Elking_around
Harmless
Posts: 9
Registered: 23-1-2023
Member Is Offline
|
|
Access to ACS Publications needed for a patent
Hello, could anyone with an access to ACS upload in this tread or email me the patent below ?
https://pubs.acs.org/doi/pdf/10.1021/jo01314a042
patentsaregreat76@protonmail.me
|
|
|
solo
International Hazard
Posts: 3931
Registered: 9-12-2002
Location: Estados Unidos de La Republica Mexicana
Member Is Offline
Mood: ....getting old and drowning in a sea of knowledge
|
|
....next time make your requests in wanted references thread
Palladium-Catalyzed Oxidation of Terminal
Olefins to Methyl Ketones by Hydrogen Peroxide
Michel Roussel and Hubert Mimoun
J. Org. Chem.
1980,45, 5387-5390 5387
....Narrative
The use of the Wacker PdC12-CuC1, system for the oxidation
of higher terminal olefins to methyl ketones
presents major drawbacks, i.e., formation of chlorinated,
aldehydic, and internal ketones as byproducts, precipitation
of metallic palladium, and corrosion.'V2 Some improvements
have been achieved by using basic3 or alcoholic4
solvents and phase-transfer catalyst^,^ but the disadvantages
have not been completely eliminated. We have
previously described a highly selective procedure using
rhodium catalysts6 and involving molecular oxygen activation,'
but a deactivation of the catalyst system was observed.
We have also recently synthesized a new class of
stable palladium alkyl peroxidic complexes with the formula
[RCO,PdOO-t-Bu],; they undergo an oxygen transfer
to terminal olefins through a pseudocyclic peroxypalladation
mechanism (eq l
Attachment: Palladium-Catalyzed Oxidation of Terminal Olefins to Methyl Ketones by Hydrogen Peroxide.pdf (511kB)
This file has been downloaded 82 times
[Edited on 17-4-2023 by solo]
It's better to die on your feet, than live on your knees....Emiliano Zapata.
|
|
|
Elking_around
Harmless
Posts: 9
Registered: 23-1-2023
Member Is Offline
|
|
Thank you so much solo and naturally, although I was unaware of it's existence unless your not being specific ? Could you let me know where it is, I
didn't see any thread like that within the pinned threads from each category of this forum.
[Edited on 18-4-2023 by Elking_around]
|
|
|
Dr.Bob
International Hazard
Posts: 2606
Registered: 26-1-2011
Location: USA - NC
Member Is Offline
Mood: No Mood
|
|
There are also a few places to get patents free off of the internet, like Google patents and a few tools in Europe, which also work in the US. You
have to ask for permission to get to the references section from one of the moderators.
|
|
|
![[*]](images/xpblue/default_icon.gif){kind=icon}
