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POCL3-Phosphorus Oxychloride Synthesis
Dry HCl may be less active against stainless at rt, but at 450C HCl will wreck just about any metal ...
4-12-2014 at 17:32
by: mnick12
POCL3-Phosphorus Oxychloride Synthesis
Table salt is probably fine, but if you want kosher salt does not have any additives.

Also I wou ...
4-12-2014 at 12:03
by: mnick12
Maltotriose or amylose?
Thanks Ozone,

My intetion for maltotriose is to develop a medium for the isolation of attenuative ...
26-11-2014 at 23:23
by: mnick12
Maltotriose or amylose?
Does anyone know where to buy Maltotriose or amylose? Sigma is waaaay to expensive.

Apparently th ...
9-11-2014 at 11:15
by: mnick12
THIOUREA - odorless or fart-scented?
DrMario,

I have had a similar experience with my bottle of thiourea, when I open the bottle it sm ...
2-10-2014 at 10:14
by: mnick12
Hydrogen Bromide for Halogenation
It could be related to other stuff besides meth, but looking at aYoungKing's post history you can se ...
2-10-2014 at 10:10
by: mnick12
Handling Formic Acid? Strength compared to other acids?
Well I don't think the pKa has a whole lot to do with how dangerous the acid is.

For example I ha ...
27-9-2014 at 16:41
by: mnick12
Oxidation of ethanol by hypochlorite
If you are going to synthesize ketones or aldehydes from alcohols from bleach you will need and acid ...
10-8-2014 at 10:58
by: mnick12
Fiberglass Cloth - Available in the US
Thanks! That is good to know.

Is it contaminated in any way with plastics or resins? Or is it pur ...
10-8-2014 at 10:55
by: mnick12
Cutting sodium
Well it doesn't sound like its and oxide/passivating layer problem. If it were it would be obvious f ...
8-8-2014 at 15:50
by: mnick12
Bad days in the lab or with glassware?
Today I pulled a kim wipe soaked with trimethylsilylmethyl lithium out of a glove box, as soon as I ...
24-7-2014 at 21:30
by: mnick12
Oxone Aromatic Halogenation in Water - Is this write-up a lie?
Well conversion is different than yield, as you seem to point out in your post. Again you cannot tal ...
20-7-2014 at 19:47
by: mnick12
Oxone Aromatic Halogenation in Water - Is this write-up a lie?
FireLion3, I understand your frustration with what appears to be a failed reaction. That being said ...
20-7-2014 at 16:26
by: mnick12
Esterfication Question
Probably, but you are going to need to reflux it for a while. I would suggest a dean-stark apparatus ...
17-7-2014 at 13:55
by: mnick12
Adding Polypyridyl complexes to Fe
Usually when we make complexes in the lab, we dissolve the ligand and metal salt in a solvent like T ...
9-7-2014 at 23:19
by: mnick12
Report on Decarboxylation of Tryptophan in various solvents
Okay this may be a silly question, but wouldn't the use of a pure ketone like acetophenone results i ...
8-7-2014 at 09:28
by: mnick12
Using Calcium Hydroxide as a base in place of Sodium Hydroxide?
Solubility might be an issue, a lot calcium compounds have terrible solubility. Also phenols are pre ...
8-7-2014 at 09:26
by: mnick12
t-butyl benzene by Friedel-Crafts: some questions...
My guess is the slow addition is to keep the concentration of t-butyl chloride low during the reacti ...
5-7-2014 at 10:34
by: mnick12
Transfer hydrogenations with glycerol
Thanks for the paper solo.

Anyway I still don't believe they reduced benzoic acid to benzyl alcoh ...
3-7-2014 at 16:07
by: mnick12
TMS-azide explosion at University of Minnesota
It looks like it was about 200g of the stuff that exploded, I think the bigger issue is someone work ...
3-7-2014 at 15:59
by: mnick12
Transfer hydrogenations with glycerol
It is a cool reaction if it actually works, they claim reduction of benzoic acid to benzyl alcohol, ...
30-6-2014 at 23:21
by: mnick12
Best way to clean tar (chemically)
Potassium hydroxide in ethanol is an excellent way to dissolve organic residue. Let it soak for one ...
21-6-2014 at 10:14
by: mnick12
Vanadium: The metal that may soon be powering your neighbourhood
Its interesting, but doesn't seem very practical. A giant vat full of sulfuric acid and vanadium sal ...
14-6-2014 at 09:56
by: mnick12
Photoredox Catalysts, & My recent preparation of Tris(bipyridine)nickel(II) hydrochloride
Coordination chemistry, yay!

Out of curiosity what does the complex look like? Also is refluxing ...
20-5-2014 at 15:39
by: mnick12
How to do KMno4 oxidation workup?
Depending on how pure you need your acid to be, I would distill the final product after acidificatio ...
18-5-2014 at 08:23
by: mnick12
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