IgnorantlyIntelligent
Moderately Insane
Posts: 280
Registered: 16-10-2003
Member Is Offline
Mood: Unhuman
|
|
Nitrated petrolium jelly
Has anyone ever nitrated petrolium jelly? What would the chemical structure look like?
Petrolium jelly is used for Vasoline.
I have read about Nitropetrolium made from nitrated gasoline but thats all.
Im very interested in this because of all the benefits it may have.
Nitrating should be similar to that of NG (very easy) and one pound of vasoline (100% petrolium jelly) is not only easy to get but cheap as dirt.
Almost anything(not really but it seems like it) can be nitrated. Ive heard of sugar, sugar substatutes, glycerin, cotton, starch,gasoline,...I could
go one forever but you get the point. I think this new explosive deserves a chance.
I say "new explosive" because I have-in many years of experiance-never heard of this being done.
[Edited on 26-10-2003 by IgnorantlyIntelligent]
[Edited on 27-10-2003 by IgnorantlyIntelligent]
[Edited on 27-10-2003 by IgnorantlyIntelligent]
\"People fear from ignorance what they do not have the intelligence to understand\"
\"Religion is the sigh of the oppressed creature, the heart of a heartless world, just as it is the spirit of a spiritless situation.\"
\"A fool would rather not question, a soldier is taught not to question, a slave dares not question.\"
\"To fight for nothing is to love nothing, to die for something is to have lived for something.\"
|
|
|
Nevermore
Hazard to Others
Posts: 140
Registered: 3-5-2003
Location: China at the moment
Member Is Offline
Mood: shopping businessman
|
|
if i remember good vaseline is mainly paraffin and paraffin oil..
Nevermore!
|
|
|
Mr.O-Nitrate
Harmless
Posts: 25
Registered: 16-10-2003
Member Is Offline
Mood: No Mood
|
|
sombody should try it
Sombody should try it.  I wonder how it would deflagrate?
|
|
|
Nevermore
Hazard to Others
Posts: 140
Registered: 3-5-2003
Location: China at the moment
Member Is Offline
Mood: shopping businessman
|
|
mr o nitrate i got some messages from you on aim a few days ago but i didn't notice much. did you fix the problem?
I think that nitrating paraffin would be a pain..
Nevermore!
|
|
|
IgnorantlyIntelligent
Moderately Insane
Posts: 280
Registered: 16-10-2003
Member Is Offline
Mood: Unhuman
|
|
No, all vasoline I've ever seen has been 100% petrolium jelly.
People always talk about ways to make an explosive into a "putty", well hopefully, nitrated petrolium jelly wouldnt need anything added to
it to make it a "putty". I think it will keep its texture like NG does.
Another good thing is price, although no on here would ever make explosives  , one
pound of petrolium jelly would cost only about $4.
plus the costs of acid(s) and a nitrate if needed.
I think nitrating petrolium jelly would be very similar to glycerin except its alot thicker and wouldnt be soluable in the acid/nitrate solution (but
hopefully Im wrong).
Well I'm off to go get some vasoline and more acid(I ran out yesterday)
I'll post results as soon as possible.
\"People fear from ignorance what they do not have the intelligence to understand\"
\"Religion is the sigh of the oppressed creature, the heart of a heartless world, just as it is the spirit of a spiritless situation.\"
\"A fool would rather not question, a soldier is taught not to question, a slave dares not question.\"
\"To fight for nothing is to love nothing, to die for something is to have lived for something.\"
|
|
|
Mr.O-Nitrate
Harmless
Posts: 25
Registered: 16-10-2003
Member Is Offline
Mood: No Mood
|
|
Nevermore
Oh, shoot, I forgot what I sent to you that day  but I probably figured it out.
Hey is Nitrocellulose a good explosive to start out with?
( I have already made Blackpowder, sucrose rockets, firecrackers,shells, and other pyrotechnics)
|
|
|
IgnorantlyIntelligent
Moderately Insane
Posts: 280
Registered: 16-10-2003
Member Is Offline
Mood: Unhuman
|
|
This is a forum for the discussion of energetic materials, not a chat room.
Try to stay on topic please......
\"People fear from ignorance what they do not have the intelligence to understand\"
\"Religion is the sigh of the oppressed creature, the heart of a heartless world, just as it is the spirit of a spiritless situation.\"
\"A fool would rather not question, a soldier is taught not to question, a slave dares not question.\"
\"To fight for nothing is to love nothing, to die for something is to have lived for something.\"
|
|
|
Nevermore
Hazard to Others
Posts: 140
Registered: 3-5-2003
Location: China at the moment
Member Is Offline
Mood: shopping businessman
|
|
i guess that petroleum jelly would give a completely different product than glicerine, being glicerine much more simple than the petroleum products
that you can find in the jelly.
BTW over here paraffin oil is called petroleum oil...
and paraffin is called petrol wax..
so check carefully =)
Nevermore!
|
|
|
froot
National Hazard
Posts: 347
Registered: 23-10-2003
Location: South Africa
Member Is Offline
Mood: refluxed
|
|
I had a half hearted go at nitrating petroleum jelly. Conc. HNO3 in a ice bath, dropped in the jelly in small amounts. A thin brown film forms on the
surface. after extraction it deflagrates slowly, but it was still a little wet. The yield was awefull. After briefly searching the net (http://www.techno-preneur.net/timeis/westbengal/INVOPP/PETRO...) I've found that the stuff is a mixture of different compounds rather than
one solitary chemical. This may make nitration to form one desired compound fairly pointless.
We salute the improvement of the human genome by honoring those who remove themselves from it.
Of necessity, this honor is generally bestowed posthumously. - www.darwinawards.com |
|
|
Nevermore
Hazard to Others
Posts: 140
Registered: 3-5-2003
Location: China at the moment
Member Is Offline
Mood: shopping businessman
|
|
pretty similar to nitrated sugar, you don't get a clear compount but a mixture of nitro esters. Unfortunately the low nitrated ones will be
parasiting the reaction and the detonation later..
i am not sure but maybe there are ways to bring the low nitrated esters to an higher nitration, or maybe is possible to separate them from the lower
ones by some solvents..
Nevermore!
|
|
|
IgnorantlyIntelligent
Moderately Insane
Posts: 280
Registered: 16-10-2003
Member Is Offline
Mood: Unhuman
|
|
That is a very good point about it being a mixture of many ingrediants instead of one basic compound.
Maybe it is pointless......
\"People fear from ignorance what they do not have the intelligence to understand\"
\"Religion is the sigh of the oppressed creature, the heart of a heartless world, just as it is the spirit of a spiritless situation.\"
\"A fool would rather not question, a soldier is taught not to question, a slave dares not question.\"
\"To fight for nothing is to love nothing, to die for something is to have lived for something.\"
|
|
|
a123x
Hazard to Self
Posts: 87
Registered: 12-1-2003
Member Is Offline
Mood: No Mood
|
|
Just so you all know, nitrated vaseline wouldn't be a nitric ester since vaseline conists only of carbon and hydrogen and thus has no OH groups
to be nitrated. If vaseline is nitratable it would be a nitro compound, I suppose it would be considered a nitro-aliphatic.
|
|
|
IgnorantlyIntelligent
Moderately Insane
Posts: 280
Registered: 16-10-2003
Member Is Offline
Mood: Unhuman
|
|
vasoline is 100% petrolium, and I have read that nitratred petrolium can be made with conc. nitric and sulfuric acid quite easily. However, the
synthesis used gasoline not vasoline. the yeilds were very poor which is why I suggested using 100% petrolium.
Go to megalomanias website and look for nitarted petrolium, maybe I just read it wrong.
\"People fear from ignorance what they do not have the intelligence to understand\"
\"Religion is the sigh of the oppressed creature, the heart of a heartless world, just as it is the spirit of a spiritless situation.\"
\"A fool would rather not question, a soldier is taught not to question, a slave dares not question.\"
\"To fight for nothing is to love nothing, to die for something is to have lived for something.\"
|
|
|
Hermes_Trismegistus
International Hazard
Posts: 602
Registered: 27-11-2003
Location: Greece, Ancient
Member Is Offline
Mood: conformation:ga
|
|
How difficult would adding that OH group really be exactly....?
and would'nt that most likely thicken the already gooey consistency towards a more ideal form (for the orig poster)?
Arguing on the internet is like running in the special olympics; even if you win: you\'re still retarded.
|
|
|
unionised
International Hazard
Posts: 5075
Registered: 1-11-2003
Location: UK
Member Is Offline
Mood: No Mood
|
|
It would be posible to add the OH, but it would be tricky. (chlorination then hydrolysis looks the obvious route to me, but I'm sure there are
others).
It makes more sense to start with something that already has the OH groups to begin with.
(Reminds me of joke with old yokel saying "If I wanted to get there, I wouldn't start from here)
|
|
|
![[*]](images/xpblue/default_icon.gif){kind=icon}
