Sciencemadness Discussion Board

8 electron reduction

Hboomans - 1-7-2014 at 06:49

I have a recipe here it is an 8 electron reduction. where one uses 8 faradays to reduce 160grams.

Now is my question if I want to reduce 20grams is there still 8 faradays needed or will this be less?

Does the amount you want to reduce affect the faradays needed for the reduction to completion?

Texium - 1-7-2014 at 07:16

You can't expect to get a real answer when you come in here talking about "recipes" and using very vague language.

PHILOU Zrealone - 1-7-2014 at 08:13

F= Na x e(-)
F = Faraday constant
Na = Avogadro's number
e(-)= electron charge

You use 8 electrons (e(-)) per molecules what implies 8 x F/mole...

So your compound is 160g/mole and 20g is 1/8th of a mole...

20g will thus require 8 times less than 8F what is 1F!

[Edited on 1-7-2014 by PHILOU Zrealone]

Artemus Gordon - 7-7-2014 at 14:52

According to Wikipedia, one faraday equals 96485.3399 coulombs. Let's call it 100,000 C to make the math easier.
A current flow of 1 Ampere equals 1C/second. So if you have a power supply that can deliver 10 amps at the voltage you need to drive your reaction, it would take 10,000 seconds to deliver 1 faraday, which is a bit more than 2 and 3/4 hours.