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Author: Subject: Possible semi-catalytic bromine synthesis
Nicodem
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[*] posted on 5-6-2009 at 13:00


Quote: Originally posted by pHzero  
Wouldnt it oxidise it to nitrosyl bromide rather than bromine?

No, you can not have nitrosyl bromide just like that (except if you meant it as a minor equilibrium species). That is because nitrosyl bromide reacts with bromide anions and so do many other species involved. It is all a matter of an equilibrium resting on redox potentials. Such systems are called dynamic equilibriums (see J. Phys. Chem., 93 (1989) 2801–2807). Essentially if you could distil out bromine without it being accompanied by nitrogen oxides, this method could be of preparative use, but since this is not simple...
Yet understanding dynamic equilibriums (that is equilibriums with low equilibrium constants) is one of the basic knowledges you need to understand which path a chemical reaction take. Many reaction pathways, particularly in organic chemistry, are actually composed of a series of dynamic equilibriums leading toward a thermodinamicaly somewhat more stable product.




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