Powder

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A powder (sometimes referred to as powdered material) is a dry bulk solid, composed of a large number of extremely fine particles, that may flow freely or become airborne when shaken or tilted. To be classified as powder, the material must be dry, as in free of any liquid. If the powder contains liquid, then it's classified as gel, paste or solid emulsion.

Powder vs other granular material

The main difference between powders and other granular materials is the size of their particles. The constituent particles that compose granular materials should be large enough such that they are not subject to thermal motion fluctuations. Thus, the lower size limit for grains in granular material is about 1 µm. In powders, the particles are generally small enough that they can become airborne if the powder is agitated or scattered in air, while granular materials cannot become airborne.

Types of powder

Metal

Metal in their powdered form are generally more reactive than in their bulk form. Extremely finely powdered iron is pyrophoric, while bulk iron is less reactive. Osmium and iridium are also a good example, in that they're very inert in their bulk form, but very reactive as powder. However, in case of some metals, such as gold or copper, there is little difference between the reactivity of their powdered and bulk forms.

Soft metals are difficult to turn into powders, as their granules will tend to coalesce over time.

Metallic powders are commonly used in fireworks and flash powders.

Nonmetal

Powdered nonmetallic materials, such as powdered elements (boron, carbon, phosphorus, sulfur, silicon), nonmetallic compounds (oxides, nitrides, carbides) are somewhat more reactive than in their bulk form, due their higher surface-to-volume ratio.

Organic

Airborne powdered organic materials can pose a serious fire or explosion hazard, such as finely powdered starch (grain flour) sugar suspended in air in confined areas, phenomenon known as dust explosion.

Other

Powdered metallic oxides are useful as catalysts or as building block in most construction materials (cement, clay, ceramic materials).

Insoluble organometallic compounds can only exist as powder, as most will decompose when heated, rather than melt. This is also true for most insoluble coordination complexes.

Availability

Metallic powders are sold by various suppliers.

Starch and sugar powder can be purchased from any food store.

Oxide powders can be purchased from many hardware stores.

Preparation

Metallic powders can be prepared by finely grinding metals of small size using ball mills. Spark-free grinding materials, like lead-antimony balls should be used to prevent the creation of sparks which can ignite the very fine powder. This is also mandatory when grinding other combustible materials, like organic compounds.

Fine metal powders can also be produced through chemical methods. Copper powder can be produced by reducing a copper salt with a more reactive metal, like iron, zinc or aluminium. Do note that due to various reasons, this method may not give just powder, but also metal sheets or flake-like copper particles.

Very fine iron powder can be obtained through the pyrolysis of iron(II) oxalate. The resulting iron powder is so fine it will spontaneously burn in air, and this type of iron powder is also known as "pyrophoric iron".

Zinc powder can be easily produced from the electrolysis of sodium zincate (made from sodium hydroxide and zinc/zinc oxide), using nickel and zinc/copper electrodes.

Projects

  • Flash powder
  • Powder metallurgy
  • Sintering
  • Make non-newtonian liquids

Handling

Safety

Flammable powders can pose a serious fire and explosion risk.

Storage

Powders should be kept in closed containers, away from draft and fire source.

Disposal

Disposal depends on the type of powder.

See also

References

Relevant Sciencemadness threads