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Author: Subject: In search of fading pigments
okitew
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[*] posted on 19-4-2019 at 00:19
In search of fading pigments


I'm looking for a pigment that will permanently disappear upon exposure to light/UV, say after a few hours.

Ideally, this pigment will be dark initially, cheap, and nontoxic. Any ideas?

The best option I've found so far is chlorophyll, but I need something darker that will fade more quickly.
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Mr. Rogers
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[*] posted on 21-4-2019 at 13:42


Nope! I never signed that contract!! See...
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okitew
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[*] posted on 23-4-2019 at 03:49


Quote: Originally posted by Mr. Rogers  
Nope! I never signed that contract!! See...

lol.... Nice.

But no, I actually need it for an obscure photography application.

Actually, I'll go so far as to say that it would be key to a new photographic process, and that I'd share that process with whoever submitted a workable solution, and if they think it's worth patenting, I'll support submitting it as a joint patent.

Disappearing ink won't work afaik because it must fade from light exposure only while dry.

[Edited on 23-4-2019 by okitew]
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phlogiston
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[*] posted on 23-4-2019 at 05:38


rhodopsin
methylene blue

You can also combine a radical-generating photoiniatior (eg benzoylperoxide, hydrogen peroxide, azobisisobutyronitrile, titanium dioxide) with an organic dye sensitive to radicals.

You may find this paper interesting:

Photoassisted bleaching of dyes utilizing TiO2 and visible light
Epling GA et al (2002) Chemosphere 46:561-570

http://nathan.instras.com/documentDB/paper-253.pdf




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okitew
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[*] posted on 24-4-2019 at 11:05


Quote:
Quote: Originally posted by phlogiston  

methylene blue

Why didn't I think of that? What can't that stuff do?
Quote: Originally posted by phlogiston  
You can also combine a radical-generating photoiniatior (eg benzoylperoxide, hydrogen peroxide, azobisisobutyronitrile, titanium dioxide) with an organic dye sensitive to radicals.

You may find this paper interesting:

Photoassisted bleaching of dyes utilizing TiO2 and visible light
Epling GA et al (2002) Chemosphere 46:561-570

http://nathan.instras.com/documentDB/paper-253.pdf

This is useful. Thanks!
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