Sciencemadness Discussion Board

Calamine--ZnCO3

darkflame89 - 2-4-2004 at 01:53

Saw a bottle of calamine at my pharmacy. I checked up my books and they said it was ZnCO3. I need to obtain it pure but the bottle contains menthol too. Anyway to get rid off it??

Incidentally, is there anyway to recover zinc metal from zinc carbonate?

I am a fish - 2-4-2004 at 02:21

In my experience, medicinal products are generally poor and expensive sources of laboratory chemicals.

Zinc oxide is cheaply and readily available from pottery suppliers. If you particularly want to make the carbonate:

1. Dissolve an excess of zinc oxide in sulphuric, hydrochloric or nitric acid.
2. Filter out the excess zinc oxide, to give a pure solution of the zinc salt corresponding to the acid used.
3. Add sodium carbonate solution, to precipitate out zinc carbonate.

A brief overview of methods to extract zinc from its compounds can be seen here:
http://www.webelements.com/webelements/scholar/elements/zinc...

A readily available source of zinc metal is the casing of zinc-carbon batteries.

Organikum - 2-4-2004 at 02:38

zinc-oxide is even more readily available at paintstores - zinc-white as pigment for white paint.

For the rest see what the fish wrote - he is absolute right.

darkflame89 - 2-4-2004 at 02:41

Unfortunately, where i live do not have such luxury. But I see the point about zinc from batteries. Can i just peel of the outer layer and react with it?

Saerynide - 2-4-2004 at 02:42

I thought the can on the Zn/C batteries was a zinc alloy?

I am a fish - 2-4-2004 at 02:52

Technically yes, but the zinc content is usually over 99%.