Difference between revisions of "Potassium iodide"
(→Chemical) |
|||
Line 5: | Line 5: | ||
When treated with a strong acid such as [[hydrochloric acid]], [[hydroiodic acid]] is formed, along with the potassium salt of the acid. A useful reagent in itself, hydroiodic acid can also be oxidized directly to elemental iodine with the addition of [[hydrogen peroxide]]. Potassium iodide, being water-soluble, is a useful source of the iodide ion in solution as well. | When treated with a strong acid such as [[hydrochloric acid]], [[hydroiodic acid]] is formed, along with the potassium salt of the acid. A useful reagent in itself, hydroiodic acid can also be oxidized directly to elemental iodine with the addition of [[hydrogen peroxide]]. Potassium iodide, being water-soluble, is a useful source of the iodide ion in solution as well. | ||
+ | |||
+ | Potassium iodide is a very strong reducing agent. It reacts readily with any oxidizer, including oxidizing acids such as sulfuric and nitric. It may be desirable if you want to use it to reduce these acids, but undesirable if you want hydrogen iodide. To avoid unwanted redox reactions, use [[phosphoric acid]], which is both non-volatile and exceptionally gentle to reducing agents. | ||
Like most iodides, it will form dark brown triiodides on contact with elemental iodine. | Like most iodides, it will form dark brown triiodides on contact with elemental iodine. | ||
+ | |||
===Physical=== | ===Physical=== | ||
Revision as of 10:43, 3 October 2015
Potassium iodide is the inorganic ionic compound with the chemical formula KI. It is a clear crystalline salt that serves as a convenient source of iodine.
Contents
Properties
Chemical
When treated with a strong acid such as hydrochloric acid, hydroiodic acid is formed, along with the potassium salt of the acid. A useful reagent in itself, hydroiodic acid can also be oxidized directly to elemental iodine with the addition of hydrogen peroxide. Potassium iodide, being water-soluble, is a useful source of the iodide ion in solution as well.
Potassium iodide is a very strong reducing agent. It reacts readily with any oxidizer, including oxidizing acids such as sulfuric and nitric. It may be desirable if you want to use it to reduce these acids, but undesirable if you want hydrogen iodide. To avoid unwanted redox reactions, use phosphoric acid, which is both non-volatile and exceptionally gentle to reducing agents.
Like most iodides, it will form dark brown triiodides on contact with elemental iodine.
Physical
At room temperature, potassium iodide follows the general pattern of alkali metal halides in that it appears as a colorless, odorless crystalline salt that is highly soluble in water.
Availability
Potassium iodide can be found as an iodine supplement or as an emergency medicine for radiation poisoning, which means it may be stocked by some survivalist/prepper outlets. It is easily purchased online.
Preparation
Potassium iodide can easily be synthesized by the action of elemental iodine or hydroiodic acid on potassium hydroxide.
Projects
- Make hydroiodic acid or iodine
Safety
Potassium iodide is a mild irritant, and due to the high mass percentage of iodine it contains, large amounts of exposure can effect the thyroid gland. It may also factor in causing birth defects.