Sciencemadness Discussion Board
Not logged in [Login ]
Go To Bottom

Printable Version  
Author: Subject: Electrophilic chlorination (no chlorine :-( )
Zombiekitten
Harmless
*




Posts: 4
Registered: 22-6-2008
Member Is Offline

Mood: BRAAAINS! *meow*

[*] posted on 22-6-2008 at 14:13
Electrophilic chlorination (no chlorine :-( )


sadly i cannot use chlorine but i need chlorobenzene alternatives?
View user's profile View All Posts By User
Klute
International Hazard
*****




Posts: 1378
Registered: 18-10-2006
Location: France
Member Is Offline

Mood: No Mood

[*] posted on 22-6-2008 at 14:35


SO2Cl2 can substitute Cl2 in sevral cases, but I doubt you cna us eit if you can't use chlorine!

Why can't you use chlorine? Inadequate ventilation/setup?




\"You can battle with a demon, you can embrace a demon; what the hell can you do with a fucking spiritual computer?\"

-Alice Parr
View user's profile View All Posts By User
Zombiekitten
Harmless
*




Posts: 4
Registered: 22-6-2008
Member Is Offline

Mood: BRAAAINS! *meow*

[*] posted on 22-6-2008 at 15:26


sadly yes.:(
is there a replacement like N-Bromosuccinimide for chlorine?

[Edited on 22-6-08 by Zombiekitten]
View user's profile View All Posts By User
Sauron
International Hazard
*****




Posts: 5351
Registered: 22-12-2006
Location: Barad-Dur, Mordor
Member Is Offline

Mood: metastable

[*] posted on 22-6-2008 at 15:36


There are a number of N-chloroimines.

trichloroisocyanuric acid (TCCA)

N-chlorosuccinimide

Various chlorine bearing hydantoins

But if you can get these why can't you get chlorobenzene?

If your lab is inadequate for chlorine, is it adequate for chlorination of benzene with any reagent?

This whole proposition seems riddled with non sequiturs.




Sic gorgeamus a los subjectatus nunc.
View user's profile View All Posts By User
Zombiekitten
Harmless
*




Posts: 4
Registered: 22-6-2008
Member Is Offline

Mood: BRAAAINS! *meow*

[*] posted on 22-6-2008 at 16:39


the great outdoors is my fume hood:D,
It is more the corrosive part then the poisonous part for me:o.
View user's profile View All Posts By User
woelen
Super Administrator
*********




Posts: 7976
Registered: 20-8-2005
Location: Netherlands
Member Is Offline

Mood: interested

[*] posted on 22-6-2008 at 22:53


TCCA & Co. also are quite corrosive. Glass and many plastics are not attacked, but metals definitely are.



The art of wondering makes life worth living...
Want to wonder? Look at https://woelen.homescience.net
View user's profile Visit user's homepage View All Posts By User
Axt
National Hazard
****




Posts: 778
Registered: 28-1-2003
Member Is Offline

Mood: No Mood

[*] posted on 22-6-2008 at 23:20


I've posted the chlorination of benzene with TCCA, no (well, little) release of Cl2, very simple.

http://www.sciencemadness.org/talk/viewthread.php?tid=8027
View user's profile Visit user's homepage View All Posts By User

  Go To Top