solution
Angelina Prokofieva, Alexander I. Prikhod'ko, Eva Anna Enyedy, Etelka Farkas, Walter Maringgele, Serhiy Demeshko, Sebastian Dechert, and Franc Meyer
pp 4298 - 4307; DOI:
10.1021/ic062434m
PDF
Phosphorescent Iridium Complexes Based on 2-Phenylimidazo[1,2-a]pyridine Ligands: Tuning of Emission Color toward the Blue Region and Application to Polymer Light-Emitting Devices
Shin-ya Takizawa, Jun-ichi Nishida, Toshimitsu Tsuzuki, Shizuo Tokito, and Yoshiro Yamashita
pp 4308 - 4319; DOI:
10.1021/ic0624322
PDF
Alkaline Earth Metal Complexes of a Phosphine-Borane-Stabilized Carbanion: Synthesis, Structures, and Stabilities
Keith Izod, Corinne Wills, William Clegg, and Ross W. Harrington
pp 4320 - 4325; DOI:
10.1021/ic062459l
PDF
Studies Directed to Understanding the Structure of Chitosan-Metal Complexes: Investigations of Mono- and Disaccharide Models with Platinum(II) Group Metals
Sine A. Johannesen, Bent O. Petersen, Jens Ø. Duus, and Troels Skrydstrup
pp 4326 - 4335; DOI:
10.1021/ic070016r
PDF
1,4,7,10-Tetraazacyclododecane Metal Complexes as Potent Promoters of Carboxyester Hydrolysis under Physiological Conditions
Michael Subat, Kristina Woinaroschy, Stefan Anthofer, Barbara Malterer, and Burkhard König
pp 4336 - 4356; DOI:
10.1021/ic070101z
PDF
Polyhedral Cobalt(II) and Iron(II) Siloxanes: Synthesis and X-ray Crystal Structure of [(RSi(OH)O2)Co(OPMe3)]4 and [(RSiO3)2(RSi(OH)-O2)4-(3-OH)2Fe8(THF)4] (R = (2,6-iPr2C6H3)N(SiMe3))
Umesh N. Nehete, Herbert W. Roesky, Hongping Zhu, Sharanappa Nembenna, Hans-Georg Schmidt, MathiasNoltemeyer, Dmitrij Bogdanov, and Konrad Samwer:
pp 4357 - 4357; DOI:
10.1021/ic700481w
PDF
One-Step Redox Route to N-Heterocyclic Phosphenium Ions
Gregor Reeske,, Clint R. Hoberg, and, and Alan H. Cowley*:
pp 4358 - 4358; DOI:
10.1021/ic700556q
PDF

Issue 11


Has Monopotassium Phthalocyanine, KPc, Been Synthesized?
Julie A. Cissell and Thomas P. Vaid
pp 4360 - 4361; DOI:
10.1021/ic070254m
PDF
Kit for Unsymmetric Dinucleating Double-Schiff-Base Ligands: Facile Access to a Versatile New Ligand System and Its First Heterobimetallic Copper-Zinc Complex
Arne Roth, Eike T. Spielberg, and Winfried Plass
pp 4362 - 4364; DOI:
10.1021/ic070088i
PDF
A Rare Chiral Self-Catenated Network Formed by Two Cationic and One Anionic Frameworks
Shi-Shen Zhang, Shun-Ze Zhan, Mian Li, Rong Peng, and Dan Li
pp 4365 - 4367; DOI:
10.1021/ic070250h
PDF
Ternary Iron(III) Complex Showing Photocleavage of DNA in the Photodynamic Therapy Window
Mithun Roy, Sounik Saha, Ashis K. Patra, Munirathinam Nethaji, and Akhil R. Chakravarty
pp 4368 - 4370; DOI:
10.1021/ic062056l
PDF
Discovery, Synthesis, and Characterization of an Isomeric Coordination Polymer with Pillared Kagome Net Topology
Hyungphil Chun and Jumi Moon
pp 4371 - 4373; DOI:
10.1021/ic070036t
PDF
Group 12 Metal Complexes of [26]Hexaphyrin(1.1.1.1.1.1)
Shigeki Mori, Soji Shimizu, Ji-Young Shin, and Atsuhiro Osuka
pp 4374 - 4376; DOI:
10.1021/ic7004216
PDF
Alcohol Addition to Acetonitrile Activated by the [Re6(3-Se)8]2+ Cluster Core
Peter Orto, Hugh D. Selby, Daniel Ferris, Jenine R. Maeyer, and Zhiping Zheng
pp 4377 - 4379; DOI:
10.1021/ic7004985
PDF
Structure-Directing Effects in the Supramolecular Intercluster Compound [Au9(PPh3)8]2[V10O28H3]2: Long-Range versus Short-Range Bonding Interactions
Martin Schulz-Dobrick and Martin Jansen
pp 4380 - 4382; DOI:
10.1021/ic700434x
PDF
13-Tungstoborate Stabilized by an Organostannoxane Hexamer
Santiago Reinoso, Michael H. Dickman, Marius F. Matei, and Ulrich Kortz
pp 4383 - 4385; DOI:
10.1021/ic7004437
PDF
Anion Detection Driven by a Surprising Internal Hydrogen-Bonding Association in a Dinuclear Rhenium(I) Complex
Diane Pelleteret, Nicholas C. Fletcher, and Andrew P. Doherty
pp 4386 - 4388; DOI:
10.1021/ic700452k
PDF
[Mo16O53F2]12-: a New Polyoxofluoromolybdate Anion
Adam K. Stover, Jesse R. Gutnick, Amy Narducci Sarjeant, and Alexander J. Norquist
pp 4389 - 4391; DOI:
10.1021/ic7004997
PDF
Properties of the Polyhydride Anions [WH5(PMe2Ph)3]- and [ReH4(PMePh2)3]- and Periodic Trends in the Acidity of Polyhydride Complexes
Justin G. Hinman, Alan J. Lough, and Robert H. Morris
pp 4392 - 4401; DOI:
10.1021/ic062037b
PDF
Influence of pH and Counteranion on the Structure of Tropolonato-Lead(II) Complexes: Structural and Infrared Characterization of Formed Lead Compounds
Krzysztof Lyczko, Wojciech Starosta, and Ingmar Persson
pp 4402 - 4410; DOI:
10.1021/ic061561f
PDF
Analysis of Phase Transition Pathways in X3H(SO4)2 (X = Rb, NH4, K, Na): Variable Temperature Single-Crystal X-ray Diffraction Studies
Diptikanta Swain and Tayur N. Guru Row
pp 4411 - 4421; DOI:
10.1021/ic061901x
PDF
Fluorescent Detection of Nitroaromatics and 2,3-Dimethyl 2,3-dinitrobutane (DMNB) by a Zinc Complex: (salophen)Zn
Meaghan E. Germain, Thomas R. Vargo, Peter G. Khalifah, and Michael J. Knapp
pp 4422 - 4429; DOI:
10.1021/ic062012c
PDF
Structural Characterization of Molybdenum(V) Species in Aqueous HCl Solutions
Farideh Jalilehvand, Vicky Mah, Bonnie O. Leung, Daniel Ross, Masood Parvez, and Ricardo F. Aroca
pp 4430 - 4445; DOI:
10.1021/ic062047c
PDF
New BEDT-TTF/[Fe(C5O5)3]3- Hybrid System: Synthesis, Crystal Structure, and Physical Properties of a Chirality-Induced Phase and a Novel Magnetic Molecular Metal
Eugenio Coronado, Simona Curreli, Carlos Giménez-Saiz, Carlos J. Gómez-García, Paola Deplano, Maria Laura Mercuri, Angela Serpe, Luca Pilia, Christophe Faulmann, and Enric Canadell
pp 4446 - 4457; DOI:
10.1021/ic062152m
PDF
Magnetic Interactions in CuII-LnIII Cyclic Tetranuclear Complexes: Is It Possible to Explain the Occurrence of SMM Behavior in CuII-TbIII and CuII-DyIII Complexes?
Takefumi Hamamatsu, Kazuya Yabe, Masaaki Towatari, Shutaro Osa, Naohide Matsumoto, Nazzareno Re, Andrzej Pochaba, Jerzy Mrozinski, Jean-Louis Gallani, Alessandro Barla, Paolo Imperia, Carley Paulsen, and Jean-Paul Kappler
pp 4458 - 4468; DOI:
10.1021/ic062252s
PDF
First Example of the Solid-State Thermal Cyclometalation of Ligated Benzophenone Imine Giving Novel Luminescent Platinum(II) Species
Yulia Yu. Scaffidi-Domianello, Alexey A. Nazarov, Matti Haukka, Markus Galanski, Bernhard K. Keppler, Jacob Schneider, Pingwu Du, Richard Eisenberg, and Vadim Yu. Kukushkin
pp 4469 - 4482; DOI:
10.1021/ic062414k
PDF
Copper-Linked Hexaniobate Lindqvist Clusters-Variations on a Theme
Ranko P. Bontchev, Eugene L. Venturini, and May Nyman
pp 4483 - 4491; DOI:
10.1021/ic0624118
PDF
Comprehensive Molecular Mechanics Model for Oxidized Type I Copper Proteins: Active Site Structures, Strain Energies, and Entatic Bulging
Robert J. Deeth
pp 4492 - 4503; DOI:
10.1021/ic062399j
PDF
Molecular-Programmed Self-Assembly of Homo- and Heterometallic Penta- and Hexanuclear Coordination Compounds: Synthesis, Crystal Structures, and Magnetic Properties of Ladder-Type CuII2MIIx (M = Cu, Ni; x = 3, 4) Oxamato Complexes with CuII2 Metallacyclophane Cores
Emilio Pardo, Rafael Ruiz-García, Francesc Lloret, Miguel Julve, Joan Cano, Jorge Pasán, Catalina Ruiz-Pérez, Yasmine Filali, Lise-Marie Chamoreau, and Yves Journaux
pp 4504 - 4514; DOI:
10.1021/ic062453w
PDF
Metalation of Cyclic Pseudopeptidic Thiosulfinates with Ni(II) and Zn(II) after Ring Opening: A Mechanistic Investigation
Erwan Galardon, Emilie Bourles, Isabelle Artaud, Jean-Claude Daran, Pascal Roussel, and Alain Tomas
pp 4515 - 4522; DOI:
10.1021/ic062480m
PDF
Synthesis, Structure, and Properties of BaAl2Si2
Cathie L. Condron, Håkon Hope, Paula M. B. Piccoli, Arthur J. Schultz, and Susan M. Kauzlarich
pp 4523 - 4529; DOI:
10.1021/ic070078h
PDF
A Heterometallic Porous Material for Hydrogen Adsorption
Ying Wang, Peng Cheng, Jun Chen, Dai-Zheng Liao, and Shi-Ping Yan
pp 4530 - 4534; DOI:
10.1021/ic070097r
PDF
Diversity of New Structural Types in Polynuclear Iron Chemistry with a Tridentate N,N,O Ligand
Rashmi Bagai, Saiti Datta, Amalia Betancur-Rodriguez, Khalil A. Abboud, Stephen Hill, and George Christou
pp 4535 - 4547; DOI:
10.1021/ic070106w
PDF
Tuning the Selectivity/Specificity of Fluorescent Metal Ion Sensors Based on N2S2 Pyridine-Containing Macrocyclic Ligands by Changing the Fluorogenic Subunit: Spectrofluorimetric and Metal Ion Binding Studies
M. Carla Aragoni, Massimiliano Arca, Andrea Bencini, Alexander J. Blake, Claudia Caltagirone, Greta De Filippo, Francesco A. Devillanova, Alessandra Garau, Thomas Gelbrich, Michael B. Hursthouse, Francesco Isaia, Vito Lippolis, Marta Mameli, Palma Mariani, Barbara Valtancoli, and Claire Wilson
pp 4548 - 4559; DOI:
10.1021/ic070169e
PDF
Conserved Mechanism of Copper Binding and Transfer. A Comparison of the Copper-Resistance Proteins PcoC from Escherichia coli and CopC from Pseudomonas syringae
Karrera Y. Djoko, Zhiguang Xiao, David L. Huffman, and Anthony G. Wedd
pp 4560 - 4568; DOI:
10.1021/ic070107o
PDF
Combination of Lacunary Polyoxometalates and High-Nuclear Transition Metal Clusters under Hydrothermal Conditions. 3. Structure and Characterization of [Cu(enMe)2]2{[Cu(enMe)2(H2O)]2[Cu6(enMe)2(B-a-SiW9O34)2]}·4H2O
Shou-Tian Zheng, Da-Qiang Yuan, Jie Zhang, and Guo-Yu Yang
pp 4569 - 4574; DOI:
10.1021/ic070160c
PDF
Influence of Oxygen Defects on the Crystal Structure and Magnetic Properties of the (Tb1-xNax)MnO3-y (0 x 0.3) System
T. S. Chan, R. S. Liu, C. C. Yang, W.-H. Li, Y. H. Lien, C.Y. Huang, Jeff. W. Lynn, J. M. Chen, and H.-S. Sheu
pp 4575 - 4582; DOI:
10.1021/ic070190f
PDF
Rich Pseudopolymorphic Behavior of the Tetranuclear [Ni4(dpyatriz)2(NO3)8] Complex
Hélène Casellas, Olivier Roubeau, Simon J. Teat, Norberto Masciocchi, Simona Galli, Angelo Sironi, Patrick Gamez, and Jan Reedijk
pp 4583 - 4591; DOI:
10.1021/ic0702015
PDF
Transformation of AeIn4 Indides (Ae = Ba, Sr) into an AeAu2In2 Structure Type Through Gold Substitution
Jing-Cao Dai and John D. Corbett
pp 4592 - 4598; DOI:
10.1021/ic070142v
PDF
Three-Coordinated Aminotroponiminate and Aminotroponate Complexes of Gold(I)
Jenni Meiners, Jost-Steffen Herrmann, and Peter W. Roesky
pp 4599 - 4604; DOI:
10.1021/ic0701662
PDF
Addition of Pt(PBut3) to Osmium-Tin Cluster Complexes
Richard D. Adams, Burjor Captain, and Lei Zhu
pp 4605 - 4611; DOI:
10.1021/ic070261a
PDF
Influence of Chelate Substituents on the Structure and Spin State of Unsaturated [N(SiMe2CH2PtBu2)2]Ru-X
Xiaofan Yang, Amy Walstrom, Nikolay Tsvetkov, Maren Pink, and Kenneth G. Caulton
pp 4612 - 4616; DOI:
10.1021/ic070283x
PDF
Zero to Three Dimensional Increase of Silver(I) Coordination Assemblies Controlled by Deprotonation of 1,3,5-Tri(2-benzimidazolyl)benzene and Aggregation of Multinuclear Building Units
Xiang-Ping Li, Jian-Yong Zhang, Mei Pan, Sheng-Run Zheng, Yu Liu, and Cheng-Yong Su
pp 4617 - 4625; DOI:
10.1021/ic070309k
PDF
Hydrogen-Bonded Metal-Complex Sulfonate (MCS) Inclusion Compounds: Effect of the Guest Molecule on the Host Framework
Xin-Yi Wang, Rachelle Justice, and Slavi C. Sevov
pp 4626 - 4631; DOI:
10.1021/ic070324p
PDF
Combined Experimental and Theoretical Study on Aromatic Hydroxylation by Mononuclear Nonheme Iron(IV)-Oxo Complexes
Sam P. de Visser, Kyungeun Oh, Ah-Rim Han, and Wonwoo Nam
pp 4632 - 4641; DOI:
10.1021/ic700462h
PDF
Metal-Metal Bonding in Tetracyanometalates (M = PtII, PdII, NiII) of Monovalent Thallium. Crystallographic and Spectroscopic Characterization of the New Compounds Tl2Ni(CN)4 and Tl2Pd(CN)4
Mikhail Maliarik, Jeffrey K. Nagle, Andrey Ilyukhin, Elena Murashova, János Mink, Mikhail Skripkin, Julius Glaser, Margit Kovacs, and Attila Horváth
pp 4642 - 4653; DOI:
10.1021/ic062092k
PDF
1D and 2D End-to-End Azide-Bridged Cobalt(II) Complexes: Syntheses, Crystal Structures, and Magnetic Properties
Morsy A. M. Abu-Youssef, Franz A. Mautner, and Ramon Vicente
pp 4654 - 4659; DOI:
10.1021/ic0622297
PDF
New Functional Model Complexes of Intradiol-Cleaving Catechol Dioxygenases: Properties and Reactivity of CuII(L)(O2Ncat)
József Kaizer, Zoltán Zsigmond, Ildikó Ganszky, Gábor Speier, Michel Giorgi, and Marius Réglier
pp 4660 - 4666; DOI:
10.1021/ic062309a
PDF
Solid-State Structures and Solution Studies of Novel Cyclopentadienyl Mercury Compounds
Abdessamad Grirrane, Irene Resa, Diego del Río, Amor Rodríguez, Eleuterio Álvarez, Kurt Mereiter, and Ernesto Carmona
pp 4667 - 4676; DOI:
10.1021/ic0624672
PDF
Synthesis and Structures of Mo3Se7Te2Br10, Mo3Se7TeI6, and Mo6Te21I22 Containing TeX3- (X = Br, I) Ligands Coordinated to a Triangular Cluster Core
Maxim N. Sokolov, Artem L. Gushchin, Pavel A. Abramov, Alexander V. Virovets, Eugenia V. Peresypkina, and Vladimir P. Fedin
pp 4677 - 4682; DOI:
10.1021/ic0700553
PDF
Solvation Effects on the Stability of Silver(I) Complexes with Pyridine-Containing Ligands Studied by Thermodynamic and DFT Methods
Silvia Del Piero, Rosalisa Fedele, Andrea Melchior, Roberto Portanova, Marilena Tolazzi, and Ennio Zangrando
pp 4683 - 4691; DOI:
10.1021/ic070124d
PDF
Formation of New Halogenothiocarbonylsulfenyl Halides, XC(S)SY, through Photochemical Matrix Reactions Starting from CS2 and a Dihalogen Molecule XY (XY = Cl2, Br2, or BrCl)
Yeny A. Tobón, Rosana M. Romano, Carlos O. Della Védova, and Anthony J. Downs
pp 4692 - 4703; DOI:
10.1021/ic070119+
PDF
Chemistry and Stereochemistry of the Interaction of the Water-Soluble Phosphine [HO(CH2)3]3P with Cinnamaldehyde in Aqueous Media
Dmitry V. Moiseev, Brian R. James, and Thomas Q. Hu
pp 4704 - 4712; DOI:
10.1021/ic0701559
PDF
Synthesis, Characterization, and Photoluminescence Property of LaCO3OH Microspheres
Youjin Zhang, Kaidong Han, Tao Cheng, and Zhiyong Fang
pp 4713 - 4717; DOI:
10.1021/ic0701458
PDF
Synthesis, Structure, and Luminescence of Di- and Trinuclear Palladium/Gold and Platinum/Gold Complexes with (2,7-Di-tert-butylfluoren-9-ylidene)methanedithiolate
José Vicente, Pablo González-Herrero, María Pérez-Cadenas, Peter G. Jones, and Delia Bautista
pp 4718 - 4732; DOI:
10.1021/ic070164h
PDF
A Novel Asymmetric Hydroarsination Reaction Promoted by a Chiral Organopalladium Complex
Maricar L. Bungabong, Kien Wee Tan, Yongxin Li, Selvasothi V. Selvaratnam, Krishna G. Dongol, and Pak-Hing Leung
pp 4733 - 4736; DOI:
10.1021/ic0701561
PDF
A New Branched Phenanthroline Derivative Ligand: Synthesis, Solution Chemistry, and Crystal Structures of Copper(II) and Zinc(II) Complexes
Gianluca Ambrosi, Mauro Formica, Vieri Fusi, Luca Giorgi, Annalisa Guerri, Mauro Micheloni, Paola Paoli, Roberto Pontellini, and Patrizia Rossi
pp 4737 - 4748; DOI:
10.1021/ic070184j
PDF
Metal-Ion Selectivity Produced by C-Alkyl Substituents on the Bridges of Chelating Ligands: The Importance of Short H-H Nonbonded van der Waals Contacts in Controlling Metal-Ion Selectivity. A Thermodynamic, Molecular Mechanics, and Crystallographic Study
Robert D. Hancock, Alvaro S. de Sousa, George B. Walton, and Joseph H. Reibenspies
pp 4749 - 4757; DOI:
10.1021/ic070239h
PDF
Platinum Complex as a Nanomolar Protein Kinase Inhibitor
Douglas S. Williams, Patrick J. Carroll, and Eric Meggers:
pp 4758 - 4758; DOI:
10.1021/ic700732n
PDF

Issue 12


Photobiological Impact of [{(bpy)2Ru(dpp)}2RhCl2]Cl5 and [{(bpy)2Os(dpp)}2RhCl2]Cl5 [bpy = 2,2'-Bipyridine; dpp = 2,3-Bis(2-pyridyl)pyrazine] on Vero Cells
Alvin A. Holder, David F. Zigler, Maria T. Tarrago-Trani, Brian Storrie, and Karen J. Brewer
pp 4760 - 4762; DOI:
10.1021/ic0619916
PDF
Rational Design of a Covalently Tethered Dinuclear [MnII(N3O2)Cl(OH2)]22+ Macrocyclic Building Block: Synthesis, Structure, and Magnetic Properties
Jian Wang, Brianna Slater, Antonio Alberola, Helen Stoeckli-Evans, Fereidoon S. Razavi, and Melanie Pilkington
pp 4763 - 4765; DOI:
10.1021/ic062212o
PDF
Prepared Chiral Nanorods of a Cobalt(II) Porphyrin Dimer and Studied Changes of UV-Vis and CD Spectra with Aggregate Morphologies under Different Temperatures
Xi ming Guo, Chang Jiang, and Tong Shun Shi
pp 4766 - 4768; DOI:
10.1021/ic0622149
PDF
Encapsulation of Halides within the Cavity of a Pentafluorophenyl-Substituted Tripodal Amine Receptor
P. S. Lakshminarayanan, I. Ravikumar, E. Suresh, and Pradyut Ghosh
pp 4769 - 4771; DOI:
10.1021/ic062380g
PDF
Square-Pyramidal/Triangular Framework Oxide: Synthesis and Structure of PKU-6
Tao Yang, Jing Ju, Guobao Li, Fuhui Liao, Xiaodong Zou, Feng Deng, Lei Chen, Yingxia Wang, and Jianhua Lin
pp 4772 - 4774; DOI:
10.1021/ic070073k
PDF
Unprecedented Eight-Connected Self-catenated Network Based on Heterometallic {Cu4V4O12} Clusters as Nodes
Xiaoshu Qu, Lin Xu, Guanggang Gao, Fengyan Li, and Yanyan Yang
pp 4775 - 4777; DOI:
10.1021/ic070114c
PDF
Synthesis, Characterization, and Optical Properties of In2O3 Semiconductor Nanowires
Guoxiu Wang, Jinsoo Park, David Wexler, Min Sik Park, and Jung-Ho Ahn
pp 4778 - 4780; DOI:
10.1021/ic700386z
PDF
Zinc-Porphyrin Phosphonate Coordination: Structural Control through a Zinc Phosphoryl-Oxygen Interaction
David L. Officer, Fabio Lodato, and Kenneth W. Jolley
pp 4781 - 4783; DOI:
10.1021/ic070344r
PDF
Mo and W Dihalide Complexes with Uncommon Trigonal-Prismatic Geometry Imposed by the Linear Tetraphosphine Ancillary Ligand and Their Reactivities toward Diazoalkanes
Hidetake Seino, Daisuke Watanabe, Takeshi Ohnishi, Chirima Arita, and Yasushi Mizobe
pp 4784 - 4786; DOI:
10.1021/ic700371b
PDF
Colloidal Unilamellar Layers of Tantalum Oxide with Open Channels
Katsutoshi Fukuda, Izumi Nakai, Yasuo Ebina, Renzhi Ma, and Takayoshi Sasaki
pp 4787 - 4789; DOI:
10.1021/ic7004002
PDF
Palladium Complexes of Perylene Diimides: Strong Fluorescence Despite Direct Attachment of Late Transition Metals to Organic Dyes
Haim Weissman, Elijah Shirman, Tal Ben-Moshe, Revital Cohen, Gregory Leitus, Linda J. W. Shimon, and Boris Rybtchinski
pp 4790 - 4792; DOI:
10.1021/ic700539b
PDF
Crystal Structures of Poly(aryl ether) Dendrons with Palladium Scorpionate Complexes at Their Focal Point
Alberto Sánchez-Méndez, Ernesto de Jesús, Juan C. Flores, and Pilar Gómez-Sal
pp 4793 - 4795; DOI:
10.1021/ic7005748
PDF
Optimized Relaxivity and Stability of [Gd(H(2,2)-1,2-HOPO)(H2O)]- for Use as an MRI Contrast Agent1
Christoph J. Jocher, Mauro Botta, Stefano Avedano, Evan G. Moore, Jide Xu, Silvio Aime, and Kenneth N. Raymond
pp 4796 - 4798; DOI:
10.1021/ic700399p
PDF
Group 4 Transition Metal CH2=MF2, CHF=MF2, and HCMF3 Complexes Formed by C-F Activation and -Fluorine Transfer
Jonathan T. Lyon and Lester Andrews
pp 4799 - 4808; DOI:
10.1021/ic061701l
PDF
Synthesis and Characterization of Low-Coordinate Divalent Aryl Transition-Metal Halide Analogues of Grignard Reagents: Precursors for Reduction to Metal-Metal-Bonded Complexes
Andrew D. Sutton, Tailuan Ngyuen, James C. Fettinger, Marilyn M. Olmstead, Gary J. Long, and Philip P. Power
pp 4809 - 4814; DOI:
10.1021/ic061121o
PDF
Uranyl Coordination in Ionic Liquids: The Competition between Ionic Liquid Anions, Uranyl Counterions, and Cl- Anions Investigated by Extended X-ray Absorption Fine Structure and UV-Visible Spectroscopies and Molecular Dynamics Simulations
C. Gaillard, A. Chaumont, I. Billard, C. Hennig, A. Ouadi, and G. Wipff
pp 4815 - 4826; DOI:
10.1021/ic061864+
PDF
Electrospray Ionization Mass Spectrometry of a Novel Family of Complexes in which Various Nitroso Compounds are Stabilized via Coordination to [IrCl5]2-
Natalia Escola, Florencia Di Salvo, Renato Haddad, Laura Perissinotti, Marcos Nogueira Eberlin, and Fabio Doctorovich
pp 4827 - 4834; DOI:
10.1021/ic061388n
PDF
Structure and Stability of VO2+ in Aqueous Solution: A Car-Parrinello and Static ab Initio Study
Aymeric Sadoc, Sabri Messaoudi, Eric Furet, Régis Gautier, Eric Le Fur, Laurent le Pollès, and Jean-Yves Pivan
pp 4835 - 4843; DOI:
10.1021/ic0614519
PDF
Multiple Bismuth(III)-Thioether Secondary Interactions Integrate Metalloporphyrin Ligands into Functional Networks
Kunhao Li, Guo Huang, Zhengtao Xu, Mingliang Zhang, Matthias Zeller, Allen D. Hunter, Stephen Sin-Yin Chui, Chi-Ming Che, and Wai-Yeung Wong
pp 4844 - 4849; DOI:
10.1021/ic061711m
PDF
Theoretical Investigation of the First-Shell Mechanism of Nitrile Hydratase
Kathrin H. Hopmann, Jing-Dong Guo, and Fahmi Himo
pp 4850 - 4856; DOI:
10.1021/ic061894c
PDF
Carbon-Fluorine Bond Cleavage in the Preparation of Osmium(III) and Osmium(IV) Fluorothiolate Complexes. Fluorine by Fluorine NMR-Assignment and Fluxional Processes
Maribel Arroyo, Sylvain Bernès, Margarita Cerón, Verónica Cortina, Consuelo Mendoza, and Hugo Torrens
pp 4857 - 4867; DOI:
10.1021/ic0619660
PDF
A Structural and Theoretical Investigation of Equatorial cis and trans Uranyl Phosphinimine and Uranyl Phosphine Oxide Complexes UO2Cl2(Cy3PNH)2 and UO2Cl2(Cy3PO)2
L. Jonas L Häller, Nikolas Kaltsoyannis, Mark J. Sarsfield, Iain May, Stéphanie M. Cornet, Michael P. Redmond, and Madeleine Helliwell
pp 4868 - 4875; DOI:
10.1021/ic062031m
PDF
Dynamic Axial Ligand-Site Exchange in Facially Discriminated Ruthenium(II) Carbonyl and Rhodium(III) Halide Metalloporphyrins
Maxwell J. Gunter and Kathleen M. Mullen
pp 4876 - 4886; DOI:
10.1021/ic062112i
PDF
Hydrothermal and Structural Chemistry of the Zinc(II)- and Cadmium(II)-1,2,4-Triazolate Systems
Wayne Ouellette, Bruce S. Hudson, and Jon Zubieta
pp 4887 - 4904; DOI:
10.1021/ic062269a
PDF
Origin of the Zero-Field Splitting in Mononuclear Octahedral Dihalide MnII Complexes: An Investigation by Multifrequency High-Field Electron Paramagnetic Resonance and Density Functional Theory
Carole Duboc, Thida Phoeung, Samir Zein, Jacques Pécaut, Marie-Noëlle Collomb, and Frank Neese
pp 4905 - 4916; DOI:
10.1021/ic062384l
PDF
Infrared Spectrum and Bonding in Uranium Methylidene Dihydride, CH2=UH2
Jonathan T. Lyon, Lester Andrews, Per-Åke Malmqvist, Björn O. Roos, Tianxiao Yang, and Bruce E. Bursten
pp 4917 - 4925; DOI:
10.1021/ic062407w
PDF
fac-[Re(CO)3(H2O)3]+ Nucleoside Monophosphate Adducts Investigated in Aqueous Solution by Multinuclear NMR Spectroscopy
Kristie M. Adams and Luigi G. Marzilli
pp 4926 - 4936; DOI:
10.1021/ic062410f
PDF
Isolated Heterometallic Cr7Ni Rings Grafted on Au(111) Surface
Valdis Corradini, Roberto Biagi, Umberto del Pennino, Valentina De Renzi, Alessandro Gambardella, Marco Affronte, Christopher A. Muryn, Grigore A. Timco, and Richard E. P. Winpenny
pp 4937 - 4943; DOI:
10.1021/ic0624266
PDF
Controlled Copper-Mediated Chlorination of Phenol Rings under Mild Conditions
Yu-Fei Song, Gerard A. van Albada, Jinkui Tang, Ilpo Mutikainen, Urho Turpeinen, Chiara Massera, Olivier Roubeau, José Sanchez Costa, Patrick Gamez, and Jan Reedijk
pp 4944 - 4950; DOI:
10.1021/ic070057n
PDF
External Magnetic Field-Induced Mesoscopic Organization of Fe3O4 Pyramids and Carbon Sheets
S. V. Pol, V. G. Pol, A. Gedanken, I. Felner, M-G Sung, and S. Asai
pp 4951 - 4959; DOI:
10.1021/ic070108g
PDF
Naphthylimido-Substituted Hexamolybdate: Preparation, Crystal Structures, Solvent Effects, and Optical Properties of Three Polymorphs
Jian Hao, Laurent Ruhlmann, Yulin Zhu, Qiang Li, and Yongge Wei
pp 4960 - 4967; DOI:
10.1021/ic070064b
PDF
1,2,3-Triazolate-Bridged Tetradecametallic Transition Metal Clusters [M14(L)6O6(OMe)18X6] (M = FeIII, CrIII and VIII/IV) and Related Compounds: Ground-State Spins Ranging from S = 0 to S = 25 and Spin-Enhanced Magnetocaloric Effect
Rachel Shaw, Rebecca H. Laye, Leigh F. Jones, David M. Low, Caytie Talbot-Eeckelaers, Qiang Wei, Constantinos J. Milios, Simon Teat, Madeleine Helliwell, James Raftery, Marco Evangelisti, Marco Affronte, David Collison, Euan K. Brechin, and Eric J. L. McInnes
pp 4968 - 4978; DOI:
10.1021/ic070320k
PDF
Dinuclear RuIIPHEHAT and -TPAC Complexes: Effects of the Second RuII Center on Their Spectroelectrochemical Properties
Benjamin Elias, Leslie Herman, Cécile Moucheron, and Andrée Kirsch-De Mesmaeker
pp 4979 - 4988; DOI:
10.1021/ic070224j
PDF
Sulfur K-Edge XAS and DFT Studies on NiII Complexes with Oxidized Thiolate Ligands: Implications for the Roles of Oxidized Thiolates in the Active Sites of Fe and Co Nitrile Hydratase
Abhishek Dey, Stephen P. Jeffery, Marcetta Darensbourg, Keith O. Hodgson, Britt Hedman, and Edward I. Solomon
pp 4989 - 4996; DOI:
10.1021/ic070244l
PDF
Fast O2 Binding at Dicopper Complexes Containing Schiff-Base Dinucleating Ligands
Anna Company, Laura Gómez, Rubén Mas-Ballesté, Ivan V. Korendovych, Xavi Ribas, Albert Poater, Teodor Parella, Xavier Fontrodona, Jordi Benet-Buchholz, Miquel Solà, Lawrence Que, Jr., Elena V. Rybak-Akimova, and Miquel Costas
pp 4997 - 5012; DOI:
10.1021/ic0701108
PDF
Control of Electronic and Magnetic Coupling via Bridging Ligand Geometry in a Bimetallic Ytterbocene Complex
Christin N. Carlson, Brian L. Scott, Richard L. Martin, Joe D. Thompson, David E. Morris, and Kevin D. John
pp 5013 - 5022; DOI:
10.1021/ic0702973
PDF
Osmium NAMI-A Analogues: Synthesis, Structural and Spectroscopic Characterization, and Antiproliferative Properties
Berta Cebrián-Losantos, Artem A. Krokhin, Iryna N. Stepanenko, Rene Eichinger, Michael A. Jakupec, Vladimir B. Arion, and Bernhard K. Keppler
pp 5023 - 5033; DOI:
10.1021/ic700405y
PDF
Synthesis and Structural Characterization of C(OTeF5)4 and a Comparative Structural Study of the Isoelectronic B(OTeF5)4- Anion
Matthew D. Moran, Hélène P. A. Mercier, and Gary J. Schrobilgen
pp 5034 - 5045; DOI:
10.1021/ic700362g
PDF
Construction of Ag/1,2,4-Triazole/Polyoxometalates Hybrid Family Varying from Diverse Supramolecular Assemblies to 3-D Rod-Packing Framework
Quan-Guo Zhai, Xiao-Yuan Wu, Shu-Mei Chen, Zhen-Guo Zhao, and Can-Zhong Lu
pp 5046 - 5058; DOI:
10.1021/ic700415w
PDF
Dual Triggering of DNA Binding and Fluorescence via Photoactivation of a Dinuclear Ruthenium(II) Arene Complex
Steven W. Magennis, Abraha Habtemariam, Olga Novakova, John B. Henry, Samuel Meier, Simon Parsons, Iain D. H. Oswald, Viktor Brabec, and Peter J. Sadler
pp 5059 - 5068; DOI:
10.1021/ic062111q
PDF
Simple General Method of Generating Non-oxo, Non-amavadine Model Octacoordinated Vanadium(IV) Complexes of Some Tetradentate ONNO Chelating Ligands from Various Oxovanadium(IV/V) Compounds and Structural Characterization of One of Them
Manas Sutradhar, Gurunath Mukherjee, Michael G. B. Drew, and Saktiprosad Ghosh
pp 5069 - 5075; DOI:
10.1021/ic062242r
PDF
Triplet State Properties of the OLED Emitter Ir(btp)2(acac): Characterization by Site-Selective Spectroscopy and Application of High Magnetic Fields
Walter J. Finkenzeller, Thomas Hofbeck, Mark E. Thompson, and Hartmut Yersin
pp 5076 - 5083; DOI:
10.1021/ic0622860
PDF
Compositional Effects in Ru, Pd, Pt, and Rh-Doped Mesoporous Tantalum Oxide Catalysts for Ammonia Synthesis
Chaoyang Yue, Longhui Qiu, Michel Trudeau, and David Antonelli
pp 5084 - 5092; DOI:
10.1021/ic062385d
PDF
Single-Phase Titania Nanocrystallites and Nanofibers from Titanium Tetrachloride in Acetone and Other Ketones
Yu Wu, Hong-Mei Liu, Bo-Qing Xu, Zao-Li Zhang, and Dang-Sheng Su
pp 5093 - 5099; DOI:
10.1021/ic070199h
PDF
Cyclopalladation of the Prochiral (Di-tert-butyl)(diphenylmethyl)phosphine: Kinetic Lability of the Corresponding (+)-Phosphapalladacyclic Pd-C Bond and the Reluctance of the Phosphine to Bind in a Monodentate Fashion
Joseph Kok-Peng Ng, Shuli Chen, Yongxin Li, Geok-Kheng Tan, Lip-Lin Koh, and Pak-Hing Leung
pp 5100 - 5109; DOI:
10.1021/ic0702320
PDF
Dinitrosyl Iron Complexes (DNICs) Containing S/N/O Ligation: Transformation of Roussin's Red Ester into the Neutral {Fe(NO)2}10 DNICs
Ming-Li Tsai, Chung-Hung Hsieh, and Wen-Feng Liaw
pp 5110 - 5117; DOI:
10.1021/ic0702567
PDF
Syntheses and Structures of Alkaline Earth Metal Bis(diphenylamides)
Martin Gärtner, Reinald Fischer, Jens Langer, Helmar Görls, Dirk Walther, and Matthias Westerhausen
pp 5118 - 5124; DOI:
10.1021/ic700459d
PDF
Structural and Magnetic Properties of Layered Copper(II) Coordination Polymers Intercalating s and f Metal Ions
Jorge A. R. Navarro,*, Elisa Barea,, Juan M. Salas,, NorbertoMasciocchi,, Simona Galli,* and, and Angelo Sironi:
pp 5125 - 5125; DOI:
10.1021/ic700896j
PDF
Olefin Epoxidation by Alkyl Hydroperoxide with a Novel Cross-Bridged Cyclam Manganese Complex: Demonstration of Oxygenation by Two Distinct Reactive Intermediates
Guochuan Yin, Andrew M. Danby, David Kitko, John D. Carter, William M. Scheper, and Daryle H. Busch:
pp 5125 - 5126; DOI:
10.1021/ic700886v
PDF
Polyhedral Cobalt(II) and Iron(II) Siloxanes: Synthesis and X-ray Crystal Structure of [(RSi(OH)O2)Co(OPMe3)]4 and [(RSiO3)2-(RSi(OH)O2)4(3-OH)2Fe8(THF)4] (R = (2,6-iPr2C6H3)N(SiMe3)).
Umesh N. Nehete, Herbert W. Roesky, Hongping Zhu, Sharanappa Nembenna, Hans-Georg Schmidt, MathiasNoltemeyer, Dmitrij Bogdanov, andKonrad Samwer:, and K. Samwer
pp 5126 - 5126; DOI:
10.1021/ic700750r
PDF
Iron-Only Hydrogenase Mimics. Thermodynamics Aspects of the Use of Electrochemistry to Evaluate Catalytic Efficiency for Hydrogen Generation
Greg A. N. Felton, Richard S. Glass, Dennis L. Lichtenberger, and Dennis H. Evans
pp 5126 - 5126; DOI:
10.1021/ic700847c
PDF

Issue 13


Phenolate- and Acetate (Both 2-1,1 and 2-1,3 Mode)-Bridged Face-Shared Trioctahedral Linear NiII3, NiII2MII (M = Mn, Co) Complexes: Ferro- and Antiferromagnetic Coupling
Anuj Kumar Sharma, Francesc Lloret, and Rabindranath Mukherjee
pp 5128 - 5130; DOI:
10.1021/ic0623157
PDF
Reversible, Electrochemically Controlled Binding of Phosphine to Iron and Cobalt Bis(dithiolene) Complexes
Rongmin Yu, Kuppuswamy Arumugam, Ashok Manepalli, Yvon Tran, Russell Schmehl, Heiko Jacobsen, and James P. Donahue
pp 5131 - 5133; DOI:
10.1021/ic0624569
PDF
Ferromagnetic vs Antiferromagnetic Coupling in Bis(-phenoxo)dicopper(II) Complexes. Tuning of the Nature of Exchange Coupling by Remote Ligand Substituents
Phalguni Chaudhuri, Rita Wagner, and Thomas Weyhermüller
pp 5134 - 5136; DOI:
10.1021/ic070238p
PDF
Design and Structure Analysis of Artificial Metalloproteins: Selective Coordination of His64 to Copper Complexes with Square-Planar Structure in the apo-Myoglobin Scaffold
Satoshi Abe, Takafumi Ueno, Pattubala A. N. Reddy, Seiji Okazaki, Tatsuo Hikage, Atsuo Suzuki, Takashi Yamane, Hiroshi Nakajima, and Yoshihito Watanabe
pp 5137 - 5139; DOI:
10.1021/ic070289m
PDF
Linear Trinuclear Mixed-Metal CoII-GdIII-CoII Single-Molecule Magnet: [L2Co2Gd][NO3]·2CHCl3 (LH3 = (S)P[N(Me)N=CH-C6H3-2-OH-3-OMe]3)
Vadapalli Chandrasekhar, Balasubramanian Murugesa Pandian, Ramachandran Azhakar, Jagadese J. Vittal, and Rodolphe Clérac
pp 5140 - 5142; DOI:
10.1021/ic070321c
PDF
Redox Behavior of Cyclo[6]pyrrole in the Formation of a Uranyl Complex
Patricia J. Melfi, Sung Kuk Kim, Jeong Tae Lee, Frédéric Bolze, Daniel Seidel, Vincent M. Lynch, Jacqueline M. Veauthier, Andrew J. Gaunt, Mary P. Neu, Zhongping Ou, Karl M. Kadish, Shunichi Fukuzumi, Kei Ohkubo, and Jonathan L. Sessler
pp 5143 - 5145; DOI:
10.1021/ic700781t
PDF
Plasma-Assisted Synthesis and Properties of Na3N
Grigori V. Vajenine
pp 5146 - 5148; DOI:
10.1021/ic700406q
PDF
Quasi-Thermoneutral P B Interactions within Di- and Tri-Phosphine Boranes
Sébastien Bontemps, Ghenwa Bouhadir, Philip W. Dyer, Karinne Miqueu, and Didier Bourissou
pp 5149 - 5151; DOI:
10.1021/ic7006556
PDF
Use of Calix[4]arenes in the Redox Chemistry of Lanthanides: the Reduction of Dinitrogen by a Calix[4]arene-Samarium Complex
Geoffroy Guillemot, Barbara Castellano, Thierry Prangé, Euro Solari, and Carlo Floriani
pp 5152 - 5154; DOI:
10.1021/ic700787d
PDF
Systematic Investigation of Trigonal-Bipyramidal Cyanide-Bridged Clusters of the First-Row Transition Metals
Mikhail Shatruk, Kristen E. Chambers, Andrey V. Prosvirin, and Kim R. Dunbar
pp 5155 - 5165; DOI:
10.1021/ic061856t
PDF
Electronic Ground State and the d-d Transitions in Bis(biuretato)cobaltate(III) Ions
Sven E. Harnung and Erik Larsen
pp 5166 - 5173; DOI:
10.1021/ic061519k
PDF
Synthesis, Structure, and Luminescent and Magnetic Properties of Novel Lanthanide Metal-Organic Frameworks with Zeolite-like Topology
Zhongyue Li, Guangshan Zhu, Xiaodan Guo, Xiaojun Zhao, Zhao Jin, and Shilun Qiu
pp 5174 - 5178; DOI:
10.1021/ic061666i
PDF
Indium Hydroxides, Oxyhydroxides, and Oxides Nanocrystals Series
Zhongbin Zhuang, Qing Peng, Junfeng Liu, Xun Wang, and Yadong Li
pp 5179 - 5187; DOI:
10.1021/ic061999f
PDF
BN-Analogues of Vinylidene Transition Metal Complexes: The Borylnitrene Isomer
Holger F. Bettinger
pp 5188 - 5195; DOI:
10.1021/ic0622104
PDF
Coordination Mode of Nitrate in Uranyl(VI) Complexes: A First-Principles Molecular Dynamics Study
Michael Bühl, Romain Diss, and Georges Wipff
pp 5196 - 5206; DOI:
10.1021/ic0622555
PDF
Structure Determination of Novel Orthoborate NaMgBO3: A Promising Birefringent Crystal
L. Wu, Y. Zhang, Y. F. Kong, T. Q. Sun, J. J. Xu, and X. L. Chen
pp 5207 - 5211; DOI:
10.1021/ic062429i
PDF
Oxidation of Tertiary Silanes by Osmium Tetroxide
Karine Valliant-Saunders, Erica Gunn, G. Robert Shelton, David A. Hrovat, Weston Thatcher Borden, and James M. Mayer
pp 5212 - 5219; DOI:
10.1021/ic062468u
PDF
Synthesis and Structural Studies of NCN Diimine Palladium Pincer Complexes Bearing m-Terphenyl Scaffolds
Liqing Ma, Philip M. Imbesi, James B. Updegraff III, Allen D. Hunter, and John D. Protasiewicz
pp 5220 - 5228; DOI:
10.1021/ic062476a
PDF
Synthesis and Characterization of Four Metal-Organophosphonates with One-, Two-, and Three-Dimensional Structures
Sanjit Konar, Jerzy Zo, Andrey V. Prosvirin, Kim R. Dunbar, and Abraham Clearfield
pp 5229 - 5236; DOI:
10.1021/ic070132u
PDF
Remarkable Changes in the Optical Properties of CeO2 Nanocrystals Induced by Lanthanide Ions Doping
Zhenling Wang, Zewei Quan, and Jun Lin
pp 5237 - 5242; DOI:
10.1021/ic0701256
PDF
Complexes of Aminosquarate Ligands with First-Row Transition Metals and Lanthanides: New Insights into Their Hydrolysis
Patrice M. T. Piggot, Shireen Seenarine, and Lincoln A. Hall
pp 5243 - 5251; DOI:
10.1021/ic070188o
PDF
Selective Reaction Based on the Linked Diamido Ligands of Dinuclear Lanthanide Complexes
Chengfu Pi, Ruiting Liu, Pengzhi Zheng, Zhenxia Chen, and Xigeng Zhou
pp 5252 - 5259; DOI:
10.1021/ic070203p
PDF
Potentiometric and Relaxometric Properties of a Gadolinium-Based MRI Contrast Agent for Sensing Tissue pH
Ferenc K. Kálmán, Mark Woods, Peter Caravan, Paul Jurek, Marga Spiller, Gyula Tircsó, Róbert Király, Ernö Brücher, and A. Dean Sherry
pp 5260 - 5270; DOI:
10.1021/ic0702926
PDF
Enhanced Silver Ion Binding to a Rigid Bisarene Molecular Cleft with Formation of Nonpolar Pleated Sheets through Non-Ionic Intermolecular Forces
Adolf Gogoll, Prasad Polavarapu, and Helena Grennberg
pp 5271 - 5275; DOI:
10.1021/ic070222z
PDF
Metal(II) Hexafluorophosphates(V) (M = Sr, Pb) Containing XeF2-Coordinated Metal Ions [M(XeF2)3](PF6)2, [Pb3(XeF2)11](PF6)6, and [Sr3(XeF2)10](PF6)6
Tina Buni, Melita Tramek, Evgeny Goreshnik, Gaper Tavar, and Boris emva
pp 5276 - 5282; DOI:
10.1021/ic0702365
PDF
DFT Modeling of Sandwich Complexes Involving Cationic Palladium Chains and Polyenic or Polycyclic Aromatic Hydrocarbons
Pierre Labéguerie, Marc Bénard, and Marie-Madeleine Rohmer
pp 5283 - 5291; DOI:
10.1021/ic070315g
PDF
Characterization and Electrochemical Properties of Molecular Icosanuclear and Bidimensional Hexanuclear Cu(II) Azido Polyoxometalates
Céline Pichon, Pierre Mialane, Anne Dolbecq, Jérôme Marrot, Eric Rivière, Bineta Keita, Louis Nadjo, and Francis Sécheresse
pp 5292 - 5301; DOI:
10.1021/ic070313w
PDF
Rare-Earth Complexes of Ferrocene-Containing Ligands: Visible-Light Excitable Luminescent Materials
Yao-Feng Yuan, Thomas Cardinaels, Kyra Lunstroot, Kristof Van Hecke, Luc Van Meervelt, Christiane Görller-Walrand, Koen Binnemans, and Peter Nockemann
pp 5302 - 5309; DOI:
10.1021/ic070303v
PDF
Rhenium and Technetium Complexes with N,N-Dialkyl-N'-benzoylthioureas
Nguyen Hung Huy and Ulrich Abram
pp 5310 - 5319; DOI:
10.1021/ic070323x
PDF
Syntheses and Structures of Ytterbium(II) Hydride and Hydroxide Complexes: Similarities and Differences with Their Calcium Analogues
Christian Ruspic, Jan Spielmann, and Sjoerd Harder
pp 5320 - 5326; DOI:
10.1021/ic700403d
PDF
Bis(-diimine)nickel Complexes: Molecular and Electronic Structure of Three Members of the Electron-Transfer Series [Ni(L)2]z (z = 0, 1+, 2+) (L = 2-Phenyl-1,4-bis(isopropyl)-1,4-diazabutadiene). A Combined Experimental and Theoretical Study
Nicoleta Muresan, Krzysztof Chlopek, Thomas Weyhermüller, Frank Neese, and Karl Wieghardt
pp 5327 - 5337; DOI:
10.1021/ic700407m
PDF
After 20 Years, Theoretical Evidence That "AuF7" Is Actually AuF5·F2
Daniel Himmel and Sebastian Riedel
pp 5338 - 5342; DOI:
10.1021/ic700431s
PDF
Solution-Chemical Synthesis of Carbon Nanotube/ZnS Nanoparticle Core/Shell Heterostructures
Feng Gu, Chunzhong Li, and Shufen Wang
pp 5343 - 5348; DOI:
10.1021/ic7004858
PDF
3D Coordination Framework [Ln4(3-OH)2Cu6I5(IN)8(OAc)3] (IN = Isonicotinate): Employing 2D Layers of Lanthanide Wheel Clusters and 1D Chains of Copper Halide Clusters
Xiaojun Gu and Dongfeng Xue
pp 5349 - 5353; DOI:
10.1021/ic7004826
PDF
Chiral-at-Metal Ruthenium Complex as a Metalloligand for Asymmetric Catalysis
Olivier Hamelin, Mickael Rimboud, Jacques Pécaut, and Marc Fontecave
pp 5354 - 5360; DOI:
10.1021/ic7005502
PDF
Elucidation of the Solution Structure and Water-Exchange Mechanism of Paramagnetic [FeII(edta)(H2O)]2-
Joachim Maigut, Roland Meier, Achim Zahl, and Rudi van Eldik
pp 5361 - 5371; DOI:
10.1021/ic700472q
PDF
Synthesis and Antimicrobial Activities of Isomers of N(4),N(11)-Dimethyl-3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane and Their Nickel(II) Complexes
Tapashi G. Roy, Saroj K. S. Hazari, Benu K. Dey, Hazarat A. Miah, Falk Olbrich, and Dieter Rehder
pp 5372 - 5380; DOI:
10.1021/ic061700t
PDF
Synthesis, Structure, Redox Properties, and Catalytic Activity of New Ruthenium Complexes Containing Neutral or Anionic and Facial or Meridional Ligands: An Evaluation of Electronic and Geometrical Effects
Isabel Serrano, Xavier Sala, Elena Plantalech, Montserrat Rodríguez, Isabel Romero, Susanna Jansat, Montserrat Gómez, Teodor Parella, Helen Stoeckli-Evans, Xavier Solans, Mercè Font-Bardia, Balamurugan Vidjayacoumar, and Antoni Llobet
pp 5381 - 5389; DOI:
10.1021/ic070087q
PDF
Structural Characterization and NMR Study of NaNbWO6 and Its Proton-Exchanged Derivatives
Alois Kuhn, María T. Azcondo, Ulises Amador, Khalid Boulahya, Isabel Sobrados, Jesús Sanz, and Flaviano García-Alvarado
pp 5390 - 5397; DOI:
10.1021/ic0701312
PDF
Tetrairon and Hexairon Hydroxo/Acetato Clusters Stabilized by Multiple Polyoxometalate Scaffolds. Structures, Magnetic Properties, and Chemistry of a Dimer and a Trimer
Bogdan Botar, Paul Kögerler, and Craig L. Hill
pp 5398 - 5403; DOI:
10.1021/ic070126y
PDF
Controlled Hydrothermal Growth and Up-Conversion Emission of NaLnF4 (Ln = Y, Dy-Yb)
Jianle Zhuang, Lifang Liang, Herman H. Y. Sung, Xianfeng Yang, Mingmei Wu, Ian D. Williams, Shouhua Feng, and Qiang Su
pp 5404 - 5410; DOI:
10.1021/ic070220e
PDF
Table Salt and Other Alkali Metal Chloride Oligomers: Structure, Stability, and Bonding
F. Matthias Bickelhaupt, Miquel Solà, and Célia Fonseca Guerra
pp 5411 - 5418; DOI:
10.1021/ic070328u
PDF
Neutral Hexa- and Pentacoordinate Silicon(IV) Complexes with SiO6 and SiO4N Skeletons
Oliver Seiler, Christian Burschka, Tassilo Fenske, Dennis Troegel, and Reinhold Tacke
pp 5419 - 5424; DOI:
10.1021/ic700389r
PDF
Double-Icosahedral Li Clusters in a New Binary Compound Ba19Li44: A Reinvestigation of the Ba-Li Phase Diagram
Volodymyr Smetana, Volodymyr Babizhetskyy, Grigori V. Vajenine, Constantin Hoch, and Arndt Simon
pp 5425 - 5428; DOI:
10.1021/ic070249i
PDF
Oxo-Molybdenum(VI,V,IV) Complexes of the Facially Coordinating Tris(mercaptoimidazolyl)borate Ligand: Synthesis, Characterization, and Oxygen Atom Transfer Reactivity
Ba L. Tran and Carl J. Carrano
pp 5429 - 5438; DOI:
10.1021/ic7005259
PDF
Preparation and Characterization of Lithium Imidoalanate Complexes Li2[(RN)4(AlH2)6] (R = Me or tBu): First Examples of Aluminum-Rich Imidoalanes with an Adamantoid Structure
Christina Y. Tang, Andrew R. Cowley, Anthony J. Downs, and Simon Parsons
pp 5439 - 5446; DOI:
10.1021/ic7006827
PDF

Issue 14


A Novel Metal-Binding Mode of Thymine Nucleobases: N(3) and O(4) Chelation
José Ruiz, María Dolores Villa, Venancio Rodríguez, Natalia Cutillas, Consuelo Vicente, Gregorio López, and Delia Bautista
pp 5448 - 5449; DOI:
10.1021/ic700843s
PDF
Hydrolytic Cleavage of DNA by a Ruthenium(II) Polypyridyl Complex
Megha S. Deshpande, Anupa A. Kumbhar, and Avinash S. Kumbhar
pp 5450 - 5452; DOI:
10.1021/ic070331d
PDF
Unusual Oxidation of an N-Heterocycle Ligand in a Metal-Organic Framework
Zhangang Han, Yulong Zhao, Jun Peng, and Carlos J. Gómez-García
pp 5453 - 5455; DOI:
10.1021/ic700432p
PDF
Resolving the Aluminum Ordering in Aluminosilicates by a Combined Experimental/Theoretical Study of 27Al Electric Field Gradients
Xavier Rocquefelte, Frédéric Clabau, Michael Paris, Philippe Deniard, Thierry Le Mercier, Stéphane Jobic, and Myung-Hwan Whangbo
pp 5456 - 5458; DOI:
10.1021/ic7004166
PDF
Tridecanuclear and Docosanuclear Manganese Phosphonate Clusters with Slow Magnetic Relaxation
Yun-Sheng Ma, You Song, Yi-Zhi Li, and Li-Min Zheng
pp 5459 - 5461; DOI:
10.1021/ic070104b
PDF
Crystal Structures and Magnetic and Ferroelectric Properties of Chiral Layered Metal-Organic Frameworks with Dicyanamide as the Bridging Ligand
Zhi-Guo Gu, Xin-Hui Zhou, Yang-Bo Jin, Ren-Gen Xiong, Jing-Lin Zuo, and Xiao-Zeng You
pp 5462 - 5464; DOI:
10.1021/ic070112s
PDF
Dioxygen Activation by Diiminodipyrromethane Complexes of Ni, Pd, and Pt
Evgeny A. Katayev, Kay Severin, Rosario Scopelliti, and Yuri A. Ustynyuk
pp 5465 - 5467; DOI:
10.1021/ic700632f
PDF
An Octadentate Luminescent Eu(III) 1,2-HOPO Chelate with Potent Aqueous Stability
Evan G. Moore, Christoph J. Jocher, Jide Xu, Eric J. Werner, and Kenneth N. Raymond
pp 5468 - 5470; DOI:
10.1021/ic700364t
PDF
Metal-Coordination-Directed Assembly of Binuclear Trigonal Prisms and Three-Dimensional Hydrogen-Bonded Networks
Wei-Wei Sun, Ai-Ling Cheng, Qin-Xiang Jia, and En-Qing Gao
pp 5471 - 5473; DOI:
10.1021/ic700610p
PDF
(Tetramethyltetraazaannulene)chromium Chloride: A Highly Active Catalyst for the Alternating Copolymerization of Epoxides and Carbon Dioxide
Donald J. Darensbourg and Shawn B. Fitch
pp 5474 - 5476; DOI:
10.1021/ic7007842
PDF
New Porphyrinoids: Vanadyl(IV) Complexes of meso-Aryl-Substituted Corrphycene and 10-Oxocorrole Ligands
Martin Bröring, Christian Hell, Frédérique Brégier, Olaf Burghaus, and Esther Cónsul Tejero
pp 5477 - 5479; DOI:
10.1021/ic700844p
PDF
First Isolation and Kinetic Study of Hypervalent 10-As-5 Organoarsenic Compounds with a C-Apical, O-Equatorial Configuration
Xin-Dong Jiang, Shiro Matsukawa, Hideaki Yamamichi, and Yohsuke Yamamoto
pp 5480 - 5482; DOI:
10.1021/ic700678a
PDF
Targeted Synthesis of -Oxo Divanadium(V) Compounds with Asymmetry in Coordination Environments
Pabitra Baran Chatterjee, Nabanita Kundu, Subhojit Bhattacharya, Ki-Young Choi, Akira Endo, and Muktimoy Chaudhury
pp 5483 - 5485; DOI:
10.1021/ic700858g
PDF
Carboxylate Coordination Chemistry of a Mononuclear Ni(II) Center in a Hydrophobic or Hydrogen Bond Donor Secondary Environment: Relevance to Acireductone Dioxygenase
Ewa Szajna-Fuller, Bonnie M. Chambers, Atta M. Arif, and Lisa M. Berreau
pp 5486 - 5498; DOI:
10.1021/ic061316w
PDF
Acireductone Dioxygenase- (ARD-) Type Reactivity of a Nickel(II) Complex Having Monoanionic Coordination of a Model Substrate: Product Identification and Comparisons to Unreactive Analogues
Ewa Szajna-Fuller, Katarzyna Rudzka, Atta M. Arif, and Lisa M. Berreau
pp 5499 - 5507; DOI:
10.1021/ic061177i
PDF
Interaction between Metal Nitrates and Carbohydrates: The Topology Coordination Behavior of Galactitol with Trivalent Lanthanide and Divalent Alkaline Earth Ions
Yunlan Su, Limin Yang, Yizhuang Xu, Zheming Wang, Shifu Weng, Chunhua Yan, Dujin Wang, and Jinguang Wu
pp 5508 - 5517; DOI:
10.1021/ic061414h
PDF
Nonconjugated Dendritic Iridium(III) Complexes with Tunable Pyridine-Based Ligands: Synthesis, Photophysical, Electrochemical, and Electroluminescent Properties
Xianghong Li, Zhao Chen, Qiang Zhao, Li Shen, Fuyou Li, Tao Yi, Yong Cao, and Chunhui Huang
pp 5518 - 5527; DOI:
10.1021/ic062041n
PDF
Toward Actinide Molecular Magnetic Materials: Coordination Polymers of U(IV) and the Organic Acceptors TCNQ and TCNE
Eric J. Schelter, David E. Morris, Brian L. Scott, Joe D. Thompson, and Jaqueline L. Kiplinger
pp 5528 - 5536; DOI:
10.1021/ic0700295
PDF
Cleavage of C-S Bonds with the Formation of a Tetranuclear Cu(I) Cluster
Chunhui Huang, Shaohua Gou, Haibin Zhu, and Wei Huang
pp 5537 - 5543; DOI:
10.1021/ic062059y
PDF
Porphyrin Framework Solids. Synthesis and Structure of Hybrid Coordination Polymers of Tetra(carboxyphenyl)porphyrins and Lanthanide-Bridging Ions
Sankar Muniappan, Sophia Lipstman, Sumod George, and Israel Goldberg
pp 5544 - 5554; DOI:
10.1021/ic0701099
PDF
Preparation and Structure of a Solid-State Hypervalent-Iodine Polymer Containing Iodine and Oxygen Atoms in Fused 12-Atom Hexagonal Rings
Helen W. Richter, Gerald F. Koser, Christopher D. Incarvito, and Arnold L. Rheingold
pp 5555 - 5561; DOI:
10.1021/ic0701716
PDF
Reversibly Reducible cis-Dichloroplatinum(II) and cis-Dichloropalladium(II) Complexes of Bis(1-methylimidazol-2-yl)glyoxal
Ece Bulak, Markus Leboschka, Brigitte Schwederski, Orkan Sarper, Tereza Varnali, Jan Fiedler, Falk Lissner, Thomas Schleid, and Wolfgang Kaim
pp 5562 - 5566; DOI:
10.1021/ic070185b
PDF
A New N,N,O Chelate for Transition Metal Chemistry: Fe5 and Fe6 Clusters from the Use of 6-Hydroxymethyl-2,2'-bipyridine (hmbpH)
Rashmi Bagai, Khalil A. Abboud, and George Christou
pp 5567 - 5575; DOI:
10.1021/ic070174i
PDF
Phenol- and Catechol-Based Ruthenium(II) Polypyridyl Complexes as Colorimetric Sensors for Fluoride Ions
D. Amilan Jose, Prasenjit Kar, Debasis Koley, Bishwajit Ganguly, Walter Thiel, Hirendra N. Ghosh, and Amitava Das
pp 5576 - 5584; DOI:
10.1021/ic070165+
PDF
Effects of Isovalent Substitution in the Manganese Sublattice on Magnetic, Thermal, and Structural Properties of BiMnO3: BiMn1-xMxO3 (M = Al, Sc, Cr, Fe, Ga; 0 x 0.2)
Alexei A. Belik and Eiji Takayama-Muromachi
pp 5585 - 5590; DOI:
10.1021/ic0701615
PDF
Technetium Fluoride Trioxide, TcO3F, Preparation and Properties
Joanna Supe, Ulrich Abram, Adelheid Hagenbach, and Konrad Seppelt
pp 5591 - 5595; DOI:
10.1021/ic070333y
PDF
Identification of the Radical Anions of C2N4S2 and P2N4S2 Rings by In Situ EPR Spectroelectrochemistry and DFT Calculations
René T. Boeré, Alan M. Bond, Tristram Chivers, Stephen W. Feldberg, and Tracey L. Roemmele
pp 5596 - 5607; DOI:
10.1021/ic070243t
PDF
Preparation of Au(I), Ag(I), and Pd(II) N-Heterocyclic Carbene Complexes Utilizing a Methylpyridyl-Substituted NHC Ligand. Formation of a Luminescent Coordination Polymer
Vincent J. Catalano and Anthony O. Etogo
pp 5608 - 5615; DOI:
10.1021/ic070260i
PDF
Solvent-Dependent Resonance Raman Spectra of High-Valent Oxomolybdenum(V) Tris[3,5-bis(trifluoromethyl)phenyl]corrolate
Roman S. Czernuszewicz, Vicky Mody, Adelajda A. Zareba, Marzena B. Zaczek, Micha Gazowski, Volodymyr Sashuk, Karol Grela, and Daniel T. Gryko
pp 5616 - 5624; DOI:
10.1021/ic070275g
PDF
Synthesis of a Mn6 Cluster and Its Self-Assembly of an Azido-Bridged Polymer
Kartik Chandra Mondal, Mike G. B. Drew, and Partha Sarathi Mukherjee
pp 5625 - 5629; DOI:
10.1021/ic0702670
PDF
Photoinduced Electron Transfer across Oligo-p-phenylene Bridges. Distance and Conformational Effects in
Ru(II)-Rh(III) Dyads

Maria Teresa Indelli, Claudio Chiorboli, Lucia Flamigni, Luisa De Cola, and Franco Scandola
pp 5630 - 5641; DOI:
10.1021/ic700430u
PDF
Electronic Structure of Neutral and Monoanionic Tris(benzene-1,2-dithiolato)metal Complexes of Molybdenum and Tungsten
Ruta R. Kapre, Eberhard Bothe, Thomas Weyhermüller, Serena DeBeer George, and Karl Wieghardt
pp 5642 - 5650; DOI:
10.1021/ic700600r
PDF
Wirelike Dinuclear Ruthenium Complexes Connected by Bis(ethynyl)oligothiophene
Li-Bin Gao, Jian Kan, Yang Fan, Li-Yi Zhang, Sheng-Hua Liu, and Zhong-Ning Chen
pp 5651 - 5664; DOI:
10.1021/ic700412m
PDF
Structural and EPR Studies on Single-Crystal and Polycrystalline Samples of Copper(II) and Cobalt(II) Complexes with N2S2-Based Macrocyclic Ligands
Abel Tamayo, Jaume Casabó, Lluís Escriche, Pablo González, Carlos Lodeiro, Alberto C. Rizzi, Carlos D. Brondino, M. C. G. Passeggi, Raikko Kivekäs, and Reijo Sillanpää
pp 5665 - 5672; DOI:
10.1021/ic700375d
PDF
General Sacrificial Template Method for the Synthesis of Cadmium Chalcogenide Hollow Structures
Jian-Jun Miao, Li-Ping Jiang, Chang Liu, Jian-Min Zhu, and Jun-Jie Zhu
pp 5673 - 5677; DOI:
10.1021/ic700404n
PDF
Alumazene Adducts with Pyridines: Synthesis, Structure, and Stability Studies
Jiri Löbl, Alexey Y. Timoshkin, Trinh Cong, Marek Necas, Herbert W. Roesky, and Jiri Pinkas
pp 5678 - 5685; DOI:
10.1021/ic700488p
PDF
Selenium Oxoanion Compounds of Palladium(II)
Jie Ling and Thomas E. Albrecht-Schmitt
pp 5686 - 5690; DOI:
10.1021/ic700524c
PDF
Conformational Effect of 2,6-Bis(imidazol-1-yl)pyridine on the Self-Assembly of 1D Coordination Chains: Spontaneous Resolution, Supramolecular Isomerism, and Structural Transformation
Chih-Yuan Chen, Pi-Yun Cheng, Hsin-Hsuan Wu, and Hon Man Lee
pp 5691 - 5699; DOI:
10.1021/ic700428e
PDF
Synthesis and Characterization of Hemicage 8-Hydroxyquinoline Chelates with Enhanced Electrochemical and Photophysical Properties
Jingjing Wang, Karl D. Oyler, and Stefan Bernhard
pp 5700 - 5706; DOI:
10.1021/ic700542t
PDF
Hydrogen and Copper Ion-Induced Molecular Reorganizations in Scorpionand-like Ligands. A Potentiometric, Mechanistic, and Solid-State Study
Begoña Verdejo, Armando Ferrer, Salvador Blasco, Carmen Esther Castillo, Jorge González, Julio Latorre, M. Angeles Máñez, Manuel García Basallote, Conxa Soriano, and Enrique García-España
pp 5707 - 5719; DOI:
10.1021/ic700643n
PDF
XAS Characterization of a Nitridoiron(IV) Complex with a Very Short Fe-N Bond
Jan-Uwe Rohde, Theodore A. Betley, Timothy A. Jackson, Caroline T. Saouma, Jonas C. Peters, and Lawrence Que, Jr.
pp 5720 - 5726; DOI:
10.1021/ic700818q
PDF
New [LNiII2]+ Complexes Incorporating 2-Formyl or 2,6-Diformyl-4-methyl Phenol as Inhibitors of the Hydrolysis of the Ligand L3-: Ni···Ni Ferromagnetic Coupling and S = 2 Ground States
Alok Ranjan Paital, Wing Tak Wong, Guillem Aromí, and Debashis Ray
pp 5727 - 5733; DOI:
10.1021/ic700496c
PDF
High-Valent Technetium Fluorides. Does TcF7 Exist?
Sebastian Riedel, Manuel Renz, and Martin Kaupp
pp 5734 - 5738; DOI:
10.1021/ic7007039
PDF
First Infrared Spectroscopic Detection of the Monobridged Diboranyl Radical (B2H5, C2v) and Its D5-Isotopomer in Low-Temperature Diborane Ices
Jonilyn G. Longenecker, Alexander M. Mebel, and Ralf I. Kaiser
pp 5739 - 5743; DOI:
10.1021/ic0622712
PDF
Photoinduced Electron-Transfer Processes Based on Novel Bipyridine-Ru(II) Complex: Properties of cis-
[Ru(2,2'-bipyridine)2(5,6-bis(3-amidopyridine)-7-oxanorbornene)](PF6)2 and cis-[Ru(2,2'-bipyridine)2(3-aminopyridine)2](PF6)2 Complexes

Simone D. Inglez, Francisco C. A. Lima, Albérico B. F. Silva, Andreza R. Simioni, Antônio C. Tedesco, Juliana F. S. Daniel, Benedito S. Lima-Neto, and Rose M. Carlos
pp 5744 - 5753; DOI:
10.1021/ic062478v
PDF
Synthesis, Crystal Structures, and Reactivity of Osmium(II) and -(IV) Complexes Containing a Dithioimidodiphosphinate Ligand
Wai-Man Cheung, Qian-Feng Zhang, Ian D. Williams, and Wa-Hung Leung
pp 5754 - 5762; DOI:
10.1021/ic070048e
PDF
Synthesis and Structural Characterization of a Series of Lanthanide(II) Amides: Steric Effect of Amido Ligand
Liying Zhou, Junfeng Wang, Yong Zhang, Yingming Yao, and Qi Shen
pp 5763 - 5772; DOI:
10.1021/ic070162x
PDF
Valence Bond Structures for the D2h Isomer of N2O4 and Some Isomers of S3O2 and S3O
Richard D. Harcourt
pp 5773 - 5778; DOI:
10.1021/ic070245d
PDF
Synthesis of Iridium Pyridinyl N-Heterocyclic Carbene Complexes and Their Catalytic Activities on Reduction of Nitroarenes
Chao-Yu Wang, Ching-Feng Fu, Yi-Hong Liu, Shei-Ming Peng, and Shiuh-Tzung Liu
pp 5779 - 5786; DOI:
10.1021/ic070330l
PDF
Low-Valent Vanadium Oxide Nanostructures with Controlled Crystal Structures and Morphologies
Guicun Li, Kun Chao, Hongrui Peng, Kezheng Chen, and Zhikun Zhang
pp 5787 - 5790; DOI:
10.1021/ic070339n
PDF
Synthesis of Ruthenium(II) Complexes Containing Hydroxymethylphosphines and Their Catalytic Activities for Hydrogenation of Supercritical Carbon Dioxide
Yoshihito Kayaki, Yoshiki Shimokawatoko, and Takao Ikariya
pp 5791 - 5797; DOI:
10.1021/ic700470n
PDF
A New Method for the Synthesis of Organopolyoxometalate Hybrid Compounds
Itsik Bar-Nahum, Jessica Ettedgui, Leonid Konstantinovski, Vladimir Kogan, and Ronny Neumann
pp 5798 - 5804; DOI:
10.1021/ic700540g
PDF
Electron Exchange Involving a Sulfur-Stabilized Ruthenium Radical Cation
Anthony P. Shaw, Bradford L. Ryland, Jack R. Norton, Daniela Buccella, and Alberto Moscatelli
pp 5805 - 5812; DOI:
10.1021/ic700580u
PDF

Issue 15


Assembly of Trigonal and Tetragonal Prismatic Cages from Octahedral Metal Ions and a Flexible Molecular Clip
Zhi-Min Liu, Yu Liu, Sheng-Run Zheng, Zhi-Quan Yu, Mei Pan, and Cheng-Yong Su
pp 5814 - 5816; DOI:
10.1021/ic062270+
PDF
Rugby-Ball-Shaped Sulfate-Water-Sulfate Adduct Encapsulated in a Neutral Molecular Receptor Capsule
D. Amilan Jose, D. Krishna Kumar, Bishwajit Ganguly, and Amitava Das
pp 5817 - 5819; DOI:
10.1021/ic062466+
PDF
Dinuclear Platinum Complexes with Biological Relevance Based on the 1,2-Diaminocyclohexane Carrier Ligand
John W. Williams, Yun Qu, Genevieve H. Bulluss, Eugenio Alvorado, and Nicholas P. Farrell
pp 5820 - 5822; DOI:
10.1021/ic700410y
PDF
Self-Assembly of Two Chiral Supramolecules with Three-Dimensional Porous Host Frameworks: (){[FeII(phen)3][FeIIINa(C2O4)3]}n and Its Enantiomer
Pei-zhou Li, Xiao-ming Lu, Bo Liu, Shuo Wang, and Xiao-jun Wang
pp 5823 - 5825; DOI:
10.1021/ic070214i
PDF
Methyl Substituent at C2 Carbon of Acetophenone Thiosemicarbazone Induces Unusual Heterobridging in the [(Ph3P)Cu(-I)2(-S-Haptsc)Cu(PPh3)] Dimer
Tarlok S. Lobana, Sonia Khanna, Ray J. Butcher, A. D. Hunter, and M. Zeller
pp 5826 - 5828; DOI:
10.1021/ic700401h
PDF
Metal-Directed Self-Assembly of a ZnII-salpyr Complex into a Supramolecular Vase Structure
Arjan W. Kleij, Mark Kuil, Duncan M. Tooke, Anthony L. Spek, and Joost N. H. Reek
pp 5829 - 5831; DOI:
10.1021/ic700408v
PDF
Lanthanide(III)-Cobalt(II) Heterometallic Coordination Polymers with Radical Adsorption Properties
Xiao-Qing Zhao, Bin Zhao, Yue Ma, Wei Shi, Peng Cheng, Zong-Hui Jiang, Dai-Zheng Liao, and Shi-Ping Yan
pp 5832 - 5834; DOI:
10.1021/ic7007446
PDF
3D Porous Metal-Organic Framework Exhibiting Selective Adsorption of Water over Organic Solvents
Jin-Zhong Gu, Wen-Guan Lu, Long Jiang, Hong-Cai Zhou, and Tong-Bu Lu
pp 5835 - 5837; DOI:
10.1021/ic7004908
PDF
New Coordination Motifs of Melamine Directed by N-H···X (X = Cl or Br) Hydrogen Bonds
Lei Zhang, Jian Zhang, Zhao-Ji Li, Jian-Kai Cheng, Pei-Xiu Yin, and Yuan-Gen Yao
pp 5838 - 5840; DOI:
10.1021/ic7005138
PDF
Thermally Stable Gold(I) -Diketiminate Complexes
H. V. Rasika Dias and Jaime A. Flores
pp 5841 - 5843; DOI:
10.1021/ic7008539
PDF
Atom Transfer Radical Addition in the Presence of Catalytic Amounts of Copper(I/II) Complexes with Tris(2-pyridylmethyl)amine
William T. Eckenhoff and Tomislav Pintauer
pp 5844 - 5846; DOI:
10.1021/ic700908m
PDF
Synthesis, Structure, and Photoluminescence Property of a New Layered Zirconium Phosphate Co(dien)2[Zr4H8P5O26]·3H2O
Yu Du, Qinhe Pan, Jiyang Li, Jihong Yu, and Ruren Xu
pp 5847 - 5851; DOI:
10.1021/ic061873i
PDF
Precursors for MOCVD and ALD of Rare Earth Oxides-Complexes of the Early Lanthanides with a Donor-Functionalized Alkoxide Ligand
Helen C. Aspinall, Jamie F. Bickley, Jeffrey M. Gaskell, Anthony C. Jones, Gael Labat, Paul R. Chalker, and Paul A. Williams
pp 5852 - 5860; DOI:
10.1021/ic061382y
PDF
Single-Molecule Magnet Behavior in Heterometallic MII-MnIII2-MII Tetramers (MII = Cu, Ni) Containing MnIII Salen-Type Dinuclear Core
Chihiro Kachi-Terajima, Hitoshi Miyasaka, Ayumi Saitoh, Naoki Shirakawa, Masahiro Yamashita, and Rodolphe Clérac
pp 5861 - 5872; DOI:
10.1021/ic0620891
PDF
Density Functional Theory Studies on Copper Phenanthroline Complexes
Arturo Robertazzi, Alessandra Magistrato, Paul de Hoog, Paolo Carloni, and Jan Reedijk
pp 5873 - 5881; DOI:
10.1021/ic0618908
PDF
EXAFS Investigation of U(VI), U(IV), and Th(IV) Sulfato Complexes in Aqueous Solution
Christoph Hennig, Katja Schmeide, Vinzenz Brendler, Henry Moll, Satoru Tsushima, and Andreas C. Scheinost
pp 5882 - 5892; DOI:
10.1021/ic0619759
PDF
Synthesis and Structure of Silver Complexes with Nicotinate-Type Ligands Having Antibacterial Activities against Clinically Isolated Antibiotic Resistant Pathogens
Morsy A. M. Abu-Youssef, Raja Dey, Yousry Gohar, Alshima'a A. Massoud, Lars Öhrström, and Vratislav Langer
pp 5893 - 5903; DOI:
10.1021/ic0621594
PDF
Spectroscopic Characterization of Hydroxylated Nanoballs in Methanol
Randy W. Larsen, Gregory J. McManus, John J. Perry IV, Edwin Rivera-Otero, and Michael J. Zaworotko
pp 5904 - 5910; DOI:
10.1021/ic062268i
PDF
A QM/MM Investigation of the Activation and Catalytic Mechanism of Fe-Only Hydrogenases
Claudio Greco, Maurizio Bruschi, Luca De Gioia, and Ulf Ryde
pp 5911 - 5921; DOI:
10.1021/ic062320a
PDF
Alkynyl Ruthenium Colorimetric Sensors: Optimizing the Selectivity toward Fluoride Anion
Jean-Luc Fillaut, Julien Andriès, Johann Perruchon, Jean-Pierre Desvergne, Loïc Toupet, Lotfi Fadel, Bachir Zouchoune, and Jean-Yves Saillard
pp 5922 - 5932; DOI:
10.1021/ic062389i
PDF
High-Dimensional Assembly Depending on Polyoxoanion Templates, Metal Ion Coordination Geometries, and a Flexible Bis(imidazole) Ligand
Bao-xia Dong, Jun Peng, Carlos J. Gómez-García, Samia Benmansour, Heng-qing Jia, and Ning-hai Hu
pp 5933 - 5941; DOI:
10.1021/ic070007i
PDF
First Ruthenium Complex of Glyoxalbis(N-phenyl)osazone (LNHPhH2): Synthesis, X-ray Structure, Spectra, and Density Functional Theory Calculations of (LNHPhH2)Ru(PPh3)2Cl2
Amit Saha Roy, Heikki M. Tuononen, Sankar P. Rath, and Prasanta Ghosh
pp 5942 - 5948; DOI:
10.1021/ic070294q
PDF
Metal-Organic Frameworks from Copper Dimers with cis- and trans-1,4-Cyclohexanedicarboxylate and cis,cis-1,3,5-Cyclohexanetricarboxylate
Hitoshi Kumagai, Motoko Akita-Tanaka, Katsuya Inoue, Kazuyuki Takahashi, Hayao Kobayashi, Serge Vilminot, and Mohamedally Kurmoo
pp 5949 - 5956; DOI:
10.1021/ic070167u
PDF
Zeolite Ionic Crystals Assembled through Direct Incorporation of Polyoxometalate Clusters within 3D Metal-Organic Frameworks
Meilin Wei, Cheng He, Qiaozhen Sun, Qingjin Meng, and Chunying Duan
pp 5957 - 5966; DOI:
10.1021/ic070274o
PDF
Manganese(III) Schiff Base Complexes: Chemistry Relevant to the Copolymerization of Epoxides and Carbon Dioxide
Donald J. Darensbourg and Eric B. Frantz
pp 5967 - 5978; DOI:
10.1021/ic7003968
PDF
Evidence for Tetraphenylporphyrin Monoacids
Giovanna De Luca, Andrea Romeo, Luigi Monsù Scolaro, Giampaolo Ricciardi, and Angela Rosa
pp 5979 - 5988; DOI:
10.1021/ic0703373
PDF
Controlling Phosphorescence Color and Quantum Yields in Cationic Iridium Complexes: A Combined Experimental and Theoretical Study
Filippo De Angelis, Simona Fantacci, Nicholas Evans, Cedric Klein, Shaik M. Zakeeruddin, Jacques-E. Moser, Kuppuswamy Kalyanasundaram, Henk J. Bolink, M. Grätzel, and Mohammed K. Nazeeruddin
pp 5989 - 6001; DOI:
10.1021/ic700435c
PDF
Polyoxomolybdenum(V/VI)-Sulfite Compounds: Synthesis, Structural, and Physical Studies
Nikolaos I. Kapakoglou, Betzios I. Panagiotis, Spiros E. Kazianis, Constantine E. Kosmidis, Chryssoula Drouza, Manolis J. Manos, Michael P. Sigalas, Anastasios D. Keramidas, and Themistoklis A. Kabanos
pp 6002 - 6010; DOI:
10.1021/ic700460b
PDF
Marked Differences in Light-Switch Behavior of Ru(II) Complexes Possessing a Tridentate DNA Intercalating Ligand
Yao Liu, Richard Hammitt, Daniel A. Lutterman, Randolph P. Thummel, and Claudia Turro
pp 6011 - 6021; DOI:
10.1021/ic700484j
PDF
Different Cation Arrangements in Au-In Networks. Syntheses and Structures of Six Intermetallic Compounds in Alkali-Metal-Au-In Systems
Bin Li and John D. Corbett
pp 6022 - 6028; DOI:
10.1021/ic700519c
PDF
Substituent Effect on Formation of Heterometallic Molecular Wheels: Synthesis, Crystal Structure, and Magnetic Properties
Zhong-Hai Ni, Li-Fang Zhang, Vassilis Tangoulis, Wolfgang Wernsdorfer, Ai-Li Cui, Osamu Sato, and Hui-Zhong Kou
pp 6029 - 6037; DOI:
10.1021/ic700528a
PDF
A New Tripodal Iron(III) Monophenolate Complex: Effects of Ligand Basicity, Steric Hindrance, and Solvent on Regioselective Extradiol Cleavage
Ramasamy Mayilmurugan, Eringathodi Suresh, and Mallayan Palaniandavar
pp 6038 - 6049; DOI:
10.1021/ic700646m
PDF
Branched NaYF4 Nanocrystals with Luminescent Properties
Xin Liang, Xun Wang, Jing Zhuang, Qing Peng, and Yadong Li
pp 6050 - 6055; DOI:
10.1021/ic700523x
PDF
Copper(I) Complex O2-Reactivity with a N3S Thioether Ligand: a Copper-Dioxygen Adduct Including Sulfur Ligation, Ligand Oxygenation, and Comparisons with All Nitrogen Ligand Analogues
Dong-Heon Lee, Lanying Q. Hatcher, Michael A. Vance, Ritimukta Sarangi, Ashley E. Milligan, Amy A. Narducci Sarjeant, Christopher D. Incarvito, Arnold L. Rheingold, Keith O. Hodgson, Britt Hedman, Edward I. Solomon, and Kenneth D. Karlin
pp 6056 - 6068; DOI:
10.1021/ic700541k
PDF
Solid-State NMR Spectroscopic Study of Coordination Compounds of XeF2 with Metal Cations and the Crystal Structure of [Ba(XeF2)5][AsF6]2
Michael Gerken, Paul Hazendonk, Adriana Iuga, Jared Nieboer, Melita Tramek, Evgeny Goreshnik, Boris emva, Shaohui Zheng, and Jochen Autschbach
pp 6069 - 6077; DOI:
10.1021/ic700557m
PDF
Liquid Crystalline Derivatives of Bis(tricarbollide)Fe(II)
Adam Januszko, Piotr Kaszynski, and Bohumír Grüner
pp 6078 - 6082; DOI:
10.1021/ic7005937
PDF
Formation and Characterization of Co(III)-Semiquinonate Phenoxyl Radical Species
Yuichi Shimazaki, Ryota Kabe, Stefan Huth, Fumito Tani, Yoshinori Naruta, and Osamu Yamauchi
pp 6083 - 6090; DOI:
10.1021/ic700596g
PDF
A Theoretical Study on the Mechanism of Boron Metathesis
Susmita De, Pattiyil Parameswaran, and Eluvathingal D. Jemmis
pp 6091 - 6098; DOI:
10.1021/ic700619g
PDF
Synthesis, Structure, and Properties of a Mixed-Valent Triiron Complex of Tetramethyl Reductic Acid, an Ascorbic Acid Analogue, and Its Relationship to a Functional Non-Heme Iron Oxidation Catalyst System
YooJin Kim, Xudong Feng, and Stephen J. Lippard
pp 6099 - 6107; DOI:
10.1021/ic700622a
PDF
Cubane Variations: Syntheses, Structures, and Magnetic Property Analyses of Lanthanide(III)-Copper(II) Architectures with Controlled Nuclearities
Christophe Aronica, Guillaume Chastanet, Guillaume Pilet, Boris Le Guennic, Vincent Robert, Wolfgang Wernsdorfer, and Dominique Luneau
pp 6108 - 6119; DOI:
10.1021/ic700645q
PDF
Synthesis of the Water Soluble Ligands dmPTA and dmoPTA and the Complex [RuClCp(HdmoPTA)(PPh3)](OSO2CF3) (dmPTA = N,N'-Dimethyl-1,3,5-triaza-7-phosphaadamantane, dmoPTA = 3,7-Dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane, HdmoPTA = 3,7-H-3,7-Dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane)
Adrián Mena-Cruz, Pablo Lorenzo-Luis, Antonio Romerosa, Mustapha Saoud, and Manuel Serrano-Ruiz
pp 6120 - 6128; DOI:
10.1021/ic070168m
PDF
Low-Valence Triruthenium Compounds via Substitution of a Bridging Acetate in the Parent Ru3O(OAc)6 Cluster Core by 2,2'-Azobispyridine (abpy) or 2,2'-Azobis(5-chloropyrimidine) (abcp)
Heng-Yun Ye, Feng-Rong Dai, Li-Yi Zhang, and Zhong-Ning Chen
pp 6129 - 6135; DOI:
10.1021/ic0702771
PDF
Desoxo Molybdenum(IV) and Tungsten(IV) Bis(dithiolene) Complexes: Monomer-Dimer Interconversion Involving Reversible Thiol Bridge Formation
Amit Majumdar, Kuntal Pal, Kowliki Nagarajan, and Sabyasachi Sarkar
pp 6136 - 6147; DOI:
10.1021/ic7006777
PDF
Hybrid Perovskite Resulting from the Solid-State Reaction between the Organic Cations and Perovskite Layers of 1-(Br-(CH2)2-NH3)2PbI4
Sebastien Sourisseau, Nicolas Louvain, Wenhua Bi, Nicolas Mercier, David Rondeau, Jean-Yves Buzaré, and Christophe Legein
pp 6148 - 6154; DOI:
10.1021/ic070240g
PDF
Synthesis, Structural Characterization, and Electrophosphorescent Properties of Rhenium(I) Complexes Containing Carrier-Transporting Groups
Zhenjun Si, Jiang Li, Bin Li, Feifei Zhao, Shiyong Liu, and Wenlian Li
pp 6155 - 6163; DOI:
10.1021/ic061645o
PDF
Pressure-Induced Cubic to Monoclinic Phase Transformation in Erbium Sesquioxide Er2O3
Qixun Guo, Yusheng Zhao, Chao Jiang, Wendy L. Mao, Zhongwu Wang, Jianzhong Zhang, and Yuejian Wang
pp 6164 - 6169; DOI:
10.1021/ic070154g
PDF
Rb3Ti3(P4S13)(PS4)3 and Cs2Ti2(P2S8)(PS4)2: Two Polar Titanium Thiophosphates with Complex One-Dimensional Tunnels
Yuandong Wu and Wolfgang Bensch
pp 6170 - 6177; DOI:
10.1021/ic700478r
PDF
A Kinetic Study of the Silyl Substitution in Tantalum Amide Silyl Complex (Me2N)3Ta[Si(SiMe3)3]2
He Qiu, Shujian Chen, and Zi-Ling Xue
pp 6178 - 6181; DOI:
10.1021/ic0703169
PDF
Binuclear Palladium(I) and Palladium(II) Complexes of ortho-Functionalized 1,3-Bis(aryl)triazenido Ligands
Juan José Nuricumbo-Escobar, Carlos Campos-Alvarado, Gustavo Ríos-Moreno, David Morales-Morales, Patrick J. Walsh, and Miguel Parra-Hake
pp 6182 - 6189; DOI:
10.1021/ic700516p
PDF
1H Relaxivity of Water in Aqueous Suspensions of Gd3+-Loaded NaY Nanozeolites and AlTUD-1 Mesoporous Material: the Influence of Si/Al Ratio and Pore Size
Magorzata Norek, Isabel C. Neves, and Joop A. Peters
pp 6190 - 6196; DOI:
10.1021/ic700699n
PDF
Reversible Bromide-Chloride Exchange in Zirconium Cluster Compounds: Synthesis by Means of Ionic Liquids, Structures, and Some Spectral Data of (EMIm)4[(Zr6Z)Br18] Cluster Phases (Z = Be, Fe)
Johannes B. Willems, Henning W. Rohm, Christine Geers, and Martin Köckerling
pp 6197 - 6203; DOI:
10.1021/ic061624u
PDF
Growth of Dumbbell-like ZnO Microcrystals under Mild Conditions and their Photoluminescence Properties
Qingjiang Yu, Cuiling Yu, Haibin Yang, Wuyou Fu, Lianxia Chang, Jing Xu, Ronghui Wei, Hongdong Li, Hongyang Zhu, Minghui Li, Guangtian Zou, Guorui Wang, Changlu Shao, and Yichun Liu
pp 6204 - 6210; DOI:
10.1021/ic070008a
PDF

Issue 16


Precise Size Control and Synchronized Synthesis of Six Colors of CdSe Quantum Dots in a Slow-Increasing Temperature Gradient
Genoveva Zlateva, Zhivko Zhelev, Rumiana Bakalova, and Iwao Kanno
pp 6212 - 6214; DOI:
10.1021/ic062045s
PDF
Two Frustrated, Bitetrahedral Single-Molecule Magnets
Constantinos J. Milios, Ian A. Gass, Alina Vinslava, Laura Budd, Simon Parsons, Wolfgang Wernsdorfer, Spyros P. Perlepes, George Christou, and Euan K. Brechin
pp 6215 - 6217; DOI:
10.1021/ic7006638
PDF
Luminescent, Three-Coordinate Azadipyrromethene Complexes of d10 Copper, Silver, and Gold
Thomas S. Teets, David V. Partyka, Arthur J. Esswein, James B. Updegraff, III, Matthias Zeller, Allen D. Hunter, and Thomas G. Gray
pp 6218 - 6220; DOI:
10.1021/ic700776t
PDF
Calix[4]bis(thiacrown): Assembly of an Endocyclic Disilver(I) Complex and Exocyclic 3D Copper(I) Coordination Polymers
Jai Young Lee, So Young Lee, Joobeom Seo, Chul Soon Park, Jung Nam Go, Wonbo Sim, and Shim Sung Lee
pp 6221 - 6223; DOI:
10.1021/ic7005875
PDF
Binuclear Fluoro-Bridged Zinc and Cadmium Complexes of a Schiff Base Expanded Porphyrin: Fluoride Abstraction from the Tetrafluoroborate Anion
Elisa Tomat, Luciano Cuesta, Vincent M. Lynch, and Jonathan L. Sessler
pp 6224 - 6226; DOI:
10.1021/ic700933p
PDF
Activation Parameters for Cyclohexene Oxygenation by an Oxoiron(IV) Porphyrin -Cation Radical Complex: Entropy Control of an Allylic Hydroxylation Reaction
Akihiro Takahashi, Takuya Kurahashi, and Hiroshi Fujii
pp 6227 - 6229; DOI:
10.1021/ic7009379
PDF
Carbene- and Carbyne-like Behavior of the Mo-P Multiple Bond in a Dimolybdenum Complex Inducing Trigonal-Pyramidal Coordination of a Phosphinidene Ligand
M. Angeles Alvarez, Inmaculada Amor, M. Esther García, Daniel García-Vivó, and Miguel A. Ruiz
pp 6230 - 6232; DOI:
10.1021/ic701055y
PDF
Porous Nonlinear-Optical Material Based on a Twin-Nest-Shaped Heterothiometallic Cluster: {[NH4][W2O2S6Cu6I3(4,4'-bipy)4]·5H2O}n
Kexuan Huang, Yinglin Song, Zhaorui Pan, Yizhi Li, Xin Zhuo, and Hegen Zheng
pp 6233 - 6235; DOI:
10.1021/ic700794y
PDF
Novel Gold(I) 7-Azacoumarin Complex: Synthesis, Structure, Optical Properties, and Cytotoxic Effects
José S. Casas, Eduardo E. Castellano, María D. Couce, Olga Crespo, Javier Ellena, Antonio Laguna, Agustín Sánchez, José Sordo, and Carmen Taboada
pp 6236 - 6238; DOI:
10.1021/ic700861a
PDF
Low-Coordinate Transition-Metal Complexes of a Carbon-Substituted Hemiporphyrazine
Anil Çetin, William S. Durfee, and Christopher J. Ziegler
pp 6239 - 6241; DOI:
10.1021/ic7011099
PDF
Toward the Rational Design of Lanthanide Coordination Polymers: a New Topological Approach
Claire Marchal, Yaroslav Filinchuk, Daniel Imbert, Jean-Claude G. Bünzli, and Marinella Mazzanti
pp 6242 - 6244; DOI:
10.1021/ic7009918
PDF
DNA Three-Way Junction with a Dinuclear Iron(II) Supramolecular Helicate at the Center: A NMR Structural Study
Leonardo Cerasino, Michael J. Hannon, and Einar Sletten
pp 6245 - 6251; DOI:
10.1021/ic062415c
PDF
Synthesis, Luminescence, and Electrochemical Studies of Tris(homoleptic) Ruthenium(II) and Osmium(II) Complexes of 6'-Tolyl-2,2':4',2' '-terpyridine
E. Rajalakshmanan and V. Alexander
pp 6252 - 6260; DOI:
10.1021/ic0700093
PDF
Electronic and Magnetic Interactions in -Stacked Bisthiadiazinyl Radicals
Alicea A. Leitch, Richard T. Oakley, Robert W. Reed, and Laurence K. Thompson
pp 6261 - 6270; DOI:
10.1021/ic0700405
PDF
Silver(I) and Thallium(I) Complexes of a PNP Ligand and Their Utility as PNP Transfer Reagents
Jessica C. DeMott, Falguni Basuli, Uriah J. Kilgore, Bruce M. Foxman, John C. Huffman, Oleg V. Ozerov, and Daniel J. Mindiola
pp 6271 - 6276; DOI:
10.1021/ic0700598
PDF
A New Hg2+-Selective Fluorescent Sensor Based on a 1,3-Alternate Thiacalix[4]arene Anchored with Four 8-Quinolinoloxy Groups
L. Praveen, V. B. Ganga, R. Thirumalai, T. Sreeja, M. L. P. Reddy, and R. Luxmi Varma
pp 6277 - 6282; DOI:
10.1021/ic070259j
PDF
Amine-Controlled Assembly of Metal-Sulfite Architecture from 1D Chains to 3D Framework
Cristina Austria, Jian Zhang, Henry Valle, Qichun Zhang, Emily Chew, Dan-Tam Nguyen, J. Y. Gu, Pingyun Feng, and Xianhui Bu
pp 6283 - 6290; DOI:
10.1021/ic070325h
PDF
Electronic Structure of the Alkyne-Bridged Dicobalt Hexacarbonyl Complex Co2 -C2H2 (CO)6: Evidence for Singlet Diradical Character and Implications for Metal-Metal Bonding
James A. Platts, Gareth. J. S. Evans, Michael P. Coogan, and Jacob Overgaard
pp 6291 - 6298; DOI:
10.1021/ic070278t
PDF
Copper(II), Cobalt(II), and Nickel(II) Complexes with a Bulky Anthracene-Based Carboxylic Ligand: Syntheses, Crystal Structures, and Magnetic Properties
Chun-Sen Liu, Jun-Jie Wang, Li-Fen Yan, Ze Chang, Xian-He Bu, E. Carolina Sañudo, and Joan Ribas
pp 6299 - 6310; DOI:
10.1021/ic070086y
PDF
A Theoretical Study of the Inner-Sphere Disproportionation Reaction Mechanism of the Pentavalent Actinyl Ions
Helen Steele and Robin J. Taylor
pp 6311 - 6318; DOI:
10.1021/ic070235c
PDF
Chemical Bonding in TiSb2 and VSb2: A Quantum Chemical and Experimental Study
Marc Armbrüster, Walter Schnelle, Ulrich Schwarz, and Yuri Grin
pp 6319 - 6328; DOI:
10.1021/ic070284p
PDF
Highly Uniform and Monodisperse -NaYF4:Ln3+ (Ln = Eu, Tb, Yb/Er, and Yb/Tm) Hexagonal Microprism Crystals: Hydrothermal Synthesis and Luminescent Properties
Chunxia Li, Zewei Quan, Jun Yang, Piaoping Yang, and Jun Lin
pp 6329 - 6337; DOI:
10.1021/ic070335i
PDF
Structural and Coordination Studies of "Pearl Oysterlike" Porphyrins
Zakaria Halime, Mohammed Lachkar, Thierry Roisnel, Philippe Richard, and Bernard Boitrel
pp 6338 - 6346; DOI:
10.1021/ic0703272
PDF
One-Dimensional Indium Sulfides with Transition Metal Complexes of Polyamines
Jian Zhou, Guo-Qing Bian, Yong Zhang, Qin-Yu Zhu, Chun-Yin Li, and Jie Dai
pp 6347 - 6352; DOI:
10.1021/ic070334q
PDF
Mechanism of Cis-Dihydroxylation and Epoxidation of Alkenes by Highly H2O2 Efficient Dinuclear Manganese Catalysts
Johannes W. de Boer, Wesley R. Browne, Jelle Brinksma, Paul L. Alsters, Ronald Hage, and Ben L. Feringa
pp 6353 - 6372; DOI:
10.1021/ic7003613
PDF
Synthesis, Structure, and LLCT Transitions in Terminal Hydrazido(2-) Bipyridine Complexes of Titanium
Sameer Patel, Yahong Li, and Aaron L. Odom
pp 6373 - 6381; DOI:
10.1021/ic700426s
PDF
Reactivity Studies on FeIII-(O22-)-CuII Compounds: Influence of the Ligand Architecture and Copper Ligand Denticity
Eduardo E. Chufán, Biplab Mondal, Thirumanavelan Gandhi, Eunsuk Kim, Nick D. Rubie, Pierre Moënne-Loccoz, and Kenneth D. Karlin
pp 6382 - 6394; DOI:
10.1021/ic700363k
PDF
Topological Metastability and Oxide Ionic Conduction in La2-xEuxMo2O9
Gwenaël Corbel, Elodie Chevereau, Stéphanie Kodjikian, and Philippe Lacorre
pp 6395 - 6404; DOI:
10.1021/ic700876d
PDF
Selective Fluorescence Zinc Ion Sensing and Binding Behavior of 4-Methyl-2,6-bis(((phenylmethyl)imino)methyl)phenol: Biological Application
Partha Roy, Koushik Dhara, Mario Manassero, Jagnyeswar Ratha, and Pradyot Banerjee
pp 6405 - 6412; DOI:
10.1021/ic700420w
PDF
Complexation of AlIII by Aromatic Amino Acids in the Gas Phase
E. Rezabal, T. Marino, J. M. Mercero, N. Russo, and J. M. Ugalde
pp 6413 - 6419; DOI:
10.1021/ic7004776
PDF
Electronic Structure of Bispidine Iron(IV) Oxo Complexes
Anna E. Anastasi, Peter Comba, John McGrady, Achim Lienke, and Heidi Rohwer
pp 6420 - 6426; DOI:
10.1021/ic700429x
PDF
Anion-Selective Interaction and Colorimeter by an Optical Metalloreceptor Based on Ruthenium(II) 2,2'-Biimidazole: Hydrogen Bonding and Proton Transfer
Ying Cui, Hao-Jun Mo, Jin-Can Chen, Yan-Li Niu, Yong-Rui Zhong, Kang-Cheng Zheng, and Bao-Hui Ye
pp 6427 - 6436; DOI:
10.1021/ic7004562
PDF
From Pseudo to True C3 Symmetry: Magnetic Anisotropy Enhanced by Site-Specific Ligand Substitution in Two Mn15-Carboxylate Clusters
Yan-Zhen Zheng, Wei Xue, Wei-Xiong Zhang, Ming-Liang Tong, and Xiao-Ming Chen
pp 6437 - 6443; DOI:
10.1021/ic7004584
PDF
Au···Au Interactions: Z ' > 1 Behavior and Structural Analysis
Kirsty M. Anderson, Andrés E. Goeta, and Jonathan W. Steed
pp 6444 - 6451; DOI:
10.1021/ic700466y
PDF
Occupation Waves the Way You Have Never Seen Them: the Orthorhombic Quasicrystal Approximants RE13Zn58+ (RE = Ho, Er, Tm, and Lu)
ShuYing Piao and Sven Lidin
pp 6452 - 6463; DOI:
10.1021/ic700476w
PDF
Synthesis, Characterization, Photophysical, and Computational Studies of Rhenium(I) Tricarbonyl Complexes Containing the Derivatives of Bipyrazine
Robert Kirgan, Megan Simpson, Curtis Moore, Jeff Day, Loan Bui, Clayton Tanner, and D. Paul Rillema
pp 6464 - 6472; DOI:
10.1021/ic700512j
PDF
Synthesis and Structural Properties of Lanthanide Complexes Formed with Tropolonate Ligands
Jian Zhang, Paul D. Badger, Steven J. Geib, and Stéphane Petoud
pp 6473 - 6482; DOI:
10.1021/ic7005343
PDF
Platinum Acetylide Two-Photon Chromophores
Joy E. Rogers, Jonathan E. Slagle, Douglas M. Krein, Aaron R. Burke, Benjamin C. Hall, Albert Fratini, Daniel G. McLean, Paul A. Fleitz, Thomas M. Cooper, Mikhail Drobizhev, Nikolay S. Makarov, Aleksander Rebane, Kye-Young Kim, Richard Farley, and Kirk S. Schanze
pp 6483 - 6494; DOI:
10.1021/ic700549n
PDF
Ni3(Mo2O8)(XO3) (X = Se, Te): The First Nickel Selenite- and Tellurite-Containing Mo4 Clusters
Hai-Long Jiang, Zhi Xie, and Jiang-Gao Mao
pp 6495 - 6501; DOI:
10.1021/ic700500q
PDF
Heterodimetallic Germanium(IV) Complex Structures with Transition Metals
Fa-Nian Shi, Luís Cunha-Silva, Michaele J. Hardie, Tito Trindade, Filipe A. Almeida Paz, and João Rocha
pp 6502 - 6515; DOI:
10.1021/ic700507j
PDF
Synthesis, Characterization, Solid-State Structures, and Spectroscopic Properties of Two Catechol-Based Luminescent Chemosensors for Biologically Relevant Oxometalates
Helen D. Batey, Adrian C. Whitwood, and Anne-K. Duhme-Klair
pp 6516 - 6528; DOI:
10.1021/ic700554n
PDF
Substituent Effects on the Structures of Silver Complexes with Monoazatrithia-12-Crown-4 Ethers Bearing Substituted Aromatic Rings
Yoichi Habata, Kanae Noto, and Futoshi Osaka
pp 6529 - 6534; DOI:
10.1021/ic700538f
PDF
Copper(I) Complexes of Bis(2-(diphenylphosphino)phenyl) Ether: Synthesis, Reactivity, and Theoretical Calculations
Ramalingam Venkateswaran, Maravanji S. Balakrishna, Shaikh M. Mobin, and Heikki M. Tuononen
pp 6535 - 6541; DOI:
10.1021/ic7005474
PDF
Organic-Acid Effect on the Structures of a Series of Lead(II) Complexes
Jin Yang, Jian-Fang Ma, Ying-Ying Liu, Ji-Cheng Ma, and Stuart R. Batten
pp 6542 - 6555; DOI:
10.1021/ic700613c
PDF
A Spectroscopic and Computational Investigation of the Vanadomolybdate Local Structure in the Lyonsite Phase Mg2.5VMoO8
Jared P. Smit, Hack-Sung Kim, Ian Saratovsky, Klaus B. Stark, George Fitzgerald, Gerry W. Zajac, Jean-François Gaillard, Kenneth R. Poeppelmeier, and Peter C. Stair
pp 6556 - 6564; DOI:
10.1021/ic7006815
PDF
Structural and Mechanistic Studies of Bis(phenolato)amine Zinc(II) Catalysts for the Polymerization of -Caprolactone
Carter M. Silvernail, Letitia J. Yao, Lyndal M. R. Hill, Marc A. Hillmyer, and William B. Tolman
pp 6565 - 6574; DOI:
10.1021/ic700581s
PDF
Copper(II) and Copper(III) Complexes of Pyrrole-Appended Oxacarbaporphyrin
Miosz Pawlicki, Izabela Kaska, and Lechosaw Latos-Grayski
pp 6575 - 6584; DOI:
10.1021/ic700631t
PDF
Repeated Dihydrogen Elimination from Amidine Adducts of Group 13 Element Hydrides: An Evaluation of the Reaction Pathways
H.-J. Himmel
pp 6585 - 6593; DOI:
10.1021/ic700653z
PDF
(6,3)-Honeycomb Structures of Uranium(VI) Benzenedicarboxylate Derivatives: The Use of Noncovalent Interactions to Prevent Interpenetration
Yong Bok Go, Xiqu Wang, and Allan J. Jacobson
pp 6594 - 6600; DOI:
10.1021/ic700693f
PDF
Incorporation of a Designed Ruthenium Nitrosyl in PolyHEMA Hydrogel and Light-Activated Delivery of NO to Myoglobin
Genevieve M. Halpenny, Marilyn M. Olmstead, and Pradip K. Mascharak
pp 6601 - 6606; DOI:
10.1021/ic700694b
PDF
Hydrothermal Synthesis of a Novel Uranium Oxalate/Glycolate via In-Situ Ligand Formation
Karah E. Knope and Christopher L. Cahill
pp 6607 - 6612; DOI:
10.1021/ic700700e
PDF
Penta- and Hexaruthenium Carbonyl 'Raft' Complexes Supported by Monocarborane Cage Ligands
Shaowu Du, Bruce E. Hodson, Peng Lei, Thomas D. McGrath, and F. Gordon A. Stone
pp 6613 - 6620; DOI:
10.1021/ic700746j
PDF
Structural, Kinetic, and Thermodynamic Characterization of the Interconverting Isomers of MS-325, a Gadolinium(III)-Based Magnetic Resonance Angiography Contrast Agent
Zoltán Tyeklár, Stephen U. Dunham, Katarina Midelfort, Daniel M. Scott, Hirano Sajiki, Karen Ong, Randall B. Lauffer, Peter Caravan, and Thomas J. McMurry
pp 6621 - 6631; DOI:
10.1021/ic7006843
PDF
Albumin Binding, Relaxivity, and Water Exchange Kinetics of the Diastereoisomers of MS-325, a Gadolinium(III)-Based Magnetic Resonance Angiography Contrast Agent
Peter Caravan, Giacomo Parigi, Jaclyn M. Chasse, Normand J. Cloutier, Jeffrey J. Ellison, Randall B. Lauffer, Claudio Luchinat, Sarah A. McDermid, Marga Spiller, and Thomas J. McMurry
pp 6632 - 6639; DOI:
10.1021/ic700686k
PDF
M(bipyridine)V4O10 (M = Cu, Ag): Hybrid Analogues of Low-Dimensional Reduced Vanadates
Bangbo Yan and Paul A. Maggard
pp 6640 - 6646; DOI:
10.1021/ic700729q
PDF
Construction of [(5-C5Me5)MoS3Cu3]-Based Supramolecular Assemblies from the [(5-C5Me5)MoS3(CuNCS)3]- Cluster Anion and Multitopic Ligands with Different Symmetries
Wen-Hua Zhang, Ying-Lin Song, Zhi-Gang Ren, Hong-Xi Li, Ling-Ling Li, Yong Zhang, and Jian-Ping Lang
pp 6647 - 6660; DOI:
10.1021/ic700762x
PDF
Study of Ba3MIIMIVWO9 (MII = Ca, Zn; MIV = Ti, Zr) Perovskite Oxides: Competition between 3C and 6H Perovskite Structures
Rohini Mani, P. Selvamani, Joby E. Joy, J. Gopalakrishnan, and Tapas Kumar Mandal
pp 6661 - 6667; DOI:
10.1021/ic7007655
PDF
Synthesis and Structural and Magnetic Characterization of {[(phen)2Ni]2(-P2O7)}·27H2O and {[(phen)2Mn]2(-P2O7)}·13H2O: Rare Examples of Coordination Complexes with the Pyrophosphate Ligand
Oluwatayo F. Ikotun, N. Gabriel Armatus, Miguel Julve, Paul E. Kruger, Francesc Lloret, Mark Nieuwenhuyzen, and Robert P. Doyle
pp 6668 - 6674; DOI:
10.1021/ic700439a
PDF
Luminescence and Photocatalytic Activity of ZnO Nanocrystals: Correlation between Structure and Property
Yuanhui Zheng, Chongqi Chen, Yingying Zhan, Xingyi Lin, Qi Zheng, Kemei Wei, Jiefang Zhu, and Yingjie Zhu
pp 6675 - 6682; DOI:
10.1021/ic062394m
PDF
Syntheses and Characterizations of Three Low-Dimensional Chloride-Rich Zincophosphates Assembled about [d-Co(en)3]3+ and [dl-Co(en)3]3+ Complex Cations
Peng Chen, Jiyang Li, Fangzheng Duan, Jihong Yu, Ruren Xu, and Raj Pal Sharma
pp 6683 - 6687; DOI:
10.1021/ic062103+
PDF
Volatile Imido-Hydrazido Compounds of the Refractory Metals Niobium, Tantalum, Molybdenum, and Tungsten
Daniel Gaess, Klaus Harms, Michael Pokoj, Wolfgang Stolz, and Jörg Sundermeyer
pp 6688 - 6701; DOI:
10.1021/ic062435e
PDF
Linear Metal-Metal-Bonded Tetranuclear M-Mo-Mo-M Complexes (M = Ir and Rh): Oxidative Metal-Metal Bond Formation in a Tetrametallic System and 1,4-Addition Reaction of Alkyl Halides
Masato Ohashi, Asuka Shima, Tobias Rüffer, Hitoshi Mizomoto, Yutaka Kaneda, and Kazushi Mashima
pp 6702 - 6714; DOI:
10.1021/ic062474q
PDF
Interaction between the DNA Model Base 9-Ethylguanine and a Group of Ruthenium Polypyridyl Complexes: Kinetics and Conformational Temperature Dependence
Eva Corral, Anna C. G. Hotze, Alessandra Magistrato, and Jan Reedijk
pp 6715 - 6722; DOI:
10.1021/ic070092u
PDF
Chelation of Vanadium(V) by Difluoromethylene Bisphosphonate, a Structural Analogue of Pyrophosphate
Debbie C. Crans, Alvin A. Holder, Tapan Kumar Saha, G. K. Surya Prakash, Muhammed Yousufuddin, Roman Kultyshev, Rehana Ismail, Myron F. Goodman, James Borden, and Jan Florián
pp 6723 - 6732; DOI:
10.1021/ic062484r
PDF
Tetrazol-2-yl as a Donor Group for Incorporation of a Spin-Crossover Function Based on Fe(II) Ions into a Coordination Network
Robert Bronisz
pp 6733 - 6739; DOI:
10.1021/ic070223r
PDF
One-Pot, High-Yield Synthesis of Size-Controlled Gold Particles with Narrow Size Distribution
Shaojun Guo and Erkang Wang
pp 6740 - 6743; DOI:
10.1021/ic700662j
PDF
Syntheses and Characterization of Organo-Group 14 Cobaloxime Compounds
Alan M. Stolzenberg, Sarah R. Workman, Jessica E. Gutshall, Jeffrey L. Petersen, and Novruz Akhmedov
pp 6744 - 6754; DOI:
10.1021/ic070251+
PDF
Effects of Central Metal Ions on Vibrational Circular Dichroism Spectra of Tris-(-diketonato)metal(III) Complexes
Hisako Sato, Tohru Taniguchi, Atsufumi Nakahashi, Kenji Monde, and Akihiko Yamagishi
pp 6755 - 6766; DOI:
10.1021/ic070300i
PDF
Kinetics and Mechanism of Oxidation Reactions of Porphyrin-Iron(IV)-Oxo Intermediates
Zhengzheng Pan and Martin Newcomb
pp 6767 - 6774; DOI:
10.1021/ic700395j
PDF
Silver Aggregation Caused by Stanna-closo-dodecaborate Coordination: Syntheses, Solid-State Structures and Theoretical Studies
Siegbert Hagen, Hartmut Schubert, Cäcilia Maichle-Mössmer, Ingo Pantenburg, Florian Weigend, and Lars Wesemann
pp 6775 - 6784; DOI:
10.1021/ic700464d
PDF
Syntheses, Structures, and Characterizations of Four New Lead(II) 5-Sulfosalicylate Complexes with Both Chelating and Bridging Neutral Ligands
Sai-Rong Fan and Long-Guan Zhu
pp 6785 - 6793; DOI:
10.1021/ic700611e
PDF
Solution NMR Studies of Iron(II) Spin-Crossover Complexes
Birgit Weber and F. Ann Walker
pp 6794 - 6803; DOI:
10.1021/ic062349e
PDF
EXAFS Study of Aqueous ZrIV and ThIV Complexes in Alkaline CaCl2 Solutions: Ca3[Zr(OH)6]4+ and Ca4[Th(OH)8]4+
B. Brendebach, M. Altmaier, J. Rothe, V. Neck, and M. A. Denecke
pp 6804 - 6810; DOI:
10.1021/ic070318t
PDF
Square-Planar Rhodium(I) Complexes Partnered with [arachno-6-SB9H12]-: A Route toward the Synthesis of New Rhodathiaboranes and Organometallic/Thiaborane Salts
Álvaro Álvarez, Ramón Macías, María José Fabra, Maria L. Martín, Fernando J. Lahoz, and Luis A. Oro
pp 6811 - 6826; DOI:
10.1021/ic700648z
PDF

Issue 17


A Double Helix Is the Repeating Unit in a Luminescent Calcium 5-Aminoisophthalate Supramolecular Edifice with Water-Filled Hexagonal Channels
Ramaswamy Murugavel, Parimal Kumar, Mrinalini G. Walawalkar, and Ramyaa Mathialagan
pp 6828 - 6830; DOI:
10.1021/ic070113k
PDF
Delocalized Mixed-Valence Bi- and Trinuclear Complexes with Short Cu-Cu Bonds
Lei Yang, Douglas R. Powell, Eric L. Klein, Andreas Grohmann, and Robert P. Houser
pp 6831 - 6833; DOI:
10.1021/ic7010474
PDF
Thiolato-Bridged RuIIAgIRuII Trinuclear Complex Composed of Bis(bipyridine)ruthenium(II) Units with Chelating 2-Aminoethanethiolate: Conversion to a Disulfide-Bridged RuIIRuII Dinuclear Complex
Motoshi Tamura, Noriyuki Matsuura, Tatsuya Kawamoto, and Takumi Konno
pp 6834 - 6836; DOI:
10.1021/ic700572r
PDF
Synthesis and Magnetic Properties of a Highly Conducting Neutral Nickel Complex with a Highly Conjugated Tetrathiafulvalenedithiolate Ligand
He-Rui Wen, Cheng-Hui Li, You Song, Jing-Lin Zuo, Bin Zhang, and Xiao-Zeng You
pp 6837 - 6839; DOI:
10.1021/ic070264n
PDF
Electrochromic Polymer Films Containing Re(I) and Pt(II) Metal Centers
Joshua R. Farrell, David P. Lavoie, Ryan T. Pennell, Anil Çetin, Janet L. Shaw, and Christopher J. Ziegler
pp 6840 - 6842; DOI:
10.1021/ic700635h
PDF
Isoreticular Homochiral Porous Metal-Organic Structures with Tunable Pore Sizes
Danil N. Dybtsev, Maxim P. Yutkin, Eugenia V. Peresypkina, Alexander V. Virovets, Christian Serre, Gérard Férey, and Vladimir P. Fedin
pp 6843 - 6845; DOI:
10.1021/ic7009226
PDF
Selective Ligand Conversion of Ethylenediamine Tetraacetate to Its Triacetate on Peroxotitanate(IV)
Zhao-Hui Zhou, Yuan-Fu Deng, Qiong-Xin Liu, Hua-Lin Zhang, Thomas C. W. Mak, and Yuan L. Chow
pp 6846 - 6848; DOI:
10.1021/ic701256e
PDF
Metal-Mediated Peptide Assembly: Use of Metal Coordination to Change the Oligomerization State of an -Helical Coiled-Coil
Mikhail V. Tsurkan and Michael Y. Ogawa
pp 6849 - 6851; DOI:
10.1021/ic700958h
PDF
Unprecedented (3,10)-Connected 2-D Metal-Organic Framework Constructed from Octanuclear Cobalt(II) Clusters and a New Bifunctional Ligand
Wen-Qiang Zou, Ming-Sheng Wang, Yan Li, A-Qing Wu, Fa-Kun Zheng, Qi-Yong Chen, Guo-Cong Guo, and Jin-Shun Huang
pp 6852 - 6854; DOI:
10.1021/ic700820d
PDF
Zirconium-Catalyzed Heterodehydrocoupling of Primary Phosphines with Silanes and Germanes
Andrew J. Roering, Samantha N. MacMillan, Joseph M. Tanski, and Rory Waterman
pp 6855 - 6857; DOI:
10.1021/ic7013144
PDF
A Rare Dimer of Dimers Having Four Hydride Linkers Joining Two Quadruply Bonded Dimolybdenum Units
F. Albert Cotton, Carlos A. Murillo, and Qinliang Zhao
pp 6858 - 6863; DOI:
10.1021/ic701048d
PDF
Synthesis, Structure, and Bonding of Eu3Bi(Sn,Bi)4. A Rare Inverse-Cr5B3-Type Structure with a New Tin/Bismuth Network
Ming-Hui Ge and John D. Corbett
pp 6864 - 6870; DOI:
10.1021/ic070281c
PDF
Gadolinium Acetylacetonate Tetraphenyl Monoporphyrinate Complex and Some of Its Derivatives: EXAFS Study and Molecular Dynamics Simulation
J. H. Agondanou, I. Nicolis, E. Curis, J. Purans, G. A. Spyroulias, A. G. Coutsolelos, and S. Bénazeth
pp 6871 - 6879; DOI:
10.1021/ic061861x
PDF
Synthesis and Characterization of Tetrahedral and Square Planar Bis(iminopyrrolyl) Complexes of Cobalt(II)
Sónia A. Carabineiro, Leonel C. Silva, Pedro T. Gomes, Laura C. J. Pereira, Luís F. Veiros, Sofia I. Pascu, M. Teresa Duarte, Sónia Namorado, and Rui T. Henriques
pp 6880 - 6890; DOI:
10.1021/ic062125w
PDF
Syntheses of Homochiral Multinuclear Ru Complexes Based on Oligomeric Bibenzimidazoles
Jun Yin and Ronald L. Elsenbaumer
pp 6891 - 6901; DOI:
10.1021/ic062148a
PDF
Structure and Properties of Dinuclear Manganese(III) Complexes with Pentaanionic Pentadentate Ligands Including Alkoxo, Amido, and Phenoxo Donors
Liliana Stoicescu, Aurélie Jeanson, Carine Duhayon, Ana Tesouro-Vallina, Athanassios K. Boudalis, Jean-Pierre Costes, and Jean-Pierre Tuchagues
pp 6902 - 6910; DOI:
10.1021/ic062398r
PDF
Bimetallic Iridium(III) Complexes Consisting of Ir(ppy)2 Units (ppy = 2-Phenylpyridine) and Two Laterally Connected NN Chelates as Bridge: Synthesis, Separation, and Photophysical Properties
Audrey Auffrant, Andrea Barbieri, Francesco Barigelletti, Jérôme Lacour, Pierre Mobian, Jean-Paul Collin, Jean-Pierre Sauvage, and Barbara Ventura
pp 6911 - 6919; DOI:
10.1021/ic700494e
PDF
Synthesis of CdTe Nanocrystals Using Te Nanorods as the Te Source and the Formation of Microtubes with Red Fluorescence
Rongbo Zheng, Shaojun Guo, and Shaojun Dong
pp 6920 - 6923; DOI:
10.1021/ic700502v
PDF
Copper(II) Complexes with New Polypodal Ligands Presenting Axial-Equatorial Phenoxo Bridges {2-[(Bis(2-pyridylmethyl)amino)methyl]-4-methylphenol, 2-[(Bis(2-pyridylmethyl)amino)methyl]-4-methyl-6-(methylthio)phenol}: Examples of Ferromagnetically Coupled Bi- and Trinuclear Copper(II) Complexes
Jorge Manzur, Hector Mora, Andrés Vega, Evgenia Spodine, Diego Venegas-Yazigi, María Teresa Garland, M. Salah El Fallah, and Albert Escuer
pp 6924 - 6932; DOI:
10.1021/ic700544b
PDF
REAu2In4 (RE = La, Ce, Pr, Nd): Polyindides from Liquid Indium
James R. Salvador, Khang Hoang, S. D. Mahanti, and Mercouri G. Kanatzidis
pp 6933 - 6941; DOI:
10.1021/ic700633b
PDF
fac-Re(CO)3L Complexes Containing Tridentate Monoanionic Ligands (L-) with a Seldom-Studied Sulfonamido Group As One Terminal Ligating Group
Anna Maria Christoforou, Frank R. Fronczek, Patricia A. Marzilli, and Luigi G. Marzilli
pp 6942 - 6949; DOI:
10.1021/ic700594a
PDF
Single-Boron Complexes of N-Confused and N-Fused Porphyrins
Anna Modzianowska, Lechosaw Latos-Grayski, Ludmia Szterenberg, and Marcin Stpie
pp 6950 - 6957; DOI:
10.1021/ic700647v
PDF
Coordinatively Unsaturated Semisandwich Complexes of Ruthenium with Phosphinoamine Ligands and Related Species: A Complex Containing (R,R)-1,2-Bis((diisopropylphosphino)amino)cyclohexane in a New Coordination Form 3P,P',N-2-P,N
M. Dolores Palacios, M. Carmen Puerta, Pedro Valerga, Agustí Lledós, and Edouard Veilly
pp 6958 - 6967; DOI:
10.1021/ic700674c
PDF
High-Spin Mn Wheels
Maria Manoli, Alessandro Prescimone, Rashmi Bagai, Abhudaya Mishra, Muralee Murugesu, Simon Parsons, Wolfgang Wernsdorfer, George Christou, and Euan K. Brechin
pp 6968 - 6979; DOI:
10.1021/ic7007528
PDF
Ag/ZnO Heterostructure Nanocrystals: Synthesis, Characterization, and Photocatalysis
Yuanhui Zheng, Lirong Zheng, Yingying Zhan, Xingyi Lin, Qi Zheng, and Kemei Wei
pp 6980 - 6986; DOI:
10.1021/ic700688f
PDF
Vibrational Properties of Polyanionic Hydrides SrAl2H2 and SrAlSiH: New Insights into Al-H Bonding Interactions
Myeong H. Lee, Otto F. Sankey, Thomas Björling, David Moser, Dag Noréus, Stewart F. Parker, and Ulrich Häussermann
pp 6987 - 6991; DOI:
10.1021/ic700722b
PDF
A U(V) Chalcogenide: Synthesis, Structure, and Characterization of K2Cu3US5
Danielle L. Gray, Lisa A. Backus, Hans-Albrecht Krug von Nidda, S. Skanthakumar, Alois Loidl, L. Soderholm, and James A. Ibers
pp 6992 - 6996; DOI:
10.1021/ic700774g
PDF
Observation of a Mixed-Metal Transition in Heterobimetallic Au/Ag Dicyanide Systems
Samanthika R. Hettiarachchi, Brian K. Schaefer, Renante L. Yson, Richard J. Staples, Regine Herbst-Irmer, and Howard H. Patterson
pp 6997 - 7004; DOI:
10.1021/ic700780k
PDF
Synthesis, Structure, Characterization, and Calculations of Two New Sn2+-W6+-oxides, Sn2WO5 and Sn3WO6
Hong Young Chang, Kang Min Ok, Jun Ho Kim, P. Shiv Halasyamani, Matthew Stoltzfus, and Patrick Woodward
pp 7005 - 7011; DOI:
10.1021/ic700740m
PDF
New Luminescent Solids in the Ln-W(Mo)-Te-O-(Cl) Systems
Hai-Long Jiang, En Ma, and Jiang-Gao Mao
pp 7012 - 7023; DOI:
10.1021/ic700793n
PDF
Interaction of Nitrogen Bases with Iron-Porphyrin Nitrito Complexes Fe(Por)(ONO) in Sublimed Solids
Tigran S. Kurtikyan, Astghik A. Hovhannisyan, Gurgen M. Gulyan, and Peter C. Ford
pp 7024 - 7031; DOI:
10.1021/ic700846x
PDF
Rates of Oxygen-Isotope Exchange between Sites in the [HxTa6O19](8-x)-(aq) Lindqvist Ion and Aqueous Solutions: Comparisons to [HxNb6O19](8-x)-(aq)
Edina Balogh, Travis M. Anderson, James R. Rustad, May Nyman, and William H. Casey
pp 7032 - 7039; DOI:
10.1021/ic700845e
PDF
Dinitrogen Activation, Partial Reduction, and Formation of Coordinated Imide Promoted by a Chromium Diiminepyridine Complex
Indu Vidyaratne, Jennifer Scott, Sandro Gambarotta, and Peter H. M. Budzelaar
pp 7040 - 7049; DOI:
10.1021/ic700810f
PDF
Synthesis of an Octanuclear Eu(III) Cage from Eu42+: Chloride Anion Encapsulation, Luminescence, and Reversible MeOH Adsorption via a Porous Supramolecular Architecture
Xiaoping Yang, Benjamin P. Hahn, Richard A. Jones, Wai-Kwok Wong, and Keith J. Stevenson
pp 7050 - 7054; DOI:
10.1021/ic7008682
PDF
Neutral-Ligand Complexes of Bis(imino)pyridine Iron: Synthesis, Structure, and Spectroscopy
Suzanne C. Bart, Emil Lobkovsky, Eckhard Bill, Karl Wieghardt, and Paul J. Chirik
pp 7055 - 7063; DOI:
10.1021/ic700869h
PDF
Luminescent Platinum(II) Complexes Containing Isoquinolinyl Indazolate Ligands: Synthetic Reaction Pathway and Photophysical Properties
Sheng-Yuan Chang, Jakka Kavitha, Jui-Yi Hung, Yun Chi, Yi-Ming Cheng, Elise Y. Li, Pi-Tai Chou, Gene-Hsiang Lee, and Arthur J. Carty
pp 7064 - 7074; DOI:
10.1021/ic700877n
PDF
A Computational Study of O-O Bond Formation Catalyzed by Mono- and Bis-MnIV-Corrole Complexes
Timofei Privalov, Licheng Sun, Björn Åkermark, Jianhui Liu, Yan Gao, and Mei Wang
pp 7075 - 7086; DOI:
10.1021/ic700940x
PDF
Rates of Ligand Exchange between >FeIII-OH2 Functional Groups on a Nanometer-Sized Aqueous Cluster and Bulk Solution
Edina Balogh,, Ana Maria Todea,, Achim Müller, and William H. Casey
pp 7087 - 7092; DOI:
10.1021/ic7009308
PDF
Synthesis and Characterization of Well-Defined Aluminum-Containing Heterobimetallic Selenides
Zhi Yang, Xiaoli Ma, Herbert W. Roesky, Ying Yang, Jörg Magull, and Arne Ringe
pp 7093 - 7096; DOI:
10.1021/ic700945a
PDF
Alkylation and Acylation of Cyclotriphosphazenes
Mark A. Benson, Stefano Zacchini, Ramamoorthy Boomishankar, Yuri Chan, and Alexander Steiner
pp 7097 - 7108; DOI:
10.1021/ic7009463
PDF
Are Chelate Rings Aromatic? Calculations of Magnetic Properties of Acetylacetonato and o-Benzoquinonediimine Chelate Rings
Milo K. Mili, Bojana D. Ostoji, and Sneana D. Zari
pp 7109 - 7114; DOI:
10.1021/ic062292w
PDF
Isomerization of trans-[Ru(PTA)4Cl2] to cis-[Ru(PTA)4Cl2] in Water and Organic Solvent: Revisiting the Chemistry of [Ru(PTA)4Cl2]
Charles A. Mebi and Brian J. Frost
pp 7115 - 7120; DOI:
10.1021/ic700971n
PDF
Luminescence Properties and Water Coordination of Eu3+ in the Binary Solvent Mixture Water/1-Butyl-3-methylimidazolium Chloride
Senthamizh Samikkanu, Kevin Mellem, Mary Berry, and P. Stanley May
pp 7121 - 7128; DOI:
10.1021/ic070329m
PDF
Rhenium(V) Oxo Complexes with Acetylacetone Derived Schiff Bases: Structure and Catalytic Epoxidation
Anna Sachse, Nadia C. Mösch-Zanetti, Ganna Lyashenko, J. Wolfram Wielandt, Kerstin Most, Jörg Magull, Fabio Dall'Antonia, Aritra Pal, and Regine Herbst-Irmer
pp 7129 - 7135; DOI:
10.1021/ic700381n
PDF
2,3,9,10,16,17,24,25-Octakis(octyloxycarbonyl)phthalocyanines. Synthesis, Spectroscopic, and Electrochemical Characteristics
Xueying Wang, Yuexing Zhang, Xuan Sun, Yongzhong Bian, Changqin Ma, and Jianzhuang Jiang
pp 7136 - 7141; DOI:
10.1021/ic700517e
PDF
Integration of Electron Density and Molecular Orbital Techniques to Reveal Questionable Bonds: The Test Case of the Direct Fe-Fe Bond in Fe2(CO)9
Joachim Reinhold, Oliver Kluge, and Carlo Mealli
pp 7142 - 7147; DOI:
10.1021/ic700390v
PDF
DNA and RNA Noncovalent Interaction of Platinum(II) Polypyridine Complexes
Matteo Cusumano, Maria Letizia Di Pietro, Antonino Giannetto, and Pasquale Antonio Vainiglia
pp 7148 - 7153; DOI:
10.1021/ic700495x
PDF
Preparation and Structure of Three Solvatomorphs of the Polymer [Co(dbm)2(4ptz)]n: Spin Canting Depending on the Supramolecular Organization
Leoní A. Barrios, Joan Ribas, Guillem Aromí, Jordi Ribas-Ariño, Patrick Gamez, Olivier Roubeau, and Simon J. Teat
pp 7154 - 7162; DOI:
10.1021/ic7004979
PDF
Structure Determination and Infrared Spectroscopy of K(UO2)(SO4)(OH)(H2O) and K(UO2)(SO4)(OH)
Tori Z. Forbes, Valerie Goss, Meha Jain, and Peter C. Burns
pp 7163 - 7168; DOI:
10.1021/ic700691k
PDF
Formation and Stability of Mononuclear and Dinuclear Eu(III) Complexes and Their Catalytic Reactivity Toward Cleavage of an RNA Analog
Erik R. Farquhar, John P. Richard, and Janet R. Morrow
pp 7169 - 7177; DOI:
10.1021/ic7005666
PDF
A Dinuclear Copper(II) Complex with Adeninate Bridge Ligands and Prominent DNA Cleavage Activity. Structural and Spectroscopic Characterization and Magnetic Properties
José Luis García-Giménez, Gloria Alzuet, Marta González-Álvarez, Alfonso Castiñeiras, Malva Liu-González, and Joaquín Borrás
pp 7178 - 7188; DOI:
10.1021/ic700751j
PDF
Raman Spectrum of [Ru(CNBut)(CO)(2-C6H4-2-CHO)(PPh3)2][BF4]·2CDCl3 Shows That the Crystallographically Determined Bifurcated Hydrogen-Bonding Interaction Cl3CD···F2BF2- Is an Example of a Blue-Shifting Hydrogen Bond
Alan K. Brisdon, Kevin R. Flower, and Robin G. Pritchard
pp 7189 - 7192; DOI:
10.1021/ic701065w
PDF
Electrophilic Ruthenium(VI) Nitrido Complex Containing Kläui's Oxygen Tripodal Ligand
Xiao-Yi Yi, Tony C. H. Lam, Yiu-Keung Sau, Qian-Feng Zhang, Ian D. Williams, and Wa-Hung Leung
pp 7193 - 7198; DOI:
10.1021/ic7007683
PDF
Synthesis and Reactivity of Metal Complexes Supported by the Tetradentate Monoanionic Ligand Bis(2-picolyl)(2-hydroxy-3,5-di-tert-butylbenzyl)amide (BPPA)
Wayne A. Chomitz, Stefan G. Minasian, Andrew D. Sutton, and John Arnold
pp 7199 - 7209; DOI:
10.1021/ic700775k
PDF
Formation of Hexacarbonylmanganese(I) Salts, [Mn(CO)6]+X-, in Anhydrous HF
Jens Geier, Helge Willner, Christian W. Lehmann, and Friedhelm Aubke
pp 7210 - 7214; DOI:
10.1021/ic700798z
PDF
Preparation, Characterization, and Structural Systematics of Diphosphane and Diarsane Complexes of Gallium(III) Halides
Fei Cheng, Andrew L. Hector, William Levason, Gillian Reid, Michael Webster, and Wenjian Zhang
pp 7215 - 7223; DOI:
10.1021/ic700895r
PDF
Carboxylate Coordination Chemistry of a Mononuclear Ni(II) Center in a Hydrophobic or Hydrogen Bond Donor Secondary Environment: Relevance to Acireductone Dioxygenase
Ewa Szajna-Fuller, Bonnie M. Chambers, Atta M. Arif, and Lisa M. Berreau:
pp 7224 - 7224; DOI:
10.1021/ic701340j
PDF

Issue 18


Redox Processes in a Uranium Bis(1,1'-diamidoferrocene) Complex
Marisa J. Monreal, Colin T. Carver, and Paula L. Diaconescu
pp 7226 - 7228; DOI:
10.1021/ic700457h
PDF
Bifunctional Ligand Approach for Constructing 3d-4f Heterometallic Clusters
Gang Wu, Ian J. Hewitt, Samir Mameri, Yanhua Lan, Rodolphe Clérac, Christopher E. Anson, Shilun Qiu, and Annie K. Powell
pp 7229 - 7231; DOI:
10.1021/ic070296a
PDF
Communication in Platinum Ethynylchalcogenophenes
Emma C. James, Marek Jura, Gabriele Kociok-Köhn, Paul R. Raithby, Emma L. Sharp, and Paul J. Wilson
pp 7232 - 7234; DOI:
10.1021/ic7006364
PDF
Efficient X-ray Generation of Sm2+ in Nanocrystalline BaFCl/Sm3+: a Photoluminescent X-ray Storage Phosphor
Hans Riesen and Wieslaw A. Kaczmarek
pp 7235 - 7237; DOI:
10.1021/ic062455g
PDF
Controlled Assembly of Zero-, One-, Two-, and Three-Dimensional Metal Chalcogenide Structures
Min Yuan, Matthew Dirmyer, John Badding, Ayusman Sen, Maria Dahlberg, and Peter Schiffer
pp 7238 - 7240; DOI:
10.1021/ic7007107
PDF
3D Homometallic Carboxylate Ferrimagnet Constructed from a Manganese(II) Succinate Carboxylate Layer Motif Pillared by Isonicotinate Spacers
Ming-Hua Zeng, Mei-Chun Wu, Hong Liang, Yan-Ling Zhou, Xiao-Ming Chen, and Seik-Weng Ng
pp 7241 - 7243; DOI:
10.1021/ic700832w
PDF
Long-Lived and Efficient Emission from Mononuclear Amidophosphine Complexes of Copper
Alexander J. M. Miller, Jillian L. Dempsey, and Jonas C. Peters
pp 7244 - 7246; DOI:
10.1021/ic7009513
PDF
Redox Control of meso-Zinc(II) Ferrocenylporphyrin Based Fluorescence Switches
Jonathan Rochford, A. Denise Rooney, and Mary T. Pryce
pp 7247 - 7249; DOI:
10.1021/ic0703326
PDF
Significant Increase of the Barrier Energy for Magnetization Reversal of a Single-4f-Ionic Single-Molecule Magnet by a Longitudinal Contraction of the Coordination Space
Satoshi Takamatsu, Tadahiko Ishikawa, Shin-ya Koshihara, and Naoto Ishikawa
pp 7250 - 7252; DOI:
10.1021/ic700954t
PDF
Phenylimido Functionalization of -[PW12O40]3-
Jeff C. Duhacek and Dean C. Duncan
pp 7253 - 7255; DOI:
10.1021/ic701024c
PDF
Structural Insights into the Active-Ready Form of [FeFe]-Hydrogenase and Mechanistic Details of Its Inhibition by Carbon Monoxide
Claudio Greco, Maurizio Bruschi, Jimmy Heimdal, Piercarlo Fantucci, Luca De Gioia, and Ulf Ryde
pp 7256 - 7258; DOI:
10.1021/ic701051h
PDF
Synthesis, Structure, and Computational Studies of the Tetrameric Magnesium Imides [2,4,6-Cl3C6H2NMg·S]4 (S = 1,4-Dioxane and Tetrahydrofuran)
Jeffrey A. Rood, Bruce C. Noll, and Kenneth W. Henderson
pp 7259 - 7261; DOI:
10.1021/ic701104s
PDF
Metal-Complex-Decorated Homochiral Heterobimetallic Telluride Single-Stranded Helix
Qichun Zhang, Xianhui Bu, Zhien Lin, Maurizio Biasini, W. P. Beyermann, and Pingyun Feng
pp 7262 - 7264; DOI:
10.1021/ic701135h
PDF
Expedient Method for the Transmetalation of Zn(II)-Centered Salphen Complexes
Eduardo C. Escudero-Adán, Jordi Benet-Buchholz, and Arjan W. Kleij
pp 7265 - 7267; DOI:
10.1021/ic701245r
PDF
Tin(IV) Cyanoximates: Synthesis, Characterization, and Cytotoxicity
Nikolay Gerasimchuk, Tiffany Maher, Paul Durham, Konstantin V. Domasevitch, Janet Wilking, and Andrew Mokhir
pp 7268 - 7284; DOI:
10.1021/ic061354f
PDF
Synthesis and Relative Stability of a Series of Compounds of Type [Fe(II)(bztpen)X]+, Where bztpen = Pentadentate Ligand, N5, and X- = Monodentate Anion
Norma Ortega-Villar, Víctor M. Ugalde-Saldívar, M. Carmen Muñoz, Luis A. Ortiz-Frade, José G. Alvarado-Rodríguez, José A. Real, and Rafael Moreno-Esparza
pp 7285 - 7293; DOI:
10.1021/ic0620743
PDF
Synthesis, Characterization, and X-ray Structure Determination of [Au18(P)2(PPh)4(PHPh)(dppm)6]Cl3
Paloma Sevillano, Olaf Fuhr, Oliver Hampe, Sergej Lebedkin, Eberhard Matern, Dieter Fenske, and Manfred M. Kappes
pp 7294 - 7298; DOI:
10.1021/ic062107e
PDF
Structural Study of Silver(I) Sulfonate Complexes with Pyrazine Derivatives
Hai-Yan Liu, Hua Wu, Jian-Fang Ma, Shu-Yan Song, Jin Yang, Ying-Ying Liu, and Zhong-Min Su
pp 7299 - 7311; DOI:
10.1021/ic070147s
PDF
Tetranuclear Complexes of [Fe(CO)2(C5H5)]+ with TCNX Ligands (TCNX = TCNE, TCNQ, TCNB): Intramolecular Electron Transfer Alternatives in Compounds (4-TCNX)[MLn]4
Amarendra N. Maity, Brigitte Schwederski, Biprajit Sarkar, Stanislav Záli, Jan Fiedler, Sanjib Kar, Goutam K. Lahiri, Carole Duboc, Matthias Grunert, Philipp Gütlich, and Wolfgang Kaim
pp 7312 - 7320; DOI:
10.1021/ic062253k
PDF
Synthesis, Crystal and Band Structures, and Properties of a New Mixed Three-Dimensional Framework Metal Pnictidehalide Semiconductor, (Hg6Sb4)(CdI6)
Jian-Ping Zou, Yan Li, Zhang-Jing Zhang, Guo-Cong Guo, Xi Liu, Ming-Sheng Wang, Li-Zhen Cai, Ying-Bing Lu, and Jin-Shun Huang
pp 7321 - 7325; DOI:
10.1021/ic0624165
PDF
MO Tripeptide Diastereomers (M = 99/99mTc, Re): Models To Identify the Structure of 99mTc Peptide Targeted Radiopharmaceuticals
Melchor V. Cantorias, Robertha C. Howell, Louis Todaro, John E. Cyr, Dietmar Berndorff, Robin D. Rogers, and Lynn C. Francesconi
pp 7326 - 7340; DOI:
10.1021/ic070077p
PDF
Ruthenium-Terpyridine Complexes with Multiple Ethynylpyrenyl or Ethynyltoluyl Subunits: X-ray Structure, Redox, and Spectroscopic Properties
Christine Goze, Cristiana Sabatini, Andrea Barbieri, Francesco Barigelletti, and Raymond Ziessel
pp 7341 - 7350; DOI:
10.1021/ic070149c
PDF
Metalloporphyrin-Based Inclusion Materials: Exploiting Ligating Topologies and Hydrogen-Bonding Backbones in Generating New Supramolecular Architectures
D. Krishna Kumar, Amitava Das, and Parthasarathi Dastidar
pp 7351 - 7361; DOI:
10.1021/ic0702163
PDF
Diverse Entangled Metal-Organic Framework Materials Incorporating Kinked Organodiimine and Flexible Aliphatic Dicarboxylate Ligands: Synthesis, Structure, Physical Properties, and Reversible Structural Reorganization
Matthew R. Montney, Subhashree Mallika Krishnan, Ronald M. Supkowski, and Robert L. LaDuca
pp 7362 - 7370; DOI:
10.1021/ic070291d
PDF
Synthesis and Structural Characterization of a New Nanoporous-like Keggin Heteropolyanion Salt: K3(H2O)4[H2SiVW11O40](H2O)8+x
Rodrigo de Paiva Floro Bonfim, Luiza Cristina de Moura, Hélène Pizzala, Stefano Caldarelli, Sébastien Paul, Jean Guillaume Eon, Olivier Mentré, Mickaël Capron, Laurent Delevoye, and Edmond Payen
pp 7371 - 7377; DOI:
10.1021/ic700384m
PDF
Ternary Magnesium Rhodium Boride Mg2Rh1-xB6+2x with a Modified Y2ReB6-Type Crystal Structure
A. M. Alekseeva, A. M. Abakumov, P. S. Chizhov, A. Leithe-Jasper, W. Schnelle, Yu. Prots, J. Hadermann, E. V. Antipov, and Yu. Grin
pp 7378 - 7386; DOI:
10.1021/ic7004453
PDF
Ethylenebis(triphenylphosphine)platinum as a Probe for Niobium-Mediated Diphosphorus Chemistry
Nicholas A. Piro and Christopher C. Cummins
pp 7387 - 7393; DOI:
10.1021/ic700514u
PDF
Transition Metal-Catalyzed Dissociation of Phosphine-Gallane Adducts: Isolation of Mechanistic Model Complexes and Heterogeneous Catalyst Poisoning Studies
Timothy J. Clark, Cory A. Jaska, Ayse Turak, Alan J. Lough, Zheng-Hong Lu, and Ian Manners
pp 7394 - 7402; DOI:
10.1021/ic700573j
PDF
Silver Telluride Nanotubes Prepared by the Hydrothermal Method
Aimiao Qin, Yueping Fang, Pingfang Tao, Jianyong Zhang, and Chengyong Su
pp 7403 - 7409; DOI:
10.1021/ic7006793
PDF
Why Does the Disorder of R-pn and rac-pn Ligands in the Quasi-One-Dimensional Bromo-Bridged NiIII Complexes, [Ni(pn)2Br]Br2 (pn = 1,2-diaminopropane) Afford Similar STM Patterns?
Hashen Wu, Daisuke Kawakami, Mari Sasaki, Jimin Xie, Shinya Takaishi, Takashi Kajiwara, Hitoshi Miyasaka, Masahiro Yamashita, Hiroyuki Matsuzaki, and Hiroshi Okamoto
pp 7410 - 7413; DOI:
10.1021/ic700379m
PDF
A Family of Octahedral Rhenium Cluster Complexes [Re6Q8(H2O)n(OH)6 - n]n - 4 (Q = S, Se; n = 0-6): Structural and pH-Dependent Spectroscopic Studies
Konstantin A. Brylev, Yuri V. Mironov, Spartak S. Yarovoi, Nikolai G. Naumov, Vladimir E. Fedorov, Sung-Jin Kim, Noboru Kitamura, Yusuke Kuwahara, Konatsu Yamada, Shoji Ishizaka, and Yoichi Sasaki
pp 7414 - 7422; DOI:
10.1021/ic7005265
PDF
Morphology-Controlled Synthesis of Lead Titanate Powders
Zongying Cai, Xianran Xing, Ranbo Yu, Xueyi Sun, and Guirong Liu
pp 7423 - 7427; DOI:
10.1021/ic700966n
PDF
Effects of the Substituents in the TpxCu Activation of Dioxygen: An Experimental Study
Miguel A. Mairena, Juan Urbano, José Carbajo, J. Joaquín Maraver, Eleuterio Alvarez, M. Mar Díaz-Requejo, and Pedro J. Pérez
pp 7428 - 7435; DOI:
10.1021/ic7007073
PDF
Characterization of the Diradical NSNSC-CNSSN and [NSNSC-CNSSN][MF6]n (n = 1, 2). The First Observation of an Excited Triplet State in Dimers of 7 -CNSSN Radicals
Andreas Decken, T. Stanley Cameron, Jack Passmore, J. Mikko Rautiainen, Robert W. Reed, Konstantin V. Shuvaev, and Laurence K. Thompson
pp 7436 - 7457; DOI:
10.1021/ic700638n
PDF
Unusual (-aqua)bis(-carboxylate) Bridge in Homometallic M(II) (M = Mn, Co and Ni) Two-Dimensional Compounds Based on the 1,2,3,4-Butanetetracarboxylic Acid: Synthesis, Structure, and Magnetic Properties
Laura Cañadillas-Delgado, Oscar Fabelo, Jorge Pasán, Fernando S. Delgado, Francesc Lloret, Miguel Julve, and Catalina Ruiz-Pérez
pp 7458 - 7465; DOI:
10.1021/ic7006765
PDF
195Pt NMR Chemical Shift Trend Analysis as a Method to Assign New Pt(IV)-Halohydroxo Complexes
Jurjen Kramer and Klaus R. Koch
pp 7466 - 7476; DOI:
10.1021/ic700804t
PDF
Systematic Studies of Early Actinide Complexes: Uranium(IV) Fluoroketimides
Eric J. Schelter, Ping Yang, Brian L. Scott, J. D. Thompson, Richard L. Martin, P. Jeffrey Hay, David E. Morris, and Jaqueline L. Kiplinger
pp 7477 - 7488; DOI:
10.1021/ic700455b
PDF
On the Origin of the Different Performance of Iron and Manganese Monocations in Catalyzing the Nitrous Oxide Reduction by Carbon Oxide
Francesca Rondinelli, Nino Russo, and Marirosa Toscano
pp 7489 - 7493; DOI:
10.1021/ic7007045
PDF
Effect of Axial Coordination on the Electronic Structure and Biological Activity of Dirhodium(II,II) Complexes
J. Dafhne Aguirre, Daniel A. Lutterman, Alfredo M. Angeles-Boza, Kim R. Dunbar, and Claudia Turro
pp 7494 - 7502; DOI:
10.1021/ic700708g
PDF
CsSc[B2P3O11(OH)3]: A New Borophosphate Oligomer Containing Boron in Three- and Fourfold Coordination
Prashanth W. Menezes, Stefan Hoffmann, Yurii Prots, and Rüdiger Kniep
pp 7503 - 7508; DOI:
10.1021/ic700914v
PDF
Lead-Poisoned Zinc Fingers: Quantum Mechanical Exploration of Structure, Coordination, and Electronic Excitations
Andrzej A. Jarzcki
pp 7509 - 7521; DOI:
10.1021/ic700731d
PDF
Highly Efficient Colloidal Cobalt- and Rhodium-Catalyzed Hydrolysis of H3N·BH3 in Air
Timothy J. Clark, George R. Whittell, and Ian Manners
pp 7522 - 7527; DOI:
10.1021/ic700806b
PDF
On the Mechanism of Triclinic Distortion in Chevrel Phase as Probed by In-Situ Neutron Diffraction
E. Levi, A. Mitelman, D. Aurbach, and O. Isnard
pp 7528 - 7535; DOI:
10.1021/ic7008573
PDF
An Experimental and Computational Study of Sulfur-Modified Nucleophilicity in a Dianionic NiN2S2 Complex
Kayla N. Green, Scott M. Brothers, Roxanne M. Jenkins, Cody E. Carson, Craig A. Grapperhaus, and Marcetta Y. Darensbourg
pp 7536 - 7544; DOI:
10.1021/ic700878y
PDF
New Spin-Transition-Like Copper(II)-Nitroxide Species
Catherine Hirel, Licun Li, Peter Brough, Kira Vostrikova, Jacques Pécaut, Boubker Mehdaoui, Maxime Bernard, Philippe Turek, and Paul Rey
pp 7545 - 7552; DOI:
10.1021/ic700851x
PDF
Synthesis, Molecular Structure (X-ray and DFT), and Solution Behavior of Titanium 4-Acyl-5-pyrazolonates. Correlations with Related Antitumor -Diketonato Derivatives
Francesco Caruso, Claudio Pettinari, Fabio Marchetti, Paolo Natanti, Christine Phillips, Joseph Tanski, and Miriam Rossi
pp 7553 - 7560; DOI:
10.1021/ic700935x
PDF
Heats of Formation of Boron Hydride Anions and Dianions and Their Ammonium Salts [BnHmy-][NH4+]y with y = 1-2
Minh Tho Nguyen, Myrna H. Matus, and David A. Dixon
pp 7561 - 7570; DOI:
10.1021/ic700941c
PDF
Layered Cobalt(II) and Nickel(II) Diphosphonates Showing Canted Antiferromagnetism and Slow Relaxation Behavior
Deng-Ke Cao, Yi-Zhi Li, and Li-Min Zheng
pp 7571 - 7578; DOI:
10.1021/ic701098t
PDF
Synthesis and Structures of an Unusual Germanium(II) Calix[4]arene Complex and the First Germanium(II) Calix[8]arene Complex and Their Reactivity with Diiron Nonacarbonyl
Anthony E. Wetherby, Jr., Lindy R. Goeller, Antonio G. DiPasquale, Arnold L. Rheingold, and Charles S. Weinert
pp 7579 - 7586; DOI:
10.1021/ic700969m
PDF
Biphenolate Phosphine Complexes of Tin(IV)
Lan-Chang Liang, Yu-Ning Chang, Han-Sheng Chen, and Hon Man Lee
pp 7587 - 7593; DOI:
10.1021/ic701006r
PDF
Synthesis, Structural Characterization, and Theoretical Investigation of Compounds Containing an Al-O-M-O-Al (M = Ti, Zr) Core
Swadhin K. Mandal, Prabhuodeyara M. Gurubasavaraj, Herbert W. Roesky, Rainer B. Oswald, Jörg Magull, and Arne Ringe
pp 7594 - 7600; DOI:
10.1021/ic701063v
PDF
Ionic and Neutral C60 Complexes with Coordination Assemblies of Metal Tetraphenylporphyrins, MIITPP2·DMP (M = Mn, Zn). Coexistence of (C60-)2 Dimers Bonded by One and Two Single Bonds in the Same Compound
Dmitri V. Konarev, Salavat S. Khasanov, Gunzi Saito, Akihiro Otsuka, and Rimma N. Lyubovskaya
pp 7601 - 7609; DOI:
10.1021/ic061628z
PDF
Selective Oxidation and Reduction of Trinuclear Titanium(II) Hexaazatrinaphthylene Complexes-Synthesis, Structure, and Electrochemical Investigations
Ingmar M. Piglosiewicz, Rüdiger Beckhaus, Gunther Wittstock, Wolfgang Saak, and Detlef Haase
pp 7610 - 7620; DOI:
10.1021/ic701009u
PDF
Diphenyl(dipyrazolyl)methane Complexes of Ni: Synthesis, Structural Characterization, and Chromotropism of NiBr2 Derivatives
Natalie Baho and Davit Zargarian
pp 7621 - 7632; DOI:
10.1021/ic070093m
PDF
Theoretical Study of Reaction Pathways to Borazine
W. Rodger Nutt and Michael L. McKee
pp 7633 - 7645; DOI:
10.1021/ic070193s
PDF
V2AlC, V4AlC3-x (x 0.31), and V12Al3C8: Synthesis, Crystal Growth, Structure, and Superstructure
Johannes Etzkorn, Martin Ade, and Harald Hillebrecht
pp 7646 - 7653; DOI:
10.1021/ic700382y
PDF
Kinetics and Mechanism of the Decomposition of Tetrathionate Ion in Alkaline Medium
Dénes Varga and Attila K. Horváth
pp 7654 - 7661; DOI:
10.1021/ic700992u
PDF
Benzimidazolin-2-stannylenes with N,N'-Alkyl (Me and Et) and Lewis Base Functional Groups
F. Ekkehardt Hahn, Lars Wittenbecher, Duc Le Van, and Alexander V. Zabula
pp 7662 - 7667; DOI:
10.1021/ic701064z
PDF
Synthesis, Crystal Structure, Aqueous Speciation, and Kinetics of Substitution Reactions in a Water-Soluble Mo3S4 Cluster Bearing Hydroxymethyl Diphosphine Ligands
Andrés G. Algarra, Manuel G. Basallote, M. Jesús Fernández-Trujillo, Eva Guillamón, Rosa Llusar, M. Dolores Segarra, and Cristian Vicent
pp 7668 - 7677; DOI:
10.1021/ic701082p
PDF
Synthesis and Molecular Structures of Phenylamides of Magnesium, Calcium, Strontium, and Barium - From Molecular to Polymeric Structures
Martin Gärtner, Helmar Görls, and Matthias Westerhausen
pp 7678 - 7683; DOI:
10.1021/ic7010524
PDF
The Solution Structure of [Cu(aq)]2+ and Its Implications for Rack-Induced Bonding in Blue Copper Protein Active Sites
Patrick Frank, Maurizio Benfatto, Robert K. Szilagyi, PaolaD'Angelo, Stefano Della Longa, and Keith O. Hodgson:
pp 7684 - 7684; DOI:
10.1021/ic701524x
PDF

Issue 19


Synthesis and Structure of a Molecular Barium Aminebis(phenolate) and Its Application as an Initiator for Ring-Opening Polymerization of Cyclic Esters
Matthew G. Davidson, Charles T. O'Hara, Matthew D. Jones, Callum G. Keir, Mary F. Mahon, and Gabriele Kociok-Köhn
pp 7686 - 7688; DOI:
10.1021/ic700583e
PDF
Coordination Complexes of the Dimethylthiophosphonium Cation and Ligand Exchange
Jan J. Weigand, Neil Burford, Devin Mahnke, and Andreas Decken
pp 7689 - 7691; DOI:
10.1021/ic7012792
PDF
Spin Transition at the Mesophase Transition Temperature in a Cobalt(II) Compound with Branched Alkyl Chains
Shinya Hayami, Reiko Moriyama, Aya Shuto, Yonezo Maeda, Kazuchika Ohta, and Katsuya Inoue
pp 7692 - 7694; DOI:
10.1021/ic700754s
PDF
Unusual Iron(II) and Cobalt(II) Complexes Derived from Monodentate Arylamido Ligands
Ho Yu Au-Yeung, Chung Hei Lam, Chi-Keung Lam, Wai-Yeung Wong, and Hung Kay Lee
pp 7695 - 7697; DOI:
10.1021/ic700850e
PDF
Two New Copper Azido Polymorphs: Structures, Magnetic Properties, and Effects of "Noninnocent" Reagents in Hydrothermal Methods
Fu-Chen Liu, Yong-Fei Zeng, Jiong-Peng Zhao, Bo-Wen Hu, E. Carolina Sañudo, Joan Ribas, and Xian-He Bu
pp 7698 - 7700; DOI:
10.1021/ic700669c
PDF
Novel Chlorotitanium Complexes Containing Chiral Tridentate Schiff Base Ligands for Ring-Opening Polymerization of Lactide
Junseong Lee, Youngjo Kim, and Youngkyu Do
pp 7701 - 7703; DOI:
10.1021/ic700493p
PDF
Radical (NO) and Nonradical (N2O) Reagents Convert a Ruthenium(IV) Nitride to the Same Nitrosyl Complex
Amy Walstrom, Maren Pink, Hongjun Fan, John Tomaszewski, and Kenneth G. Caulton
pp 7704 - 7706; DOI:
10.1021/ic700789y
PDF
In Situ Hydrothermal Synthesis of Nanolamellate CaTiO3 with Controllable Structures and Wettability
Daoai Wang, Zhiguang Guo, Youming Chen, Jingcheng Hao, and Weimin Liu
pp 7707 - 7709; DOI:
10.1021/ic700777f
PDF
The Highest D Value for a MnII Ion: Investigation of a Manganese(II) Polyoxometalate Complex by High-Field Electron Paramagnetic Resonance
Céline Pichon, Pierre Mialane, Eric Rivière, Guillaume Blain, Anne Dolbecq, Jérôme Marrot, Francis Sécheresse, and Carole Duboc
pp 7710 - 7712; DOI:
10.1021/ic701193f
PDF
Germanium Phthalocyanine, GePc, and the Reduced Complexes SiPc(pyridine)2 and GePc(pyridine)2 Containing Antiaromatic -Electron Circuits
Julie A. Cissell, Thomas P. Vaid, Antonio G. DiPasquale, and Arnold L. Rheingold
pp 7713 - 7715; DOI:
10.1021/ic701248u
PDF
A Convergent Coordination Chemistry-Based Approach to Dissymmetric Macrocyclic Cofacial Porphyrin Complexes
Christopher G. Oliveri, Jungseok Heo, SonBinh T. Nguyen, Chad A. Mirkin, and Zdzislaw Wawrzak
pp 7716 - 7718; DOI:
10.1021/ic701424j
PDF
Nickel-Based Oxyphosphide Superconductor with a Layered Crystal Structure, LaNiOP
Takumi Watanabe, Hiroshi Yanagi, Toshio Kamiya, Yoichi Kamihara, Hidenori Hiramatsu, Masahiro Hirano, and Hideo Hosono
pp 7719 - 7721; DOI:
10.1021/ic701200e
PDF
Novel Mixed-Metal Alkoxide Clusters of Lanthanide and Sodium: Synthesis and Extremely Active Catalysts for the Polymerization of -Caprolactone and Trimethylene Carbonate
Hongting Sheng, Fan Xu, Yingming Yao, Yong Zhang, and Qi Shen
pp 7722 - 7724; DOI:
10.1021/ic701238w
PDF
Copper-Homoscorpionate Complexes as Active Catalysts for Atom Transfer Radical Addition to Olefins
José María Muñoz-Molina, Ana Caballero, M. Mar Díaz-Requejo, Swiatoslaw Trofimenko, Tomás R. Belderraín, and Pedro J. Pérez
pp 7725 - 7730; DOI:
10.1021/ic0702872
PDF
Crystallographic and Vibrational Spectroscopic Studies of Octakis(DMSO)lanthanoid(III) Iodides
Alireza Abbasi, Emiliana Damian Risberg, Lars Eriksson, János Mink, Ingmar Persson, Magnus Sandström, Yurii V. Sidorov, Mikhail Yu. Skripkin, and Ann-Sofi Ullström
pp 7731 - 7741; DOI:
10.1021/ic7006588
PDF
X-ray Absorption Fine Structure Spectroscopic Studies of Octakis(DMSO)lanthanoid(III) Complexes in Solution and in the Solid Iodides
Ingmar Persson, Emiliana Damian Risberg, Paola D'Angelo, Simone De Panfilis, Magnus Sandström, and Alireza Abbasi
pp 7742 - 7748; DOI:
10.1021/ic700659u
PDF
A Copper(II) Ion-Selective On-Off-Type Fluoroionophore Based on Zinc Porphyrin-Dipyridylamino
Yan-Qin Weng, Fan Yue, Yong-Rui Zhong, and Bao-Hui Ye
pp 7749 - 7755; DOI:
10.1021/ic061709v
PDF
Tuning Intermolecular Magnetic Exchange Interactions in the Solids CxF2x(CNSSS)2(AsF6)2: Structural, EPR, and Magnetic Characterization of Dimeric (x = 2, 4) Diradicals
Andreas Decken, Mohammad Ebdah, Radoslaw M. Kowalczyk, Christopher P. Landee, Eric J. L. McInnes, Jack Passmore, Konstantin V. Shuvaev, and Laurence K. Thompson
pp 7756 - 7766; DOI:
10.1021/ic062475i
PDF
Supramolecular Self-Assembled Polynuclear Complexes from Tritopic, Tetratopic, and Pentatopic Ligands: Structural, Magnetic and Surface Studies
Subrata K. Dey, Tareque S. M. Abedin, Louise N. Dawe, Santokh S. Tandon, Julie L. Collins, Laurence K. Thompson, Andrei V. Postnikov, Mohammad S. Alam, and Paul Müller
pp 7767 - 7781; DOI:
10.1021/ic070336a
PDF
Mixed-Valence Iron(II, III) Trimesates with Open Frameworks Modulated by Solvents
Linhua Xie, Shuxia Liu, Chaoying Gao, Ruige Cao, Jianfang Cao, Chunyan Sun, and Zhongmin Su
pp 7782 - 7788; DOI:
10.1021/ic062273m
PDF
Tripodal Bis(imidazole) Thioether Copper(I) Complexes: Mimics of the CuM Site of Copper Hydroxylase Enzymes
Lei Zhou, Douglas Powell, and Kenneth M. Nicholas
pp 7789 - 7799; DOI:
10.1021/ic700447k
PDF
Selective Low-Temperature Syntheses of Facial and Meridional Tris-cyclometalated Iridium(III) Complexes
Kari A. McGee and Kent R. Mann
pp 7800 - 7809; DOI:
10.1021/ic700440c
PDF
Preparation of Ammonia Borane in High Yield and Purity, Methanolysis, and Regeneration
P. Veeraraghavan Ramachandran and Pravin D. Gagare
pp 7810 - 7817; DOI:
10.1021/ic700772a
PDF
Exploring the Interaction of Mercury(II) by N2S2 and NS3 Anthracene-Containing Macrocyclic Ligands: Photophysical, Analytical, and Structural Studies
Abel Tamayo, Bruno Pedras, Carlos Lodeiro, Lluis Escriche, Jaume Casabó, José Luis Capelo, Berta Covelo, Raikko Kivekäs, and Reijo Sillanpää
pp 7818 - 7826; DOI:
10.1021/ic700489e
PDF
Electronic Structures of Tris(dioxolene)chromium and Tris(dithiolene)chromium Complexes of the Electron-Transfer Series [Cr(dioxolene)3]z and [Cr(dithiolene)3]z (z = 0, 1-, 2-, 3-). A Combined Experimental and Density Functional Theoretical Study
Ruta R. Kapre, Eberhard Bothe, Thomas Weyhermüller, Serena DeBeer George, Nicoleta Muresan, and Karl Wieghardt
pp 7827 - 7839; DOI:
10.1021/ic7008607
PDF
Modulating Electronic Coupling Using O- and S-donor Linkers
F. Albert Cotton, Zhong Li, Chun Y. Liu, and Carlos A. Murillo
pp 7840 - 7847; DOI:
10.1021/ic700932s
PDF
Seven-Coordinate Iron Complex as a Ditopic Receptor for Lithium Salts: Study of Host-Guest Interactions and Substitution Behavior
David Sarauli, Vesselina Popova, Achim Zahl, Ralph Puchta, and Ivana Ivanovi-Burmazovi
pp 7848 - 7860; DOI:
10.1021/ic7005056
PDF
31P Magic Angle Spinning NMR Spectroscopy for Probing Local Environments in Paramagnetic Europium-Substituted Wells-Dawson Polyoxotungstates
Wenlin Huang, Lynn C. Francesconi, and Tatyana Polenova
pp 7861 - 7869; DOI:
10.1021/ic700521p
PDF
The First Hexanuclear Copper(I) Carboxylate: X-ray Crystal Structure and Reactivity in Solution and Gas-Phase Reactions
Yulia Sevryugina, Andrey Yu. Rogachev, and Marina A. Petrukhina
pp 7870 - 7879; DOI:
10.1021/ic7005327
PDF
The Monoanionic -Radical Redox State of -Iminoketones in Bis(ligand)metal Complexes of Nickel and Cobalt
Connie C. Lu, Eckhard Bill, Thomas Weyhermüller, Eberhard Bothe, and Karl Wieghardt
pp 7880 - 7889; DOI:
10.1021/ic7008094
PDF
Spin-State Energetics and Spin-Crossover Behavior of Pseudotetrahedral Cobalt(III)-Imido Complexes. The Role of the Tripodal Supporting Ligand
Ingar H. Wasbotten and Abhik Ghosh
pp 7890 - 7898; DOI:
10.1021/ic700543f
PDF
Investigations on a Novel Silyl Transfer Reaction in Heterodimetallic Chemistry
Abdelatif Messaoudi, Peter Deglmann, Pierre Braunstein, and Peter Hofmann
pp 7899 - 7909; DOI:
10.1021/ic700761e
PDF
[Ph3PCH2Ph]2[Zn3(tp)3Cl2] and Ni3(tma)2(H2O)8: Two Unusual Claylike Frameworks of Metal-Polycarboxylate Coordination Polymers (tp = Terephthalate, tma = Trimesate)
Guo-Dong Yang, Jing-Cao Dai, Yun-Xia Lian, Wen-Shi Wu, Jian-Ming Lin, Sheng-Min Hu, Tian-Lu Sheng, Zhi-Yong Fu, and Xin-Tao Wu
pp 7910 - 7916; DOI:
10.1021/ic700882n
PDF
Self-Catenated and Interdigitated Layered Coordination Polymers Constructed from Kinked Dicarboxylate and Organodiimine Ligands
David P. Martin, Ronald M. Supkowski, and Robert L. LaDuca
pp 7917 - 7922; DOI:
10.1021/ic700931u
PDF
Lanthanide Complexes of the Chiral Hexaaza Macrocycle and Its meso-Type Isomer: Solvent-Controlled Helicity Inversion
Janusz Gregoliski, Katarzyna lepokura, and Jerzy Lisowski
pp 7923 - 7934; DOI:
10.1021/ic700831z
PDF
Synthesis, Structure, and Upconversion Studies on Organically Templated Uranium Phosphites
Sukhendu Mandal, Manabendra Chandra, and Srinivasan Natarajan
pp 7935 - 7943; DOI:
10.1021/ic700866f
PDF
Pore-Size Tunable Mesoporous Zirconium Organophosphonates with Chiral L-Proline for Enzyme Adsorption
Xin Shi, Jian Liu, Congming Li, and Qihua Yang
pp 7944 - 7952; DOI:
10.1021/ic700892z
PDF
Steric Stabilization of a Monomeric Proalumatrane: Experimental and Theoretical Studies
Weiping Su, Junji Kobayashi, Arkady Ellern, Takayuki Kawashima, and John G. Verkade
pp 7953 - 7959; DOI:
10.1021/ic7010327
PDF
Highly Selective Ferric Ion Sorption and Exchange by Crystalline Metal Phosphonates Constructed from Tetraphosphonic Acids
Jie Wu, Hongwei Hou, Huayun Han, and Yaoting Fan
pp 7960 - 7970; DOI:
10.1021/ic062014x
PDF
Synthesis and Electrochemistry of New Rh-Centered and Conjuncto Rhodium Carbonyl Clusters. X-ray Structure of [NEt4]3[Rh15(CO)27], [NEt4]3[Rh15(CO)25(MeCN)2]·2MeCN, and [NEt4]3[Rh17(CO)37]
Davide Collini, Fabrizia Fabrizi De Biani, Serena Fedi, Cristina Femoni, Francesco Kaswalder, Maria Carmela Iapalucci, Giuliano Longoni, Cristina Tiozzo, Stefano Zacchini, and Piero Zanello
pp 7971 - 7981; DOI:
10.1021/ic0623718
PDF
Solvent Effects on the Spectroscopic and Photophysical Properties of the trans-(1,4,8,11-Tetraazacyclotetradecane)diisothiocyanatochromium(III) Ion, trans-[Cr(cyclam)(NCS)2]+
Duane A. Friesen, Rodney E. Nashiem, and William L. Waltz
pp 7982 - 7991; DOI:
10.1021/ic701096g
PDF
O-O Bond Cleavage in Dinuclear Peroxo Complexes of Iron Porphyrins: a Quantum Chemical Study
Margareta R. A. Blomberg, Adam Johannes Johansson, and Per E. M. Siegbahn
pp 7992 - 7997; DOI:
10.1021/ic7007182
PDF
Adventures in Crystallization. Crystalline Salts Containing One, Two, or Even Three Chemically Distinct Cations Obtained from Solutions of [(Cyclohexyl Isocyanide)4RhI]+
Ngon T. Tran, Jay R. Stork, David Pham, Christopher J. Chancellor, Marilyn M. Olmstead, James C. Fettinger, and Alan L. Balch
pp 7998 - 8007; DOI:
10.1021/ic7008013
PDF
Analysis of Uranium Azide and Nitride Complexes by Atmospheric Pressure Chemical Ionization Mass Spectrometry
William J. Evans, Kevin A. Miller, Joseph W. Ziller, and John Greaves
pp 8008 - 8018; DOI:
10.1021/ic7006099
PDF
Template-Free Fabrication of Hexagonal ZnO Microprism with an Interior Space
Shi-Yong Yu, Hong-Jie Zhang, Ze-Ping Peng, Li-Ning Sun, and Wei-Dong Shi
pp 8019 - 8023; DOI:
10.1021/ic7008978
PDF
In Search of the Bailar and Rây-Dutt Twist Mechanisms That Racemize Chiral Trischelates: A Computational Study of ScIII, TiIV, CoIII, ZnII, GaIII, and GeIV Complexes of a Ligand Analogue of Acetylacetonate
Henry S. Rzepa and Marion E. Cass
pp 8024 - 8031; DOI:
10.1021/ic062473y
PDF
A CASPT2 Study of the Electronic Spectrum of Hexacyanoosmate(III)
Willem Van den Heuvel, Marc F. A. Hendrickx, and Arnout Ceulemans
pp 8032 - 8037; DOI:
10.1021/ic7004612
PDF
The Solventless Syntheses of Unique PbS Nanowires of X-Shaped Cross Sections and the Cooperative Effects of Ethylenediamine and a Second Salt
Jing Chen, Ling Chen, and Li-Ming Wu
pp 8038 - 8043; DOI:
10.1021/ic7008336
PDF
Carbon-Sulfur Bond Formation via Alkene Addition to an Oxidized Ruthenium Thiolate
Craig A. Grapperhaus, Kiran B. Venna, and Mark S. Mashuta
pp 8044 - 8050; DOI:
10.1021/ic701078e
PDF
Transition-Metal-Induced Fluorescence Resonance Energy Transfer in a Cryptand Derivatized with Two Different Fluorophores
Kalyan K. Sadhu, Bamaprasad Bag, and Parimal K. Bharadwaj
pp 8051 - 8058; DOI:
10.1021/ic700506r
PDF
Synthesis, Structure, and Electrochemistry of Di- and Zerovalent Nickel, Palladium, and Platinum Monomers and Dimers Derived from an Enantiopure (S,S)-Tetra(tertiary Phosphine)
Heather J. Kitto, A. David Rae, Richard D. Webster, Anthony C. Willis, and S. Bruce Wild
pp 8059 - 8070; DOI:
10.1021/ic700912q
PDF
Amide-Silyl Ligand Exchanges and Equilibria among Group 4 Amide and Silyl Complexes
Hu Cai, Xianghua Yu, Shujian Chen, He Qiu, Ilia A. Guzei, and Zi-Ling Xue
pp 8071 - 8078; DOI:
10.1021/ic7010293
PDF
Preparation of Stable and Metastable Coordination Compounds: Insight into the Structural, Thermodynamic, and Kinetic Aspects of the Formation of Coordination Polymers
Christian Näther, Gaurav Bhosekar, and Inke Jess
pp 8079 - 8087; DOI:
10.1021/ic701079x
PDF
New Fluorescent Chemosensors for Heavy Metal Ions Based on Functionalized Pendant Arm Derivatives of 7-Anthracenylmethyl-1,4,10-trioxa-7,13-diazacyclopentadecane
M. Carla Aragoni, Massimiliano Arca, Andrea Bencini, Alexander J. Blake, Claudia Caltagirone, Andrea Danesi, Francesco A. Devillanova, Alessandra Garau, Thomas Gelbrich, Francesco Isaia, Vito Lippolis, Michael B. Hursthouse, Barbara Valtancoli, and Claire Wilson
pp 8088 - 8097; DOI:
10.1021/ic700657j
PDF
Synthesis, Gas-Phase Photoelectron Spectroscopic, and Theoretical Studies of Stannylated Dinuclear Iron Dithiolates
Richard S. Glass, Nadine E. Gruhn, Edward Lorance, Maya S.Singh, Nhu Y T. Stessman, and Uzma I. Zakai:
pp 8098 - 8098; DOI:
10.1021/ic701541g
PDF
Iron-Only Hydrogenase Mimics. Thermodynamic Aspects of the Use of Electrochemistry to Evaluate Catalytic Efficiency for Hydrogen Generation
Greg A. N. Felton, Richard S. Glass, Dennis L. Lichtenberger, and Dennis H. Evans:
pp 8098 - 8098; DOI:
10.1021/ic701610s
PDF

Issue 20


Unprecedented Examples of Heterobimetallic Cerium(IV) Disiloxanediolates
Stephan Giessmann, Steffen Blaurock, Volker Lorenz, and Frank T. Edelmann
pp 8100 - 8101; DOI:
10.1021/ic701320d
PDF
A New Quasi-1D Spin System with Spin Transition Exhibiting Novel CN··· Interactions
Zhengfang Tian, Xiaoming Ren, Yizhi Li, You Song, and Qingjin Meng
pp 8102 - 8104; DOI:
10.1021/ic700758c
PDF
Structural Diversity in Copper-Sulfur Chemistry: Synthesis of Novel Cu/S Clusters through Metathesis Reactions
John T. York, Itsik Bar-Nahum, and William B. Tolman
pp 8105 - 8107; DOI:
10.1021/ic700760p
PDF
A "Cation-less" Oxalate-Based Ferromagnet Formed by Neutral Bimetallic Layers: {[Co(H2O)2]3[Cr(ox)3]2(18-crown-6)2} (ox = Oxalate Dianion; 18-crown-6 = C12H24O6)
Eugenio Coronado, José R. Galán-Mascarós, and Carlos Martí-Gastaldo
pp 8108 - 8110; DOI:
10.1021/ic700808h
PDF
New Mn12 Clusters with Tunable Oxidation States via the Use of N,N,N',N'-Tetrakis(2-hydroxyethyl)ethylenediamine
Ai-Ju Zhou, Lian-Jing Qin, Christopher C. Beedle, Shu Ding, Motohiro Nakano, Ji-Dong Leng, Ming-Liang Tong, and David N. Hendrickson
pp 8111 - 8113; DOI:
10.1021/ic7011588
PDF
Group 4 Complexes of a New [OSSO]-Type Dianionic Ligand. Coordination Chemistry and Preliminary Polymerization Catalysis Studies
Ad Cohen, Adi Yeori, Israel Goldberg, and Moshe Kol
pp 8114 - 8116; DOI:
10.1021/ic701370t
PDF
Tripodal Phenylamine-Based Ligands and Their CoII Complexes
Matthew B. Jones and Cora E. MacBeth
pp 8117 - 8119; DOI:
10.1021/ic701289y
PDF
Formal DNA Hydrolysis by Mono- and Dinuclear Iron Complexes
Thomas A. Shell, Jessica E. Glass, Megan A. Mackey, Kathryn A. Layman, and Debra L. Mohler
pp 8120 - 8122; DOI:
10.1021/ic701231d
PDF
Reversible Guest-Induced Magnetic and Structural Single-Crystal-to-Single-Crystal Transformation in Microporous Coordination Network {[Ni(cyclam)]3[W(CN)8]2}n
Beata Nowicka, Micha Rams, Katarzyna Stadnicka, and Barbara Sieklucka
pp 8123 - 8125; DOI:
10.1021/ic701168x
PDF
Heterometallic Cubane Single-Molecule Magnets
Patrick L. Feng, Christopher C. Beedle, Wolfgang Wernsdorfer, Changhyun Koo, Motohiro Nakano, Stephen Hill, and David N. Hendrickson
pp 8126 - 8128; DOI:
10.1021/ic7012107
PDF
Binding of Pertechnetate to Uranyl(VI) in Aqueous Solution. A Density Functional Theory Molecular Dynamics Study
Michael Bühl and Volodymyr Golubnychiy
pp 8129 - 8131; DOI:
10.1021/ic701431u
PDF
Synthesis and Properties of a Cationic Bidentate Lewis Acid
Min Hyung Lee and François P. Gabbaï
pp 8132 - 8138; DOI:
10.1021/ic700360a
PDF
Reactivity of an Adsorbed Ru(VI)-Oxo Complex: Oxidation of Benzyl Alcohol
Brooks J. Hornstein, Dana M. Dattelbaum, Jon R. Schoonover, and Thomas J. Meyer
pp 8139 - 8145; DOI:
10.1021/ic0700506
PDF
Computational Studies of EPR Parameters for Paramagnetic Molybdenum Complexes. II. Larger MoV Systems Relevant to Molybdenum Enzymes
Jörg Fritscher, Peter Hrobárik, and Martin Kaupp
pp 8146 - 8161; DOI:
10.1021/ic070341e
PDF
Two Multi-Copper-Containing Heteropolyoxotungstates Constructed from the Lacunary Keggin Polyoxoanion and the High-Nuclear Spin Cluster
Zhiming Zhang, Yanfei Qi, Chao Qin, Yangguang Li, Enbo Wang, Xinlong Wang, Zhongmin Su, and Lin Xu
pp 8162 - 8169; DOI:
10.1021/ic7012864
PDF
Chiral Recognition and Conglomerate Crystallization Induced by Self-Organization of Cobalt(III) Complexes of a Tripodal Ligand Containing Three Imidazole Groups
Hirofumi Nakamura, Yukinari Sunatsuki, Masaaki Kojima, and Naohide Matsumoto
pp 8170 - 8181; DOI:
10.1021/ic070286+
PDF
Spin-Crossover Behavior in Cyanide-Bridged Iron(II)-Silver(I) Bimetallic 2D Hofmann-like Metal-Organic Frameworks
M.C. Munoz, M. Carmen Muñoz, Ana B. Gaspar, and Ana Galet
pp 8182 - 8192; DOI:
10.1021/ic700607x
PDF
Metal-Porphyrin Orbital Interactions in Highly Saddled Low-Spin Iron(III) Porphyrin Complexes
Yoshiki Ohgo, Akito Hoshino, Tomoya Okamura, Hidehiro Uekusa, Daisuke Hashizume, Akira Ikezaki, and Mikio Nakamura
pp 8193 - 8207; DOI:
10.1021/ic700827w
PDF
Mixed-Ligand Copper(II)-phenolate Complexes: Effect of Coligand on Enhanced DNA and Protein Binding, DNA Cleavage, and Anticancer Activity
Venugopal Rajendiran, Ramasamy Karthik, Mallayan Palaniandavar, Helen Stoeckli-Evans, Vaiyapuri Subbarayan Periasamy, Mohammad Abdulkader Akbarsha, Bangalore Suresh Srinag, and Hanumanthappa Krishnamurthy
pp 8208 - 8221; DOI:
10.1021/ic700755p
PDF
Migration of a cis-(NH3)2PtII Moiety along Two Adenine Nucleobases, from N1 to N6, is Markedly Facilitated by Additional PtII Entities Coordinated to N7
Marta Garijo Añorbe, Thea Welzel, and Bernhard Lippert
pp 8222 - 8227; DOI:
10.1021/ic7008754
PDF
Supramolecular Aggregation of Mononuclear Triorganophosphinegold(I) 2-Mercaptobenzamides: Solution Structures, Thermal Decomposition, and Photoluminescence
Jun-Gill Kang, Hyung-Kook Cho, Changmoon Park, Sock-Sung Yun, Jae-Kyung Kim, Grant A. Broker, Douglas R. Smyth, and Edward R. T. Tiekink
pp 8228 - 8237; DOI:
10.1021/ic701022e
PDF
DFT Study of the Systematic Variations in Metal-Ligand Bond Lengths of Coordination Complexes: the Crucial Role of the Condensed Phase
Rosalie K. Hocking, Robert J. Deeth, and Trevor W. Hambley
pp 8238 - 8244; DOI:
10.1021/ic701166p
PDF
Areneruthenium(II) 4-Acyl-5-pyrazolonate Derivatives: Coordination Chemistry, Redox Properties, and Reactivity
Fabio Marchetti, Claudio Pettinari, Riccardo Pettinari, Adele Cerquetella, Augusto Cingolani, Eric J. Chan, Kozo Kozawa, Brian W. Skelton, Allan H. White, Riccardo Wanke, Maxim L. Kuznetsov, Luisa M. D. R. S. Martins, and Armando J. L. Pombeiro
pp 8245 - 8257; DOI:
10.1021/ic700394r
PDF
Sulfoxide as a Ligand in Iron(II) Porphyrinates: S- or O-Bound?
Chuanjiang Hu, Bruce C. Noll, and W. Robert Scheidt
pp 8258 - 8263; DOI:
10.1021/ic7008495
PDF
Polymer-like Structures of LiSCN, NaSCN, KSCN, RbSCN, and CsSCN Complexes with an Armed Monoaza-15-crown-5 Ether Bearing a 3',5'-Difluoro-4'-hydroxybenzyl Group
Yoichi Habata, Chizuko Okazaki, Kinuko Ogura, Sadatoshi Akabori, Xian X. Zhang, and Jerald S. Bradshaw
pp 8264 - 8270; DOI:
10.1021/ic7011606
PDF
Seven-Coordination versus Six-Coordination in Divalent First-Row Transition-Metal Complexes Derived from 1,10-Diaza-15-crown-5
Lea Vaiana, Martín Regueiro-Figueroa, Marta Mato-Iglesias, Carlos Platas-Iglesias, David Esteban-Gómez, Andrés de Blas, and Teresa Rodríguez-Blas
pp 8271 - 8282; DOI:
10.1021/ic7008946
PDF
Syntheses and Structures of Organic-Inorganic Hybrid Compounds Based on Metal-Fluconazole Coordination Polymers and the -Mo8O26 Anion
Shun-Li Li, Ya-Qian Lan, Jian-Fang Ma, Jin Yang, Xiao-Hong Wang, and Zhong-Min Su
pp 8283 - 8290; DOI:
10.1021/ic700913m
PDF
Cadmium(II) Complexes of (Arylazo)imidazoles: Synthesis, Structure, Photochromism, and Density Functional Theory Calculation
K. K. Sarker, D. Sardar, K. Suwa, J. Otsuki, and C. Sinha
pp 8291 - 8301; DOI:
10.1021/ic7012073
PDF
New Organically Templated Copper(I) Sulfites: the Role of Sulfite Anion as Both Soft and Hard Ligand
Pei-Xin Li, Hai-Long Jiang, Mei-Ling Feng, and Jiang-Gao Mao
pp 8302 - 8308; DOI:
10.1021/ic7009622
PDF
Novel Dinuclear Uranyl Complexes with Asymmetric Schiff Base Ligands: Synthesis, Structural Characterization, Reactivity, and Extraction Studies
Mohan S. Bharara, Kara Strawbridge, Jonah Z. Vilsek, Travis H. Bray, and Anne E. V. Gorden
pp 8309 - 8315; DOI:
10.1021/ic7010315
PDF
An Unusual Reaction: a GaCl3-Assisted Methyl/Chlorine Exchange in Silylated Hydrazinodichloroarsane
Axel Schulz, Peter Mayer, and Alexander Villinger
pp 8316 - 8322; DOI:
10.1021/ic701081s
PDF
PtII-Mediated 1,3-Dipolar Cycloaddition of Oxazoline N-Oxides to Nitriles as a Key Step to Dihydrooxazolo-1,2,4-oxadiazoles
Anastassiya V. Makarycheva-Mikhailova, Julia A. Golenetskaya, Nadezhda A. Bokach, Irina A. Balova, Matti Haukka, and Vadim Yu. Kukushkin
pp 8323 - 8331; DOI:
10.1021/ic701133b
PDF
Sulfur X-ray Absorption and Vibrational Spectroscopic Study of Sulfur Dioxide, Sulfite, and Sulfonate Solutions and of the Substituted Sulfonate Ions X3CSO3- (X = H, Cl, F)
Emiliana Damian Risberg, Lars Eriksson, János Mink, Lars G. M. Pettersson, Mikhail Yu. Skripkin, and Magnus Sandström
pp 8332 - 8348; DOI:
10.1021/ic062440i
PDF
Oxidation of Guanine in Double-Stranded DNA by [Ru(bpy)2dppz]Cl2 in Cationic Reverse Micelles
Sarah E. Evans, Armine Grigoryan, and Veronika A. Szalai
pp 8349 - 8361; DOI:
10.1021/ic0700708
PDF
Iron Chelation Equilibria, Redox, and Siderophore Activity of a Saccharide Platform Ferrichrome Analogue
Suraj Dhungana, James M. Harrington, Peter Gebhardt, Ute Möllmann, and Alvin L. Crumbliss
pp 8362 - 8371; DOI:
10.1021/ic070158l
PDF
Controlled Synthesis of the ZnWO4 Nanostructure and Effects on the Photocatalytic Performance
Jie Lin, Jun Lin, and Yongfa Zhu
pp 8372 - 8378; DOI:
10.1021/ic701036k
PDF
Unpaired Spin Densities from NMR Shifts
Rudolf Knorr, Hermann Hauer, Alfons Weiss, Heinz Polzer, Friedrich Ruf, Peter Löw, Peter Dvortsák, and Petra Böhrer
pp 8379 - 8390; DOI:
10.1021/ic700656r
PDF
Iron(III)-Catecholato Complexes as Structural and Functional Models of the Intradiol-Cleaving Catechol Dioxygenases
Pieter C. A. Bruijnincx, Martin Lutz, Anthony L. Spek, Wilfred R. Hagen, Gerard van Koten, and Robertus J. M. Klein Gebbink
pp 8391 - 8402; DOI:
10.1021/ic700741v
PDF
New Series of Indium Formates: Hydrothermal Synthesis, Structure and Coordination Modes
Jie Su, Yingxia Wang, Sihai Yang, Guobao Li, Fuhui Liao, and Jianhua Lin
pp 8403 - 8409; DOI:
10.1021/ic7007599
PDF
X-ray Absorption Spectroscopic Studies of High-Spin Nonheme (Alkylperoxo)iron(III) Intermediates
Xiaopeng Shan, Jan-Uwe Rohde, Kevin D. Koehntop, Yuming Zhou, Michael R. Bukowski, Miquel Costas, Kiyoshi Fujisawa, and Lawrence Que Jr.
pp 8410 - 8417; DOI:
10.1021/ic700649w
PDF
Cyclic Se6 and Helical 1[Sex] as Neutral Ligands in the New Compounds PdBr2Se6 and PdCl2Se8
Hans-Joerg Deiseroth, Christof Reiner, Marc Schlosser, Xiaowen Wang, Humayun Ajaz, and Lorenz Kienle
pp 8418 - 8425; DOI:
10.1021/ic701108c
PDF
Anisole-Diphenoxide Ligands and Their Zirconium Dichloride and Dialkyl Complexes
Tsukasa Matsuo and Hiroyuki Kawaguchi
pp 8426 - 8434; DOI:
10.1021/ic7011167
PDF

Issue 21


Cluster Carbonyls of the [Re6(3-Se)8]2+ Core
Peter J. Orto, Gary S. Nichol, Ruiyao Wang, and Zhiping Zheng
pp 8436 - 8438; DOI:
10.1021/ic700561q
PDF
[CH3NH2(CH2)2NH2CH3][M2(HCOO)6] (M = MnII and CoII): Weak Ferromagnetic Metal Formate Frameworks of Unique Binodal 6-Connected (412·63)(49·66) Topology, Templated by a Diammonium Cation
Zheming Wang, Xueyu Zhang, Stuart R. Batten, Mohamedally Kurmoo, and Song Gao
pp 8439 - 8441; DOI:
10.1021/ic700924j
PDF
One-Dimensional Array of Two- and Three-Center Cation-Cation Bonds in the Structure of Li4[(UO2)10O10(Mo2O8)]
Evgeny V. Alekseev, Sergey V. Krivovichev, Thomas Malcherek, and Wulf Depmeier
pp 8442 - 8444; DOI:
10.1021/ic7009385
PDF
[2]Pseudorotaxane and [2]Rotaxane Molecular Shuttles: Self-Assembly through Second-Sphere Coordination of Thiocyanate Ligands
Barry A. Blight, Xu Wei, James A. Wisner, and Michael C. Jennings
pp 8445 - 8447; DOI:
10.1021/ic701021p
PDF
One-Pot Synthesis of Schiff-Base-Containing Ni8 Clusters: Solvothermal Synthesis, Structure, and Magnetic Properties
Feng Luo, Ji-min Zheng, and Mohamedally Kurmoo
pp 8448 - 8450; DOI:
10.1021/ic7010259
PDF
Unprecedented 4264 Topological 2-D Rare-Earth Coordination Polymers from a Flexible Tripodal Acid with Additional Amide Groups
Ran Sun, Suna Wang, Hang Xing, Junfeng Bai, Yizhi Li, Yi Pan, and Xiaozeng You
pp 8451 - 8453; DOI:
10.1021/ic7010502
PDF
Three-Dimensional 3d-4f Polymers Containing Heterometallic Rings: Syntheses, Structures, and Magnetic Properties
Yan Ouyang, Wei Zhang, Na Xu, Gong-Feng Xu, Dai-Zheng Liao, Kazuyoshi Yoshimura, Shi-Ping Yan, and Peng Cheng
pp 8454 - 8456; DOI:
10.1021/ic701097k
PDF
Solvent-Free Aerobic Oxidation of n-Alkane by Iron(III)-Substituted Polyoxotungstates Immobilized on SBA-15
Lifang Chen, Kake Zhu, Li-Hua Bi, Andreas Suchopar, Markus Reicke, Georges Mathys, Helge Jaensch, Ulrich Kortz, and Ryan M. Richards
pp 8457 - 8459; DOI:
10.1021/ic701178a
PDF
In Situ Generation of Oxo-sulfidobis(dithiolene)tungsten(VI) Complexes: Active-Site Models for the Aldehyde Ferredoxin Oxidoreductase Family of Tungsten Enzymes
Hideki Sugimoto, Hiroyuki Tano, Reiko Tajima, Hiroyuki Miyake, Hiroshi Tsukube, Hiromi Ohi, and Shinobu Itoh
pp 8460 - 8462; DOI:
10.1021/ic7012733
PDF
Tris(pyrrolyl--methyl)amines that Sterically Protect a Trigonal Metal Site
Keith M. Wampler and Richard R. Schrock
pp 8463 - 8465; DOI:
10.1021/ic701472y
PDF
Eu3(AsS4)2 and AxEu3-yAs5-zS10 (A = Li, Na): Compounds with Simple and Complex Thioarsenate Building Blocks
Tarun K. Bera, Ratnasabapathy G. Iyer, Christos D. Malliakas, and Mercouri G. Kanatzidis
pp 8466 - 8468; DOI:
10.1021/ic701067r
PDF
Direct Evidence on the Existence of [Mo132] Keplerate-Type Species in Aqueous Solution
Soumyajit Roy, Karel L. Planken, Robbert Kim, Dexx v. d. Mandele, and Willem K. Kegel
pp 8469 - 8471; DOI:
10.1021/ic701076s
PDF
Novel Bis(ethylenedithio)tetrathiafulvalene-Based Organic Conductor with 1,1'-Ferrocenedisulfonate
Hiroki Akutsu, Ryo Ohnishi, Jun-ich Yamada, Shin'ichi Nakatsuji, and Scott S. Turner
pp 8472 - 8474; DOI:
10.1021/ic701392z
PDF
Highly Diastereoselective Nucleophilic Addition to Myrtenal. Straightforward Synthesis of an Enantiopure Scorpionate Ligand
Antonio Otero, Juan Fernández-Baeza, Antonio Antiñolo, Juan Tejeda, Agustín Lara-Sánchez, Luis F. Sánchez-Barba, Margarita Sánchez-Molina, Sonia Franco, Maria I. López-Solera, and Ana M. Rodríguez
pp 8475 - 8477; DOI:
10.1021/ic701388w
PDF
Weak Ferromagnetism in a Semiconducting (Ethylenedithiodiselenadithiafulvalenoquinone-1,3-diselenolemethide)2·FeBr4 Salt
Toshiki Hayashi, Xunwen Xiao, Hideki Fujiwara, Toyonari Sugimoto, Hiroyuki Nakazumi, Satoru Noguchi, and Hiroko Aruga Katori
pp 8478 - 8480; DOI:
10.1021/ic701260p
PDF
Ferrimagnetic FeIII-MnIII Zigzag Chain Formed by a New mer-Positioned Iron(III) Cyanide Precursor
Jae Il Kim, Houng Sik Yoo, Eui Kwan Koh, Hyoung Chan Kim, and Chang Seop Hong
pp 8481 - 8483; DOI:
10.1021/ic701361a
PDF
A Thallium Mediated Route to -Arylalkynyl Complexes of Bipyridyltricarbonylrhenium(I)
Brendan J. Liddle, Sergey V. Lindeman, Daniel L. Reger, and James R. Gardinier
pp 8484 - 8486; DOI:
10.1021/ic701406y
PDF
Novel Coordination Polymers Based on the Tetrathioterephthalate Dianion as the Bridging Ligand
Eleftheria Neofotistou, Christos D. Malliakas, and Pantelis N. Trikalitis
pp 8487 - 8489; DOI:
10.1021/ic701414v
PDF
A Triply Interpenetrated Microporous Metal-Organic Framework for Selective Sorption of Gas Molecules
Banglin Chen, Shengqian Ma, Eric J. Hurtado, Emil B. Lobkovsky, and Hong-Cai Zhou
pp 8490 - 8492; DOI:
10.1021/ic7014034
PDF
Four-Stranded Coordination Helices Containing Silver-Adenine (Purine) Metallaquartets
Chandra Shekhar Purohit, Ashutosh Kumar Mishra, and Sandeep Verma
pp 8493 - 8495; DOI:
10.1021/ic701465d
PDF
Reductive Elimination of Ethane from Five-Coordinate Platinum(IV) Alkyl Complexes
Avery T. Luedtke and Karen I. Goldberg
pp 8496 - 8498; DOI:
10.1021/ic701504z
PDF
Ultramicroporous Metal-Organic Framework Based on 9,10-Anthracenedicarboxylate for Selective Gas Adsorption
Shengqian Ma, Xi-Sen Wang, Christopher D. Collier, Erika S. Manis, and Hong-Cai Zhou
pp 8499 - 8501; DOI:
10.1021/ic701507r
PDF
Synthesis and Structural Characterization of a -Keggin-Type Dimeric Silicotungstate with a Bis(-hydroxo) Dizirconium Core [(-SiW10O36)2Zr2(-OH)2]10-
Syuhei Yamaguchi, Yuji Kikukawa, Kazutaka Tsuchida, Yoshinao Nakagawa, Kazuhiro Uehara, Kazuya Yamaguchi, and Noritaka Mizuno
pp 8502 - 8504; DOI:
10.1021/ic701488s
PDF
Synthesis and Structure of Ag(1-Me-12-SiPh3-CB11F10): Selective F12 Substitution in 1-Me-CB11F11- and the First Ag(arene)4+ Tetrahedron
Yoshihiro Kobayashi, Alexey A. Popov, Susie M. Miller, Oren P. Anderson, and Steven H. Strauss
pp 8505 - 8507; DOI:
10.1021/ic701606p
PDF
A Highly Efficient Dioxo(-oxo)molybdenum(VI) Dimer Catalyst for Olefin Epoxidation
Cláudia C. L. Pereira, Salete S. Balula, Filipe A. Almeida Paz, Anabela A. Valente, Martyn Pillinger, Jacek Klinowski, and Isabel S. Gonçalves
pp 8508 - 8510; DOI:
10.1021/ic701746r
PDF
Spectroscopic and Computational Studies of Ni3+ Complexes with Mixed S/N Ligation: Implications for the Active Site of Nickel Superoxide Dismutase
Adam T. Fiedler and Thomas C. Brunold
pp 8511 - 8523; DOI:
10.1021/ic061237k
PDF
Lanthanide Diruthenium(II,III) Compounds Showing Layered and PtS-Type Open Framework Structures
Bin Liu, Bao-Long Li, Yi-Zhi Li, Yu Chen, Song-Song Bao, and Li-Min Zheng
pp 8524 - 8532; DOI:
10.1021/ic0621695
PDF
The Role of Substituents on Functionalized 1,10-Phenanthroline in Controlling the Emission Properties of Cationic Iridium(III) Complexes of Interest for Electroluminescent Devices
Claudia Dragonetti, Luigi Falciola, Patrizia Mussini, Stefania Righetto, Dominique Roberto, Renato Ugo, Adriana Valore, Filippo De Angelis, Simona Fantacci, Antonio Sgamellotti, Miguel Ramon, and Michele Muccini
pp 8533 - 8547; DOI:
10.1021/ic700414z
PDF
Electrical Conductivity and Spin Crossover: A New Achievement with a Metal Bis Dithiolene Complex
Christophe Faulmann, Kane Jacob, Stéphane Dorbes, Stéphane Lampert, Isabelle Malfant, Marie-Liesse Doublet, Lydie Valade, and José A. Real
pp 8548 - 8559; DOI:
10.1021/ic062461c
PDF
A Novel Bis Tridentate Bipyridine Carboxamide Ligand and Its Complexation to Copper(II): Synthesis, Structure, and Magnetism
Jian Wang, Brandon Djukic, Jingyi Cao, Antonio Alberola, Fereidoon S. Razavi, and Melanie Pilkington
pp 8560 - 8568; DOI:
10.1021/ic700469v
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Room-Temperature Emission from Platinum(II) Complexes Intercalated into Zirconium Phosphate-Layered Materials
Eladio J. Rivera, Cristina Figueroa, Jorge L. Colón, Levi Grove, and William B. Connick
pp 8569 - 8576; DOI:
10.1021/ic7006183
PDF
Hydrogen Bonding and Multiphonon Structure in Copper Pyrazine Coordination Polymers
S. Brown, J. Cao, J. L. Musfeldt, M. M. Conner, A. C. McConnell, H. I. Southerland, J. L. Manson, J. A. Schlueter, M. D. Phillips, M. M. Turnbull, and C. P. Landee
pp 8577 - 8583; DOI:
10.1021/ic070122t
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Singlet Diradical Complexes of Chromium, Molybdenum, and Tungsten with Azo Anion Radical Ligands from M(CO)6 Precursors
Anasuya Sanyal, Sudipta Chatterjee, Alfonso Castiñeiras, Biprajit Sarkar, Priti Singh, Jan Fiedler, Stanislav Záli, Wolfgang Kaim, and Sreebrata Goswami
pp 8584 - 8593; DOI:
10.1021/ic700584x
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Redox Reactions between Phosphines (R3P; R = nBu, Ph) or Carbene (iPr2IM) and Chalcogen Tetrahalides ChX4 (iPr2IM = 2,5-diisopropylimidazole-2-ylidene; Ch = Se, Te; X = Cl, Br)
Jason L. Dutton, Raymond Tabeshi, Michael C. Jennings, Alan J. Lough, and Paul J. Ragogna
pp 8594 - 8602; DOI:
10.1021/ic700627f
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Trinuclear Platinum(II) 4,6-Diphenyl-2,2'-bipyridyl Complex with Bis(diphenylphosphinomethyl)phenylphosphine Auxiliary Ligand: Synthesis, Structural Characterization, and Photophysics
Pin Shao and Wenfang Sun
pp 8603 - 8612; DOI:
10.1021/ic700757x
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Use of Drug Discovery Tools in Rational Organometallic Catalyst Design
Michael L. Drummond and Bobby G. Sumpter
pp 8613 - 8624; DOI:
10.1021/ic700670s
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Probing Lead(II) Bonding Environments in 4-Substituted Pyridine Adducts of (2,6-Me2C6H3S)2Pb: An X-ray Structural and Solid-State 207Pb NMR Study
Glen G. Briand, Andrew D. Smith, Gabriele Schatte, Aaron J. Rossini, and Robert W. Schurko
pp 8625 - 8637; DOI:
10.1021/ic700738w
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Synthesis, Structure, Spectroscopic Properties, and Electrochemical Oxidation of Ruthenium(II) Complexes Incorporating Monocarboxylate Bipyridine Ligands
Nickita Nickita, Matthew J. Belousoff, Anand I. Bhatt, Alan M. Bond, Glen B. Deacon, Gilles Gasser, and Leone Spiccia
pp 8638 - 8651; DOI:
10.1021/ic700796m
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Synthesis, Structural Characterization, and Biological Studies of New Antimony(III) Complexes with Thiones. The Influence of the Solvent on the Geometry of the Complexes
Ibrahim I. Ozturk, Sotiris K. Hadjikakou, Nick Hadjiliadis, Nikolaos Kourkoumelis, Maciej Kubicki, Martin Baril, Ian S. Butler, and Jan Balzarini
pp 8652 - 8661; DOI:
10.1021/ic700756e
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Sandwich Compounds of Cyanotrispyrazolylborates: Complexation-Induced Ligand Isomerization
Ningfeng Zhao, Michael J. Van Stipdonk, Cary Bauer, Charles Campana, and David M. Eichhorn
pp 8662 - 8667; DOI:
10.1021/ic700628b
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Structurally Homologous - and meso-Alkynyl Amidinium Porphyrins
Joel Rosenthal, Elizabeth R. Young, and Daniel G. Nocera
pp 8668 - 8675; DOI:
10.1021/ic700838s
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Catalysis Design for Ring-Opening Polymerization of Cyclic Esters: 1. Group 1 Metal and Thallium(I) Trispyrazolylborate Complexes with Hemilabile Ligands
Malcolm H. Chisholm, Judith C. Gallucci, and Gülah Yaman
pp 8676 - 8683; DOI:
10.1021/ic700965d
PDF
Magnetic Properties of Synthetic Libethenite Cu2PO4OH: a New Spin-Gap System
Alexei A. Belik, Hyun-Joo Koo, Myung-Hwan Whangbo, Naohito Tsujii, Pane Naumov, and Eiji Takayama-Muromachi
pp 8684 - 8689; DOI:
10.1021/ic7008418
PDF
Structure and Properties of Gd3Ge4: The Orthorhombic RE3Ge4 Structures Revisited (RE = Y, Tb-Tm)
Paul H. Tobash, Gary DiFilippo, Svilen Bobev, Namjung Hur, Joe D. Thompson, and John L. Sarrao
pp 8690 - 8697; DOI:
10.1021/ic7009034
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A Series of New Copper Iodobismuthates: Structural Relationships, Optical Band Gaps Affected by Dimensionality, and Distinct Thermal Stabilities
Wen-Xiang Chai, Li-Ming Wu, Jun-Qian Li, and Ling Chen
pp 8698 - 8704; DOI:
10.1021/ic700904d
PDF
Selective Gas Sorption within a Dynamic Metal-Organic Framework
Banglin Chen, Shengqian Ma, Eric J. Hurtado, Emil B. Lobkovsky, Chengdu Liang, Haoguo Zhu, and Sheng Dai
pp 8705 - 8709; DOI:
10.1021/ic7013573
PDF
Accurate Computation of Reduction Potentials of 4Fe-4S Clusters Indicates a Carboxylate Shift in Pyrococcus furiosus Ferredoxin
Kasper P. Jensen, Bee-Lean Ooi, and Hans E. M. Christensen
pp 8710 - 8716; DOI:
10.1021/ic7009836
PDF
Two Coordination Polymers Created via In Situ Ligand Synthesis Involving C-N and C-C Bond Formation
Russell K. Feller, Paul M. Forster, Fred Wudl, and Anthony K. Cheetham
pp 8717 - 8721; DOI:
10.1021/ic700997c
PDF
Ca4Au10In3: Synthesis, Structure, and Bonding Analysis. The Chemical and Electronic Transformations from the Isotypic Zr7Ni10 Intermetallic
Qisheng Lin and John D. Corbett
pp 8722 - 8727; DOI:
10.1021/ic700995e
PDF
Infrared and DFT Investigations of the XCReX3 and HCReX3 Complexes: Jahn-Teller Distortion and the Methylidyne C-X(H) Stretching Absorptions
Jonathan T. Lyon, Han-Gook Cho, Lester Andrews, Han-Shi Hu, and Jun Li
pp 8728 - 8738; DOI:
10.1021/ic701014u
PDF
Synthesis, Structure, and Unexpected Magnetic Properties of La3Re2O10
Heather L. Cuthbert, John E. Greedan, Ignacio Vargas-Baca, Shahab Derakhshan, and Ian P. Swainson
pp 8739 - 8745; DOI:
10.1021/ic701011r
PDF
Magnetic Properties of Bulk BiCrO3 Studied with dc and ac Magnetization and Specific Heat
Alexei A. Belik, Naohito Tsujii, Hiroyuki Suzuki, and Eiji Takayama-Muromachi
pp 8746 - 8751; DOI:
10.1021/ic701099f
PDF
Spectroscopic and Computational Studies of a Ru(II) Terpyridine Complex: The Importance of Weak Intermolecular Forces to Photophysical Properties
Claudio Garino, Roberto Gobetto, Carlo Nervi, Luca Salassa, Edward Rosenberg, J. B. Alexander Ross, Xi Chu, Kenneth I. Hardcastle, and Cristiana Sabatini
pp 8752 - 8762; DOI:
10.1021/ic7010343
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Two Iron-Containing Tungstogermanates: [K(H2O)(-Fe2GeW10O37(OH))(-GeW10O36)]12- and [{-Fe2GeW10O37(OH)2}2]12-
Nadeen H. Nsouli, Sib Sankar Mal, Michael H. Dickman, Ulrich Kortz, Bineta Keita, Louis Nadjo, and Juan M. Clemente-Juan
pp 8763 - 8770; DOI:
10.1021/ic701084x
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Luminescent Charge-Transfer Platinum(II) Metallacycle
Fei Hua, Solen Kinayyigit, Aaron A. Rachford, Elena A. Shikhova, Sébastien Goeb, John R. Cable, Christopher J. Adams, Kristin Kirschbaum, A. Alan Pinkerton, and Felix N. Castellano
pp 8771 - 8783; DOI:
10.1021/ic701103u
PDF
Anion-Solvent Dependence of Bistability in a Family of Meridional N-Donor-Ligand-Containing Iron(II) Spin Crossover Complexes
Ben A Leita, Suzanne M. Neville, Gregory J. Halder, Boujemaa Moubaraki, Cameron J. Kepert, Jean-François Létard, and Keith S. Murray
pp 8784 - 8795; DOI:
10.1021/ic7010919
PDF
Syntheses of Mono- and Dinuclear Diiodoboryl Complexes of Platinum
Holger Braunschweig, Krzysztof Radacki, and Katharina Uttinger
pp 8796 - 8800; DOI:
10.1021/ic7011028
PDF
Planar versus Puckered Nets in the Polar Intermetallic Series EuGaTt (Tt = Si, Ge, Sn)
Tae-Soo You, Yuri Grin, and Gordon J. Miller
pp 8801 - 8811; DOI:
10.1021/ic701111e
PDF
Syntheses and Structures of New Phases AeMxIn4-x (Ae = Sr, Ba; M = Mg, Zn): Size Effects and Site Preferences in BaAl4-Type Structures
Bin Li and John D. Corbett
pp 8812 - 8818; DOI:
10.1021/ic701127f
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Influence of Ligand Geometry on the Formation of In-O Chains in Metal-Oxide Organic Frameworks (MOOFs)
Marie Vougo-Zanda, Xiqu Wang, and Allan J. Jacobson
pp 8819 - 8824; DOI:
10.1021/ic701126t
PDF
Seven-Coordinate Iron and Manganese Complexes with Acyclic and Rigid Pentadentate Chelates and Their Superoxide Dismutase Activity
Gao-Feng Liu, Milo Filipovi, Frank W. Heinemann, and Ivana Ivanovi-Burmazovi
pp 8825 - 8835; DOI:
10.1021/ic7012039
PDF
Dinitrogen Coordination and Cleavage Promoted by a Vanadium Complex of a ,,-Donor Ligand
Indu Vidyaratne, Patrick Crewdson, Emeric Lefebvre, and Sandro Gambarotta
pp 8836 - 8842; DOI:
10.1021/ic701219h
PDF
Ferromagnetic Coupling in a 1D Coordination Polymer Containing a Symmetric [Cu(1,1-N3)2Cu(1,1-N3)2Cu]2+ Core and Based on an Organic Ligand Obtained from the Solid State
Theocharis C. Stamatatos, Giannis S. Papaefstathiou, Leonard R. MacGillivray, Albert Escuer, Ramon Vicente, Eliseo Ruiz, and Spyros P. Perlepes
pp 8843 - 8850; DOI:
10.1021/ic070018b
PDF
Magnetic Excitations in Cu6 and Mn6 Hexagons Embedded in D3d-Symmetric Polyoxotungstates
Noa Zamstein, Alex Tarantul, and Boris Tsukerblat
pp 8851 - 8858; DOI:
10.1021/ic700585c
PDF
Rates of Electronic Excitation Hopping in Anisotropic Ionic Crystals of [Ru(2,2'-bipyridine)3]X2 (X = ClO4-, PF6-, SbF6-); Monte Carlo Simulation of Single- and Multi-Exponential Emission Decays
Takeshi Ohno, Koichi Nozaki, Mayuko Nakamura, Yoshiaki Motojima, Minoru Tsushima, and Noriaki Ikeda
pp 8859 - 8870; DOI:
10.1021/ic060948f
PDF
Electronic Structure of the Sulfonyl and Phosphonyl Groups: A Computational and Crystallographic Study
Emma Denehy, Jonathan M. White, and Spencer J. Williams
pp 8871 - 8886; DOI:
10.1021/ic700687t
PDF
Importance of Counterion Reactivity on the Deactivation of Co-Salen Catalysts in the Hydrolytic Kinetic Resolution of Epichlorohydrin
Surbhi Jain, Xiaolai Zheng, Christopher W. Jones, Marcus Weck, and Robert J. Davis
pp 8887 - 8896; DOI:
10.1021/ic700782f
PDF
Copper(I) Cyanide Networks: Synthesis, Luminescence Behavior and Thermal Analysis. Part 1. Diimine Ligands
Tristan A. Tronic, Kathryn E. deKrafft, Mi Jung Lim, Amanda N. Ley, and Robert D. Pike
pp 8897 - 8912; DOI:
10.1021/ic7007057
PDF
Mononuclear Ni(II)-Thiolate Complexes with Pendant Thiol and Dinuclear Ni(III/II)-Thiolate Complexes with Ni···Ni Interaction Regulated by the Oxidation Levels of Nickels and the Coordinated Ligands
Chien-Ming Lee, Tzung-Wen Chiou, Hsin-Hung Chen, Chao-Yi Chiang, Ting-Shen Kuo, and Wen-Feng Liaw
pp 8913 - 8923; DOI:
10.1021/ic700719h
PDF
Tuning of Magnetic Properties of Polynuclear Lanthanide(III)-Octacyanotungstate(V) Systems: Determination of Ligand-Field Parameters and Exchange Interaction
Pawe Przychodze, Robert Peka, Krzysztof Lewiski, Justyna Supel, Micha Rams, Krzysztof Tomala, and Barbara Sieklucka
pp 8924 - 8938; DOI:
10.1021/ic700795q
PDF
On the Reactivity Toward Ketones of New Methyl Amino Complexes of Rh(III) and Ag(I). Synthesis of Ortho-Rhodiated Acetophenone Methyl Imine Complexes
José Vicente, María Teresa Chicote, Inmaculada Vicente-Hernández, and Delia Bautista
pp 8939 - 8949; DOI:
10.1021/ic700963h
PDF
Bifunctional Amine-Tethered Ruthenium(II) Arene Complexes Form Monofunctional Adducts on DNA
Michael Melchart, Abraha Habtemariam, Olga Novakova, Stephen A. Moggach, Francesca P. A. Fabbiani, Simon Parsons, Viktor Brabec, and Peter J. Sadler
pp 8950 - 8962; DOI:
10.1021/ic700799w
PDF
Correlation of Metal Spin-State in -Diimine Iron Catalysts with Polymerization Mechanism
Laura E. N. Allan, Michael P. Shaver, Andrew J. P. White, and Vernon C. Gibson
pp 8963 - 8970; DOI:
10.1021/ic701500y
PDF
Effect of Strain in the Proximal Ligand on the Binding of Nitric Oxide and Carbon Monoxide to Chelated Protoheme Complexes
Michele Gullotti, Laura Santagostini, Enrico Monzani, and Luigi Casella
pp 8971 - 8975; DOI:
10.1021/ic700852c
PDF
[W6S8] Octahedral Tungsten Clusters Functionalized with Thiophene Derivatives: toward Polymerizable Building Blocks
Sandrine Perruchas, Samuel Flores, Bruno Jousselme, Emil Lobkovsky, Hector Abruña, and Francis J. DiSalvo
pp 8976 - 8987; DOI:
10.1021/ic7010748
PDF
Synthesis and Structural Characterization of Complexes of a DO3A-Conjugated Triphenylphosphonium Cation with Diagnostically Important Metal Ions
Chang-Tong Yang, Yongxin Li, and Shuang Liu
pp 8988 - 8997; DOI:
10.1021/ic7010452
PDF
Formation of a Phosphine-phosphinite Ligand in RhCl(PRR'2)[P,P-R'(R)POCH2P(CH2OH)2] and R'H from cis-RhCl(PRR'2)2[P(CH2OH)3] via P-C Bond Cleavage
Fabio Lorenzini, Brian O. Patrick, and Brian R. James
pp 8998 - 9002; DOI:
10.1021/ic7012182
PDF
Tridentate Facial Ligation of Tris(pyridine-2-aldoximato)nickel(II) and Tris(imidazole-2-aldoximato)nickel(II) To Generate NiIIFeIIINiII, MnIIINiII, NiIINiII, and ZnIINiII and the Electrooxidized MnIVNiII, NiIINiIII, and ZnIINiIII Species: A Magnetostructural, Electrochemical, and EPR Spectroscopic Study
Phalguni Chaudhuri, Thomas Weyhermüller, Rita Wagner, Sumit Khanra, Biplab Biswas, Eberhard Bothe, and Eckhard Bill
pp 9003 - 9016; DOI:
10.1021/ic701073j
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Issue 22


Compound I of Naked Heme (Iron Protoporphyrin IX)
Maria Elisa Crestoni and Simonetta Fornarini
pp 9018 - 9020; DOI:
10.1021/ic700698d
PDF
A Novel Helical Double-Layered Cobalt(II)-Organic Framework with Tetranuclear [Co4(3-OH)2] Clusters Linked by an Unsymmetrical Pyridylbenzoate Ligand
Junhua Luo, Yusheng Zhao, Hongwu Xu, Tiffany L. Kinnibrugh, Dali Yang, Tatiana V. Timofeeva, Luke L. Daemen, Jianzhong Zhang, Wei Bao, Joe D. Thompson, and Robert P. Currier
pp 9021 - 9023; DOI:
10.1021/ic701003z
PDF
Titanium-Manganese Compound with a Chiral Mn3Ti Center
Lucjan B. Jerzykiewicz, Józef Utko, ukasz John, Marek Duczmal, and Piotr Sobota
pp 9024 - 9026; DOI:
10.1021/ic7013094
PDF
A Pillared Discrete Bilayer Formed from Guanidinium and Ferrocenedisulfonate Ions: Synthesis, Crystal Structure, and Initial Electrochemical Properties
Jingli Xie, Michelle T. Ma, Brendan F. Abrahams, and Anthony G. Wedd
pp 9027 - 9029; DOI:
10.1021/ic7011974
PDF
Metal-Based Netropsin Mimics Showing AT-Selective DNA Binding and DNA Cleavage Activity at Red Light
Ashis K. Patra, Tuhin Bhowmick, Suryanarayanarao Ramakumar, and Akhil R. Chakravarty
pp 9030 - 9032; DOI:
10.1021/ic701326z
PDF
Structure and Magnetic Ordering of KxH1-xNi(OH2)4[Ru2(CO3)4zH2O
Bretni S. Kennon, Jae-Hyuk Her, Peter W. Stephens, William W. Shum, and Joel S. Miller
pp 9033 - 9035; DOI:
10.1021/ic701318q
PDF
New Polypyridine Ligands Functionalized with Redox-Active Fe(II) Organometallic Fragments
Frédéric Paul, Sébastien Goeb, Frédéric Justaud, Gilles Argouarch, Loic Toupet, Raymond F. Ziessel, and Claude Lapinte
pp 9036 - 9038; DOI:
10.1021/ic7014379
PDF
Facile High-Yield Synthesis of Pure, Crystalline Mg(BH4)2
Pierino Zanella, Laura Crociani, Norberto Masciocchi, and Giovanni Giunchi
pp 9039 - 9041; DOI:
10.1021/ic701436c
PDF
Iron(III) Complexes with a Biologically Relevant Aroylhydrazone: Crystallographic Evidence for Coordination Versatility
Dariusz Matoga, Janusz Szklarzewicz, Katarzyna Stadnicka, and Musa S. Shongwe
pp 9042 - 9044; DOI:
10.1021/ic701435x
PDF
Molecules Composed of Two Weakly Magnetically Coupled [MnIII4] Clusters
E. Carolina Sañudo, Thomas Cauchy, Eliseo Ruiz, Rebecca H. Laye, Olivier Roubeau, Simon J. Teat, and Guillem Aromí
pp 9045 - 9047; DOI:
10.1021/ic701467y
PDF
Strategy To Tether Organometallic Ruthenium-Arene Anticancer Compounds to Recombinant Human Serum Albumin
Wee Han Ang, Elisa Daldini, Lucienne Juillerat-Jeanneret, and Paul J. Dyson
pp 9048 - 9050; DOI:
10.1021/ic701474m
PDF
Photochemical Synthesis of mer-[Re(bpy)(CO)3Cl]
Shunsuke Sato, Tatsuki Morimoto, and Osamu Ishitani
pp 9051 - 9053; DOI:
10.1021/ic701458h
PDF
Uncommon Ferromagnetic Interactions in a Homometallic Co(II) Chain Bridged by a Single End-to-End Azide
Houng Sik Yoo, Jae Il Kim, Namgeun Yang, Eui Kwan Koh, Je-Geun Park, and Chang Seop Hong
pp 9054 - 9056; DOI:
10.1021/ic7014995
PDF
Evidence of the Facile Hydride and Enolate Addition to the Imine Bond of an Aluminum-Salophen Complex
Massimo Cametti, Antonella Dalla Cort, Marcello Colapietro, Gustavo Portalone, Luca Russo, and Kari Rissanen
pp 9057 - 9059; DOI:
10.1021/ic701521s
PDF
Volatile Magnesium Octahydrotriborate Complexes as Potential CVD Precursors to MgB2. Synthesis and Characterization of Mg(B3H8)2 and Its Etherates
Do Young Kim, Yu Yang, John R. Abelson, and Gregory S. Girolami
pp 9060 - 9066; DOI:
10.1021/ic701037t
PDF
Hydrothermal Synthesis, Structural Chemistry, and Magnetic Properties of Materials of the MII/Triazolate/Anion Family, Where MII = Mn, Fe, and Ni
Wayne Ouellette, Andrey V. Prosvirin, Jamie Valeich, Kim R. Dunbar, and Jon Zubieta
pp 9067 - 9082; DOI:
10.1021/ic700790h
PDF
Temperature Induced Single-Crystal-to-Single-Crystal Transformations and Structure Directed Effects on Magnetic Properties
Yves-Marie Legrand, Arie van der Lee, Nathalie Masquelez, Pierre Rabu, and Mihail Barboiu
pp 9083 - 9089; DOI:
10.1021/ic700867b
PDF
Ligand and Counterion Control of Ag(I) Architectures: Assembly of a {Ag8} Ring Cluster Mediated by Hydrophobic and Ag···Ag Interactions
John Fielden, De-liang Long, Alexandra M. Z. Slawin, Paul Kögerler, and Leroy Cronin
pp 9090 - 9097; DOI:
10.1021/ic700872b
PDF
Structural and Kinetic Study of Reversible CO2 Fixation by Dicopper Macrocyclic Complexes. From Intramolecular Binding to Self-Assembly of Molecular Boxes
Anna Company, Joo-Eun Jee, Xavi Ribas, Josep Maria Lopez-Valbuena, Laura Gómez, Montserrat Corbella, Antoni Llobet, José Mahía, Jordi Benet-Buchholz, Miquel Costas, and Rudi van Eldik
pp 9098 - 9110; DOI:
10.1021/ic700692t
PDF
Magnetic Circular Dichroism of Porphyrins Containing M = Ca, Ni, and Zn. A Computational Study Based on Time-Dependent Density Functional Theory
G. A. Peralta, Michael Seth, and Tom Ziegler
pp 9111 - 9125; DOI:
10.1021/ic7008545
PDF
Polypyridyl Ruthenium(II) Complexes with Tetrazolate-Based Chelating Ligands. Synthesis, Reactivity, and Electrochemical and Photophysical Properties
Stefano Stagni, Enrico Orselli, Antonio Palazzi, Luisa De Cola, Stefano Zacchini, Cristina Femoni, Massimo Marcaccio, Francesco Paolucci, and Simone Zanarini
pp 9126 - 9138; DOI:
10.1021/ic7011556
PDF
Luminescent Iridium Phenanthroline Crown Ether Complex for the Detection of Silver(I) Ions in Aqueous Media
Michael Schmittel and Hengwei Lin
pp 9139 - 9145; DOI:
10.1021/ic700413v
PDF
A Pnictogen of Peculiar Posture
Anne Poduska and Roald Hoffmann
pp 9146 - 9154; DOI:
10.1021/ic700881d
PDF
Mo/Rh Carboxylate: Heterometallic Compound Built of Homometallic Paddlewheel Units
Bo Li, Haitao Zhang, Lan Huynh, Mikhael Shatruk, and Evgeny V. Dikarev
pp 9155 - 9159; DOI:
10.1021/ic7009012
PDF
Synthesis and Characterization of a Mn22 Single-Molecule Magnet and a [Mn22]n Single-Chain Magnet
Jonathan T. Brockman, Theocharis C. Stamatatos, Wolfgang Wernsdorfer, Khalil A. Abboud, and George Christou
pp 9160 - 9171; DOI:
10.1021/ic7011292
PDF
Reactions of fac-[Re(CO)3(H2O)3]+ with Nucleoside Diphosphates and Thiamine Diphosphate in Aqueous Solution Investigated by Multinuclear NMR Spectroscopy
Kristie M. Adams, Patricia A. Marzilli, and Luigi G. Marzilli
pp 9172 - 9181; DOI:
10.1021/ic701038f
PDF
1,2-Hydroxypyridonates as Contrast Agents for Magnetic Resonance Imaging: TREN-1,2-HOPO
Christoph J. Jocher, Evan G. Moore, Jide Xu, Stefano Avedano, Mauro Botta, Silvio Aime, and Kenneth N. Raymond
pp 9182 - 9191; DOI:
10.1021/ic700985j
PDF
Hydroxide-Promoted Core Conversions of Molybdenum-Iron-Sulfur Edge-Bridged Double Cubanes: Oxygen-Ligated Topological PN Clusters
Mark L. Hlavinka, Taichi Miyaji, Richard J. Staples, and R. H. Holm
pp 9192 - 9200; DOI:
10.1021/ic701070w
PDF
Synthesis, Photophysical, and Anion-Sensing Properties of Quinoxalinebis(sulfonamide) Functionalized Receptors and Their Metal Complexes
Tzu-Pin Lin, Chan-Yu Chen, Yuh-Sheng Wen, and Shih-Sheng Sun
pp 9201 - 9212; DOI:
10.1021/ic701300a
PDF
Syntheses, Structures, Magnetism, and Optical Properties of Lutetium-Based Interlanthanide Selenides
Geng Bang Jin, Eun Sang Choi, Robert P. Guertin, James S. Brooks, Corwin H. Booth, and Thomas E. Albrecht-Schmitt
pp 9213 - 9220; DOI:
10.1021/ic701012j
PDF
Nickel-Cysteine Binding Supported by Phosphine Chelates
Patrick J. Desrochers, Davis S. Duong, Ariel S. Marshall, Stacey A. Lelievre, Bonnie Hong, Josh R. Brown, Richard M. Tarkka, Jerald M. Manion, Garen Holman, Jon W. Merkert, and David A. Vicic
pp 9221 - 9233; DOI:
10.1021/ic701150q
PDF
Applications of Bis(1-R-imidazol-2-yl)disulfides and Diselenides as Ligands for Main-Group and Transition Metals: 2-(N,N) Coordination, S-S Bond Cleavage, and S-S/E-E (E = S, Se) Bond Metathesis Reactions
Joshua S. Figueroa, Kevin Yurkerwich, Jonathan Melnick, Daniela Buccella, and Gerard Parkin
pp 9234 - 9244; DOI:
10.1021/ic701228y
PDF
Reactivity and Mechanism of Stable Heterocyclic Silylenes with Carbon Tetrachloride
Ruei-En Li, Jeng-Horng Sheu, and Ming-Der Su
pp 9245 - 9253; DOI:
10.1021/ic7012446
PDF
Spectroelectrochemistry and DFT Analysis of a New {RuNO}n Redox System with Multifrequency EPR Suggesting Conformational Isomerism in the {RuNO}7 State
Priti Singh, Jan Fiedler, Stanislav Záli, Carole Duboc, Mark Niemeyer, Falk Lissner, Thomas Schleid, and Wolfgang Kaim
pp 9254 - 9261; DOI:
10.1021/ic701206a
PDF
Dizinc Enzyme Model/Complexometric Indicator Pairs in Indicator Displacement Assays for Inorganic Phosphates under Physiological Conditions
Brad P. Morgan, Susan He, and Rhett C. Smith
pp 9262 - 9266; DOI:
10.1021/ic701374h
PDF
Periodic Trends within a Series of Five-Coordinate Thiolate-Ligated [MII(SMe2N4(tren))]+ (M = Mn, Fe, Co, Ni, Cu, Zn) Complexes, Including a Rare Example of a Stable CuII-Thiolate
Lisa M. Brines, Jason Shearer, Jessica K. Fender, Dirk Schweitzer, Steven C. Shoner, David Barnhart, Werner Kaminsky, Scott Lovell, and Julie A. Kovacs
pp 9267 - 9277; DOI:
10.1021/ic701433p
PDF
Diastereoselectivity in the Self-Assembly of As2L2Cl2 Macrocycles is Directed by the As- Interaction
Virginia M. Cangelosi, Aaron C. Sather, Lev N. Zakharov, Orion B. Berryman, and Darren W. Johnson
pp 9278 - 9284; DOI:
10.1021/ic701290h
PDF
Investigating the Vanadium Environments in Hydroxylamido V(V) Dipicolinate Complexes Using 51V NMR Spectroscopy and Density Functional Theory
Kristopher J. Ooms, Stephanie E. Bolte, Jason J. Smee, Bharat Baruah, Debbie C. Crans, and Tatyana Polenova
pp 9285 - 9293; DOI:
10.1021/ic7012667
PDF
Enhancement in Electronic Communication upon Replacement of Mo-O by Mo-S Bonds in Tetranuclear Clusters of the Type [Mo2]2(-E-E)2 (E = O or S)
F. Albert Cotton, Zhong Li, Chun Y. Liu, and Carlos A. Murillo
pp 9294 - 9302; DOI:
10.1021/ic701303k
PDF
Revisiting the 1,2,4-Triaza-3,5-diborolyl Ligand: and Coordination Modes in the Alkali Metal and Rhodium Complexes of a Planar, 6--Electron B2N3- Ring
Hanh V. Ly, Joanna H. Chow, Masood Parvez, Robert McDonald, and Roland Roesler
pp 9303 - 9311; DOI:
10.1021/ic7013286
PDF
Tuneable Intramolecular Intermetallic Interactions as a New Tool for Programming Linear Heterometallic 4f-4f Complexes
Natalia Dalla-Favera, Josef Hamacek, Michal Borkovec, Damien Jeannerat, Gianfranco Ercolani, and Claude Piguet
pp 9312 - 9322; DOI:
10.1021/ic701308h
PDF
Amine Nitrosation via NO Reduction of the Polyamine Copper(II) Complex Cu(DAC)2+
Chosu Khin, Mark D. Lim, Kiyoshi Tsuge, Alexei Iretskii, Guang Wu, and Peter C. Ford
pp 9323 - 9331; DOI:
10.1021/ic7015929
PDF
Strength of the Zn-N Coordination Bond in Zinc Porphyrins on the Basis of Experimental Thermochemistry
Rodrigo Patiño, Myriam Campos, and Luis Alfonso Torres
pp 9332 - 9336; DOI:
10.1021/ic0702522
PDF
Charge Separation in a Ruthenium-Quencher Conjugate Bound to DNA
Katherine E. Augustyn, E. D. A. Stemp, and Jacqueline K. Barton
pp 9337 - 9350; DOI:
10.1021/ic701276t
PDF
Comparisons of Phosphorus Ligation Properties in P(CH2NR)3P
Natesan Thirupathi, Phillip M. Stricklen, Xiaodong Liu, Reed Oshel, Ilia Guzei, Arkady Ellern, and John G. Verkade
pp 9351 - 9363; DOI:
10.1021/ic0703070
PDF
Iron(III) Complexes with a Tripodal N3O Ligand Containing an Internal Base as a Model for Catechol Intradiol-Cleaving Dioxygenases
Fei Li, Mei Wang, Ping Li, Tingting Zhang, and Licheng Sun
pp 9364 - 9371; DOI:
10.1021/ic700664u
PDF
Reactivity of the "yl"-Bond in Uranyl(VI) Complexes. 1. Rates and Mechanisms for the Exchange between the trans-dioxo Oxygen Atoms in (UO2)2(OH)22+ and Mononuclear UO2(OH)n2-n Complexes with Solvent Water
Zoltán Szabó and Ingmar Grenthe
pp 9372 - 9378; DOI:
10.1021/ic700817y
PDF
Controlled Syntheses, Characterization, and Reactivity of Neutral and Anionic Lanthanide Amides Supported by Methylene-Linked Bis(phenolate) Ligands
Xiaoping Xu, Zhongjian Zhang, Yingming Yao, Yong Zhang, and Qi Shen
pp 9379 - 9388; DOI:
10.1021/ic701148z
PDF
Interaction of Tertiary Phosphines with Lignin-Type, ,-Unsaturated Aldehydes in Water
Dmitry V. Moiseev, Brian O. Patrick, Brian R. James, and Thomas Q. Hu
pp 9389 - 9399; DOI:
10.1021/ic7007478
PDF
Labeling of the Neuropeptide Enkephalin with Functionalized Tris(pyrazolyl)borate Complexes: Solid-Phase Synthesis and Characterization of p-[Enk-OH]COC6H4TpPtMe3 and p-[Enk-OH]COC6H4TpMeRe(CO)3
Matthew C. Kuchta, Annika Gross, Antonio Pinto, and Nils Metzler-Nolte
pp 9400 - 9404; DOI:
10.1021/ic701316n
PDF
Synthesis, Characterization, and Reactivity of Ruthenium Diene/Diamine Complexes Including Catalytic Hydrogenation of Ketones
M. Esther Morilla, Pilar Rodríguez, Tomás R. Belderrain, Claudia Graiff, Antonio Tiripicchio, M. Carmen Nicasio, and Pedro J. Pérez
pp 9405 - 9414; DOI:
10.1021/ic701363g
PDF
Trapping of Anionic Organic Radicals by (TpMe2)2Ln (Ln = Sm, Eu)
Ângela Domingos, Irene Lopes, João C. Waerenborgh, Noémia Marques, G.Y. Lin, X.W. Zhang, Josef Takats, Robert McDonald, Anna C. Hillier, Andrea Sella, Mark R. J. Elsegood, and Victor W. Day
pp 9415 - 9424; DOI:
10.1021/ic701364k
PDF
Syntheses, Solution Multi-NMR Characterization, and Reactivities of [C6F5Xe]+ Salts of Weakly Coordinating Borate Anions, [BY4]- (Y = CF3, C6F5, CN, or OTeF5)
Karsten Koppe, Vural Bilir, Hermann-J. Frohn, Hélène P. A. Mercier, and Gary J. Schrobilgen
pp 9425 - 9437; DOI:
10.1021/ic7010138
PDF
Sensitization of Europium(III) Luminescence by Benzophenone-Containing Ligands: Regioisomers, Rearrangements and Chelate Ring Size, and Their Influence on Quantum Yields
Andrew J. Wilkinson, Davide Maffeo, Andrew Beeby, Clive E. Foster, and J. A. Gareth Williams
pp 9438 - 9449; DOI:
10.1021/ic701113c
PDF
Synthesis, Structure, Spectral and Electrochemical Properties, and Catalytic Use of Cobalt(III)-Oxo Cubane Clusters
Rajesh Chakrabarty, Sanchay J. Bora, and Birinchi K. Das
pp 9450 - 9462; DOI:
10.1021/ic7011759
PDF
Structurally Diverse Aggregating Condensations of Ti(IV) Catecholates
Warren A. Wallace and Pierre G. Potvin
pp 9463 - 9472; DOI:
10.1021/ic7013495
PDF
Aerosol Assisted Chemical Vapor Deposition of In2O3 Films from Me3In and Donor Functionalized Alcohols
Siama Basharat, Claire J. Carmalt, Sarah A. Barnett, Derek A. Tocher, and Hywel O. Davies
pp 9473 - 9480; DOI:
10.1021/ic701372b
PDF
Synthesis and Structure of New Compounds with Zn-Ga Bonds: Insertion of the Gallium(I) Bisimidinate Ga(DDP) into Zn-X (X = CH3, Cl) and the Homoleptic Complex Cation [Zn(GaCp*)4]2+
Andreas Kempter, Christian Gemel, Thomas Cadenbach, and Roland A. Fischer
pp 9481 - 9487; DOI:
10.1021/ic7013804
PDF
Novel Stereochemistry, Reactivity, and Stability of an Arsenic Heterocycle in a Metal-Promoted Asymmetric Cycloaddition Reaction
Mengtao Ma, Sumod A. Pullarkat, Yongxin Li, and Pak-Hing Leung
pp 9488 - 9494; DOI:
10.1021/ic701419j
PDF
High-Temperature Single-Site Ethylene Polymerization Behavior of Titanate Complexes Supported by 1,3-Bis(3,5-dialkylpyrazol-1-yl)propan-2-olate Ligation
Richard Eaves, Sean Parkin, and Folami T. Ladipo
pp 9495 - 9502; DOI:
10.1021/ic701221f
PDF
In Situ Ligand Reactions under Hydrothermal Conditions Afford a Novel Zinc-Substituted Polyoxovanadate Dimer
Shou-Tian Zheng, Ming-Hui Wang, and Guo-Yu Yang
pp 9503 - 9508; DOI:
10.1021/ic700562m
PDF

Issue 23


Electrochemical Behavior of an Aminotrithioether Ligand: Copper(II)-Mediated Oxidative C-C Bond Formation
Raúl Huerta, Aarón Flores-Figueroa, Víctor M. Ugalde-Saldívar, and Ivan Castillo
pp 9510 - 9512; DOI:
10.1021/ic7009429
PDF
New Oxalate-Bridged CrIII-MnII Polymeric Network Incorporating a Spin-Crossover [Co(terpy)2]2+ Cation
Hui-Zhong Kou and Osamu Sato
pp 9513 - 9515; DOI:
10.1021/ic701043f
PDF
Changing the Oxothiomolybdate Ring from an Anionic to a Cationic Receptor
Jean-François Lemonnier, Sébastien Floquet, Jérôme Marrot, Ali Kachmar, Marc Bénard, Marie-Madeleine Rohmer, Mohamed Haouas, Francis Taulelle, Marc Henry, and Emmanuel Cadot
pp 9516 - 9518; DOI:
10.1021/ic701432s
PDF
Versatile Host for Metallo Anions and Cations
Sanjib Ghosh, Brian Roehm, Rowshan Ara Begum, Jerry Kut, Md. Alamgir Hossain, Victor W. Day, and Kristin Bowman-James
pp 9519 - 9521; DOI:
10.1021/ic701371f
PDF
Chiral Molecular Ferromagnets Based on Copper(II) Polymers with End-On Azido Bridges
Zhi-Guo Gu, You Song, Jing-Lin Zuo, and Xiao-Zeng You
pp 9522 - 9524; DOI:
10.1021/ic7015325
PDF
Oligometallic Template Strategy for Ring-Closing Olefin Metathesis: Highly Cis- and Trans-Selective Synthesis of a 32-Membered Macrocyclic Tetraoxime
Shigehisa Akine, Satoko Kagiyama, and Tatsuya Nabeshima
pp 9525 - 9527; DOI:
10.1021/ic701585x
PDF
DNA Strand Cleavage near a CC Mismatch Directed by a Metalloinsertor
Mi Hee Lim, Irvin H. Lau, and Jacqueline K. Barton
pp 9528 - 9530; DOI:
10.1021/ic701598k
PDF
Missing Link in the Ligand-Field Photolysis of [Mo(CN)8]4-: Synthesis, X-ray Crystal Structure, and Physicochemical Properties of [Mo(CN)6]2-
Janusz Szklarzewicz, Dariusz Matoga, Agnieszka Niezgoda, Daisuke Yoshioka, and Masahiro Mikuriya
pp 9531 - 9533; DOI:
10.1021/ic701395r
PDF
Recognition of Imidazoles by Strapped Zinc(II) Porphyrin Receptors: Insight into the Induced-Fit Mechanism
Jeremy Brandel, Ali Trabolsi, Frédéric Melin, Mourad Elhabiri, Jean Weiss, and Anne-Marie Albrecht-Gary
pp 9534 - 9536; DOI:
10.1021/ic701590x
PDF
Templateless, Surfactantless, Electrochemical Route to a Cuprous Oxide Microcrystal: From Octahedra to Monodisperse Colloid Spheres
Shaojun Guo, Youxing Fang, Shaojun Dong, and Erkang Wang
pp 9537 - 9539; DOI:
10.1021/ic7016193
PDF
Self-Optimizing Charge-Transfer Energy Phenomena in Metallosupramolecular Complexes by Dynamic Constitutional Self-Sorting
Yves-Marie Legrand, Arie van der Lee, and Mihail Barboiu
pp 9540 - 9547; DOI:
10.1021/ic701122a
PDF
Isolation of a Pentadentate Ligand and Stepwise Synthesis, Structures, and Magnetic Properties of a New Family of Homo- and Heterotrinuclear Complexes
Ling-Ling Zheng, Wei-Xiong Zhang, Lian-Jing Qin, Ji-Dong Leng, Jun-Xian Lu, and Ming-Liang Tong
pp 9548 - 9557; DOI:
10.1021/ic070343z
PDF
Thermally Induced Two-Step, Two-Site Incomplete 6A1 2T2 Crossover in a Mononuclear Iron(III) Phenolate-Pyridyl Schiff-Base Complex: A Rare Crystallographic Observation of the Coexistence of Pure S = 5/2 and 1/2 Metal Centers in the Asymmetric Unit
Musa S. Shongwe, Badria A. Al-Rashdi, Harry Adams, Michael J. Morris, Masahiro Mikuriya, and Giovanni R. Hearne
pp 9558 - 9568; DOI:
10.1021/ic700397u
PDF
Synthesis, Crystal Structure, and Magnetic Properties of Hexanuclear [{MnL2}4{Nb(CN)8}2] and Nonanuclear [{MnL2}6{Nb(CN)8}3] Heterometallic Clusters (L = bpy, phen)
Thengarai S. Venkatakrishnan, Raghunathan Rajamani, S. Ramasesha, and Jean-Pascal Sutter
pp 9569 - 9574; DOI:
10.1021/ic062383t
PDF
Magnetic and Electronic Properties of CaCu3Cr4O12 and CaCu3Cr2Sb2O12 by First-Principles Density Functional Calculation
H. P. Xiang, X. J. Liu, E. J. Zhao, J. Meng, and Z. J. Wu
pp 9575 - 9583; DOI:
10.1021/ic070213q
PDF
Cation Deficient Layered Ruddlesden-Popper-Related Oxysulfides La2LnMS2O5 (Ln = La, Y; M = Nb, Ta)
Laurent Cario, Aurelian Florin Popa, Alain Lafond, Catherine Guillot-Deudon, Houria Kabbour, A. Meerschaut, Simon J Clarke, and Paul Adamson
pp 9584 - 9590; DOI:
10.1021/ic700422r
PDF
Preparation, Characterization, Molecular and Electronic Structures, TDDFT, and TDDFT/PCM Study of the Solvatochromism in Cyanovinylferrocenes
Victor N. Nemykin, Elena A. Makarova, Jeffrey O. Grosland, Ryan G. Hadt, and Alexey Y. Koposov
pp 9591 - 9601; DOI:
10.1021/ic700558v
PDF
Cu-Pd-Cu and Cu-Pt-Cu Linear Frameworks: Synthesis, Magnetic Properties, and Theoretical Analysis of Two Mixed-Metal Complexes of Dipyridylamide (dpa), Isostructural, and Isoelectronic with [Cu3(dpa)4Cl2]+
Isiah Po-Chun Liu, Gene-Hsiang Lee, Shie-Ming Peng, Marc Bénard, and Marie-Madeleine Rohmer
pp 9602 - 9608; DOI:
10.1021/ic070319l
PDF
A 3D Porous Cobalt-Organic Framework Exhibiting Spin-Canted Antiferromagnetism and Field-Induced Spin-Flop Transition
You-Gui Huang, Da-Qiang Yuan, Long Pan, Fei-Long Jiang, Ming-Yan Wu, Xu-Dong Zhang, Wei Wei, Qiang Gao, Jeong Yong Lee, Jing Li, and Mao-Chun Hong
pp 9609 - 9615; DOI:
10.1021/ic700559z
PDF
On the Prospects of Polynuclear Complexes with Acetylenedithiolate Bridging Units
Wolfram W. Seidel, Matthias J. Meel, Udo Radius, Markus Schaffrath, and Tania Pape
pp 9616 - 9629; DOI:
10.1021/ic7008286
PDF
Syntheses, Structures, and Properties of Five Coordination Polymers Containing Fluorescent Whitener
Ruibiao Fu, Shengmin Hu, and Xintao Wu
pp 9630 - 9640; DOI:
10.1021/ic700597k
PDF
TCNE Dimer Dianion Coordination Complexes, [Mn(TPA)(TCNE)]2[2-(TCNE)2] and [Mn(TPA)(4-C4(CN)8)0.5]·ClO4, TPA = tris(2-Pyridylmethyl)amine: Synthesis, Structure and Magnetic Properties
Guangbin Wang, Carla Slebodnick, and Gordon T. Yee
pp 9641 - 9645; DOI:
10.1021/ic700590c
PDF
Thermal- and Pressure-Induced Cooperative Spin Transition in the 2D and 3D Coordination Polymers {Fe(5-Br-pmd)z[M(CN)x]y} (M = AgI, AuI, NiII, PdII, PtII)
Gloria Agustí, Ana Belén Gaspar, M. Carmen Muñoz, and José Antonio Real
pp 9646 - 9654; DOI:
10.1021/ic700993s
PDF
S K-Edge XAS and DFT Calculations on Square-Planar NiII-Thiolate Complexes: Effects of Active and Passive H-Bonding
Abhishek Dey, Kayla N. Green, Roxanne M. Jenkins, Stephen P. Jeffrey, Marcetta Darensbourg, Keith O. Hodgson, Britt Hedman, and Edward I. Solomon
pp 9655 - 9660; DOI:
10.1021/ic7006292
PDF
Hybrid Molecular Material Exhibiting Single-Molecule Magnet Behavior and Molecular Conductivity
Hiroki Hiraga, Hitoshi Miyasaka, Kazuya Nakata, Takashi Kajiwara, Shinya Takaishi, Yugo Oshima, Hiroyuki Nojiri, and Masahiro Yamashita
pp 9661 - 9671; DOI:
10.1021/ic700727n
PDF
Synthesis, Structure, and Magnetic Properties of [(CH3CN)5V-O-V(CH3CN)5][BF4]4
Julie A. Cissell, Narpinder Kaur, Saritha Nellutla, Naresh S. Dalal, and Thomas P. Vaid
pp 9672 - 9677; DOI:
10.1021/ic700920z
PDF
Mixed Transition Metal-Lanthanide Complexes at High Oxidation States: Heteronuclear CeIVMnIV Clusters
Anastasios J. Tasiopoulos, Paul L. Milligan Jr., Khalil A. Abboud, Ted A. O'Brien, and George Christou
pp 9678 - 9691; DOI:
10.1021/ic700994p
PDF
Oxidative Addition of Small Molecules to a Dinuclear Au(I) Amidinate Complex, Au2[(2,6-Me2Ph)2N2CH]2. Syntheses and Characterization of Au(II) Amidinate Complexes Including One Which Possesses Au(II)-Oxygen Bonds
Hanan E. Abdou, Ahmed A. Mohamed, and John P. Fackler, Jr.
pp 9692 - 9699; DOI:
10.1021/ic700929e
PDF
Ligand-Induced Interconversion of a Coordination-Organized Porphyrin Dimer: a Potential Fluorescence-Based Molecular Memory Monitor
Akiharu Satake, Junichi Tanihara, and Yoshiaki Kobuke
pp 9700 - 9707; DOI:
10.1021/ic7010056
PDF
Small Scorpionate Ligands: Silver(I)-Organophosphane Complexes of 5-CF3-Substituted Scorpionate Ligand Combining a B-H···Ag Coordination Motif
H. V. Rasika Dias, Simone Alidori, Giancarlo Gioia Lobbia, Grazia Papini, Maura Pellei, and Carlo Santini
pp 9708 - 9714; DOI:
10.1021/ic701041k
PDF
Synthesis and Reactivity of [(silox)2Mo=NR]2Hg (R = tBu, tAmyl; silox = OSitBu3): Unusual Thermal Stability and Ready Nucleophilic Cleavage Rationalized by Electronic Factors
Devon C. Rosenfeld, Peter T. Wolczanski, Khaldoon A. Barakat, Corneliu Buda, Thomas R. Cundari, Frank C. Schroeder, and Emil B. Lobkovsky
pp 9715 - 9735; DOI:
10.1021/ic7010953
PDF
Self-Assembly of a Mn9 Nanoscopic Mixed-Valent Cluster: Synthesis, Crystal Structure, and Magnetic Behavior
Kartik Chandra Mondal, You Song, and Partha Sarathi Mukherjee
pp 9736 - 9742; DOI:
10.1021/ic701018x
PDF
Synthesis, Structural, and Magnetic Studies on a Redox Family of Tetrametallic Vanadium Clusters: {VIV4}, {VIII2VIV2}, and {VIII4} Butterfly Complexes
Ian S. Tidmarsh, Emma Scales, Paul R. Brearley, Joanna Wolowska, Lorenzo Sorace, Andrea Caneschi, Rebecca H. Laye, and Eric J.L. McInnes
pp 9743 - 9753; DOI:
10.1021/ic7011183
PDF
Structural Characterization of Shielded Isomeric Europium Complexes with Metal-Metal Contact
Ga-Lai Law, Ka-Leung Wong, Yang-Yi Yang, Qiao-Yuan Yi, Guohua Jia, Wing-Tak Wong, and Peter A. Tanner
pp 9754 - 9759; DOI:
10.1021/ic701162j
PDF
Novel Approach to the Concept of Bond-Valence Vectors
Janusz Zachara
pp 9760 - 9767; DOI:
10.1021/ic7011809
PDF
The Thermodynamic Solvate Difference Rule: Solvation Parameters and Their Use in Interpretation of the Role of Bound Solvent in Condensed-Phase Solvates
Leslie Glasser and H. Donald Brooke Jenkins
pp 9768 - 9778; DOI:
10.1021/ic701105p
PDF
[Os(bipy)(CN)4]2- and Its Relatives as Components of Polynuclear Assemblies: Structural and Photophysical Properties
Svetlana G. Baca, Harry Adams, Christopher S. Grange, Alec P. Smith, Igor Sazanovich, and Michael D. Ward
pp 9779 - 9789; DOI:
10.1021/ic701169c
PDF
Phosphine-Substituted Dithiolene Complexes as Ligands: Communication between Ruthenium(II) Centers Through a Dimolybdenum Bis(dithiolene) Core
Harry Adams, Michael J. Morris, Andrea E. Riddiough, Lesley J. Yellowlees, and A. B. P. Lever
pp 9790 - 9807; DOI:
10.1021/ic701201x
PDF
Archetypical Modeling and Amphiphilic Behavior of Cobalt(II)-Containing Soft-Materials with Asymmetric Tridentate Ligands
Rajendra Shakya, Sarmad Sahiel Hindo, Libo Wu, Marco M. Allard, Mary Jane Heeg, Hrant P. Hratchian, Bruce R. McGarvey, Sandro R. P. da Rocha, and Cláudio N. Verani
pp 9808 - 9818; DOI:
10.1021/ic7011815
PDF
Molecularly Nonstoichiometric Crystals in Phosphorus Compounds
Manab Chakravarty, R. Rama Suresh, and K. C. Kumara Swamy
pp 9819 - 9826; DOI:
10.1021/ic701173x
PDF
4-Amino- and 4-Nitrodipicolinatovanadium(V) Complexes and Their Hydroxylamido Derivatives: Synthesis, Aqueous, and Solid-State Properties
Jason J. Smee, Jason A. Epps, Guillaume Teissedre, Mandy Maes, Nichola Harding, Luqin Yang, Bharat Baruah, Susie M. Miller, Oren P. Anderson, Gail R. Willsky, and Debbie C. Crans
pp 9827 - 9840; DOI:
10.1021/ic701233y
PDF
Conformationally Rigid Chelate Rings in Metal Complexes of Pyridyloxy-Substituted 2,2'-Dioxybiphenyl-Cyclotetra- and Cyclotriphosphazene Platforms
Eric W. Ainscough, Andrew M. Brodie, Andreas Derwahl, Steve Kirk, and Carl A. Otter
pp 9841 - 9852; DOI:
10.1021/ic701241v
PDF
Synthesis and Characterization of Ruthenium and Rhenium Nucleosides
Peijiao Wang, Jeremiah E. Miller, Lawrence M. Henling, Charlotte L. Stern, Natia L. Frank, Amanda L. Eckermann, and Thomas J. Meade
pp 9853 - 9862; DOI:
10.1021/ic701250r
PDF
Electron-Transfer-Catalyzed Rearrangement of Unsymmetrically Substituted Diiron Dithiolate Complexes Related to the Active Site of the [FeFe]-Hydrogenases
Salah Ezzaher, Jean-François Capon, Frédéric Gloaguen, François Y. Pétillon, Philippe Schollhammer, and Jean Talarmin
pp 9863 - 9872; DOI:
10.1021/ic701327w
PDF
[1-H2N-CB11F11]- - Synthesis and Reactions of a Functionalized Fluorinated Carbadodecaborate Anion
Maik Finze, Guido J. Reiss, and Manfred Zähres
pp 9873 - 9883; DOI:
10.1021/ic701398u
PDF
Novel Manganese(II) Sulfonate-Phosphonates with Dinuclear, Tetranuclear, and Hexanuclear Clusters
Zi-Yi Du, Andrey V. Prosvirin, and Jiang-Gao Mao
pp 9884 - 9894; DOI:
10.1021/ic701213g
PDF
A Tetracopper(II)-Tetraradical Cuboidal Core and Its Reactivity as a Functional Model of Phenoxazinone Synthase
Chandan Mukherjee, Thomas Weyhermüller, Eberhard Bothe, Eva Rentschler, and Phalguni Chaudhuri
pp 9895 - 9905; DOI:
10.1021/ic7012599
PDF
Structures and Physical Properties of New Semiconducting Polyselenides Ba2CuAg4-Se5 with Unprecedented Linear Se34- Units
Abdeljalil Assoud, Jianxiao Xu, and Holger Kleinke
pp 9906 - 9911; DOI:
10.1021/ic701278b
PDF
Urea-Based Ruthenium(II)-Polypyridyl Complex as an Optical Sensor for Anions: Synthesis, Characterization, and Binding Studies
Amrita Ghosh, Bishwajit Ganguly, and Amitava Das
pp 9912 - 9918; DOI:
10.1021/ic701447g
PDF
Synthesis, Characterization and Photophysics of a New Series of Anionic C,N,C Cyclometalated Platinum Complexes
Jesús R. Berenguer, Elena Lalinde, and Javier Torroba
pp 9919 - 9930; DOI:
10.1021/ic701298z
PDF
Phosphorus-Nitrogen Compounds. 14. Synthesis, Stereogenism, and Structural Investigations of Novel N/O Spirocyclic Phosphazene Derivatives
Elif Ece lter, Nuran Asmafiliz, Zeynel Kiliç, Muhammet Iiklan, Tuncer Hökelek, Nagihan Çaylak, and Ertan ahin
pp 9931 - 9944; DOI:
10.1021/ic701216f
PDF
Cyclic Tetranuclear and Hexanuclear Palladium(II) Complexes and Their Host-guest Chemistry
Judith A. Walmsley, Shourong Zhu, Antonio Matilla, Tiffanee G. Donowick, Jessica E. Cramp, Jose Manuel Tercero, and Tatyana Dalrymple
pp 9945 - 9953; DOI:
10.1021/ic700830v
PDF
Coordination of Pyridinethiols in Gold(I) Complexes
Minna T. Räisänen, Nino Runeberg, Martti Klinga, Martin Nieger, Michael Bolte, Pekka Pyykkö, Markku Leskelä, and Timo Repo
pp 9954 - 9960; DOI:
10.1021/ic700453t
PDF
Effects of Water Uptake on the Inherently Oxygen-Deficient Compounds Ln26O27(BO3)8 (Ln = La, Nd)
Samuel Noirault, Stéphane Célérier, Olivier Joubert, Maria Teresa Caldes, and Yves Piffard
pp 9961 - 9967; DOI:
10.1021/ic701059z
PDF
Systematic Investigation of Lanthanide Phosphonatoethanesulfonate Framework Structures by High-Throughput Methods, Ln(O3P-C2H4-SO3)(H2O) (Ln = La-Dy)
Andreas Sonnauer, Christian Näther, Henning A. Höppe, Jürgen Senker, and Norbert Stock
pp 9968 - 9974; DOI:
10.1021/ic7009397
PDF
An Attempt to Discriminate between the Hydrophobic and Aromatic - Interactions in the Copper(II) Ternary Complexes CuLA with L = 1,10-Phenanthroline or 2,2'-Bipyridyl and A = para-X-Substituted Phenylalaninates
Motoharu Tanaka and Masaaki Tabata
pp 9975 - 9978; DOI:
10.1021/ic701261e
PDF
Synthesis and Characterization of New Nitrogen-Donor-Stabilized N-Silylphosphoranimine Cations
Keith Huynh, Eric Rivard, Alan J. Lough, and Ian Manners
pp 9979 - 9987; DOI:
10.1021/ic7006342
PDF
Mono- versus Bis-chelate Formation in Triazenide and Amidinate Complexes of Magnesium and Zinc
Nonsee Nimitsiriwat, Vernon C. Gibson, Edward L. Marshall, Pittaya Takolpuckdee, Atanas K. Tomov, Andrew J. P. White, David J. Williams, Mark R. J. Elsegood, and Sophie H. Dale
pp 9988 - 9997; DOI:
10.1021/ic701061q
PDF
[Cd3(H2O)3((O3PCH2)2NH-CH2C6H4-COOH)2]·11H2O: A Layered Cadmium Phosphonate with Reversible Dehydration/Hydration Properties
Sebastian Bauer, Jérôme Marrot, Thomas Devic, Gérard Férey, and Norbert Stock
pp 9998 - 10002; DOI:
10.1021/ic7014918
PDF
Synthesis, Reactivity, and Properties of N-Fused Porphyrin Rhenium(I) Tricarbonyl Complexes
Motoki Toganoh, Shinya Ikeda, and Hiroyuki Furuta
pp 10003 - 10015; DOI:
10.1021/ic701208g
PDF
Heats of Formation of Krypton Fluorides and Stability Predictions for KrF4 and KrF6 from High Level Electronic Structure Calculations
David A. Dixon, Tsang-Hsiu Wang, Daniel J. Grant, Kirk A. Peterson, Karl O. Christe, and Gary J. Schrobilgen
pp 10016 - 10021; DOI:
10.1021/ic701313h
PDF
Reduction of Carbodiimides by Samarium(II) Bis(trimethylsilyl)amides-Formation of Oxalamidinates and Amidinates through C-C Coupling or C-H Activation
Glen B. Deacon, Craig M. Forsyth, Peter C. Junk, and Jun Wang
pp 10022 - 10030; DOI:
10.1021/ic701497c
PDF

Issue 24


Synthesis, Structure, and Emissive Properties of Copper(I) Complexes [CuI2(-X)2(-1,8-naphthyridine)(PPh3)2] (X = I, Br) with a Butterfly-Shaped Dinuclear Core Having a Short Cu-Cu Distance
Hiromi Araki, Kiyoshi Tsuge, Yoichi Sasaki, Shoji Ishizaka, and Noboru Kitamura
pp 10032 - 10034; DOI:
10.1021/ic7010925
PDF
A Criterion for the Anisotropy Barrier in Single-Molecule Magnets
Oliver Waldmann
pp 10035 - 10037; DOI:
10.1021/ic701365t
PDF
New Copper(II)/Cyclic Tetrapeptide System That Easily Oxidizes to Copper(III) under Atmospheric Oxygen
Alessandro Pratesi, Piero Zanello, Gianluca Giorgi, Luigi Messori, Franco Laschi, Angela Casini, Maddalena Corsini, Chiara Gabbiani, Marco Orfei, Claudia Rosani, and Mauro Ginanneschi
pp 10038 - 10040; DOI:
10.1021/ic701411y
PDF
Ferromagnetically Coupled Dimer of CuII-Substituted -Decatungstosilicate
Hongsheng Liu, Carlos J. Gómez-García, Jun Peng, Yuhua Feng, Zhongmin Su, Jingquan Sha, and Lixia Wang
pp 10041 - 10043; DOI:
10.1021/ic701296m
PDF
Toward Quartz and Cristobalite: Spontaneous Resolution, Structures, and Characterization of Chiral Silica-Mimetic Silver(I)-Organic Materials
Tzuoo-Tsair Luo, Yen-Hsiang Liu, Chun-Chieh Chan, Sheng-Ming Huang, Bor-Chen Chang, Yi-Long Lu, Gene-Hsiang Lee, Shih-Ming Peng, Ju-Chun Wang, and Kuang-Lieh Lu
pp 10044 - 10046; DOI:
10.1021/ic701412q
PDF
Multiple Bonding in Heavier Element Compounds Stabilized by Bulky Terphenyl Ligands
Eric Rivard and Philip P. Power
pp 10047 - 10064; DOI:
10.1021/ic700813h
PDF
Effects of Protonation and Metal Coordination on Intramolecular Charge Transfer of Tetrathiafulvalene Compound
Qin-Yu Zhu, Yu Liu, Wen Lu, Yong Zhang, Guo-Qing Bian, Gai-Yan Niu, and Jie Dai
pp 10065 - 10070; DOI:
10.1021/ic700672e
PDF
cis-Dichloro-bis(4,4'-dicarboxy-2,2-bipyridine)osmium(II)-Modified Optically Transparent Electrodes: Application as Cathodes in Stacked Dye-Sensitized Solar Cells
Michael J. Scott, Jeremy J. Nelson, Stefano Caramori, Carlo A. Bignozzi, and C. Michael Elliott
pp 10071 - 10078; DOI:
10.1021/ic700709k
PDF
Magnetic Properties and Magnetic Structures of Cu3(OD)4XO4, X = Se or S: Cycloidal versus Collinear Antiferromagnetic Structure
Serge Vilminot, Gilles André, Francoise Bourée-Vigneron, Mireille Richard-Plouet, and Mohamedally Kurmoo
pp 10079 - 10086; DOI:
10.1021/ic700900b
PDF
CrII Reactivity of Taurine/-Ketoglutarate Dioxygenase
Piotr K. Grzyska and Robert P. Hausinger
pp 10087 - 10092; DOI:
10.1021/ic700383q
PDF
[CrIII(NCMe)6]3+-a Labile CrIII Source Enabling Formation of Cr[M(CN)6] (M = V, Cr, Mn, Fe) Prussian Blue-Type Magnetic Materials
Kendric J. Nelson, Matthew C. Daniels, William M. Reiff, Shayla A. Troff, and Joel S. Miller
pp 10093 - 10107; DOI:
10.1021/ic7008489
PDF
Structural Units in Three Uranyl Perrhenates
Oxana V. Karimova and Peter C. Burns
pp 10108 - 10113; DOI:
10.1021/ic701128b
PDF
Conformational Change Induced by Metal-Ion-Binding to DNA Containing the Artificial 1,2,4-Triazole Nucleoside
Dominik Böhme, Nicole Düpre, Dominik A. Megger, and Jens Müller
pp 10114 - 10119; DOI:
10.1021/ic700884q
PDF
Acetonitrile Hydration and Ethyl Acetate Hydrolysis by Pyrazolate-Bridged Cobalt(II) Dimers Containing Hydrogen-Bond Donors
Paul J. Zinn, Thomas N. Sorrell, Douglas R. Powell, Victor W. Day, and A. S. Borovik
pp 10120 - 10132; DOI:
10.1021/ic700685g
PDF
Selective Cyclopalladation of R3P=NCH2Aryl Iminophosphoranes. Experimental and Computational Study
Raquel Bielsa, Rafael Navarro, Esteban P. Urriolabeitia, and Agustí Lledós
pp 10133 - 10142; DOI:
10.1021/ic701144y
PDF
Mononuclear and Polynuclear Copper(I) Complexes with a New N,N',S-Donor Ligand and with Structural Analogies to the Copper Thionein Core
Marcello Gennari, Maurizio Lanfranchi, Roberto Cammi, Maria Angela Pellinghelli, and Luciano Marchiò
pp 10143 - 10152; DOI:
10.1021/ic701189b
PDF
Magnetic Interaction of Tri- and Di-oxytriphenylamine Radical Cation FeCl4 Salts
Masato Kuratsu, Shuichi Suzuki, Masatoshi Kozaki, Daisuke Shiomi, Kazunobu Sato, Takeji Takui, and Keiji Okada
pp 10153 - 10157; DOI:
10.1021/ic7012649
PDF
Oxygen-Bridged Hybrid Metallocene-Nonmetallocene Polymetallic Catalysts of Group 4 Metals for Bimodal Activity in Olefin Polymerization: Synthesis, Characterization, and Theoretical Investigation
Swadhin K. Mandal, Prabhuodeyara M. Gurubasavaraj, Herbert W. Roesky, Gerald Schwab, Dietmar Stalke, Rainer B. Oswald, and Volker Dolle
pp 10158 - 10167; DOI:
10.1021/ic7011765
PDF
Interesting Anion-Inclusion Behavior of Cucurbit[5]uril and Its Lanthanide-Capped Molecular Capsule
Jing-Xin Liu, La-Sheng Long, Rong-Bin Huang, and Lan-Sun Zheng
pp 10168 - 10173; DOI:
10.1021/ic701236v
PDF
Simultaneous Fluoride Binding to Ferrocene-Based Heteronuclear Bidentate Lewis Acids
Ramez Boshra, Krishnan Venkatasubbaiah, Ami Doshi, Roger A. Lalancette, Lazaros Kakalis, and Frieder Jäkle
pp 10174 - 10186; DOI:
10.1021/ic7013754
PDF
Synthesis and Characterization of Iridium(III) Cyclometalated Complexes with Oligonucleotides: Insights into Redox Reactions with DNA
Fangwei Shao, Benjamin Elias, Wei Lu, and Jacqueline K. Barton
pp 10187 - 10199; DOI:
10.1021/ic7014012
PDF
Adaptable Thermochromism in the CuMo1 - xWxO4 Series (0 x < 0.1): A Behavior Related to a First-Order Phase Transition with a Transition Temperature Depending on x
M. Gaudon, C. Carbonera, A. E. Thiry, A. Demourgues, P. Deniard, C. Payen, J.-F. Létard, and S. Jobic
pp 10200 - 10207; DOI:
10.1021/ic701263c
PDF
Porous Metal-Organic Frameworks Based on Metal-Organic Polyhedra with Nanosized Cavities as Supramolecular Building Blocks: Two-Fold Interpenetrating Primitive Cubic Networks of [Cu6L8]12+ Nanocages
Jaejoon Park, Seunghee Hong, Dohyun Moon, Mira Park, Kyungjin Lee, Sangmi Kang, Yang Zou, Rohith P. John, Ghyung Hwa Kim, and Myoung Soo Lah
pp 10208 - 10213; DOI:
10.1021/ic7013623
PDF
One- and Two-Dimensional Silver and Zinc Uranyl Phosphates Containing Bipyridyl Ligands
Yaqin Yu, Wei Zhan, and Thomas E. Albrecht-Schmitt
pp 10214 - 10220; DOI:
10.1021/ic701571w
PDF
Magneto-Structural Correlation in a Series of Bimetallic Alternating Chain Complexes of [CrIIIL(CN)4]n[MnIII(salpn)]n·nSolvents (L = 2,2'-bipy or 9,10-phen, salpn = Substituted Salicyldehyde, Solvents = Water and Methanol)
Feng Pan, Zhe-Ming Wang, and Song Gao
pp 10221 - 10228; DOI:
10.1021/ic701387z
PDF
Influence of Steric Hindrance on the Core Geometry and Sulfoxidation Chemistry of Carboxylate-Rich Diiron(II) Complexes
Erwin Reisner, Tanya C. Abikoff, and Stephen J. Lippard
pp 10229 - 10240; DOI:
10.1021/ic7014176
PDF
Synthesis, Structural Characterization, and Electrochemical Studies of Nickel Porphyrins Bearing Two Peripheral Conjugated Chelating Groups
Sébastien Richeter, Christophe Jeandon, Jean-Paul Gisselbrecht, Romain Ruppert, and Henry J. Callot
pp 10241 - 10251; DOI:
10.1021/ic701484r
PDF
Synthesis, Structures, and Optical Properties of Cadmium Iodide/Phenethylamine Hybrid Materials with Controlled Structures and Emissions
Wei Wang, Juan Qiao, Liduo Wang, Lian Duan, Deqiang Zhang, Weitao Yang, and Yong Qiu
pp 10252 - 10260; DOI:
10.1021/ic7007304
PDF
A Series of Lanthanide-Transition Metal Frameworks Based on 1-, 2-, and 3D Metal-Organic Motifs Linked by Different 1D Copper(I) Halide Motifs
Jian-Wen Cheng, Shou-Tian Zheng, and Guo-Yu Yang
pp 10261 - 10267; DOI:
10.1021/ic701468q
PDF
Thioether-Functionalized Ferrocenyl-bis(phosphonite), Fe{(C5H4)P(-OC10H6(-S)C10H6O-)}2: Synthesis, Coordination Behavior, and Application in Suzuki-Miyaura Cross-Coupling Reactions
Benudhar Punji, Joel T. Mague, and Maravanji S. Balakrishna
pp 10268 - 10275; DOI:
10.1021/ic701537k
PDF
Strategic Design and Synthesis of Osmium(II) Complexes Bearing a Single Pyridyl Azolate -Chromophore: Achieving High-Efficiency Blue Phosphorescence by Localized Excitation
Yi-Ming Cheng, Elise Y. Li, Gene-Hsiang Lee, Pi-Tai Chou, Sue-Yi Lin, Ching-Fong Shu, Kwun-Chi Hwang, Yao-Lun Chen, Yi-Hwa Song, and Yun Chi
pp 10276 - 10286; DOI:
10.1021/ic7015269
PDF
Novel Inorganic-Organic Hybrid Fluorescence Chemosensor Derived from SBA-15 for Copper Cation
Ling Gao, Jian Qiang Wang, Li Huang, Xiao Xing Fan, Jian Hua Zhu, Ying Wang, and Zhi Gang Zou
pp 10287 - 10293; DOI:
10.1021/ic7008732
PDF
Iron(III) Complexes of Tridentate 3N Ligands as Functional Models for Catechol Dioxygenases: The Role of Ligand N-alkyl Substitution and Solvent on Reaction Rate and Product Selectivity
Kusalendiran Visvaganesan, Ramasamy Mayilmurugan, Eringathodi Suresh, and Mallayan Palaniandavar
pp 10294 - 10306; DOI:
10.1021/ic700822y
PDF
A Shape-Controlled Method to Functionalize Multiwalled Carbon Nanotubes with Ni3S2
Ji Min Du and Dae Joon Kang
pp 10307 - 10311; DOI:
10.1021/ic700936c
PDF
Enantiomeric Separations of Ruthenium(II) Polypyridyl Complexes Using High-Performance Liquid Chromatography (HPLC) with Cyclodextrin Chiral Stationary Phases (CSPs)
Ping Sun, Arthi Krishnan, Abhishek Yadav, Shreeyukta Singh, Frederick M. MacDonnell, and Daniel W. Armstrong
pp 10312 - 10320; DOI:
10.1021/ic701023x
PDF
Exploring the Reactivity of Four-Coordinate PNPCoX with Access to Three-Coordinate Spin Triplet PNPCo
Michael J. Ingleson, Maren Pink, Hongjun Fan, and Kenneth G. Caulton
pp 10321 - 10334; DOI:
10.1021/ic701171p
PDF
Evidence That Imidazolium-Based Ionic Ligands Can be Metal(0)/Nanocluster Catalyst Poisons in at Least the Test Case of Iridium(0)-Catalyzed Acetone Hydrogenation
Lisa Starkey Ott, Sarah Campbell, Kenneth R. Seddon, and Richard G. Finke
pp 10335 - 10344; DOI:
10.1021/ic700976z
PDF
Co(III) Complexes with N2(SO)2-Type Equatorial Planar Ligands Similar to the Active Center of Nitrile Hydratase: Role of the Sulfenate Group in the Enzymatic Reaction
Takuma Yano, Yuko Wasada-Tsutsui, Hidekazu Arii, Syuhei Yamaguchi, Yasuhiro Funahashi, Tomohiro Ozawa, and Hideki Masuda
pp 10345 - 10353; DOI:
10.1021/ic701107x
PDF
Six-Membered Ring Chelate Complexes of Ru(II): Structural and Photophysical Effects
Maria Abrahamsson, Hans-Christian Becker, Leif Hammarström, Celine Bonnefous, Charles Chamchoumis, and Randolph P. Thummel
pp 10354 - 10364; DOI:
10.1021/ic7011827
PDF
Synthesis, X-Ray, and Electronic Structures of a New Nickel Dibromide Complex. Activity in the Regioselective Catalyzed Dimerization of Ethylene into 1-Butene
Guilhem Mora, Steven van Zutphen, Christian Klemps, Louis Ricard, Yves Jean, and Pascal Le Floch
pp 10365 - 10371; DOI:
10.1021/ic701529a
PDF
Solid-State Synthesis of Monazite-type Compounds Containing Tetravalent Elements
Damien Bregiroux, Olivier Terra, Fabienne Audubert, Nicolas Dacheux, Virgine Serin, Renaud Podor, and Didier Bernache-Assollant
pp 10372 - 10382; DOI:
10.1021/ic7012123
PDF
Structural Varieties in Heterobimetallic Lanthanide Disiloxanediolates: "Inorganic Metallocenes" versus In-Plane Metallacrowns
Stephan Giessmann, Steffen Blaurock, Volker Lorenz, and Frank T. Edelmann
pp 10383 - 10389; DOI:
10.1021/ic701227n
PDF
Hydrothermal Method of Preparation of Actinide(IV) Phosphate Hydrogenphosphate Hydrates and Study of Their Conversion into Actinide(IV) Phosphate Diphosphate Solid Solutions
N. Dacheux, S. Grandjean, J. Rousselle, and N. Clavier
pp 10390 - 10399; DOI:
10.1021/ic701297v
PDF
Lithium Aryloxo Magnesiates: an Examination of Ligand Size and Donor Effects
Maria Felisa Zuniga, Johannes Kreutzer, Weijie Teng, and Karin Ruhlandt-Senge
pp 10400 - 10409; DOI:
10.1021/ic701423r
PDF
Bis(diphenylphosphido) Derivatives of the Heavier Group 2 Elements
Mark R. Crimmin, Anthony G. M. Barrett, Michael S. Hill, Peter B. Hitchcock, and Panayiotis A. Procopiou
pp 10410 - 10415; DOI:
10.1021/ic701608x
PDF
High Tc Ferrimagnetic Organic-Inorganic Hybrid Materials with MnII-L-MnII and MnII-NC-NbIV Linkages (L = Pyrazine, Pyrazine-N,N'-dioxide, Bipyrimidine)
Robert Podgajny, Dawid Pinkowicz, Tomasz Korzeniak, Wojciech Nitek, Micha Rams, and Barbara Sieklucka
pp 10416 - 10425; DOI:
10.1021/ic7018132
PDF
Big Ligands for Stabilization of Small Functionalities in Calcium Chemistry
Christian Ruspic and Sjoerd Harder
pp 10426 - 10433; DOI:
10.1021/ic701479r
PDF
Diphenyllead(IV) Chloride Complexes with Benzilthiosemicarbazones. The First Bis(Thiosemicarbazone) Derivatives
David G. Calatayud, Elena López-Torres, and M. Antonia Mendiola
pp 10434 - 10443; DOI:
10.1021/ic701490j
PDF
In Search of the Bailar Twist and Rây-Dutt Mechanisms That Racemize Chiral Trischelates: A Computational Study of ScIII, TiIV, CoIII, ZnII, GaIII, and GeIV Complexes of a Ligand Analogue of Acetylacetonate
Henry S. Rzepa and Marion E. Cass:
pp 10444 - 10444; DOI:
10.1021/ic701900f
PDF
One-Pot, High-Yield Synthesis of Size-Controlled Gold Particles with Narrow Size Distribution
Shaojun Guo and and Erkang Wang:
pp 10444 - 10444; DOI:
10.1021/ic7020275
PDF

Issue 25


Cleavage of Proteins by a Mixed-Ligand Copper(II) Phenolate Complex: Hydrophobicity of the Diimine Coligand Promotes Cleavage
Venugopal Rajendiran, Mallayan Palaniandavar, Palanisami Swaminathan, and Lakshmanan Uma
pp 10446 - 10448; DOI:
10.1021/ic700823q
PDF
Crystalline Zinc Diphosphonate Metal-Organic Framework with Three-Dimensional Microporosity
Junmei Liang and George K. H. Shimizu
pp 10449 - 10451; DOI:
10.1021/ic701628f
PDF
Honeycomb Layer of Cobalt(II) Azide Hydrazine Showing Weak Ferromagnetism
Xiu-Teng Wang, Zhe-Ming Wang, and Song Gao
pp 10452 - 10454; DOI:
10.1021/ic7016775
PDF
Novel 2-Mercaptopyridine-Ruthenium Complex Exhibiting Electrochemically Induced Linkage Isomerization Switched On/Off by Protolysis
Tomohiko Hamaguchi, Kikujiro Ujimoto, and Isao Ando
pp 10455 - 10457; DOI:
10.1021/ic701186k
PDF
Binding Interaction of [Re(H2O)3(CO)3]+ with the DNA Fragment d(CpGpG)
Fabio Zobi, Olivier Blacque, Roland K. O. Sigel, and Roger Alberto
pp 10458 - 10460; DOI:
10.1021/ic701647m
PDF
Field-Induced Metamagnetic Transition in the FeIII-MnIII Bimetallic Chain Built by a New Cyanide-Bearing FeIII Precursor
Jae Il Kim, Houng Sik Yoo, Eui Kwan Koh, and Chang Seop Hong
pp 10461 - 10463; DOI:
10.1021/ic702001q
PDF
Excited-State Equilibration over 30 Å in a Platinum(II) Quinolinolate-Bridge-Platinum(II) Porphyrin Complex
Victor A. Montes, Michael A. J. Rodgers, and Pavel Anzenbacher, Jr.
pp 10464 - 10466; DOI:
10.1021/ic701557q
PDF
Dinuclear Oxovanadium(IV) Thiolate Complexes with Ferromagnetically Coupled Interaction between Vanadium Centers
Yi-Fang Tsai, Gui-Shih Huang, Chen-I Yang, Hui-Lien Tsai, Yi-Hung Liu,, Ting-Shen Kuo,and, and Hua-Fen Hsu
pp 10467 - 10469; DOI:
10.1021/ic7017117
PDF
Dinuclear Transition-Metal Terpyridine Complexes with a Dithienylcyclo- pentene Bridge Directed toward Molecular Electronic Applications
Yu-Wu Zhong, Neus Vila, Jay C. Henderson, Samuel Flores-Torres, and Héctor D. Abruña
pp 10470 - 10472; DOI:
10.1021/ic701784b
PDF
X-ray and Neutron Diffraction Studies of Water-Encapsulated inside Potassium Aryloxide Aggregates: Complementary Host-Guest Stabilization of Mono- and Dihydrated Cages
J. Jacob Morris, Bruce. C. Noll, Arthur J. Schultz, Paula M. B. Piccoli, and Kenneth W. Henderson
pp 10473 - 10475; DOI:
10.1021/ic7018082
PDF
Synthesis and Characterization of an Iron(II) 2-Hydrazine Complex
Justin L. Crossland, Lev N. Zakharov, and David R. Tyler
pp 10476 - 10478; DOI:
10.1021/ic702007r
PDF
Mononuclear Rh(II) PNP-Type Complexes. Structure and Reactivity
Moran Feller, Eyal Ben-Ari, Tarkeshwar Gupta, Linda J. W. Shimon, Gregory Leitus, Yael Diskin-Posner, Lev Weiner, and David Milstein
pp 10479 - 10490; DOI:
10.1021/ic701044b
PDF
Structural and Thermodiffractometric Analysis of Coordination Polymers. Part I: Tin Derivatives of the Bim ligand [Bim = Bis(1-imidazolyl)methane])
Norberto Masciocchi, Claudio Pettinari, Enrica Alberti, Riccardo Pettinari, Corrado Di Nicola, Alessandro Figini Albisetti, and Angelo Sironi
pp 10491 - 10500; DOI:
10.1021/ic701530c
PDF
Structural and Thermodiffractometric Analysis of Coordination Polymers. Part II:1 Zinc and Cadmium Derivatives of the Bim ligand [Bim = Bis(1-imidazolyl)methane]
Norberto Masciocchi, Claudio Pettinari, Enrica Alberti, Riccardo Pettinari, Corrado Di Nicola, Alessandro Figini Albisetti, and Angelo Sironi
pp 10501 - 10509; DOI:
10.1021/ic7015319
PDF
Theoretical Studies on Structures of Neptunyl Carbonates: NpO2(CO3)m(H2O)nq- (m = 1-3, n = 0-3) in Aqueous Solution
K. Balasubramanian and Zhiji Cao
pp 10510 - 10519; DOI:
10.1021/ic700486u
PDF
Light-Induced Geometrical Changes in Acyclic Ruthenium(II) Complexes and Their Ruthena-Macrocyclic Analogues
Sylvestre Bonnet, Jean-Paul Collin, and Jean-Pierre Sauvage
pp 10520 - 10533; DOI:
10.1021/ic700734q
PDF
{LnIII[5-2,1,1,1,1-1,2-(CO2)2C6H4][isonicotine][H2O]}2CuI·X (Ln = Eu, Sm, Nd; X = ClO4-, Cl-): A New Pillared-Layer Approach to Heterobimetallic 3d-4f 3D-Network Solids
Jian-Wen Cheng, Shou-Tian Zheng, En Ma, and Guo-Yu Yang
pp 10534 - 10538; DOI:
10.1021/ic700893w
PDF
Predicting Exchange Coupling Constants in Frustrated Molecular Magnets Using Density Functional Theory
Indranil Rudra, Qin Wu, and Troy Van Voorhis
pp 10539 - 10548; DOI:
10.1021/ic700871f
PDF
CMPO-Functionalized C3-Symmetric Tripodal Ligands in Liquid/Liquid Extractions: Efficient, Selective Recognition of Pu(IV) with Low Affinity for 3+ Metal Ions
Kornelia Matloka, Ajay K. Sah, Matthew W. Peters, Priya Srinivasan, Artem V. Gelis, Monica Regalbuto, and Michael J. Scott
pp 10549 - 10563; DOI:
10.1021/ic700800a
PDF
Cu2+ Colorimetric Sensing and Fluorescence Enhancement and Hg2+ Fluorescence Diminution in "Scorpionate"-like Tetrathienyl-Substituted Boron-Dipyrrins
Shin Hei Choi, Keliang Pang, Kibong Kim, and David G. Churchill
pp 10564 - 10577; DOI:
10.1021/ic701101j
PDF
Bimetallic MV2CuII3 (M = Mo, W) Coordination Complexes Based on Octacyanometalates: Structures and Magnetic Variations Tuned by Chelated Tetradentate Macrocyclic Ligands
Jeong Hak Lim, Young Sin You, Houng Sik Yoo, Jung Hee Yoon, Jae Il Kim, Eui Kwan Koh, and Chang Seop Hong
pp 10578 - 10586; DOI:
10.1021/ic701243w
PDF
An Effective Hydrothermal Route for the Synthesis of Multiple PDDA-Protected Noble-Metal Nanostructures
Hongjun Chen, Yuling Wang, and Shaojun Dong
pp 10587 - 10593; DOI:
10.1021/ic7009572
PDF
Unraveling the Reactive Species of a Functional Non-Heme Iron Monooxygenase Model Using Stopped-Flow UV-Vis Spectroscopy
Gerard T. Rowe, Elena V. Rybak-Akimova, and John P. Caradonna
pp 10594 - 10606; DOI:
10.1021/ic7011217
PDF
Mononuclear and Binuclear Copper(I) Complexes Ligated by Bis(3,5-diisopropyl-1-pyrazolyl)methane: Insight into the Fundamental Coordination Chemistry of Three-Coordinate Copper(I) Complexes with a Neutral Coligand
Kiyoshi Fujisawa, Yuki Noguchi, Yoshitaro Miyashita, Ken-ichi Okamoto, and Nicolai Lehnert
pp 10607 - 10623; DOI:
10.1021/ic7011342
PDF
Direct Atomic Scale Observation of Linkage Isomerization of As4S4 Clusters during the Photoinduced Transition of Realgar to Pararealgar
Pane Naumov, Petre Makreski, and Gligor Jovanovski
pp 10624 - 10631; DOI:
10.1021/ic701299w
PDF
Fine-Tuning Ligand-Receptor Design for Selective Molecular Recognition of Dicarboxylic Acids
Arnau Arbuse, Carmen Anda, Ma Angeles Martínez, Javier Pérez-Mirón, Carlos Jaime, Teodor Parella, and Antoni Llobet
pp 10632 - 10638; DOI:
10.1021/ic701288n
PDF
Photoelectron Spectroscopy and Electronic Structure Calculations of d1 Vanadocene Compounds with Chelated Dithiolate Ligands: Implications for Pyranopterin Mo/W Enzymes
Matthew A. Cranswick, Alice Dawson, J. Jon A. Cooney, Nadine E. Gruhn, Dennis L. Lichtenberger, and John H. Enemark
pp 10639 - 10646; DOI:
10.1021/ic701338s
PDF
Influence of the Thiazole Backbone on the Structural, Redox, and Optical Properties of Dithiolene and Diselenolene Complexes
Samar Eid, Marc Fourmigué, Thierry Roisnel, and Dominique Lorcy
pp 10647 - 10654; DOI:
10.1021/ic7013682
PDF
Homolysis of the Peroxynitrite Anion Detected with Permanganate
Manuel Sturzbecher, Reinhard Kissner, Thomas Nauser, and Willem H. Koppenol
pp 10655 - 10658; DOI:
10.1021/ic7013978
PDF
Electron Transfer Activity of Nickelacyclic Complex Analogues of Nickelocene: Synthesis of (5-R-cyclopentadienyl){4-[1-(5-R-cyclopentadienyl)]-2,3,4,5-tetraphenyl-1-nickela-2-cyclopentenyl}nickel Complexes (R = H, CH3) and Crystal Structures of the Redox Couples [(5- Methylcyclopentadienyl){4-[1-(5-methylcyclopentadienyl)]-2,3,4,5-tetraphenyl-1-nickela-2-cyclopentenyl}nickel](0/+) and [(5-Methylcyclopentadienyl){5-[1-(5-methylcyclopentadienyl)-1-nickelafluorenyl}nickel](0/+)
Serena Losi, Fulvio Rossi, Franco Laschi, Fabrizia Fabrizi de Biani, Piero Zanello, Piotr Buchalski, Kinga Burakowska, Katarzyna Piwowar, Jolanta Zbrzezna, Stanisaw Pasynkiewicz, Antoni Pietrzykowski, Kinga Suwiska, and Lucjan Jerzykiewicz
pp 10659 - 10669; DOI:
10.1021/ic701226d
PDF
Ionothermal Syntheses of Six Three-Dimensional Zinc Metal-Organic Frameworks with 1-Alkyl-3-methylimidazolium Bromide Ionic Liquids as Solvents
Ling Xu, Eun-Young Choi, and Young-Uk Kwon
pp 10670 - 10680; DOI:
10.1021/ic701393w
PDF
Synchronized Fluxional Motion and Cyclometalation of Ligands in Platinum(II) Complexes
Raffaello Romeo, Giuseppina D'Amico, Emanuela Guido, Alberto Albinati, and Silvia Rizzato
pp 10681 - 10692; DOI:
10.1021/ic701396j
PDF
Electronic Structures of Main-Group Carbene Analogues
Heikki M. Tuononen, Roland Roesler, Jason L. Dutton, and Paul J. Ragogna
pp 10693 - 10706; DOI:
10.1021/ic701350e
PDF
Mechanistic Insights into the Chemistry of Ru(II) Complexes Containing Cl and DMSO Ligands
Joaquim Mola, Isabel Romero, Montserrat Rodríguez, Fernando Bozoglian, Albert Poater, Miquel Solà, Teodor Parella, Jordi Benet-Buchholz, Xavier Fontrodona, and Antoni Llobet
pp 10707 - 10716; DOI:
10.1021/ic701421w
PDF
C3-Symmetric Trinuclear Molybdenum Cluster Sulfides: Configurational Stability, Supramolecular Stereocontrol, and Absolute Configuration Assignment
Richard Frantz, Eva Guillamón, Jérôme Lacour, Rosa Llusar, Victor Polo, and Cristian Vicent
pp 10717 - 10723; DOI:
10.1021/ic701522p
PDF
Anion- Interactions in Bisadenine Derivatives: A Combined Crystallographic and Theoretical Study
Angel Garcia-Raso, Francisca M. Albertí, Juan J. Fiol, Andres Tasada, Miquel Barceló-Oliver, Elies Molins, Daniel Escudero, Antonio Frontera, David Quiñonero, and Pere M. Deyà
pp 10724 - 10735; DOI:
10.1021/ic701555n
PDF
Antimony-121 Mössbauer Spectral Study of the Eu14MnSb11 and Yb14MnSb11 Zintl Compounds
Raphaël P. Hermann, Fernande Grandjean, D. Kafle, Dennis E. Brown, C. E. Johnson, S. M. Kauzlarich, and Gary J. Long
pp 10736 - 10740; DOI:
10.1021/ic7014226
PDF
Facile Synthesis of BiCuOS by Hydrothermal Methods
William C. Sheets, Evan S. Stampler, Houria Kabbour, Mariana I. Bertoni, Laurent Cario, Thomas O. Mason, Tobin J. Marks, and Kenneth R. Poeppelmeier
pp 10741 - 10748; DOI:
10.1021/ic7014622
PDF
An Unknown Coordination Mode of the Phosphite Unit and a Carbon-Free Heterocycle in Two Different Heterobimetallic Alumophosphites
A. Paulina Gómora-Figueroa, Vojtech Jancik, Raymundo Cea-Olivares, and Rubén A. Toscano
pp 10749 - 10753; DOI:
10.1021/ic701614c
PDF
A Planar Carboxylate-Rich Tetrairon(II) Complex and Its Conversion to Linear Triiron(II) and Paddlewheel Diiron(II) Complexes
Erwin Reisner, Joshua Telser, and Stephen J. Lippard
pp 10754 - 10770; DOI:
10.1021/ic701663j
PDF
Anion-Directed Synthesis of Metal-Organic Frameworks Based on 2-Picolinate Cu(II) Complexes: A Ferromagnetic Alternating Chain and Two Unprecedented Ferromagnetic Fish Backbone Chains
Chaitali Biswas, Pampa Mukherjee, Michael G. B. Drew, Carlos J. Gómez-García, Juan M. Clemente-Juan, and Ashutosh Ghosh
pp 10771 - 10780; DOI:
10.1021/ic701440x
PDF
Amine-Templated Open-Framework Zinc Arsenates of Varying Dimensionalities: Synthesis, Structure, Polymorphism, and Transformation Reactions
V. Koteswara Rao, Sandip Chakrabarti, and Srinivasan Natarajan
pp 10781 - 10790; DOI:
10.1021/ic7014594
PDF
Functionalization of Corroles: The Nitration Reaction
Manuela Stefanelli, Marco Mastroianni, Sara Nardis, Silvia Licoccia, Frank R. Fronczek, Kevin M. Smith, Weihua Zhu, Zhongping Ou, Karl M. Kadish, and Roberto Paolesse
pp 10791 - 10799; DOI:
10.1021/ic7014572
PDF
Quantitative Assessment of the Stereoelectronic Profile of Phosphine Ligands
Jomon Mathew, Tinto Thomas, and Cherumuttathu H. Suresh
pp 10800 - 10809; DOI:
10.1021/ic701547h
PDF
A Fourth Isolated Oxidation Level of the [Mn12O12(O2CR)16(H2O)4] Family of Single-Molecule Magnets
Rashmi Bagai and George Christou
pp 10810 - 10818; DOI:
10.1021/ic7015758
PDF
Stoichiometry and Structure of Uranyl(VI) Hydroxo Dimer and Trimer Complexes in Aqueous Solution
Satoru Tsushima, André Rossberg, Atsushi Ikeda, Katharina Müller, and Andreas C. Scheinost
pp 10819 - 10826; DOI:
10.1021/ic701607e
PDF
Vanadium Complexes Possessing N2O2S2-Based Ligands: Highly Active Procatalysts for the Homopolymerization of Ethylene and Copolymerization of Ethylene/1-hexene
Damien M. Homden, Carl Redshaw, and David L. Hughes
pp 10827 - 10839; DOI:
10.1021/ic701461b
PDF
Effect of Axial Ligands and Macrocyclic Structure on Redox Potentials and Electron-Transfer Mechanisms of Sn(IV) Porphyrins
Zhongping Ou, Wenbo E, Weihua Zhu, Pall Thordarson, Paul J. Sintic, Maxwell J. Crossley, and Karl M. Kadish
pp 10840 - 10849; DOI:
10.1021/ic7016165
PDF
Mechanism of the MoO2Cl2-Catalyzed Hydrosilylation: A DFT Study
Markus Drees and Thomas Strassner
pp 10850 - 10859; DOI:
10.1021/ic7017314
PDF
Synthesis and Structural Characterization of Monomeric Heterobimetallic Oxides with a Ge(II)-O-M Skeleton (M = Yb, Y)
Ying Yang, Herbert W. Roesky, Peter G. Jones, Cheuk-Wai So, Zhensheng Zhang, Regine Herbst-Irmer, and Hongqi Ye
pp 10860 - 10863; DOI:
10.1021/ic701262x
PDF
Reevaluation of the Kinetics of Polynuclear Mimics for Manganese Catalases
Sandra Signorella, Annette Rompel, Klaudia Büldt-Karentzopoulos, Bernt Krebs, Vincent L. Pecoraro, and Jean-Pierre Tuchagues
pp 10864 - 10868; DOI:
10.1021/ic070180e
PDF
DNA Binding and Topoisomerase II Inhibitory Activity of Water-Soluble Ruthenium(II) and Rhodium(III) Complexes
Sanjay Kumar Singh, Shweta Joshi, Alok Ranjan Singh, Jitendra Kumar Saxena, and Daya Shankar Pandey
pp 10869 - 10876; DOI:
10.1021/ic700885m
PDF
Luminescent Dinuclear Lanthanide Complexes of 5-Me-HXTA
Louise S. Natrajan, Phillipa L. Timmins, Matthew Lunn, and Sarah L. Heath
pp 10877 - 10886; DOI:
10.1021/ic701366f
PDF
Crystal Structures of Ln4Ni3O8 (Ln = La, Nd) Triple Layer T'-type Nickelates
Viktor V. Poltavets, Konstantin A. Lokshin, Mark Croft, Tapas K. Mandal, Takeshi Egami, and Martha Greenblatt
pp 10887 - 10891; DOI:
10.1021/ic701480v
PDF
Syntheses, Structures, and Sensitized Lanthanide Luminescence by Pt Ln (Ln = Eu, Nd, Yb) Energy Transfer for Heteronuclear PtLn2 and Pt2Ln4 Complexes with a Terpyridyl-Functionalized Alkynyl Ligand
Xiu-Ling Li, Lin-Xi Shi, Li-Yi Zhang, Hui-Min Wen, and Zhong-Ning Chen
pp 10892 - 10900; DOI:
10.1021/ic7015676
PDF
Electrochemical and EPR Studies of the Corannulene Ruthenium(II) Sandwich Complex [(6-C6Me6)Ru(6-C20H10)](SbF6)2
Robert J. Angelici, Bolin Zhu, Serena Fedi, Franco Laschi, and Piero Zanello
pp 10901 - 10906; DOI:
10.1021/ic7015512
PDF
Thermodynamics of Oxygen Activation by Macrocyclic Complexes of Rhodium
Ewa Szajna-Fuller and Andreja Bakac
pp 10907 - 10912; DOI:
10.1021/ic7015337
PDF
Wurster's Crowns: A Comparative Study of ortho- and para-Phenylenediamine-Containing Macrocyclic Receptors
John W. Sibert, Philip B. Forshee, Greg R. Hundt, Andrew L. Sargent, Simon G. Bott, and Vincent Lynch
pp 10913 - 10925; DOI:
10.1021/ic701560n
PDF
Theoretical Study of Metal-Ligand Interaction in Sm(III), Eu(III), and Tb(III) Complexes of Coumarin-3-Carboxylic Acid in the Gas Phase and Solution
Ivelina Georgieva, Natasha Trendafilova, Adélia J. A. Aquino, and Hans Lischka
pp 10926 - 10936; DOI:
10.1021/ic7016616
PDF

Issue 26


Ionic Liquids with Perfluorinated Alkoxyaluminates
Tudor Timofte, Slawomir Pitula, and Anja-Verena Mudring
pp 10938 - 10940; DOI:
10.1021/ic7009995
PDF
Formation of a Sulfur-Atom-Inserted N-Confused Porphyrin Iron Nitrosyl Complex by Denitrosation and C-S Bond Cleavage of an S-Nitrosothiol
Chen-Hsiung Hung, Wei-Min Ching, Gao-Fong Chang, Chuan-Hung Chuang, Han-Wei Chu, and Way-Zen Lee
pp 10941 - 10943; DOI:
10.1021/ic7018378
PDF
Combination of Lacunary Polyoxometalates and High-Nuclear Transition-Metal Clusters under Hydrothermal Conditions. 5. A Novel Tetrameric Cluster of [{FeIIFeIII12(3-OH)12(4-PO4)4}(B--PW9O34)4]22-
Jun-Wei Zhao, Jie Zhang, Shou-Tian Zheng, and Guo-Yu Yang
pp 10944 - 10946; DOI:
10.1021/ic701810t
PDF
Synthesis and Reactivity of a Dipyrrinatolithium Complex
Judy Cipot-Wechsler, Adeeb Al-Sheikh Ali, Erin E. Chapman, T. Stanley Cameron, and Alison Thompson
pp 10947 - 10949; DOI:
10.1021/ic701369h
PDF
Magnetic Circular Dichroism Evidence for a Weakly Coupled Heme-Radical Pair at the Active Site of Cytochrome cd1, a Nitrite Reductase
Vasily S. Oganesyan, Myles R. Cheesman, and Andrew J. Thomson
pp 10950 - 10952; DOI:
10.1021/ic701556y
PDF
Organo-Zintl Clusters Soluble in Conventional Organic Solvents: Setting the Stage for Organo-Zintl Cluster Chemistry
Michael W. Hull and Slavi C. Sevov
pp 10953 - 10955; DOI:
10.1021/ic702151q
PDF
Unusual Inorganic Ring Systems of Scandium and Yttrium Containing Group 13 Metals: Coordination of Monomeric Me2InOMe to Yttrium
Stephan Giessmann, Steffen Blaurock, Volker Lorenz, and Frank T. Edelmann
pp 10956 - 10958; DOI:
10.1021/ic701909m
PDF
In Situ Hydrothermal Reduction of Neptunium(VI) as a Route to Neptunium(IV) Phosphonates
Travis H. Bray, Anna-Gay D. Nelson, Geng Bang Jin, Richard G. Haire, and Thomas E. Albrecht-Schmitt
pp 10959 - 10961; DOI:
10.1021/ic702136h
PDF
Development of a Series of P(CH2N=CHR)3 and Trisubstituted 1,3,5-Triaza-7-phosphaadamantane Ligands
Rongcai Huang and Brian J. Frost
pp 10962 - 10964; DOI:
10.1021/ic701864g
PDF
Ambient-Temperature Metal-to-Ligand Charge-Transfer Phosphorescence Facilitated by Triarylboron: Bnpa and Its Metal Complexes
Shu-Bin Zhao, Theresa MCormick, and Suning Wang
pp 10965 - 10967; DOI:
10.1021/ic7021215
PDF
Adventures in Bioinorganic Chemistry
Thomas G. Spiro
pp 10968 - 10980; DOI:
10.1021/ic700555y
PDF
A Pyrazolate-Supported Fe3(3-O) Core: Structural, Spectroscopic, Electrochemical, and Magnetic Study
Dalice Piñero, Peter Baran, Roman Boca, Radovan Herchel, Michael Klein, Raphael G. Raptis, Franz Renz, and Yiannis Sanakis
pp 10981 - 10989; DOI:
10.1021/ic0701460
PDF
Octacyanotungstate(V)-Based Magnetic Complex Consisting of Dimeric Mn2 and Tetrameric Mn2W2
Zhao-Xi Wang, Xi-Li Li, Tian-Wei Wang, Yi-Zhi Li, Shin-ichi Ohkoshi, Kazuhito Hashimoto, You Song, and Xiao-Zeng You
pp 10990 - 10995; DOI:
10.1021/ic070195c
PDF
Green Coloration of Co-Doped ZnO Explained from Structural Refinement and Bond Considerations
M. Gaudon, O. Toulemonde, and A. Demourgues
pp 10996 - 11002; DOI:
10.1021/ic701157j
PDF
cis-Dicyanoosmium(II) Diimine Complexes Bearing Phosphine or Sulfoxide Ligands: Spectroscopic and Luminescent Studies
Siu-Wai Lai, Queenie K.-W. Chan, Nianyong Zhu, and Chi-Ming Che
pp 11003 - 11016; DOI:
10.1021/ic070290l
PDF
Synthesis, Crystal Structure, and Magnetic Studies of Oxo-Centered Trinuclear Chromium(III) Complexes: [Cr3(3-O)(2-PhCOO)6(H2O)3]NO3· 4H2O·2CH3OH, a Case of Spin-Frustrated System, and [Cr3(3-O)- (2-PhCOO)2(2-OCH2CH3)2(bpy)2(NCS )3], a New Type of [Cr3O] Core
Albert Figuerola, Vassilis Tangoulis, Joan Ribas, Hans Hartl, Irene Brüdgam, Miguel Maestro, and Carmen Diaz
pp 11017 - 11024; DOI:
10.1021/ic700606e
PDF
Synthesis, Crystal Structures, and Photophysical Properties of Homodinuclear Lanthanide Xanthene-9-carboxylates
R. Shyni, S. Biju, M. L. P. Reddy, Alan H. Cowley, and Michael Findlater
pp 11025 - 11030; DOI:
10.1021/ic701075u
PDF
Temperature-Triggered Self-Assembly of ZnO: from Nanocrystals to Nanorods to Tablets
Yong Hu, Ting Mei, Jun Guo, and Tim White
pp 11031 - 11035; DOI:
10.1021/ic700863g
PDF
Fast Synthesis of ZnO Nanostructures by Laser-Induced Decomposition of Zinc Acetylacetonate
Christian Fauteux, Rémi Longtin, Joseph Pegna, and Daniel Therriault
pp 11036 - 11047; DOI:
10.1021/ic700915z
PDF
Structural Diversity and Supramolecular Aggregation in Calcium, Strontium, and Barium Salicylates Incorporating 1,10-Phenanthroline and 4,4'-Bipyridine: Probing the Softer Side of Group 2 Metal Ions with Pyridinic Ligands
Ramaswamy Murugavel and Remya Korah
pp 11048 - 11062; DOI:
10.1021/ic700977w
PDF
New Potassium Bismuth Thiophosphates Including the Modulated K1.5Bi2.5(PS4)3
Matthew A. Gave, David P. Weliky, and Mercouri G. Kanatzidis
pp 11063 - 11074; DOI:
10.1021/ic701211a
PDF
Selective Phosphorescence Chemosensor for Homocysteine Based on an Iridium(III) Complex
Huili Chen, Qiang Zhao, Yanbo Wu, Fuyou Li, Hong Yang, Tao Yi, and, and Chunhui Huang
pp 11075 - 11081; DOI:
10.1021/ic7010887
PDF
Blue-Emitting Iridium Complexes with Substituted 1,2,4-Triazole Ligands: Synthesis, Photophysics, and Devices
Enrico Orselli, Gregg S. Kottas, Asgeir E. Konradsson, Paolo Coppo, Roland Fröhlich, Luisa De Cola, Addy van Dijken, Michael Büchel, and Herbert Börner
pp 11082 - 11093; DOI:
10.1021/ic701110p
PDF
Facilitated Hydride Binding in an Fe-Fe Hydrogenase Active-Site Biomimic Revealed by X-ray Absorption Spectroscopy and DFT Calculations
Simone Löscher, Lennart Schwartz, Matthias Stein, Sascha Ott, and Michael Haumann
pp 11094 - 11105; DOI:
10.1021/ic701255p
PDF
Prussian Blue Analogue CsFe[Cr(CN)6] as a Matrix for the Fe(II) Spin-Crossover
Boris Le Guennic, Serguei Borshch, and Vincent Robert
pp 11106 - 11111; DOI:
10.1021/ic701352c
PDF
DNA Cleavage by New Oxovanadium(IV) Complexes of N-Salicylidene -Amino Acids and Phenanthroline Bases in the Photodynamic Therapy Window
Pijus K. Sasmal, Ashis K. Patra, Munirathinam Nethaji, and Akhil R. Chakravarty
pp 11112 - 11121; DOI:
10.1021/ic7011793
PDF
New Insights into the Visible-Light-Induced DNA Cleavage Activity of Dipyridoquinoxaline Complexes of Bivalent 3d-Metal Ions
Mithun Roy, Biswarup Pathak, Ashis K. Patra, Eluvathingal D. Jemmis, Munirathinam Nethaji, and Akhil R. Chakravarty
pp 11122 - 11132; DOI:
10.1021/ic701450a
PDF
Diorganoruthenium Complexes Incorporating Noninnocent [C6H2(CH2ER2)2-3,5]22- (E = N, P) Bis-Pincer Bridging Ligands: Synthesis, Spectroelectrochemistry, and DFT Studies
Marcella Gagliardo, Catelijne H. M. Amijs, Martin Lutz, Anthony L. Spek, Remco W. A. Havenith, Frantiek Hartl, Gerard P. M. van Klink, and Gerard van Koten
pp 11133 - 11144; DOI:
10.1021/ic701501q
PDF
Rates of Proton Transfer to Fe-S-Based Clusters: Comparison of Clusters Containing {MFe(2-S)2}n+ and {MFe3(3-S)4}n+ (M = Fe, Mo, or W) Cores
Katie Bates, Brendan Garrett, and Richard A. Henderson
pp 11145 - 11155; DOI:
10.1021/ic7015484
PDF
Silylation, Sulfidation, and Benzene-1,2-dithiolate Complexation Reactions of Oxo- and Oxosulfidomolybdates(VI) and -Tungstates(VI)
Jun-Jieh Wang and R. H. Holm
pp 11156 - 11164; DOI:
10.1021/ic701294y
PDF
Dinuclear and Tetranuclear Gold-Nitrogen Complexes. Solvent Influences on Oxidation and Nuclearity of Gold Guanidinate Derivatives
Ahmed A. Mohamed, Andrew P. Mayer, Hanan E. Abdou, Michael D. Irwin, Lisa M. Pérez, and John P. Fackler, Jr.
pp 11165 - 11172; DOI:
10.1021/ic701399s
PDF
fac-[Re(CO)3L]+ Complexes with N-CH2-CH2-X-CH2-CH2-N Tridentate Ligands. Synthetic, X-ray Crystallographic, and NMR Spectroscopic Investigations
Anna Maria Christoforou, Patricia A. Marzilli, Frank R. Fronczek, and Luigi G. Marzilli
pp 11173 - 11182; DOI:
10.1021/ic701576u
PDF
Asymmetrical Polar Modification of a Bivanadium-Capped Keggin POM by Multiple Cu-N Coordination Polymeric Chains
Jing-quan Sha, Jun Peng, Hong-sheng Liu, Jing Chen, Ai-xiang Tian, and Peng-peng Zhang
pp 11183 - 11189; DOI:
10.1021/ic7014308
PDF
Synthesis and Characterization of Ruthenium Bis(-diketonato) Pyridine-Imidazole Complexes for Hydrogen Atom Transfer
Adam Wu, Joshua Masland, Rodney D. Swartz, Werner Kaminsky, and James M. Mayer
pp 11190 - 11201; DOI:
10.1021/ic7015726
PDF
Blue-Emitting Platinum(II) Complexes Bearing both Pyridylpyrazolate Chelate and Bridging Pyrazolate Ligands: Synthesis, Structures, and Photophysical Properties
Sheng-Yuan Chang, Jing-Lin Chen, Yun Chi, Yi-Ming Cheng, Gene-Hsiang Lee, Chang-Ming Jiang, and Pi-Tai Chou
pp 11202 - 11212; DOI:
10.1021/ic701586c
PDF
Rare Examples of Transition-Metal-Main-Group Metal Heterometallic Metal-Organic Frameworks from Gallium and Indium Dipyrrinato Complexes and Silver Salts: Synthesis and Framework Variability
Jay R. Stork, Van S. Thoi, and Seth M. Cohen
pp 11213 - 11223; DOI:
10.1021/ic7016159
PDF
Determination of the Intrinsic Affinities of Multiple Site-Specific Mg2+ Ions Coordinated to Domain 6 of a Group II Intron Ribozyme
Michèle C. Erat and Roland K. O. Sigel
pp 11224 - 11234; DOI:
10.1021/ic701627t
PDF
Azide-Bridged One-Dimensional MnIII Polymers: Effects of Side Group of Schiff Base Ligands on Structure and Magnetism
Mei Yuan, Fei Zhao, Wen Zhang, Zhe-Ming Wang, and Song Gao
pp 11235 - 11242; DOI:
10.1021/ic701655w
PDF
Self-Assembled Metallacycles with Pyrazine Edges: A New Example in Which the Unexpected Molecular Triangle Prevails over the Expected Molecular Square
Sofia Derossi, Massimo Casanova, Elisabetta Iengo, Ennio Zangrando, Mauro Stener, and Enzo Alessio
pp 11243 - 11253; DOI:
10.1021/ic7019507
PDF
Synthesis, Structure, and Magnetic Behavior of Bis(2-amino-5-fluoropyridinium) Tetrachlorocuprate(II)
Lixin Li, Mark M. Turnbull, Christopher P. Landee, Joaquim Jornet, Mercè Deumal, Juan J. Novoa, and Jan L. Wikaira
pp 11254 - 11265; DOI:
10.1021/ic701645y
PDF
Structural, Thermal, and Magnetic Study of Solvation Processes in Spin-Crossover [Fe(bpp)2][Cr(L)(ox)2]2·nH2O Complexes
Miguel Clemente-León, Eugenio Coronado, M. Carmen Giménez-López, and Francisco M. Romero
pp 11266 - 11276; DOI:
10.1021/ic700910n
PDF
Substituent Effects in Formally Quintuple-Bonded ArCrCrAr Compounds (Ar = Terphenyl) and Related Species
Robert Wolf, Chengbao Ni, Tailuan Nguyen, Marcin Brynda, Gary J. Long, Andrew D. Sutton, Roland C. Fischer, J. C. Fettinger, Matthew Hellman, Lihung Pu, and Philip P. Power
pp 11277 - 11290; DOI:
10.1021/ic702112e
PDF
Synthesis of Pendant-Type Anthraquinone-Bridged Cofacial Dinuclear Platinum(II) Complexes and Their Emission Properties
Mitsuya Utsuno, Tomona Yutaka, Masaki Murata, Masato Kurihara, Naoto Tamai, and Hiroshi Nishihara
pp 11291 - 11296; DOI:
10.1021/ic700953k
PDF
The Presumption of Innocence? A DFT-Directed Verdict on Oxidized Amavadin and Vanadium Catecholate Complexes
K. R. Geethalakshmi, Mark P. Waller, and Michael Bühl
pp 11297 - 11307; DOI:
10.1021/ic701650y
PDF
Structural, Spectroscopic, and Electrochemical Properties of a Series of High-Spin Thiolatonickel(II) Complexes
Jaeheung Cho, Glenn P. A. Yap, and Charles G. Riordan
pp 11308 - 11315; DOI:
10.1021/ic701743z
PDF
Highly Air-Stable Anionic Mononuclear and Neutral Binuclear Palladium(II) Complexes for C-C and C-N Bond-Forming Reactions
Benudhar Punji, Joel T. Mague, and Maravanji S. Balakrishna
pp 11316 - 11327; DOI:
10.1021/ic701674x
PDF
Synthesis and Platinum Coordination Chemistry of the Perfluoroalkyl Acceptor Pincer Ligand, 1,3-(CH2P(CF3)2)2C6H4
Jeramie J. Adams, Ade Lau, Navamoney Arulsamy, and Dean M. Roddick
pp 11328 - 11334; DOI:
10.1021/ic701426u
PDF
Speciation of Uranyl Complexes in Ionic Liquids by Optical Spectroscopy
Peter Nockemann, Kelly Servaes, Rik Van Deun, Kristof Van Hecke, Luc Van Meervelt, Koen Binnemans, and Christiane Görller-Walrand
pp 11335 - 11344; DOI:
10.1021/ic701752j
PDF
Structural Comparisons of Silver(I) Complexes of Third-Generation Ligands Built from Tridentate (o-C6H4[CH2OCH2C(pz)3]2) versus Bidentate Poly(1-pyrazolyl)methane Units (o-C6H4[CH2OCH2CH(pz)2]2) (pz = Pyrazolyl Ring)
Daniel L. Reger, Elizabeth A. Foley, Radu F. Semeniuc, and Mark D. Smith
pp 11345 - 11355; DOI:
10.1021/ic7017743
PDF
Tetrakis- and Tris(1-Methyluracil) Complexes of PtII: Formation and Properties of a Carbon-Bonded Nucleobase Species as Well as of Heternonuclear Derivatives
Lars Holland, Wei-Zheng Shen, Wolfgang Micklitz, and Bernhard Lippert
pp 11356 - 11365; DOI:
10.1021/ic701768a
PDF
Threshold CID Investigation of Isomeric Cu(I) Azabox Complexes
Eva Zocher, Raphael Sigrist, and Peter Chen
pp 11366 - 11370; DOI:
10.1021/ic701688t
PDF
Conversion of Methanol to 2,2,3-Trimethylbutane (Triptane) over Indium(III) Iodide
John E. Bercaw, Paula L. Diaconescu, Robert H. Grubbs, Nilay Hazari, Richard D. Kay, Jay A. Labinger, Parisa Mehrkhodavandi, George E. Morris, Glenn J. Sunley, and Patrick Vagner
pp 11371 - 11380; DOI:
10.1021/ic7014447
PDF
Reactions of a Tungsten Trisulfido Complex of Hydridotris(3,5-dimethylpyrazol-1-yl)borate (Tp*) [Et4N][Tp*WS3] with CuX (X = Cl, NCS, or CN): Isolation, Structures, and Third-Order NLO Properties
Jing Wang, Zhen-Rong Sun, Li Deng, Zheng-Hong Wei, Wen-Hua Zhang, Yong Zhang, and Jian-Ping Lang
pp 11381 - 11389; DOI:
10.1021/ic701641h
PDF
Valence Bond Approach of Metal-Ligand Bonding in the Dewar-Chatt-Duncanson Model
Mathieu Linares, Benoit Braida, and Stéphane Humbel
pp 11390 - 11396; DOI:
10.1021/ic701434e
PDF
Synthesis, Characterization, and OFET Properties of Amphiphilic Heteroleptic Tris(phthalocyaninato) Europium(III) Complexes with Hydrophilic Poly(oxyethylene) Substituents
Renjie Li, Pan Ma, Shuai Dong, Xianyao Zhang, Yanli Chen, Xiyou Li, and Jianzhuang Jiang
pp 11397 - 11404; DOI:
10.1021/ic7016825
PDF
Thermally Induced Spin Transitions in Nitroxide-Copper(II)-Nitroxide Spin Triads Studied by EPR
Matvey Fedin, Sergey Veber, Igor Gromov, Ksenia Maryunina, Sergey Fokin, Galina Romanenko, Renad Sagdeev, Victor Ovcharenko, and Elena Bagryanskaya
pp 11405 - 11415; DOI:
10.1021/ic7014385
PDF
FeIII Complexes of 1,4,8,11-Tetraaza[14]annulenes as Catalase Mimics
Reiner Sustmann, Hans-Gert Korth, Diana Kobus, Jörg Baute, Karl-Heinz Seiffert, Elisabeth Verheggen, Eckhard Bill, Michael Kirsch, and Herbert de Groot
pp 11416 - 11430; DOI:
10.1021/ic700961b
PDF
Syntheses and Structural Characterization of a Series of One-Dimensional Fluorotitanophosphates (NH4)xK4 - x[Ti2PO4F9] (x = 0, 0.70, 1.00, 1.25)
Sihai Yang, Guobao Li, Lei Li, Shujian Tian, Fuhui Liao, Ming Xiong, and, and Jianhua Lin
pp 11431 - 11436; DOI:
10.1021/ic701715k
PDF
Testing if the Interstitial Atom, X, of the Nitrogenase Molybdenum-Iron Cofactor Is N or C: ENDOR, ESEEM, and DFT Studies of the S = 3/2 Resting State in Multiple Environments
Dmitriy Lukoyanov, Vladimir Pelmenschikov, Nathan Maeser, Mikhail Laryukhin, Tran Chin Yang, Louis Noodleman, Dennis R. Dean, David A. Case, Lance C. Seefeldt, and Brian M. Hoffman
pp 11437 - 11449; DOI:
10.1021/ic7018814
PDF
N,N'-Diisopropyl-N' '-bis(trimethylsilyl)guanidinate Ligand as a Supporting Coordination Environment in Yttrium Chemistry. Synthesis, Structure, and Properties of Complexes [(Me3Si)2NC(Ni-Pr)2]YCl2(THF)2, [(Me3Si)2NC(Ni-Pr)2]Y(CH2SiMe3)2(THF)2, and [(Me3Si)2NC(Ni-Pr)2]Y[(-H)(-Et)2BEt]2(THF)
Dmitrii M. Lyubov, Georgy K. Fukin, and Alexander A. Trifonov
pp 11450 - 11456; DOI:
10.1021/ic701215t
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Unprecedented Gold-Tellurolate Clusters [Au8(-TeR)8(PR'3)4]
Oana Bumbu, Carmen Ceamanos, Olga Crespo, M. Concepción Gimeno, Antonio Laguna, Cristian Silvestru, and M. Dolores Villacampa
pp 11457 - 11460; DOI:
10.1021/ic7013545
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Kinetics of Dissociation of Molecular Oxygen from a Superoxorhodium(III) Complex and Reactivity of a Macrocyclic Rhodium(II) Ion
Magdalena Furczon, Oleg Pestovsky, and Andreja Bakac
pp 11461 - 11466; DOI:
10.1021/ic701686g
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New Tertiary Phosphines from Cinnamaldehydes and Diphenylphosphine
Dmitry V. Moiseev, Brian O. Patrick, and Brian R. James
pp 11467 - 11474; DOI:
10.1021/ic701597g
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