Sciencemadness Discussion Board

Does Gold dissolve in mix of NaNO3 and NaOH?

AndroidOS - 29-5-2015 at 23:27

I think PGM's like Ir, Os... are dissolved like this.

Should it be melted, or can be done in water?
I've heard that people "think" that Au(OH)3 dissolves in bases forming "probably" soluble aurate. Nitrate acts as oxidant, and base as dissolver (just like for Al)...

Can Sodium Peroxide or Superoxide (both easy to make, just heat oxide or carbonate or hydroxide) be used instead of nitrate?

I prefer to use bases instead of acids! And also don't want cyanides. Because bases dissolve more elements than acids forming for example (with oxides or hydroxides) soluble salts (e.g. Germanate, Silicate, Aurate, Zirconate, Hafnate...). Also I would use bases for getting elements from rocks or soil, because acid's can*t do anythiing (silica blocks reaching other chemicals like Na, K, Ca, Mg, Fe, Al...).

[Edited on 30-5-2015 by AndroidOS]

hissingnoise - 30-5-2015 at 01:54

Gold is not affected by alkaline sols ─ see here?

(websearch took 12 seconds)


blogfast25 - 30-5-2015 at 05:56

Quote: Originally posted by hissingnoise  

(websearch took 12 seconds)



Humbug, slow connection!

hissingnoise - 30-5-2015 at 06:37

Fibre ─ probably faster than yours, damn yer eyes . . . ?

And I never time myself, much rather plucking random numbers from the æther!


DraconicAcid - 30-5-2015 at 06:39

Nitrate isn't a very good oxidizer in basic solution.

blogfast25 - 30-5-2015 at 07:20

Quote: Originally posted by DraconicAcid  
Nitrate isn't a very good oxidizer in basic solution.


It is when you fuse it with 'things'! :D

DraconicAcid - 30-5-2015 at 07:30

Quote: Originally posted by blogfast25  

It is when you fuse it with 'things'! :D


Alright, let me rephrase that to "basic aqueous solutions".