https://www.sciencemadness.org/smwiki/index.php?title=Nickel_hydrazine_nitrate&feed=atom&action=history
Nickel hydrazine nitrate - Revision history
2024-03-29T09:46:11Z
Revision history for this page on the wiki
MediaWiki 1.25.1
https://www.sciencemadness.org/smwiki/index.php?title=Nickel_hydrazine_nitrate&diff=13606&oldid=prev
Mabus at 20:32, 1 November 2020
2020-11-01T20:32:09Z
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<td colspan='2' style="background-color: white; color:black; text-align: center;">Revision as of 20:32, 1 November 2020</td>
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<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>| OtherFunction_label =  </div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>| OtherFunction_label =  </div></td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>| OtherCompounds = [[Hydrazine nitrate]]<br>[[Nickel(II) nitrate]]</div></td><td class='diff-marker'>+</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>| OtherCompounds = [[Hydrazine nitrate]]<br>[[Nickel(II) nitrate<ins class="diffchange diffchange-inline">]]<br>[[Nickel hydrazine perchlorate</ins>]]</div></td></tr>
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Mabus
https://www.sciencemadness.org/smwiki/index.php?title=Nickel_hydrazine_nitrate&diff=13063&oldid=prev
Mabus at 16:47, 30 June 2020
2020-06-30T16:47:18Z
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<td colspan='2' style="background-color: white; color:black; text-align: center;">Revision as of 16:47, 30 June 2020</td>
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<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>| ImageSize1 =  </div></td><td class='diff-marker'>+</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>| ImageSize1 = <ins class="diffchange diffchange-inline">300</ins></div></td></tr>
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<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>| ImageName1 =  </div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>| ImageName1 =  </div></td></tr>
<tr><td colspan="2"> </td><td class='diff-marker'>+</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div><ins style="font-weight: bold; text-decoration: none;">| ImageCaption1 = Structure of the NHN coordination compound</ins></div></td></tr>
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Mabus
https://www.sciencemadness.org/smwiki/index.php?title=Nickel_hydrazine_nitrate&diff=13047&oldid=prev
Mabus at 19:05, 16 June 2020
2020-06-16T19:05:05Z
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<td colspan='2' style="background-color: white; color:black; text-align: center;">← Older revision</td>
<td colspan='2' style="background-color: white; color:black; text-align: center;">Revision as of 19:05, 16 June 2020</td>
</tr><tr><td colspan="2" class="diff-lineno" id="L105" >Line 105:</td>
<td colspan="2" class="diff-lineno">Line 105:</td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>| OtherFunction =  </div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>| OtherFunction =  </div></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>| OtherFunction_label =  </div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>| OtherFunction_label =  </div></td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>| OtherCompounds = [[Hydrazine nitrate]]</div></td><td class='diff-marker'>+</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>| OtherCompounds = [[Hydrazine <ins class="diffchange diffchange-inline">nitrate]]<br>[[Nickel(II) </ins>nitrate]]</div></td></tr>
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<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>==Preparation==</div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>==Preparation==</div></td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>Nickel nitrate is added to an aqueous solution of hydrazine (hydrazine hydrate), which is kept heated to 65 °C, in order to allow hot filtration. The solution should be 'hot filtered' at 65 °C. Letting it cool down first and then filtering will give an inconsistent product. Approximately 0.1-1% of the total system by weight of [[dextrin]] may be added to increase the bulk density from 0.9 mg/cm<sup>3</sup> to 1.2 mg/cm<sup>3</sup>. Successfully produced NHN will have a talcum powder-like consistency when dried without the need to crush the NHN. Unsuccessfully produced NHN will have the aspect of hard chunks that need to be crushed and then maintain a consistency of grains of sand. The latter is the result of mixing at a lower temperature and using alcohol instead of water as the mixing solution.<ref>https://www.sciencedirect.com/science/article/pii/S0304389402002479?via%3Dihub</ref><ref>https://onlinelibrary.wiley.com/doi/abs/10.1002/prep.19970220604</ref><ref>http://nopr.niscair.res.in/handle/123456789/5478</ref></div></td><td class='diff-marker'>+</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div><ins class="diffchange diffchange-inline">[[</ins>Nickel<ins class="diffchange diffchange-inline">(II) </ins>nitrate<ins class="diffchange diffchange-inline">]] </ins>is added to an aqueous solution of hydrazine (hydrazine hydrate), which is kept heated to 65 °C, in order to allow hot filtration. The solution should be 'hot filtered' at 65 °C. Letting it cool down first and then filtering will give an inconsistent product. Approximately 0.1-1% of the total system by weight of [[dextrin]] may be added to increase the bulk density from 0.9 mg/cm<sup>3</sup> to 1.2 mg/cm<sup>3</sup>. Successfully produced NHN will have a talcum powder-like consistency when dried without the need to crush the NHN. Unsuccessfully produced NHN will have the aspect of hard chunks that need to be crushed and then maintain a consistency of grains of sand. The latter is the result of mixing at a lower temperature and using alcohol instead of water as the mixing solution.<ref>https://www.sciencedirect.com/science/article/pii/S0304389402002479?via%3Dihub</ref><ref>https://onlinelibrary.wiley.com/doi/abs/10.1002/prep.19970220604</ref><ref>http://nopr.niscair.res.in/handle/123456789/5478</ref></div></td></tr>
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<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>==Projects==</div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>==Projects==</div></td></tr>
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Mabus
https://www.sciencemadness.org/smwiki/index.php?title=Nickel_hydrazine_nitrate&diff=11209&oldid=prev
Mabus at 20:54, 16 May 2019
2019-05-16T20:54:00Z
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</tr><tr><td colspan="2" class="diff-lineno" id="L112" >Line 112:</td>
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<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>==Properties==</div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>==Properties==</div></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>===Chemical===</div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>===Chemical===</div></td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>Nickel hydrazine nitrate decomposes violently, releasing nickel powder and combustion gases.</div></td><td class='diff-marker'>+</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>Nickel hydrazine nitrate decomposes violently, releasing <ins class="diffchange diffchange-inline">[[</ins>nickel<ins class="diffchange diffchange-inline">]] </ins>powder and combustion gases.</div></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>===Physical===</div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>===Physical===</div></td></tr>
<tr><td colspan="2" class="diff-lineno" id="L131" >Line 131:</td>
<td colspan="2" class="diff-lineno">Line 131:</td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>==Handling==</div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>==Handling==</div></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>===Safety===</div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>===Safety===</div></td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>Nickel nitrate contains nickel and hydrazine, which are harmful.</div></td><td class='diff-marker'>+</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>Nickel nitrate contains nickel and hydrazine, <ins class="diffchange diffchange-inline">both </ins>which are harmful.</div></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>===Storage===</div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>===Storage===</div></td></tr>
</table>
Mabus
https://www.sciencemadness.org/smwiki/index.php?title=Nickel_hydrazine_nitrate&diff=9498&oldid=prev
Mabus at 22:58, 28 August 2018
2018-08-28T22:58:54Z
<p></p>
<table class='diff diff-contentalign-left'>
<col class='diff-marker' />
<col class='diff-content' />
<col class='diff-marker' />
<col class='diff-content' />
<tr style='vertical-align: top;'>
<td colspan='2' style="background-color: white; color:black; text-align: center;">← Older revision</td>
<td colspan='2' style="background-color: white; color:black; text-align: center;">Revision as of 22:58, 28 August 2018</td>
</tr><tr><td colspan="2" class="diff-lineno" id="L150" >Line 150:</td>
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<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>[[Category:Coordination complexes]]</div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>[[Category:Coordination complexes]]</div></td></tr>
<tr><td colspan="2"> </td><td class='diff-marker'>+</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div><ins style="font-weight: bold; text-decoration: none;">[[Category:Nickel complexes]]</ins></div></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>[[Category:Nitrates]]</div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>[[Category:Nitrates]]</div></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>[[Category:Energetic materials]]</div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>[[Category:Energetic materials]]</div></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>[[Category:Primary explosives]]</div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>[[Category:Primary explosives]]</div></td></tr>
</table>
Mabus
https://www.sciencemadness.org/smwiki/index.php?title=Nickel_hydrazine_nitrate&diff=9284&oldid=prev
Mabus at 22:26, 1 August 2018
2018-08-01T22:26:53Z
<p></p>
<table class='diff diff-contentalign-left'>
<col class='diff-marker' />
<col class='diff-content' />
<col class='diff-marker' />
<col class='diff-content' />
<tr style='vertical-align: top;'>
<td colspan='2' style="background-color: white; color:black; text-align: center;">← Older revision</td>
<td colspan='2' style="background-color: white; color:black; text-align: center;">Revision as of 22:26, 1 August 2018</td>
</tr><tr><td colspan="2" class="diff-lineno" id="L147" >Line 147:</td>
<td colspan="2" class="diff-lineno">Line 147:</td></tr>
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<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>[[Category:Chemical compounds]]</div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>[[Category:Chemical compounds]]</div></td></tr>
<tr><td colspan="2"> </td><td class='diff-marker'>+</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div><ins style="font-weight: bold; text-decoration: none;">[[Category:Inorganic compounds]]</ins></div></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>[[Category:Nickel compounds]]</div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>[[Category:Nickel compounds]]</div></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>[[Category:Coordination complexes]]</div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>[[Category:Coordination complexes]]</div></td></tr>
</table>
Mabus
https://www.sciencemadness.org/smwiki/index.php?title=Nickel_hydrazine_nitrate&diff=9283&oldid=prev
Mabus: Created page with "{{Chembox | Name = Nickel hydrazine nitrate | Reference = | IUPACName = Nickel hydrazine nitrate | PIN = | SystematicName = | OtherNames = Nickel hydrazinium nitrate <!-- Imag..."
2018-08-01T22:22:54Z
<p>Created page with "{{Chembox | Name = Nickel hydrazine nitrate | Reference = | IUPACName = Nickel hydrazine nitrate | PIN = | SystematicName = | OtherNames = Nickel hydrazinium nitrate <!-- Imag..."</p>
<p><b>New page</b></p><div>{{Chembox<br />
| Name = Nickel hydrazine nitrate<br />
| Reference =<br />
| IUPACName = Nickel hydrazine nitrate<br />
| PIN =<br />
| SystematicName =<br />
| OtherNames = Nickel hydrazinium nitrate<br />
<!-- Images --><br />
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| ImageSize = <br />
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<!-- Sections --><br />
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| 3DMet = <br />
| Abbreviations = <br />
| SMILES = <br />
}}<br />
| Section2 = {{Chembox Properties<br />
| AtmosphericOHRateConstant = <br />
| Appearance = Purple solid<br />
| BoilingPt = <br />
| BoilingPtC = <br />
| BoilingPt_ref = <br />
| BoilingPt_notes = <br />
| Density = 2.129 g/cm<sup>3</sup><br />
| Formula = NiH<sub>12</sub>N<sub>8</sub>O<sub>6</sub><br>[Ni(N<sub>2</sub>H<sub>4</sub>)<sub>3</sub>](NO<sub>3</sub>)<sub>2</sub><br />
| HenryConstant = <br />
| LogP = <br />
| MolarMass = 278.69 g/mol<br />
| MeltingPt = <br />
| MeltingPtC = <br />
| MeltingPt_ref = <br />
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| Odor = Odorless<br />
| pKa = <br />
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| Solubility = Insoluble<br />
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| Section4 = {{Chembox Thermochemistry<br />
| DeltaGf = <br />
| DeltaHc = 5,225 kJ/kg<br />
| DeltaHf = -449 kJ/mol<br />
| Entropy = <br />
| HeatCapacity = <br />
}}<br />
| Section5 = {{Chembox Explosive<br />
| ShockSens = <br />
| FrictionSens = 1.6<br />
| DetonationV = 7,000 m/s<br />
| REFactor = 1.05<br />
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| Section6 = {{Chembox Hazards<br />
| AutoignitionPt = <br />
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'''Nickel hydrazine nitrate''' ('''NHN'''), is an energetic coordination compound having explosive properties in between that of primary and secondary, with the chemical formula '''[Ni(N<sub>2</sub>H<sub>4</sub>)<sub>3</sub>](NO<sub>3</sub>)<sub>2</sub>'''.<br />
<br />
==Properties==<br />
===Chemical===<br />
Nickel hydrazine nitrate decomposes violently, releasing nickel powder and combustion gases.<br />
<br />
===Physical===<br />
Nickel hydrazine nitrate is a purple solid, practically soluble in water.<br />
<br />
===Explosive===<br />
NHN straddles the line between primary and secondary. Because of this it is a relatively safe explosive to work with having much less sensitivity to shock and friction (16.0 N) than Lead Azide (0.1N). Its detonation velocity is estimated around 7,000 m/s.<ref>http://www.chemikinternational.com/pdf/2011/01_2011/chemik_2011_65_1_24-27.pdf</ref><br />
<br />
==Availability==<br />
Nickel hydrazine nitrate is not sold by chemical suppliers and has to be made.<br />
<br />
==Preparation==<br />
Nickel nitrate is added to an aqueous solution of hydrazine (hydrazine hydrate), which is kept heated to 65 °C, in order to allow hot filtration. The solution should be 'hot filtered' at 65 °C. Letting it cool down first and then filtering will give an inconsistent product. Approximately 0.1-1% of the total system by weight of [[dextrin]] may be added to increase the bulk density from 0.9 mg/cm<sup>3</sup> to 1.2 mg/cm<sup>3</sup>. Successfully produced NHN will have a talcum powder-like consistency when dried without the need to crush the NHN. Unsuccessfully produced NHN will have the aspect of hard chunks that need to be crushed and then maintain a consistency of grains of sand. The latter is the result of mixing at a lower temperature and using alcohol instead of water as the mixing solution.<ref>https://www.sciencedirect.com/science/article/pii/S0304389402002479?via%3Dihub</ref><ref>https://onlinelibrary.wiley.com/doi/abs/10.1002/prep.19970220604</ref><ref>http://nopr.niscair.res.in/handle/123456789/5478</ref><br />
<br />
==Projects==<br />
*Blasting cap<br />
<br />
==Handling==<br />
===Safety===<br />
Nickel nitrate contains nickel and hydrazine, which are harmful.<br />
<br />
===Storage===<br />
NHN should be kept in small amounts in small containers. While it's stable for long periods of time, it's best to use it as soon as possible.<br />
<br />
===Disposal===<br />
Can be easily neutralized by safely detonating in a safe or remote area.<br />
<br />
==References==<br />
<references/><br />
===Relevant Sciencemadness threads===<br />
*[http://www.sciencemadness.org/talk/viewthread.php?tid=1778 Exotic Primaries - Complex Salts]<br />
*[http://www.sciencemadness.org/talk/viewthread.php?tid=64480 NHN Toxicity ]<br />
*[http://www.sciencemadness.org/talk/viewthread.php?tid=61127 NHN from hydrazine sulfate?]<br />
<br />
[[Category:Chemical compounds]]<br />
[[Category:Nickel compounds]]<br />
[[Category:Coordination complexes]]<br />
[[Category:Nitrates]]<br />
[[Category:Energetic materials]]<br />
[[Category:Primary explosives]]</div>
Mabus