Sciencemadness Discussion Board

Strange colouration in organic ligand

Ramiel - 10-8-2006 at 05:04

I recently made bis glycinato copper... Cu(gly)<sub>2</sub>.H<sub>2</sub>O by reaction of Cup. acetate with glycine. After the reaction occured, the product was filtered and then heated under reflux for about an hour on a steam bath with some of the filtrate. Left to cool and then filtered, the isomer of glycinato copper was what can only be described accuratly as a "crushed velvet" colour. It was dark blue and a wavy chrome colour, very vivid. Now I know these compounds are called cinato after their extreme colours, but what could have caused this metallic sheen to a crystalline salt? any guesses here... I'm stumped!

p.s. yes, it was very well dried, thank you! and no impurities were present ;)

The_Davster - 10-8-2006 at 05:11

I also once obtained a metallic sheen on a precipitate I filtered. The precipitate was neodymium carbonate, and dissapaeared in a following batch when it was washed better.

Or perhaps in this case it is the copper in the compound oxidizing or something.

Nick F - 10-8-2006 at 05:18

Can you get a picture? It'd help to explain what you mean...