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Author: Subject: comparison between CaCO3 and ZnCO3
sudhiarta
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smile.gif posted on 29-4-2018 at 19:20
comparison between CaCO3 and ZnCO3


Guys I need help with my research

I'm having problem with CaCO3 scale and I'm gonna use ZN2+ as intervention agent so that CaCO3 can be minimalize. I've try to analyze it with galvanic volta prediction and I got that the reaction between Zn and Ca can be a spontaneous reaction.

the reaction is Ca(HCO3)2 + ZN => Zn(HCO3)2 + Ca

my questions are :
1. is my reaction correct ?
2. we know that ZnCo3 isn't soluble in water , is it safer than CaCO3 ??
3. maybe anyone can give me more about ZnCO3 physical and chemical properties would be better

a fast respon would very appreciate guys really need help

thank you
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[*] posted on 29-4-2018 at 20:16


I can't think of much that would be safer than calcium carbonate. And no, zinc is not going to displace calcium from solution.



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sudhiarta
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[*] posted on 29-4-2018 at 20:33


so could u give me the most possibly reaction between Zinc and CaCO3 if we want to remove the scaling that happened ?
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[*] posted on 30-4-2018 at 01:30


Zinc and CaCO3 do not react at all, unless maybe when heated at 1000 C or so.

If you have hard water (with a lot of Ca(HCO3)2 dissolved in it, then you could use calgon to minimize formation of calcium carbonate or pre-heat the water before it gets in sensitive equipment. This leads to formation of calcium carbonate outside of the sensitive equipment: Ca(HCO3)2 --> CaCO3 + H2O + CO2

You also every now and then can descale the equipment, e.g. with dilute sulfamic acid or dilute acetic acid.




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