Difference between revisions of "Flame test"

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(Flame colors: Sorted colors in alphabetical order, to make them easier to find)
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==Flame colors==
 
==Flame colors==
===Violet===
 
Potassium (masked easily)
 
 
===Azure===
 
===Azure===
Copper halides
+
*Copper halides (copper(II) chloride)
===Light blue===
+
*Bismuth
Arsenic, selenium, cesium, lead
+
===Emerald===
+
Copper non-halides
+
  
Ytterbium metal powder
 
===Pure green===
 
Boron, tellurium, thallium
 
===Yellowish-green===
 
Barium
 
 
===Bluish-green===
 
===Bluish-green===
Phosphates with sulfuric acid
+
*Phosphates with sulfuric acid
===Whitish-green===
+
*Phosphorus
Zinc metal
+
*Zinc metal
 +
 
 +
===Brick red===
 +
*Cadmium
 +
 
 +
===Carmine===
 +
*Lithium (violet through blue glass, invisible through green glass, masked by barium)
 +
 
 +
===Crimson red===
 +
*Radium
 +
 
 +
===Emerald===
 +
*Copper non-halides
 +
*Ytterbium metal powder
 +
 
 
===Feeble green===
 
===Feeble green===
Antimony, ammonium
+
*Ammonium
===Yellow===
+
*Antimony
Sodium (masks everything, invisible through blue glass)
+
 
 +
===Gray===
 +
*[https://www.youtube.com/watch?v=eMNsnZ5jSmc Nitromethane]
 +
 
 +
===Light blue===
 +
*Arsenic
 +
*Cesium
 +
*Lead
 +
*Selenium
 +
 
 
===Orange===
 
===Orange===
Calcium (greenish through blue glass, green through green glass, masked by barium)
+
*Calcium (greenish through blue glass, green through green glass, masked by barium)
===Scarlet===
+
*Scandium
Strontium (violet through blue glass, yellowish through green glass, masked by barium)
+
 
===Carmine===
+
===Pale blue===
Lithium (violet through blue glass, invisible through green glass, masked by barium)
+
*Germanium
 +
 
 +
===Pale green===
 +
*Antimony
 +
 
 
===Pink===
 
===Pink===
Samarium metal
+
*Samarium metal
 +
 
 +
===Pure green===
 +
*Boron
 +
*Tellurium
 +
*Thallium
 +
 
 +
===Purple===
 +
*Potassium chloride
 +
 
 +
===Red===
 +
*Mercury
 +
 
 +
===Red-violet===
 +
*Rubidium
 +
 
 +
===Scarlet===
 +
*Strontium (violet through blue glass, yellowish through green glass, masked by barium)
 +
 
 +
===Silvery-white===
 +
*Aluminium
 +
*Chromium
 +
*Cobalt
 +
*Nickel
 +
 
 +
===Violet===
 +
*Potassium (masked easily)
 +
 
 +
===White===
 +
*Beryllium
 +
*Magnesium
 +
 
 +
===Yellow===
 +
*Sodium (masks everything, invisible through blue glass)
 +
 
 +
===Yellowish-green===
 +
*Barium
 +
*Manganese
 +
*Molybdenum
 +
*Vanadium
  
 
== Spectroscopy ==
 
== Spectroscopy ==

Revision as of 16:22, 15 April 2016

A flame test is an analytical procedure that can determine the presence of certain elements.

Procedure

A flame test is carried out by placing a sample on a clean wire (commonly made out of platinum or nichrome), and placing it in a hot non-luminous flame (one that does not exhibit black-body radiation).


Flame colors

Azure

  • Copper halides (copper(II) chloride)
  • Bismuth

Bluish-green

  • Phosphates with sulfuric acid
  • Phosphorus
  • Zinc metal

Brick red

  • Cadmium

Carmine

  • Lithium (violet through blue glass, invisible through green glass, masked by barium)

Crimson red

  • Radium

Emerald

  • Copper non-halides
  • Ytterbium metal powder

Feeble green

  • Ammonium
  • Antimony

Gray

Light blue

  • Arsenic
  • Cesium
  • Lead
  • Selenium

Orange

  • Calcium (greenish through blue glass, green through green glass, masked by barium)
  • Scandium

Pale blue

  • Germanium

Pale green

  • Antimony

Pink

  • Samarium metal

Pure green

  • Boron
  • Tellurium
  • Thallium

Purple

  • Potassium chloride

Red

  • Mercury

Red-violet

  • Rubidium

Scarlet

  • Strontium (violet through blue glass, yellowish through green glass, masked by barium)

Silvery-white

  • Aluminium
  • Chromium
  • Cobalt
  • Nickel

Violet

  • Potassium (masked easily)

White

  • Beryllium
  • Magnesium

Yellow

  • Sodium (masks everything, invisible through blue glass)

Yellowish-green

  • Barium
  • Manganese
  • Molybdenum
  • Vanadium

Spectroscopy

A mad scientist with a more technical bent can improve this technique by building a simple spectroscope, which decomposes the light from the flame into a spectrum. The advantages of spectroscopy is that it does not require any colored glass, all spectral lines are visible separately without them.