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Lead Acetate distillation with PAA
I've seen numerous people state that iron salts work better, however, I have been unable to find any ...
22-5-2007 at 23:00
by: tupence_hapeny
Nitrostyrene to phenyl-nitro-propanol with formaldehyde
[quote]one hint: the alpha carbon of nitroalkanes bears an acidic proton, and only that one. no chan ...
22-5-2007 at 20:48
by: tupence_hapeny
Nitrostyrene to phenyl-nitro-propanol with formaldehyde
The rather pretty reaction scheme (in the first of the links, so kindly reproduced by your good self ...
22-5-2007 at 07:51
by: tupence_hapeny
Nitrostyrene to phenyl-nitro-propanol with formaldehyde
Well, having gone down this track I find out that 2-nitroethanol is condensed with benzaldehyde to [ ...
21-5-2007 at 21:30
by: tupence_hapeny
Nitrostyrene to phenyl-nitro-propanol with formaldehyde
[quote][b]stoichiometric_steve[/b]
The other salient fact is that this very procedure is being usel ...
21-5-2007 at 17:39
by: tupence_hapeny
Nitrostyrene to phenyl-nitro-propanol with formaldehyde
Nitroalkanes undergo an aldol condensation with aldehydes, this much is known...

So, I suggest th ...
21-5-2007 at 08:30
by: tupence_hapeny
Oxone Promoted NEF Reaction
Developments in the NEF (and associated) reactions

http://www.4shared.com/file/16343168/c66289d2/ ...
20-5-2007 at 18:31
by: tupence_hapeny
Preparation of Isonicotinic Acid and Ethyl Isonotinate
Cannot see the proposed scheme, is it possible for you to provide it in full? I have a rather long a ...
20-5-2007 at 08:39
by: tupence_hapeny
Potential uses of Citric Acid
Here is an article (a fucking recent article) on the use of my very favouritest 'ghetto' style, oh s ...
20-5-2007 at 08:03
by: tupence_hapeny
1,4-Dioxane - Anyone here use it?
[quote][b]Nicodem said[/b]
1. I don't live in a country where chemists are paranoid about "ethers f ...
19-5-2007 at 09:29
by: tupence_hapeny
Potential route to amphetamine...
[url=http://pubs.acs.org/cgi-bin/abstract.cgi/joceah/1983/48/i10/f-pdf/jo00158a042.pdf]Here[/url] is ...
19-5-2007 at 07:11
by: tupence_hapeny
Metallo-5,10,15,20-tetraphenylporphyrin synthesis (MW)
Good point, however, the substrate (the porphyrin) is organic - thus they were put here for the mome ...
19-5-2007 at 06:28
by: tupence_hapeny
Need help with prep. of phthalic anhydride from naphthalene
I just found this article:

M. Gupta et al. 'ZnO for Benzylic Oxidations' Tetrahedron Letters 46 ...
19-5-2007 at 01:46
by: tupence_hapeny
Metallo-5,10,15,20-tetraphenylporphyrin synthesis (MW)
Here is an interesting use of iron-tetra(substituted)phenylporphyrins, namely as a catalyst for tran ...
19-5-2007 at 00:12
by: tupence_hapeny
Potential route to amphetamine...
Here is a reduction of the phenylalaninal to phenylalaninol using only baker's yeast:

Here is the ...
15-5-2007 at 06:13
by: tupence_hapeny
Amino alcohol via Akabori, trial run
Jon,

If I can post the sucker it will be here in separate pages very soon.

tup
15-5-2007 at 04:44
by: tupence_hapeny
Phosphorus Chlorides
Righto,

I don't normally come to this side, however, I have some things you may like...

The de ...
24-4-2007 at 02:16
by: tupence_hapeny
Amino alcohol via Akabori, trial run
look at the reaction procedures for producing phenylserine, the structure of which is here:

http: ...
24-4-2007 at 00:42
by: tupence_hapeny
H2SO4 by the Lead Chamber Process - success
Ummm,

I finally found full-text access to the journal article regarding the oxidation of sulfurou ...
23-4-2007 at 19:12
by: tupence_hapeny
toluene --> benzaldehyde
Tally ho,

ummmm, I have to go elsewhere for the next month or so (family issues), I will attempt ...
23-4-2007 at 17:57
by: tupence_hapeny
Potential route to amphetamine...
righto,

There appears to be some diehards on this topic, so I wish to do what I can...

Amino A ...
23-4-2007 at 16:56
by: tupence_hapeny
toluene --> benzaldehyde
Thanks organikum,

I honestly looked and did not find that in the search engine, shit, I thought I ...
21-4-2007 at 02:23
by: tupence_hapeny
toluene --> benzaldehyde
Nicodem,

[quote]What are you talking again? I was replying to your discussion about CCl4 as a sol ...
21-4-2007 at 02:07
by: tupence_hapeny
toluene --> benzaldehyde
@Nicodem,

Benzyl Chloride most assuredly can be oxidised to benzaldehyde in over 80% yield, I agr ...
21-4-2007 at 01:47
by: tupence_hapeny
toluene --> benzaldehyde
[quote] Hmmm. You forgot to mention a wee detail. Your 44% chlorination of toluene w/TCCA ONLY RUNS ...
20-4-2007 at 23:54
by: tupence_hapeny
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