Miscibility

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Miscibility is the property of substances to mix in all proportions, forming a homogeneous solution. If the two substances are soluble, but do not mix in all proportions, they are soluble, but not miscible. Although the term is most often applied to liquids, it can also be used to gases and even solids.

The table below displays the miscibility of various liquids, at standard conditions (T = 20 °C, p = 1 atm). The liquids are considered pure and free of other solvents or water (expect water of course).

Miscibility of various solvents

Solvent 1,2-Dichloroethane 1,4-Dioxane 2,2,4-Trimethylpentane Acetaldehyde Acetic acid Acetone Acetonitrile Benzene Butane Butanol Butyl acetate Carbon disulfide Carbon tetrachloride Chloroform Cyclohexane Dichloromethane Diethyl ether Diisopropyl ether Dimethylformamide Dimethyl sulfoxide Ethanol Ethyl acetate Ethylene glycol Ethylenediamine Formic acid Glycerol Heptane Hexane Isopropanol Limonene Methanol Methyl ethyl ketone Methyl formate Methyl tert-butyl ether Nitromethane Octyl acetate Pentane Petroleum ether Propanol Propylene carbonate Propylene glycol Pyridine Schweizer's reagent Tetrahydrofuran Trichloroethylene Toluene Water Xylene
1,2-Dichloroethane
1,4-Dioxane
2,2,4-Trimethylpentane
Acetaldehyde
Acetic acid
Acetone
Acetonitrile
Benzene
Butane
Butanol
Butyl acetate
Carbon disulfide
Carbon tetrachloride
Chloroform
Cyclohexane
Dichloromethane
Diethyl ether
Diisopropyl ether
Dimethylformamide
Dimethyl sulfoxide
Ethanol
Ethyl acetate
Ethylene glycol
Ethylenediamine
Formic acid
Glycerol
Heptane
Hexane
Isopropanol
Limonene
Methanol
Methyl ethyl ketone
Methyl formate
Methyl tert-butyl ether
Nitromethane
Octyl acetate
Pentane
Petroleum ether
Propanol
Propylene carbonate
Propylene glycol
Pyridine
Schweizer's reagent
Tetrahydrofuran
Trichloroethylene
Toluene
Water
Xylene

References