Sciencemadness Discussion Board

Light sensitive compount storage

Ramiel - 15-4-2003 at 20:15

I was just cruising about the webernet and I came across thisie here link for <html><a href="http://www.sisweb.com/lab/wheaton/bottle19.htm">white PE bottles</a></html>

Now some people have had trouble storing reactive and or light sensitive chemicals (eg. Nitric Acid). This kind of thing ought to be much more satisfactory when compared to brown glass containers, don't you think?

[Edited on 16-4-2003 by Ramiel]

madscientist - 15-4-2003 at 22:19

PE = polyethylene, which is susceptible to oxidation - nitric acid is a powerful oxidizing agent. Therefore PE bottles wouldn't be well suited for storing nitric acid. :(

Why not just paint the exterior of the brown bottles in order to further limit the quantity of light that strikes the contents? :)

o' contraire

Ramiel - 15-4-2003 at 22:27

Originally Posted by PHILOU Zrealone
Quote:

...PE restist acids and oxydisers...

(from <html><a href="http://www.sciencemadness.org/talk/viewthread.php?tid=156">A cautionary tale</a></html>;)

[Edited on 16-4-2003 by Ramiel]

PHILOU Zrealone - 29-4-2003 at 04:39

All chem boxes from chemi companies are eather glass or PE!

PE has the structure CH3-(CH2)n-CH3 thus oxydation will be very hard at ambiant T!
Alcanes need to be over 300/400°C to start to react with oxydisers...this is far over the melting point of PE!

:mad::mad::mad:

PHILOU Zrealone - 29-4-2003 at 06:01

The best way to have light sensitive chems is to store them in a dark closed box, case the container can be transparent then and exposure to light is reduced to the moment of use!Most light sensitive chems can stand a little exposition HNO3 is really not a problem!