Sciencemadness Discussion Board

Nickel benzoate

vano - 21-12-2020 at 11:42

What do you think? Has anyone tried this?


PicsArt_12-21-11.40.05.jpg - 240kB

njl - 21-12-2020 at 12:23

Source?

RustyShackleford - 21-12-2020 at 12:32

I have tried thermal decomposition of calcium benzoate to make benzophenone but it didnt work at all

vano - 21-12-2020 at 12:35

Quote: Originally posted by njl  
Source?


Chinese wikipedia.

valeg96 - 21-12-2020 at 22:41

My best guess is that those claims come from some negligible literature results, at least on the productive scale. Whoever reported that probably ran the combustion or TGA fumes through a GC-MS and identified all those molecules in traces.

Sure, if you heat to decomposition Ni benzoate you probably can find a couple ppm of biphenyl in the fumes, but that's miles away from being a productive route. If it was that simple, biphenyl wouldn't be that expensive, for one thing.

JJay - 22-12-2020 at 13:01

Quote: Originally posted by RustyShackleford  
I have tried thermal decomposition of calcium benzoate to make benzophenone but it didnt work at all


Did you use a vacuum? I'm pretty sure that's a viable synthetic method (though undoubtedly low-yielding).