Difference between revisions of "SN1"
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Revision as of 16:27, 10 February 2016
SN1 is an acronym for an Nucleophilic substitution reaction where the rate of the reaction is dependent on the concentration of one of the reactants:
(S)substitution (N)Nucleophilic (1)reactant determines rate.
Counter intuitively, SN1 reactions proceed in two steps, the first of which is the rate determining step and the second of which occurs almost instantaneously. A good analogy is sitting down on a park bench where all the benches are occupied by sleeping vagrants. You wait for one to wake up and shamble off - then you sit down.
The more vagrants you have, the faster one will wake up and vacate a bench. In this scenario we call the vagrant a leaving group. The leaving group is an anion. When it leaves, the park bench becomes a carbocation, and is ready for you - it's Nucleophile.
to be continued.