Sciencemadness Discussion Board

Telling if a reaction will occur

DalisAndy - 30-7-2015 at 15:59

I was wondering how one would calculate if a reaction will take place? I have an AP Chem textbook. If that would help

blogfast25 - 30-7-2015 at 16:04

Have a look at this, just for starters:

http://hyperphysics.phy-astr.gsu.edu/hbase/chemical/gibbspon...

For ΔG < 0, a chemical reaction is thermodynamically favourable. That theory and the related theory of reaction kinetics are complex and cannot be summarised in a few sentences here.


[Edited on 31-7-2015 by blogfast25]

diddi - 30-7-2015 at 16:12

how about redox potentials?
for inorganics anyway :)

blogfast25 - 30-7-2015 at 16:16

Quote: Originally posted by diddi  
how about redox potentials?
for inorganics anyway :)


They only work in watery solutions. As such they are a 'special case' of chemical thermodynamics and kinetics.

softbeard - 30-7-2015 at 16:19

In general, a reaction has thermodynamic impetus to go forward if the equation's Gibbs Free Energy change (delta G) is negative (<0). But that's just thermodynamics. It says nothing about a reaction's kinetics which may be extremely slow and take a very long time before equilibrium is achieved.
Note that the delta G for a reaction may be a strong function of temperature, pressure (in the case of gases/vapours), or both. So it is very important you consider reaction conditions (eg. 273 Celcius, 1 atm.) while asking this question.