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Author: Subject: New Energetic Materials - Current Research
PHILOU Zrealone
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Mood: Bis-diazo-dinitro-hydroquinonic

[*] posted on 22-10-2017 at 07:15


Quote: Originally posted by Mr.Greeenix  
-Ammonium-dinitroguanidine (ADNQ)
-1,7-diamino-1,7-dinitrimino-2,4,6-trinitro-2,4,6-triazaheptane (APX)


Both Materials possess very good detonation parameters:

APX (Vdet = 9540 m·s–1, pC–J = 395kbar, Qv = –5935 kJ·kg–1)
ADNQ (Vdet = 9066 m·s–1, pC–J = 332 kbar, Qv = –5193 kJ·kg–1),


with moderate safety parameters:

APX: IS ≥ 3 J, FS ≥ 80 N and ESD ≥ 0.1 J
ADNQ: IS ≥ 10 J, FS ≥ 252 N and ESD ≥ 0.4 J,


Two very interesting compounds, however preparing dinitroguanidine seems to be a problem i think.




Nice information thanks...

Strange that they only think to allow monopotassium salt to enter into reaction and not the dipotassium salt... that way you may get other interesting goodies... like imino-RDX if cyclisation or n-poly-ITNTAH (linear poly-imino-trinitro-triazahexane)
See annexed drawing... :);):P
Based onto the density increase effect observed for polymers... one should expect poly-ITNTAH to be denser than APX...but also to display a lower or equal sensitivity to shock...

APX is named by them as 1,7-diamino-1,7-dinitrimino-2,4,6-trinitro-2,4,6-triazaheptane but this could be aswel be named 2,8-diimino-1,3,5,7,9-pentanitro-1,3,5,7,9-pentaazanonane (following me more appropriate) (DIPNPAN)

ClCH2-NNO2-CH2Cl + 2 O2N-NK-C(=NH2(+))-N(+)-NO2 -->
O2N-N(-)-C(=NH2(+))-NNO2-CH2-NNO2-CH2-NNO2-C(=NH2(+))-N(-)-NO2

APX, imino-RDX and n-poly-ITNTAH.jpg - 129kB




PH Z (PHILOU Zrealone)

"Physic is all what never works; Chemistry is all what stinks and explodes!"-"Life that deadly disease, sexually transmitted."(W.Allen)
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