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Author: Subject: smells, glorious smells.
nitroboy
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[*] posted on 14-10-2004 at 03:14
smells, glorious smells.


I've been thinking about making some foul smelling compounds for some time.

I figure for H2S i would just drip dilute sulphuric acid onto ZnS (is it dilute or concentrated for it to act as an acid)i think it would react according to:

ZnS + H2SO4 => ZnSO4 + H2S

But then i came across ethane thiol.
Would bubbling H2S through ethanol yield ethane thiol?

Also, i read somewhere that bubbling H2S through NH4OH will give NH4S, which is supposedly stinky in itself.
Any thoughts or suggestions?
Thanks for any help.

[Edited on 14-10-2004 by nitroboy]
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Marvin
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[*] posted on 14-10-2004 at 05:13


I think you should start to understand the toxicity of a substance before wanting to make it for its smell. The very high toxicity of H2S and the fact your nose becomes desensitised to it has been covered before.

I would not expect ethanol and H2S to make EtSH. I would expect you to have to react a haloalkane with sodium or potassium hydrosulphide (might work, unsure), or with a disulphide Na2S2 to form Et-S-S-Et and then reduce to EtSH (certain to work but might be needlessly complicated).
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guy
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[*] posted on 14-10-2004 at 14:14


How about chlorine?

Almost everything smelly is poisonous, so I wuldnt mess around with it




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vulture
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[*] posted on 14-10-2004 at 14:34


What exactly is the point of this thread? We have a thread about foul smelling substances...



One shouldn't accept or resort to the mutilation of science to appease the mentally impaired.
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MadHatter
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[*] posted on 14-10-2004 at 20:18
Fart


To others posting in this thread, not you Vulture, how about the plain
old FART ? Any ANALyis anybody ?

KILL THIS THREAD !




From opening of NCIS New Orleans - It goes a BOOM ! BOOM ! BOOM ! MUHAHAHAHAHAHAHA !
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guy
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[*] posted on 14-10-2004 at 20:38


Fart is methane, hydrogen sulfide (espically if you eat eggs) and the smell of your food, Nasty mix.

You can also buy meat and leave outside and get cadavarine. mmm...




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nitroboy
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[*] posted on 14-10-2004 at 22:14


Ok, would perhaps bubbling H2S through an acidified solution of ethylene glycol produce mercaptoethanol?
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vulture
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[*] posted on 15-10-2004 at 04:51


http://www.sciencemadness.org/talk/viewthread.php?tid=1216

Search engine...

Closed.




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