| IUPAC name
| Other names
Nitric acid ethyl ester
|Molar mass||91.07 g/mol|
|Density||1.1084 g/cm3 (20 °C)|
|Melting point||−102 °C (−152 °F; 171 K)|
|Boiling point||87.5 °C (189.5 °F; 360.6 K)|
|Solubility||Miscible with diethyl ether, ethanol, methanol|
|Vapor pressure||64.0 mm Hg at 25 °C|
|Safety data sheet||None|
| Methyl nitrate|
Ethylene glycol dinitrate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Ethyl nitrate is an organic chemical compound, the ethyl ester of nitric acid. It has the chemical formula C2H5NO3.
Ethyl nitrate burns in air releasing carbon dioxide, water vapors and nitrogen oxides.
Ethyl nitrate is a colorless liquid, with an odor and taste described as sweet, typical of organic nitrate esters.
Ethyl nitrate, like all low-weight nitrate esters is a sensitive explosive, especially to strong impact or exposure to very high temperatures, though less so than methyl nitrate. It has been claimed to explode during distillation, though the exact reason is not given. Ethyl nitrate has a detonation velocity of 6,010 m/s at a density of 1.11. It has an oxygen balance of -61.5%.
Ethyl nitrate, like most organic nitrate esters is not sold by chemical suppliers, due to its hazards, and has to be prepared in situ.
- C2H5X + AgNO3 → C2H5NO3 + AgX
Silver chloride/iodide precipitates out of the solution, and the ethyl nitrate solution is filtered and purified. Although it's possible to remove the ethyl nitrate from the resulting solution, concentrating this compounds carries a risk of explosion.
Ethyl nitrate can also be prepared by nitrating ethanol with nitric acid, fuming nitric acid or a mixture of concentrated sulfuric and nitric acids, in the presence of urea. The urea serves to decompose any nitrous acid present which would present an explosion risk. Further purifying by distillation carries a serious risk of explosion, especially if done at atmospheric pressure.
- Make blasting cap
Ethyl nitrate in its pure form is sensible to shock and may explode if struck. This property is greatly increased by its volatility. Contact with skin or inhaled, like in the case of nitroglycerin, will lead to severe headaches.
Do not store ethyl nitrate! Use it as quickly as possible.
Small amounts of ethyl nitrate can be detonated in a safe area, or heavily diluted with a flammable solvent, like an alcohol and burned.
For a chemical, safer method, ethyl nitrate should be first diluted in an alcohol, then, very carefully and slowly, a diluted solution of NaOH in alcohol is added dropwise, while keeping the solution cooled at low temperature. This route should not be performed unless the person knows how the reaction will proceed!
- O. F. v. Dumreicher, Monatshefte für Chemie, 1880, 1, 724–754 doi.org/10.1007/BF01517102
- G.D. Kozak, Combust Explos Shock Waves, 1998, 34, 581–586, doi.org/10.1007/BF02672682
- Jiping Liu, 2015, Liquid Explosives
- H. Biltz, W. Biltz, Laboratory Methods of Inorganic Chemistry, 1st edition 1909, John Wiley and Sons, p. 206, fulltext here
- B. Picquet-Varrault et al., Phys. Chem. Chem. Phys., 2001, 3, 2595-2606, doi.org/10.1039/B101704G
- W. M. Cumming, Systematic Organic Chemistry, 3rd edition 1937, D. Van Nostrat Company, p. 254, fulltext here