Sciencemadness Discussion Board

Synthesis of Hexaammine nickel II chloride

vibbzlab - 8-12-2019 at 08:07

Hexaammine nickel II Chloride is a complex formed with nickel II Chloride and ammonia

Materials required

4g ammonium chloride
5g nickel II Chloride
Distilled water
10ml 30% ammonia

Procedure

Weigh out seperately 5g Nickel (II) chloride and 4g ammonium chloride in two seperate beakers.
Now preparing saturated solutions of them by
Adding 4ml of distilled water to nickel chloride and 10ml of water to ammonium chloride.
After preparation of the saturated solutions seperately, pour ammonium chloride solution into nickel chloride solution
Into this solution add 10ml of 30% cold ammonia and mix well. Allow the ppt to sediment now filter the precipitate. Wash the container with cold ammonia solution to get all the solid out into the filtration unit and also wash the solid in filter paper with cold ammonia .
Dry the precipitate and weigh.

Nickel ions in water forms a complex
With 6 molecules of H2O around nickel 2+ ion.
When we add ammonia this water molecules are replaced by 6 molecules of ammonia forming the complex
[Ni(H2O)6]2+(aq) + 6NH3(aq) ==> [Ni(NH3)6]2+ +6H2O
Thanks to everyone who helped me do this video

Here's the video to my version of synthesis
https://youtu.be/GUxen09r5C0

IMG_20191208_134803_222.jpg - 1.2MB

Bedlasky - 8-12-2019 at 09:11

Nice synthesis :). What purpose have NH4Cl?

UC235 - 8-12-2019 at 10:10

Quote: Originally posted by Bedlasky  
Nice synthesis :). What purpose have NH4Cl?


Buffer. Otherwise, you get hexaammine nickel II hydroxide due to the high pH probably.

DraconicAcid - 8-12-2019 at 12:15

No, ammonium chloride is not needed. Perhaps it increases the chloride concentration so that you get a better yield.

vibbzlab - 8-12-2019 at 16:13

Yes that's just to increase the chloride ions.common ion effect

DraconicAcid - 8-12-2019 at 16:50

You can also add methanol to help precipitate the complex.

vibbzlab - 8-12-2019 at 22:42

I've got it all