Sciencemadness Discussion Board
Not logged in [Login ]
Go To Bottom

Printable Version  
Author: Subject: Hydrogen Perozide and Chlorine
johnnygeneric
Harmless
*




Posts: 1
Registered: 7-12-2004
Member Is Offline

Mood: No Mood

[*] posted on 7-12-2004 at 05:43
Hydrogen Perozide and Chlorine


Hydrogen Peroxide is used to suck up dissolved Chlorine in water in the Chlor alkali business. What does it form??? Anyone know?
View user's profile View All Posts By User
cyclonite4
Hazard to Others
***




Posts: 480
Registered: 16-11-2004
Location: is unknown
Member Is Offline

Mood: Amphoteric

[*] posted on 7-12-2004 at 06:24
A possible solution...


Do you mean that they remove chloride ions from the water?

Hydrogen Peroxide reacts with chloride ions to produce free chlorine, water and oxide ions(water in the case of HCL) ... (heres the reaction)...

H2O2 + 2Cl- --> H2O + Cl2 + O2-

This may be it .... im not really sure based on ur description...
View user's profile View All Posts By User This user has MSN Messenger
I am a fish
undersea enforcer
****




Posts: 600
Registered: 16-1-2003
Location: Bath, United Kingdom
Member Is Offline

Mood: Ichthyoidal

[*] posted on 7-12-2004 at 11:26


When chlorine dissolves in water, it exists as a mixture of hydrochloric and hypochlorous acids (except at low pH):

Cl<sub>2</sub> + H<sub>2</sub>O <--> HCl + HOCl

Hydrogen peroxide is capable of reducing hypochlorous acid into hydrochloric acid:

HOCl + H<sub>2</sub>O<sub>2</sub> -> HCl + H<sub>2</sub>O + O<sub>2</sub>

Therefore hydrogen peroxide can be used as a dechlorination agent, as its net effect is to convert chlorine into relatively inert hydrochloric acid:

Cl<sub>2</sub> + H<sub>2</sub>O<sub>2</sub> -> 2HCl + O<sub>2</sub>




1f `/0u (4|\\| |234d 7|-|15, `/0u |234||`/ |\\|33d 70 937 0u7 /\\/\\0|23.
View user's profile Visit user's homepage View All Posts By User
I am a fish
undersea enforcer
****




Posts: 600
Registered: 16-1-2003
Location: Bath, United Kingdom
Member Is Offline

Mood: Ichthyoidal

[*] posted on 7-12-2004 at 11:39


Quote:
Originally posted by cyclonite4
Do you mean that they remove chloride ions from the water?

Hydrogen Peroxide reacts with chloride ions to produce free chlorine, water and oxide ions(water in the case of HCL) ... (heres the reaction)...

H2O2 + 2Cl- --> H2O + Cl2 + O2-

This may be it .... im not really sure based on ur description...

That certainly wouldn't happen.


Iodide and bromide ions are oxidised to the respective elements as follows:

2X<sup>-</sup> + H<sub>2</sub>O<sub>2</sub> -> X<sub>2</sub> + 2OH<sup>-</sup>

However, this reaction doesn't happen with chloride ions.


[Edited to fix subscript text]

[Edited on 8-12-2004 by I am a fish]




1f `/0u (4|\\| |234d 7|-|15, `/0u |234||`/ |\\|33d 70 937 0u7 /\\/\\0|23.
View user's profile Visit user's homepage View All Posts By User
cyclonite4
Hazard to Others
***




Posts: 480
Registered: 16-11-2004
Location: is unknown
Member Is Offline

Mood: Amphoteric

[*] posted on 8-12-2004 at 04:37


i stand corrected:D.... ive heard of these reactions with bromide and iodide... so i assumed it applied to all the halides :(
View user's profile View All Posts By User This user has MSN Messenger

  Go To Top