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Author: Subject: Cu(NO3)2 + Sn = ?
Romix
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[*] posted on 9-10-2025 at 08:32
Cu(NO3)2 + Sn = ?


CuNO3 + Sn = Stannic acid and no visible displacement, nitrate was lightly acidic.



[Edited on 9-10-2025 by Romix]
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chempyre235
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[*] posted on 9-10-2025 at 10:36


Did you get any fumes? Any precipitate? Color shift?



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Romix
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[*] posted on 9-10-2025 at 10:39


Quote: Originally posted by chempyre235  
Did you get any fumes? Any precipitate? Color shift?
No fumes, precipitate white jelly Stannic acid, blue solution before and after addition of Sn.
DSC00099.JPG.2a955dd456bbf3d35ae045b8eb751db7.jpg - 128kB

[Edited on 9-10-2025 by Romix]
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DraconicAcid
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[*] posted on 9-10-2025 at 10:57


Odd. Surely you mean Cu(NO3)2, btw.

How long did you leave it?




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Romix
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[*] posted on 9-10-2025 at 11:06


Quote: Originally posted by DraconicAcid  
Odd. Surely you mean Cu(NO3)2, btw.

How long did you leave it?

Yes, sorry, wrong valency, precipitate formed almost immediately.
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[*] posted on 9-10-2025 at 11:14


The nitrate, was it bought or you made it?



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[*] posted on 9-10-2025 at 11:15


The stannic hydroxide ppt is going to be voluminous. Leaving it sitting for a while, and you'll probably start to see copper metal forming.



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Romix
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[*] posted on 9-10-2025 at 11:18


Quote: Originally posted by bnull  
The nitrate, was it bought or you made it?

I made it.
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Romix
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[*] posted on 9-10-2025 at 11:19


Quote: Originally posted by DraconicAcid  
The stannic hydroxide ppt is going to be voluminous. Leaving it sitting for a while, and you'll probably start to see copper metal forming.

Was there for couple of days, with out any visible displacement.
Maybe not enough Sn and solution too acidic, I will try this experiment again.

[Edited on 9-10-2025 by Romix]
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chempyre235
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[*] posted on 9-10-2025 at 11:33


@Romix: In the picture you posted, it appears that you'd started to dissolve circuit boards in the solution. Was this after the tin, or was it your source of tin?



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[*] posted on 9-10-2025 at 11:47


Quote: Originally posted by chempyre235  
@Romix: In the picture you posted, it appears that you'd started to dissolve circuit boards in the solution. Was this after the tin, or was it your source of tin?

Source of tin.
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[*] posted on 9-10-2025 at 12:24


Quote:
Source of tin.

Source of tin and lead, you mean.




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[*] posted on 9-10-2025 at 12:28


And probably several other metals.



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Romix
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[*] posted on 9-10-2025 at 12:39


Quote: Originally posted by bnull  
Quote:
Source of tin.

Source of tin and lead, you mean.

No, lead free solder used on PCBs.
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[*] posted on 9-10-2025 at 12:43


Source of tin and silver, then. But remember that not every PCB uses lead free solder, what with those damned whiskers and all.



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[*] posted on 9-10-2025 at 12:44


Quote: Originally posted by chempyre235  
And probably several other metals.

No, only Tin able to displace in these.
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[*] posted on 9-10-2025 at 12:45


How did you make the nitrate? Acid plus copper?



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[*] posted on 9-10-2025 at 12:51


Quote: Originally posted by bnull  
How did you make the nitrate? Acid plus copper?
3% nitric + Copper, correct.
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