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Author: Subject: New Energetic Materials - Current Research
PHILOU Zrealone
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Mood: Bis-diazo-dinitro-hydroquinonic

[*] posted on 22-10-2017 at 07:15


Quote: Originally posted by Mr.Greeenix  
-Ammonium-dinitroguanidine (ADNQ)
-1,7-diamino-1,7-dinitrimino-2,4,6-trinitro-2,4,6-triazaheptane (APX)


Both Materials possess very good detonation parameters:

APX (Vdet = 9540 m·s–1, pC–J = 395kbar, Qv = –5935 kJ·kg–1)
ADNQ (Vdet = 9066 m·s–1, pC–J = 332 kbar, Qv = –5193 kJ·kg–1),


with moderate safety parameters:

APX: IS ≥ 3 J, FS ≥ 80 N and ESD ≥ 0.1 J
ADNQ: IS ≥ 10 J, FS ≥ 252 N and ESD ≥ 0.4 J,


Two very interesting compounds, however preparing dinitroguanidine seems to be a problem i think.




Nice information thanks...

Strange that they only think to allow monopotassium salt to enter into reaction and not the dipotassium salt... that way you may get other interesting goodies... like imino-RDX if cyclisation or n-poly-ITNTAH (linear poly-imino-trinitro-triazahexane)
See annexed drawing... :);):P
Based onto the density increase effect observed for polymers... one should expect poly-ITNTAH to be denser than APX...but also to display a lower or equal sensitivity to shock...

APX is named by them as 1,7-diamino-1,7-dinitrimino-2,4,6-trinitro-2,4,6-triazaheptane but this could be aswel be named 2,8-diimino-1,3,5,7,9-pentanitro-1,3,5,7,9-pentaazanonane (following me more appropriate) (DIPNPAN)

ClCH2-NNO2-CH2Cl + 2 O2N-NK-C(=NH2(+))-N(+)-NO2 -->
O2N-N(-)-C(=NH2(+))-NNO2-CH2-NNO2-CH2-NNO2-C(=NH2(+))-N(-)-NO2

APX, imino-RDX and n-poly-ITNTAH.jpg - 129kB




PH Z (PHILOU Zrealone)

"Physic is all what never works; Chemistry is all what stinks and explodes!"-"Life that deadly disease, sexually transmitted."(W.Allen)
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Laboratory of Liptakov
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[*] posted on 1-3-2018 at 01:37
new EM on Cu - KClO3 base


Some message from research a new energetic material from 16.2.2018
http://sci-hub.tw/https://pubs.acs.org/doi/abs/10.1021/jacs....

pic 1.jpg - 342kB




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[*] posted on 4-3-2018 at 20:48


LoL, What does this mean, have you produced it? my chemistry is not well enough...
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[*] posted on 5-3-2018 at 03:15


Haha....not. All news energetics matrials in not from my lab. Preparation is difficult. Only info for someone, for everybody.



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[*] posted on 20-3-2018 at 23:24


Recently I tried to make a methanolic solution of hydrazine mixing hydrazine sulfate and calcium hydroxide in methanol, then filtering. But this way it's difficult to get a concentrated solution due to low methanol volume required. My goal is to sensitized NM.

Could dissolving hydrazine sulfate in sodium methoxide solution and the filtering the sodium sulfate work?
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[*] posted on 21-3-2018 at 00:26


Your goal is some nitromethane gel...reliable sensitive on No.8 ? Or liquide NM as solution ? On No.8 cap sensitive ?



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[*] posted on 21-3-2018 at 12:48


Quote: Originally posted by Laboratory of Liptakov  
Your goal is some nitromethane gel...reliable sensitive on No.8 ? Or liquide NM as solution ? On No.8 cap sensitive ?


My goal is a PLX-type liquid exposive, capable of detonation by 0.5 grams MHN. I hope something like 90% NM/10% hydrazine solution in methanol works.
For sensitizing NM, there are cheaper amines like hexamine, I tried but it requires a big booster. I even tried sensitizing NM with sodium nitrite, just for fun, and also failed.
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[*] posted on 22-3-2018 at 00:40


You can try this gel. Nitrocellulose (12,4N+) 10%, ( 8 -15) microballoons 2% (1 -
3) aluminium bright type for colors 5%. (5 -10). + NM 80 %. Were tested again and again without fails. From 0,3g ETN.




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[*] posted on 23-3-2018 at 12:33


Quote: Originally posted by Laboratory of Liptakov  
You can try this gel. Nitrocellulose (12,4N+) 10%, ( 8 -15) microballoons 2% (1 -
3) aluminium bright type for colors 5%. (5 -10). + NM 80 %. Were tested again and again without fails. From 0,3g ETN.


Thank you, very useful!
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