Sciencemadness Discussion Board
Not logged in [Login ]
Go To Bottom

Printable Version  
Author: Subject: How to tell borosilicate from non-borosilicate glass
SuperOxide
National Hazard
****




Posts: 410
Registered: 24-7-2019
Location: Devils Anus
Member Is Offline


[*] posted on 8-4-2022 at 17:18
How to tell borosilicate from non-borosilicate glass


I have a pretty decent amount of glassware, a lot of it I buy from Biotech Bargans and they buy it from colleges or companies that have labs and are shutting down or getting rid of excess glassware. A lot of what I get is Pyrex, Chemglass, Ace, Laboy, etc. And I try to steer clear of anything that's soda-lime. I know the difference between PYREX and pyrex. And according to this article, you can tell the difference between borosilicate and soda-lime by the color of the edges:
Quote:
If you have a dish at home that you want to test you can also try just looking at the hue. If you look at the edge of a dish and it is made out of soda-lime glass it will be a blueish-green hue. If the glass is Borosilicate then you should not see any color.


So this was my quick test that I would use, but the problem is - A lot of the PYREX stuff I have (some of it was new, some used) has that green color. And I tested some of this by cranking my hotplate up to pretty high temperatures and then putting the glassware on it, filled with cold water to see if it would break (as well as some other tests that break things like salsa jars pretty easily), and I haven't had any of them break.

I've never had any of these break or crack during any experiments/synthesis I've done, and I have definitely abused some of it quite a bit.

I posted some pictures to an Imgur album and put captions to each one. https://imgur.com/a/XEUXJB7

Im hoping someone can make some of these make sense. I could maybe believe that some of my Pyrex is fake, but all of it? No way. Some of it is from Germany, some from BiotechBargans, some from other sellers.




View user's profile View All Posts By User
Twospoons
International Hazard
*****




Posts: 1191
Registered: 26-7-2004
Location: Middle Earth
Member Is Offline

Mood: A trace of hope...

[*] posted on 8-4-2022 at 22:45


The green tint is from traces of iron in the glass. No reason why borosilicate couldn't have that too. I know you can get iron free soda-glass ( its just costs more), so it would not have that tint.
Borosilicate should be harder than soda, so there is always the scratch test.




Helicopter: "helico" -> spiral, "pter" -> with wings
View user's profile View All Posts By User
Chemetix
National Hazard
****




Posts: 369
Registered: 23-9-2016
Location: Oztrayleeyah
Member Is Offline

Mood: Wavering between lucidity and madness

[*] posted on 9-4-2022 at 02:27


All the glassware you have is borosilicate. There is practically no one making soda glass beaker like the ones you have. The decals seem like older Kimble glass at least on one item that I can make out, but that's circumstantial.

Really, the only scientific glass that commonly isn't borosilicate is burette or other volumetric ware. It's termed AR glass which is a type of soda.
View user's profile View All Posts By User
SuperOxide
National Hazard
****




Posts: 410
Registered: 24-7-2019
Location: Devils Anus
Member Is Offline


[*] posted on 9-4-2022 at 09:39


Quote: Originally posted by Twospoons  
The green tint is from traces of iron in the glass. No reason why borosilicate couldn't have that too. I know you can get iron free soda-glass ( its just costs more), so it would not have that tint.
Borosilicate should be harder than soda, so there is always the scratch test.

I see, that makes total sense. Thanks!

Quote: Originally posted by Chemetix  
All the glassware you have is borosilicate. There is practically no one making soda glass beaker like the ones you have. The decals seem like older Kimble glass at least on one item that I can make out, but that's circumstantial.

Right, but it's not like that doesn't happen. For example, I think in that Life After Detonation thread he said he was using a "Pyrox" soda-lime beaker without realizing it.




View user's profile View All Posts By User
Tsjerk
International Hazard
*****




Posts: 2829
Registered: 20-4-2005
Location: Netherlands
Member Is Offline

Mood: Mood

[*] posted on 10-4-2022 at 01:51


You can easily test what you have by boiling some water in the beaker and cooling that in an ice bath. Soda lime can't handle anything more than 30 - 40 degrees heat gradient over a certain distance. This gradient you can easily reach with boiling and freezing water while borosilicate should easily handle these gradients when not thick vacuum glass or something.
View user's profile View All Posts By User
unionised
International Hazard
*****




Posts: 4931
Registered: 1-11-2003
Location: UK
Member Is Offline

Mood: No Mood

[*] posted on 10-4-2022 at 12:03


I think Pyrex cookware is available in a range of colours.
The traditional way to tell soda glass from borosilicate was by refractive index.
Pyrex "disappears" in glycerine.
Not very useful if you are looking at a whole beaker, but handy if you are glassblowing and have lots of tune + rod.
View user's profile View All Posts By User
Dr.Bob
International Hazard
*****




Posts: 2449
Registered: 26-1-2011
Location: USA - NC
Member Is Offline

Mood: No Mood

[*] posted on 10-4-2022 at 17:35


I have seen borosilicate with clear, green, blue green and other tints, as stated, it is the iron content, which does not change the temperature stability. There are a few simple density and refractive index tests for boro verses soda lime, but almost all lab glass is boro. I'd guess there is some way to see with a UV-VIS or some other simple test, but rarely done.
View user's profile View All Posts By User
Twospoons
International Hazard
*****




Posts: 1191
Registered: 26-7-2004
Location: Middle Earth
Member Is Offline

Mood: A trace of hope...

[*] posted on 10-4-2022 at 18:42


Reading around I found the density and refractive index ranges for boro and soda overlap. Only distinctive diff I could find was hardness : 7 for boro, 6 for soda



Helicopter: "helico" -> spiral, "pter" -> with wings
View user's profile View All Posts By User
yobbo II
International Hazard
*****




Posts: 577
Registered: 28-3-2016
Member Is Offline

Mood: No Mood

[*] posted on 11-4-2022 at 14:07



Soda glass will fluoress under UV light a bit.
View user's profile View All Posts By User
SuperOxide
National Hazard
****




Posts: 410
Registered: 24-7-2019
Location: Devils Anus
Member Is Offline


[*] posted on 12-4-2022 at 15:10


I think what Twospoons and Chemetix mentioned is pretty convincing. The color is just from some iron contamination (which when I Google it, seems pretty accurate), and it would be very unlikely that anyone make such glassware in soda-lime, especially the 4 and 6L erlenmeyer flasks.

I was just being paranoid... lol
View user's profile View All Posts By User
Texium
Administrator
********




Posts: 3879
Registered: 11-1-2014
Location: Salt Lake City
Member Is Offline

Mood: Triturated

[*] posted on 12-4-2022 at 15:24


I think the color thing is a common misconception that has developed because most borosilicate lab ware is colorless, whereas most soda lime glass has a green tint. Really it’s a correlation-not-causation situation. It’s more likely that higher value borosilicate glass destined for lab ware will use higher quality ingredients with fewer impurities. Thus, no color.



Come check out the Official Sciencemadness Wiki
They're not really active right now, but here's my YouTube channel and my blog.
View user's profile Visit user's homepage View All Posts By User

  Go To Top