Sciencemadness Discussion Board

Tetrakis(dimethylamino)ethylene

-cyan- - 25-2-2007 at 14:33

hi
does anybody have an idea how to create Tetrakis(dimethylamino)ethylene ?


thx and greets
fabian :)

ps:sry for my english xD

Aqua-regia1 - 2-2-2008 at 13:46

Very interesting matter for luminescens. It is a big question me too.

matei - 2-2-2008 at 14:35

Tetrakisdimethylamino-ethylene, a Strong Electron Donor
Angewandte Chemie International Edition in English
Volume 1, Issue 7, Date: July 1962, Pages: 406
Nils Wiberg, J. W. Buchler

A New Synthesis of Tetrakis(dimethylamino)ethylene (p 971)
H. Bredereck, F. Effenberger, H. J. Bredereck
Published Online: Dec 17 2003 7:17PM
DOI: 10.1002/anie.196609711

[Edited on 2-2-2008 by matei]

garage chemist - 2-2-2008 at 14:43

Ullmann says it is made from Chlorotrifluoroethylene and Dimethylamine. This method of synthesis is also subject of a patent which can be easily found by a search for the target compound.

Aqua-regia1 - 3-2-2008 at 05:44

Quote:
Originally posted by matei
A New Synthesis of Tetrakis(dimethylamino)ethylene (p 971)
H. Bredereck, F. Effenberger, H. J. Bredereck
Published Online: Dec 17 2003 7:17PM
DOI: 10.1002/anie.196609711

[Edited on 2-2-2008 by matei]


It is possible this script to send to me? I should be glad to become this article.

Aqua-regia1 - 3-2-2008 at 05:52

Quote:
Originally posted by garage chemist
Chlorotrifluoroethylene quote]
This stuff is really impossible to access. Self the tetrakis... synthesis is easier!