Sciencemadness Discussion Board

Toluene > benzyl chloride

chucknorris - 25-1-2013 at 22:10

I found one method which uses toluene and hypochlorite, but I found no user references whatsoever.

Should the chlorination of toluene with HCl work as with benzyl alcohol? Toluene is otc, but benzyl alcohol is very difficult to obtain.

Mercedesbenzene - 25-1-2013 at 23:19

Chlorination of toluene uses Cl2, not HCl, with a black light it proceeds quite rapidly.

Inny_G - 26-1-2013 at 06:58

Mervedesbenzene i think your method would make chloro-toluenes rather than benzyl chloride.

Chucknorris, i cant really say anything specific about this because i'm just on my phone atm but it is possible to make phenol from toluene and there are detailed syntheses on youtube

killer_lapin - 26-1-2013 at 07:26

mercedesbenzene is right the substitution is mostly on the substituent it self, producing benzyl chloride. Here is a couple of synthesis ways http://www.erowid.org/archive/rhodium/chemistry/benzylchlori...

Inny_G - 26-1-2013 at 07:39

Ergh my bad. I was thinking of chlorobenzene rather than benzyl chloride

Benzyl Alcohol

cal - 26-1-2013 at 08:16

Benzyl Alcohol on eBay
http://www.ebay.com/itm/Benzyl-Alcohol-99-5-Pure-8-oz-Solven...

blankets - 26-1-2013 at 15:25

Benzyl alcohol http://lemelange.com/benzyl-alcohol.aspx