symboom
International Hazard
Posts: 1143
Registered: 11-11-2010
Location: Wrongplanet
Member Is Offline
Mood: Doing science while it is still legal since 2010
|
|
Tetramine nickel chlorate
After working with tetramine nickel perchlorate which is insouble in water
The procedure
Nickel sulfate is reacted with sodium carbonate
To form nickel carbonate this is reacted with tartaric acid
To form soluble nickel tartarate this is the added to a hot solution of potassium chlorate to form insouble potassium tartrate.
nickel chlorate is then added to ammonia to form ammonium chlorate and nickel hydroxide then more ammonia to form tetramine nickel chlorate which
should be insoluble
[Edited on 29-3-2017 by symboom]
|
|
|
myristicinaldehyde
Hazard to Others
Posts: 166
Registered: 23-4-2016
Location: .͐͌ ͛҉̻̫̰̻̖E̮ͮ̐́̚ ̢̗̅̉ͩ͂̒̌.̯̻̺̯̀̎͂̄ͩ̚
Member Is Offline
Mood: сорок пять
|
|
Symboom, your post is blank.
If we don't study the mistakes of the future we're doomed to repeat them for the first time.
|
|
|
symboom
International Hazard
Posts: 1143
Registered: 11-11-2010
Location: Wrongplanet
Member Is Offline
Mood: Doing science while it is still legal since 2010
|
|
I know accidentally submitted
I guess I could still call it scary nickel complex which was what I was going to label it as
[Edited on 29-3-2017 by symboom]
|
|
|
PHILOU Zrealone
International Hazard
Posts: 2893
Registered: 20-5-2002
Location: Brussel
Member Is Online
Mood: Bis-diazo-dinitro-hydroquinonic
|
|
@Symboom,
If it is copper then it is tetracoordinated --> Copper tetramine chlorate
If it is nickel, cobalt, zinc, cadmium then it is hexacoordinated --> Nickel hexamine perchlorate or chlorate
From now on your post is only a previsional synthesis...beware that NH4ClO3 is already unstable...so the incorporation of a catalytic metallic core
may increase this unstability so indeed to be considered scary.
Good luck and dont forget to post pictures and testing results of the obtained complex (flame sensitivity, heat confinement test, impact test)
PH Z (PHILOU Zrealone)
"Physic is all what never works; Chemistry is all what stinks and explodes!"-"Life that deadly disease, sexually transmitted."(W.Allen)
|
|
|
symboom
International Hazard
Posts: 1143
Registered: 11-11-2010
Location: Wrongplanet
Member Is Offline
Mood: Doing science while it is still legal since 2010
|
|
Your right got do used to the copper complex just realized I have the wrong complex name title should be hexamine nickel chlorate unfortunately I cant
change the title
It's a blue green precipitate very little formed I hate the potassium chlorate and ammonium tartrate method It flared up like black powder I think its
impure going to try barium chlorate and mix it with the nickel sulfate then add ammonia
[Edited on 1-4-2017 by symboom]
[Edited on 1-4-2017 by symboom]
|
|
|
symboom
International Hazard
Posts: 1143
Registered: 11-11-2010
Location: Wrongplanet
Member Is Offline
Mood: Doing science while it is still legal since 2010
|
|
Stubborn complex
So I have been trying to make hexamine nickel chlorate
Then tried to make hexmethyleneamine nickel chlorate
And last but not least
Ethylamine nickel chlorate
Hexamethylene nickel chlorate solution added to ethanol white percipitate forms it Is energetic probally ammonium chlorate
Cant seem to get a metal chlorate complex
There has got to be more than hexamine nickel perchlorate
|
|
|
PHILOU Zrealone
International Hazard
Posts: 2893
Registered: 20-5-2002
Location: Brussel
Member Is Online
Mood: Bis-diazo-dinitro-hydroquinonic
|
|
Quote: Originally posted by symboom  | Stubborn complex
So I have been trying to make hexamine nickel chlorate
Then tried to make hexmethyleneamine nickel chlorate
And last but not least
Ethylamine nickel chlorate
Hexamethylene nickel chlorate solution added to ethanol white percipitate forms it Is energetic probally ammonium chlorate
Cant seem to get a metal chlorate complex
There has got to be more than hexamine nickel perchlorate |
If it is white there is more than probably no nickel into the precipitate...nickel complexes and precipitates are usually colorfull.
Instead of (tetra or hexa) ethylamine nickel (II) chlorate
Ni(C2H5-NH2)4(H2O)2(ClO3)2
Ni(C2H5-NH2)6(ClO3)2
You should focus onto stronger complex of ethylenediamine...this will improve the oxygen balance.
Ni(H2N-C2H4-NH2)3(ClO3)2
PH Z (PHILOU Zrealone)
"Physic is all what never works; Chemistry is all what stinks and explodes!"-"Life that deadly disease, sexually transmitted."(W.Allen)
|
|
|
![[*]](images/xpblue/default_icon.gif){kind=icon}
