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Speculative reaction of alcohols to carbonic acids with Mg and CO2
[quote]
As for your second point, as per my mechanism, the conceivable way is that the alkoxide for ... |
18-11-2013 at 05:25
by: vulture |
Speculative reaction of alcohols to carbonic acids with Mg and CO2
Ah crap, I got confused again. 
Anyway, this shows that reactions with alkoxides results in ... |
18-11-2013 at 02:40
by: vulture |
Speculative reaction of alcohols to carbonic acids with Mg and CO2
UC:
Isopropylchloride is added, reaction starts, vigorous boiling ensues, iPrCl evaporates, react ... |
18-11-2013 at 00:22
by: vulture |
2,5-Dibromo-1,4-benzoquinone Reactivity?
1) Do we have any references for this attack of amines on quinones? If yes, please supply. The propo ... |
18-11-2013 at 00:07
by: vulture |
grignard reaction
I'm not sure, I expect this reaction to show oscillating behavior.
iPrMgCl is made in large amoun ... |
17-11-2013 at 14:49
by: vulture |
2,5-Dibromo-1,4-benzoquinone Reactivity?
I'm having a hard time following this synthesis, could you draw a scheme?
By which mechanism do b ... |
17-11-2013 at 14:41
by: vulture |
grignard reaction
Whoopsie, I was thinking about chloropropane. Indeed, with isopropyl chloride it's theoretically pos ... |
17-11-2013 at 14:31
by: vulture |
grignard reaction
EDIT: Ignore, I made a dumb comment below.
Depends on which isomer of isopropyl chloride you use. ... |
17-11-2013 at 12:27
by: vulture |
N-bromosuccinimide removal at workup
[quote]
I think that should come out in any aqueous wash (and I'll likely have at least one dilute ... |
17-11-2013 at 10:57
by: vulture |
N-bromosuccinimide removal at workup
NaHSO[sub]3[/sub] works, so does Na[sub]2[/sub]S[sub]2[/sub]O[sub]3[/sub]. However, regardless of th ... |
17-11-2013 at 07:10
by: vulture |
2,5-Dibromo-1,4-benzoquinone Reactivity?
DABCO is very similar in its reactivity to DBU, only weaker, so this might not be a good choice. |
17-11-2013 at 01:26
by: vulture |
Remarkable reaction with adjustable delay
Some thinking points:
Did you try the other reactions with the same quantities of water? Maybe th ... |
7-11-2013 at 12:47
by: vulture |
No comment
[quote]
The authors are those well-known humorists Lewandowsky and Mann, now in a double act now po ... |
7-11-2013 at 00:57
by: vulture |
How are neutrons held in the nucleus?
I'm not well versed in particle physics, so I can't really answer this for you. However, this is one ... |
5-11-2013 at 15:09
by: vulture |
cyanuric bromide, or, "one of those dehydrating thingies"
Vacuum sublimation is not very hard if the required vacuum is within reasonable ranges, i.e. not low ... |
5-11-2013 at 06:34
by: vulture |
NO2 ion to create N2
I suspect you will run into trouble by using ammonium salts, since the catalysts are basic. You'll h ... |
4-11-2013 at 11:46
by: vulture |
NO2 ion to create N2
Nucleating site for what? Precipitation? PU forming reaction?
Are you trying to make foams? |
4-11-2013 at 06:21
by: vulture |
Toma's acid salt: ammonium guanidinium bisulfate sulfuric acid salt
[quote]
On the other hand, by proposing that my chemical is an ammonium guanidinium bisulfate sulfu ... |
4-11-2013 at 05:48
by: vulture |
Failed OTC preparation of ammonium carbamate from urea
[quote]
At most, I believe that sulfamic acid, if any formed, is an impurity and present in small a ... |
4-11-2013 at 05:38
by: vulture |
Project turns to sensors in sewers to catch bomb-makers
Any reasonable chemist does not dump their waste down the drain without prior selection and/or neutr ... |
4-11-2013 at 05:32
by: vulture |
Toma's acid salt: ammonium guanidinium bisulfate sulfuric acid salt
[quote]
Let's try to stick to disproving that this is what I think it is.
[/quote]
While I like ... |
4-11-2013 at 05:23
by: vulture |
Why Hot Water Freezes Faster Than Cold—Physicists Solve the Mpemba Effect
[quote]
How strange then, and how remarkable, that the lowest specific heat of this "inorganic" sub ... |
3-11-2013 at 02:28
by: vulture |
tetrafluoroammonium perchlorate superoxidant
[quote]
We do so love speculating a little on super oxidants on SM don't we? I'll keep it short and ... |
30-10-2013 at 10:50
by: vulture |
The Right To Bear Arms ( and propellants )
I have no problem with gun ownership, if people like guns I guess it's just like I enjoy fireworks o ... |
28-10-2013 at 13:07
by: vulture |
Does nitroammonium exist ? or similar cations ?
[quote]
Dry CaCl2, mixed with snow (crushed ice) is a good cooling agent- this mixture decreases te ... |
28-10-2013 at 12:59
by: vulture |
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