Sciencemadness Discussion Board

Testing for urea

cnidocyte - 3-12-2010 at 08:46

I boiled a solution of NH2NO3 and urea that I got from an instant cold pack in water for a long time and at around 5C, a lot of white solid crystallised out of the water. I'm not fully sure that the urea is gone though. Carbonyl groups significantly lower the basicity of amino groups attached to them but since theres 2 amino groups in urea would it still be basic enough to be able to identify it by checking the pH?

Magpie - 3-12-2010 at 10:43

Quote: Originally posted by cnidocyte  
I boiled a solution of NH2NO3 and urea that...


Do you mean NH4NO3 and urea?

According to Baker MSDSs pH for NH4NO3 is 5.4 and that for urea is 7.2.

What was the pH before and after the crystal removal?

cnidocyte - 3-12-2010 at 11:23

Forgot to test the pH before, its at about 6 now. Definitely below 7. This isn't a good way to test for urea, I thought urea would be a lot more basic than that.

entropy51 - 3-12-2010 at 12:22

Berthelot's reaction using alkaline hypochlorite and phenol gives a blue color with urea. It may be too sensitive for your purposes, however.

Paddywhacker - 3-12-2010 at 21:05

You may have urea nitrate.

TheOrbit - 4-12-2010 at 06:40

i know u can check for urea by buiret test "on solid "