D4RR3N
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Potassium compounds
First post on this forum, a reader for a while.
I am interested in the following potassium compounds but had no luck in finding any info or suppliers. Firstly I would like to know if these compounds
are possible and secondly how could I produce them in a small quantity from relatively common chemicals.
KCuO2
KAgO2
KWO2
"edit"
I was looking at the archives and noticed that “brauer” is often thought as an authority on similar compounds, sorry to ask but who is Brauer and
what book?
[Edited on 9-1-2007 by D4RR3N]
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Bromine
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potassium cuprate can be made by disolving CuO in KOH solution.
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woelen
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I don't think the other compounds exist.
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falconZ
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Handbook of Preparative Inorganic Chemistry,
by Georg Brauer
Publisher: Academic Press (1963)
ASIN: B000M0IVDQ
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D4RR3N
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| Quote: | Originally posted by Bromine
potassium cuprate can be made by disolving CuO in KOH solution. |
Thanks, will this produce KCuO2 or KCuO3 ??? Is it just a matter of heating the solution to get the KCuO2 solid?
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D4RR3N
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| Quote: | Originally posted by falconZ
Handbook of Preparative Inorganic Chemistry,
by Georg Brauer
Publisher: Academic Press (1963)
ASIN: B000M0IVDQ |
Just looked on Amazon $595
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kaviaari
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| Quote: | Originally posted by D4RR3N
Just looked on Amazon $595 |
Just look from http://www.sciencemadness.org/library/index.html  Those books are lifesavers
to any chemist!
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h0lx
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Wolframates exist, but I believe they were WO3 or WO4
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woelen
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Wolframates (tungstates) do exist, but they have tungsten in the +6 oxidation state, the formula KWO2 suggests a +3 oxidation state. Actually I have
some tungstate, the compound Na2WO4.
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guy
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When you acidify tungstates (and molybdenates), you get a cluster...but its not just a random cluster, its a set amount; ive always wondered why? If
anyone knows the chemistry behind that.
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Ozone
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I'm too tired now to explain all of that (clustering) in detail (in fact, clusters are a hot-topic these days). Check out coordination number and the
18 electron rule (which includes 14, 24, and others...). It is quite do-able. For example, to have metal-metal- quadruple bonds; see
tetrabutylammonium-octachlorodirhenate, for example (I had to make it as an undergrad; they blew it up at Sandia).
Coordination occurs frequently without a change in formal oxidation state (excepting, usually, oxidative addition and reductive eliminations); for
more on this look at olefin pi complexes.
Hope that helps, goodnight all,
O3
-Anyone who never made a mistake never tried anything new.
--Albert Einstein
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