symboom
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Oxone (peroxymonopersulfate) and its uses as an oxidizer
Potassium peroxymonopersulfat
Finding organic oxidation reactions with oxone is hard
reacts with acetone to produce dimethyldioxirane
monoethanolamine oxidized to mononitroethanol??
MPS is a versatile oxidant. It oxidizes aldehydes to carboxylic acids; in the presence of alcoholic solvents, the esters may be obtained.[3] Internal
alkenes may be cleaved to two carboxylic acids (see below), while terminal alkenes may be epoxidized.
Alcohol to aldehyde
Aldehyde to carboxlic acid
Acetylene to oxalic acid
Ethylene to ethylene glycol
Vs https://www.nextgurukul.in/nganswers/ask-question/answer/Ace...
Acetylene reacts with Cold KMnO4 to form formic acid and on reaction with hot KMnO4 it forms Oxalic acid.
[Edited on 12-6-2017 by symboom]
[Edited on 12-6-2017 by symboom]
[Edited on 12-6-2017 by symboom]
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AvBaeyer
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The literature is loaded with references using ozone as an oxidizer. For example, check out Fieser and Fieser "Reagents for Organic Synthesis." Also
see the reagents database at paperplane.io if you do not have access to a library. Wikipedia is completely useless. You could also go to the ACS
website and do a search using oxone as the search term. Though you will not have direct access to the papers, you willl be able to get a good look at
some of the literature available.
Things are not so truly hard to find - it is just learning where and how to look. It takes practice.
AvB
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Velzee
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Quote: Originally posted by AvBaeyer  | The literature is loaded with references using ozone as an oxidizer. For example, check out Fieser and Fieser "Reagents for Organic Synthesis." Also
see the reagents database at paperplane.io if you do not have access to a library. Wikipedia is completely useless. You could also go to the ACS
website and do a search using oxone as the search term. Though you will not have direct access to the papers, you willl be able to get a good look at
some of the literature available.
Things are not so truly hard to find - it is just learning where and how to look. It takes practice.
AvB |
OP is referring to oxone not ozone.
Check out the ScienceMadness Wiki: http://www.sciencemadness.org/smwiki/index.php/Main_Page
"All truth passes through three stages. First, it is ridiculed. Second, it is violently opposed. Third, it is accepted as being self-evident."
—Arthur Schopenhauer
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Melgar
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I think the "ozone" was just a typo or a phone autocorrect thing. The second time it's mentioned AvBaeyer wrote "oxone", and so clearly understood
what OP was referring to.
The first step in the process of learning something is admitting that you don't know it already.
I'm givin' the spam shields max power at full warp, but they just dinna have the power! We're gonna have to evacuate to new forum software!
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AvBaeyer
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Melgar,
Thank you for your post. Indeed it was a typo. I am not used to my small ipad keyboard and the z and x are next to each other. Need to do better
proofreading.
AvB
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symboom
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Oxone combination with permanganate
Now this is going to sound odd but potassium peroxymonosulfate has no reaction with potassium permanganate two powerful oxidizers together what could
test if its more powerful than each alone
KMnO4 + 2 KF + 10 HF + 3 H2O2 → 2 K2MnF6 + 8 H2O + 3 O2
KMnO4 + KHSO5 + KF → K2MnF6 + unimportant stuff
Might not need HF because oxone is an acidic triple salt and possible form HF from KF in solution
Substituting oxone for hydrogen peroxide
Would this work
Peroxide and permanganate decompose so maybe anyone what to try I have no fluoride compounds :-(
[Edited on 13-6-2017 by symboom]
[Edited on 13-6-2017 by symboom]
[Edited on 13-6-2017 by symboom]
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Melgar
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Peroxide and permanganate are kid of an exception, although peroxide does a similar thing with other oxidizers. Because they are losing oxygen in the
+0 state, from an initial negative state, it's actually the oxygen being oxidized, and the other two being reduced.
Mixing strong oxidizers together is like mixing strong acids together, or mixing strong bases together. Most likely, no reaction is the EXPECTED
result.
[Edited on 6/15/17 by Melgar]
The first step in the process of learning something is admitting that you don't know it already.
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AJKOER
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See my comments at https://www.sciencemadness.org/whisper/viewthread.php?tid=71... .
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Velzee
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| Quote: Originally posted by Melgar |
I think the "ozone" was just a typo or a phone autocorrect thing. The second time it's mentioned AvBaeyer wrote "oxone", and so clearly understood
what OP was referring to. |
Oops, my apologies.
Check out the ScienceMadness Wiki: http://www.sciencemadness.org/smwiki/index.php/Main_Page
"All truth passes through three stages. First, it is ridiculed. Second, it is violently opposed. Third, it is accepted as being self-evident."
—Arthur Schopenhauer
"¡Vivá Cristo Rey!"
—Saint José Sánchez del Río |
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