What would drive the reactions? Also, mixing ammonia and copper salts with oxidizing anions might be a bad idea, as it could lead to formation of
sensitive tetraamine copper salts.
http://www.sciencemadness.org/talk/viewthread.php?tid=16220
Copper perchlorate is usually the hexahydrate. Dehydrating it to anhydrous might be impossible, going off of copper nitrate as an example.
If you really want the perchlorate, you could try reacting perchloric acid (be careful!) with copper oxide/hydroxide/basic carbonate.
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