|Name, symbol||Vanadium, V|
|Vanadium in the periodic table|
|Standard atomic weight (Ar)||50.9415(1)|
|Group, block||, d-block|
|Electron configuration||[Ar] 3d3 4s2|
|2, 8, 11, 2|
|Melting point||2183 K (1910 °C, 3470 °F)|
|Boiling point||3680 K (3407 °C, 6165 °F)|
|Density near r.t.||6.0 g/cm3|
|when liquid, at||5.5 g/cm3|
|Heat of fusion||21.5 kJ/mol|
|Heat of||444 kJ/mol|
|Molar heat capacity||24.89 J/(mol·K)|
|Oxidation states||+5, +4, +3, +2, +1, −1, −3 (an amphoteric oxide)|
|Electronegativity||Pauling scale: 1.63|
1st: 650.9 kJ/mol |
2nd: 1414 kJ/mol
3rd: 2830 kJ/mol
|Atomic radius||empirical: 134 pm|
|Covalent radius||153±8 pm|
|Crystal structure||body-centered cubic (bcc)|
|Speed of sound thin rod||4560 m/s (at 20 °C)|
|Thermal expansion||8.4 µm/(m·K) (at 25 °C)|
|Thermal conductivity||30.7 W/(m·K)|
|Electrical resistivity||197 Ω·m (at 20 °C)|
|Young's modulus||128 GPa|
|Shear modulus||47 GPa|
|Bulk modulus||160 GPa|
|Vickers hardness||628–640 MPa|
|Brinell hardness||600–742 MPa|
|CAS Registry Number||7440-62-2|
|Discovery||Andrés Manuel del Río (1801)|
|First isolation||Nils Gabriel Sefström (1830)|
|Named by||Nils Gabriel Sefström (1830)|
Vanadium is a chemical element with symbol V and atomic number 23. It is mainly used in industry for high strength steels.
It has good resistance to corrosion and it is stable against alkali and sulfuric and hydrochloric acids. It is oxidized in air at about 933 K (660 °C, 1220 °F), although an oxide layer forms even at room temperature.
Vanadium is a medium-hard, ductile, malleable, strong silvery-gray or steel-blue metal. Vanadium is harder than most pure metals and common steels. Vanadium has a high melting point of 1910 °C and boils at 3407 °C. Vanadium is lighter than steel, with a density of 6 g/cm3.
Vanadium is sold by various chemical suppliers.
It can also be extracted from chromium-vanadium steels, generally encountered in tools and other devices. However, you will need a lot of tools, since the percentage of vanadium is usually below 1%, except for special steels. Ferrovanadium is also a source.
In industries is Vanadium metal is obtained via a multistep process that begins with the roasting of crushed ore with NaCl or Na2CO3 at about 850 °C to give Sodium metavanadate (NaVO3). An aqueous extract of this solid is acidified to give "red cake", a polyvanadate salt, which is reduced with calcium metal. Vanadium can be also obtained by reducing vanadium pentoxide with aluminium, magnesium, or hydrogen. Note that aluminum is soluble in vanadium, so to isolate pure metal one must not use an excess of aluminum. Magnesium does not share this level of solubility in vanadium metal, but the reaction between V2O5 and Mg is sufficiently energetic to boil the V metal produced.
Pure vanadium metal can be obtained through the thermal decomposition of vanadium(III) iodide:
- 2 V + 3 I2 ⇌ 2 VI3
- Make vanadium pentoxide
- Make various high strength steels
Vanadium compounds show toxicity and should be handled with care.
Vanadium should be stored in closed containers.
Vanadium powder should be stored away from air.
Vanadium should be taken to disposal facilities.
Elementcollector1: Isolation notes based on experience, feel free to argue.