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Author: Subject: Sulfur-heterocycles-brainstorming
BASF
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[*] posted on 18-2-2004 at 02:10
Sulfur-heterocycles-brainstorming


1)I drawed a sulfur-analogue of furoxan (nitrogens in place of nitrogen) using chemsketch....it has a wonderful density.
Sulfur formally is +6 here. +6 is possibly not very stable (hydrolizes). So steric protection is necessary.

2)ever thought of -S-S- bridges?

3) -C-SO2-C- in a (poly)cyclic-structure is very dense and provides sp2-hybridization(plane molecule=>higher densities).
It seems stable enough against moisture in a ring structure(steric protection?).

(i excluded -SF5 because it is popular anyway)

Just brain-storming....

[Edited on 23-2-2004 by BASF]
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