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making SCl2 From TCCA-Na2S,possible or not?
Ever snell SCl2?
It's a lot nastier than Cl2.
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2-4-2010 at 12:44
by: Sauron |
making SCl2 From TCCA-Na2S,possible or not?
Make Cl2 from TCCA and run it into molten sulfur.
Brauer teaches how to isolate SCl2 from S2Cl2 a ... |
2-4-2010 at 06:11
by: Sauron |
Novichoks and Related 3rd/4th Gen. OP Agents
A lot has happened in this corner of military medicine since 1971 (hell since 1991!) and it is well ... |
12-3-2010 at 06:05
by: Sauron |
Novichoks and Related 3rd/4th Gen. OP Agents
Pinacolyl alcohol is slow to hydrolyse for reason os steric hindrance, as in GD soman a German gift ... |
11-3-2010 at 23:49
by: Sauron |
Novichoks and Related 3rd/4th Gen. OP Agents
Sorry but that is rather confused.
The hypothetical structure you posted is not "substituted VX" ... |
11-3-2010 at 04:18
by: Sauron |
Novichoks and Related 3rd/4th Gen. OP Agents
I lost most of my interest in this series once I ascertained that the US and NATO has been well awar ... |
9-3-2010 at 06:22
by: Sauron |
Elemental Chloorination Catalyzed by Quaternary Amine
In another US patent to Hoechst (as assignee) in 1997, GAC is the catalyst for chlorination of acyl ... |
8-3-2010 at 04:58
by: Sauron |
Elemental Chloorination Catalyzed by Quaternary Amine
I ran across a US patent from mid 1970s assigned to Dow, which teaches the use of various pyridines, ... |
7-3-2010 at 00:22
by: Sauron |
CCl4 and CHCl3 from CH2Cl2
@Panache
I posted this OT stuff about the Rhone process patent simply because I thought you were ... |
25-2-2010 at 21:33
by: Sauron |
CCl4 and CHCl3 from CH2Cl2
@Eclectic
Note that Brown obtained 88% AcCl with 1.5 mols benzoyl chloride per mo; AcOH while for ... |
25-2-2010 at 05:45
by: Sauron |
CCl4 and CHCl3 from CH2Cl2
I ran across a patent that described prep of tricgloroacetyl cghloride in high yield by chlorination ... |
25-2-2010 at 03:55
by: Sauron |
CCl4 and CHCl3 from CH2Cl2
In my opinion the main advantage of proceeding from ethanol rather than GAA is that UV is only used ... |
24-2-2010 at 22:04
by: Sauron |
CCl4 and CHCl3 from CH2Cl2
You could avoid the acronym muddle by using KMnO4 rather than TCCA as reagent to generate Cl2 from c ... |
24-2-2010 at 20:37
by: Sauron |
CCl4 and CHCl3 from CH2Cl2
I'm through with you, liar, and this yj\\thread has returned to chemistry not your spleen.
[Edited ... |
23-2-2010 at 18:53
by: Sauron |
CCl4 and CHCl3 from CH2Cl2
SbCl3 is quite cheap and I have no problem obtaining it. Wheel weights (OTC) are Db and are used by ... |
23-2-2010 at 09:32
by: Sauron |
CCl4 and CHCl3 from CH2Cl2
Chlorination of trichloroacetic acid to trichloroacetyl chloride by means of benzoyl cghloride (not ... |
23-2-2010 at 09:15
by: Sauron |
CCl4 and CHCl3 from CH2Cl2
No, I avoid rabid things such as curs, coons, skunks and you.
You in effect accused me of lyimg a ... |
23-2-2010 at 05:27
by: Sauron |
CCl4 and CHCl3 from CH2Cl2
That should come as no surprise to anyone who has spent much time in Wiley's journals. I have compla ... |
23-2-2010 at 05:22
by: Sauron |
CCl4 and CHCl3 from CH2Cl2
Thanks fractional
Here is the original paper by "Hofmann" p264 Annalen 115 (1860)
READ IT AND ... |
23-2-2010 at 04:53
by: Sauron |
CCl4 and CHCl3 from CH2Cl2
I can't help it that you don't know how to search.
You are just setting yourself up for a fall, b ... |
23-2-2010 at 03:47
by: Sauron |
CCl4 and CHCl3 from CH2Cl2
That is because you are an arrogant ass.
I posted the German original in Wanted References Needed ... |
23-2-2010 at 03:18
by: Sauron |
Another very old chemical: P2S3?
ATBOIC Phosphorus does describe a prep from the elements and cite the primary report bit still as yo ... |
22-2-2010 at 03:35
by: Sauron |
Sodium Hydride
QED
Case closed. |
18-2-2010 at 04:49
by: Sauron |
Sodium Hydride
Hook up 100 Ephoton clones in series to an EEg and all you get is baseline noise. |
17-2-2010 at 21:15
by: Sauron |
Another very old chemical: P2S3?
Every modern reference says "P2S3" does not exisrt nor P4S6.
There are P4S3, P4S5, P4S7 and P4S10 ... |
16-2-2010 at 10:11
by: Sauron |
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