Sciencemadness Discussion Board

Chromium Sulphate from Stainless Steel

mesanaw - 28-6-2017 at 15:47

I'm trying to make Chrome Alum from stainless steel as a starting material, but I am having trouble separating chromium sulfate from the ferrous sulfate.

The resulting mixture from reacting stainless steel with dilute sulfuric acid is two parts: one is a dark liquid and the other a green slushy-like material. The dark liquid portion clearly has some ferrous sulfate in it.

Is there any way to separate the two compounds while leaving the chromium sulfate in tact?

DraconicAcid - 28-6-2017 at 15:49

Isolation of chromium compounds from stainless steel has been discussed in other threads.

I suggest sodium hydroxide. Cr forms a soluble complex ion; Fe does not.