Random
International Hazard
Posts: 1018
Registered: 7-5-2010
Location: In ur closet
Member Is Offline
Mood: Energetic
|
|
Salt + Citric acid = HCl?
http://castboolits.gunloads.com/showthread.php?t=83978
I was reading the page above that says HCl is made with reaction of citric acid and table salt. Is this true? It looks false because citric acid alone
would react with zinc.
|
|
|
psychokinetic
National Hazard
Posts: 558
Registered: 30-8-2009
Location: Nouveau Sheepelande.
Member Is Offline
Mood: Constantly missing equilibrium
|
|
Acid + Salt = Acid-+Sa + Hlt, but I am still dubious.
“If Edison had a needle to find in a haystack, he would proceed at once with the diligence of the bee to examine straw after straw until he found
the object of his search.
I was a sorry witness of such doings, knowing that a little theory and calculation would have saved him ninety per cent of his labor.”
-Tesla
|
|
|
Anders Hoveland
Banned
Posts: 208
Registered: 15-6-2010
Member Is Offline
Mood: No Mood
|
|
It all depends on your perspective. Cl- and H+ will be dissolved in the same solution.
Does this mean HCl is made? Not quite, as the solution is still no more acidic than citric acid and you will (almost certainly) not be at boil out
HCl. You cannot boil out HCl from NaCl and water, for instance.
However, possibly fusing molten NaCl and citric acid together, but I think the citric acid will likely decompose before you get any HCl.
You can, however, boil out HCl from NaCl and H3PO4 solution, and H3PO4 is not a strong acid, so I would not "entirely" discount what you heard. I
think phosphoric acid is much stronger than citric though, so can more easily shift the equilibrium.
|
|
|
densest
Hazard to Others
Posts: 359
Registered: 1-10-2005
Location: in the lehr
Member Is Offline
Mood: slowly warming to strain point
|
|
pK1 of citric acid is about 3.1, so less than 1/1000 of the Cl- could be distilled out as HCl. Not a good route, but in desperation it would produce a
very little HCl.
|
|
|
![[*]](images/xpblue/default_icon.gif){kind=icon}
