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Author: Subject: Reduction potential of Si
Anolia
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smile.gif posted on 26-1-2006 at 15:37
Reduction potential of Si


I am trying to figure out what the reduction potential of silicon is, specifically Si+4 seeing as it is the oxidation state of silicon in SiO2. I can't seem to find it anywhere - in any book I look in there is a dash through the line in the table where it should be. Why hasn't anyone determined its reduction potential? It is such an abundant element. This is baffling me - any input would be great.
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[*] posted on 26-1-2006 at 16:06


Si(4+) doesn't exist in solution, AFAIK. SiF6(2-) might work though. I doubt SiO4(4-) or SiO3(2-) would work. Come to think of it, all of these species are pretty well equivalent, using a strongly electropositive component, no? And such ions tend not to reduce in H2O solution, don't they?

Best way to electrically reduce it would be like aluminum: from a salt melt. :(

Tim




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