Sciencemadness Discussion Board
Not logged in [Login ]
Go To Bottom

Printable Version  
Author: Subject: Elusive Reaction
blue_vitriol
Harmless
*




Posts: 11
Registered: 28-12-2012
Member Is Offline

Mood: No Mood

[*] posted on 25-4-2013 at 17:37
Elusive Reaction


I have been searching and I cannot fine the products for the following reaction:
Sb2S3 + KOH
View user's profile View All Posts By User
elementcollector1
International Hazard
*****




Posts: 2684
Registered: 28-12-2011
Location: The Known Universe
Member Is Offline

Mood: Molten

[*] posted on 25-4-2013 at 18:56


At a guess, and assuming you're roasting the stuff:
Sb2S3 + 3KOH -> 3K2S + Sb(OH)3
2Sb(OH)3 -> Sb2O3 + 3H2O
Or, possibly:
Sb2S3 + KOH -> KSb(OH)6 (un-balance-able)

This is speculation from general knowledge of chemistry (though I did have to look up if there is such thing as an "antimonate ion" on Wikipedia).




Elements Collected:52/87
Latest Acquired: Cl
Next in Line: Nd
View user's profile View All Posts By User
woelen
Super Administrator
*********




Posts: 7977
Registered: 20-8-2005
Location: Netherlands
Member Is Offline

Mood: interested

[*] posted on 25-4-2013 at 22:37


The last thing is wrong. You write yourself that this equation is unbalanceable. If an equation is unbalanceable mathematically, then one for sure knows that it cannot occur in reality!

The problem with your equation is that Sb at the left is in oxidation state +3 and at the right it is in oxidation state +5 and besides that, no sulphur is at the right.

Sb2S3 + KOH also can react in aqueous solution. This may lead to thioantimonites (one or more oxygen atoms replaced by sulphur). The Sb2S3, however, must be freshly precipitated (the orange stuff). The black crystalline stuff is more inert and only reacts with KOH with great difficulty, but I'm not 100% sure whether it is completely unreactive or not.




The art of wondering makes life worth living...
Want to wonder? Look at https://woelen.homescience.net
View user's profile Visit user's homepage View All Posts By User
elementcollector1
International Hazard
*****




Posts: 2684
Registered: 28-12-2011
Location: The Known Universe
Member Is Offline

Mood: Molten

[*] posted on 26-4-2013 at 05:27


I didn't think it it would work, but decided to include in the realm of possibility. And then forgot the sulfur. :D




Elements Collected:52/87
Latest Acquired: Cl
Next in Line: Nd
View user's profile View All Posts By User

  Go To Top