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debromination with Zinc Dust
-CHBr-CH2Br group
11-3-2012 at 17:03
by: cactusmae
debromination with Zinc Dust
Zinc dust was bought at 2001.
11-3-2012 at 16:52
by: cactusmae
debromination with Zinc Dust
I tried debromination to get alkene and failed several times. The procedure I carried with the zinc ...
11-3-2012 at 14:29
by: cactusmae
selective reduce nitroaromatics
[rquote=236818&tid=18839&author=Dr.Bob]Sodium dithionate might work. That is an interestin ...
17-2-2012 at 08:05
by: cactusmae
selective reduce nitroaromatics
I finially figured out the problem with my reduction with nitroaromatics with Iron and HCl. The prob ...
14-2-2012 at 07:38
by: cactusmae
reduce nitro aromatic compound to very polar amine
I did try Rainey Ni once but no product. Is there any trick part for this reaction? Such as dry cond ...
19-10-2011 at 18:19
by: cactusmae
reduce nitro aromatic compound to very polar amine
I did use Zinc/HCl with ammonium formate at room temperature.
http://www.erowid.org/archive/rhodium ...
19-10-2011 at 09:24
by: cactusmae
reduce nitro aromatic compound to very polar amine
My substrate is perfluorinated carbon chain with brominate protected double bond. I tried to run the ...
19-10-2011 at 09:04
by: cactusmae
reduce nitro aromatic compound to very polar amine
Also the Fe/HCl reduction takes really long time. Should I heat up or add other cosolvent to speed u ...
19-10-2011 at 08:53
by: cactusmae
reduce nitro aromatic compound to very polar amine
But the product is strong base sensative. That is why I avoid of base reduction in the first place.
19-10-2011 at 08:36
by: cactusmae
reduce nitro aromatic compound to very polar amine
Product amine is very polar and has good solubility in water, so less amont of water is perferred fo ...
19-10-2011 at 07:58
by: cactusmae

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