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Aldehyde oxidation
[rquote=659774&tid=157419&author=DraconicAcid]
Is Sodium Perborate in Acetic Acid, not suit ...
12-5-2021 at 18:05
by: clearly_not_atara
Anhydrous Aluminum Chloride
The attached ref gives procedures for the preparation of anhydrous FeCl2 and CrCl2. Either of these ...
12-5-2021 at 12:58
by: clearly_not_atara
Aldehyde oxidation
Methanol is the least susceptible to oxidation. I don't recommend it at all, but if you had to choos ...
11-5-2021 at 05:29
by: clearly_not_atara
Aldehyde oxidation
^slowly. In a cold solution it will give metastable AcOCl. It's already used in the paper, after all ...
11-5-2021 at 04:53
by: clearly_not_atara
Making silicon tetrachloride
You will not successfully convert Si(OR)4 to SiCl4, even if you can obtain the former; the affinity ...
9-5-2021 at 16:19
by: clearly_not_atara
Separating cloudy suspension of Benzyl Alcohol on water
Shouldn't you want more strongly immiscible liquids? Anisole/water seems like a better choice than B ...
9-5-2021 at 13:04
by: clearly_not_atara
methanol/ionic liquid electroplaing of metals
pKa H2O: 15.7
pKa MeOH: 15.5

Methanol gets you practically nothing as far as stability for elect ...
7-5-2021 at 11:59
by: clearly_not_atara
Question about Ethyl Bromide
The production of toxic levels of carbonyl bromide in an EtBr flame is not very likely. Unlike phosg ...
6-5-2021 at 09:55
by: clearly_not_atara
Reduction of Sodium using organic solvent
^It's not as simple as it sounds. Everything must be anhydrous, the operating voltage must be carefu ...
5-5-2021 at 16:13
by: clearly_not_atara
Ketalization of Phenol
Hm, wait. The Birch reduction of phenol or anisole gives the 3-cyclohexenone, not 2-cyclohexenone or ...
5-5-2021 at 03:55
by: clearly_not_atara
Green fluorobenzene for nontoxic bisphenol A replacements
[file]88395[/file]

The direct fluorination of benzene with CuF2 seems like a solution waiting fo ...
1-5-2021 at 11:33
by: clearly_not_atara
Ketalization of Phenol
What you can do is a Birch reduction of phenol to alpha-cyclohexenone. This might then form a ketal ...
30-4-2021 at 15:24
by: clearly_not_atara
preparation/acquisition of acetone (weird problem ik)
What a strange problem to have. If you are not planning to use acetone as a reagent (as for indigo), ...
29-4-2021 at 17:54
by: clearly_not_atara
Acetic anhydride preparation
Recently a number of people on a sister forum have reported success with the acetonitrile/HCl method ...
28-4-2021 at 15:30
by: clearly_not_atara
Path to 4-Anisaldehyde
I have read recently a paper suggesting that methanolic deacetylation is quite effective. The solubi ...
28-4-2021 at 14:56
by: clearly_not_atara
Path to 4-Anisaldehyde
Uniquely for an alkene, anethole can be cleaved to anisaldehyde by chromic acid:

http://www.scien ...
27-4-2021 at 17:45
by: clearly_not_atara
Preparation of elemental phosphorus
See ref for LiCl-KCl eutectic production reference:

https://iopscience.iop.org/article/10.1149/1. ...
27-4-2021 at 10:14
by: clearly_not_atara
Preparation of elemental phosphorus
njl: You've used a density of 1 for the molten salt (I said "liter", you said "kilogram"), which is ...
27-4-2021 at 09:04
by: clearly_not_atara
Path to 4-Anisaldehyde
Cyanide is an especially weird poison because it is far more dangerous to some people than others. I ...
27-4-2021 at 08:33
by: clearly_not_atara
Path to 4-Anisaldehyde
Start with the substrate. 4-methoxytoluene is electron-rich and therefore easily oxidized. As such, ...
27-4-2021 at 08:01
by: clearly_not_atara
What makes liquor taste like rubbing alcohol?
IIRC, alcohol produced by the hydration of ethylene is legal for food use if it's pure enough. Behol ...
26-4-2021 at 10:57
by: clearly_not_atara
Hydrazine
I think you could make methyl carbazate via the reaction of hydroxyurea with dimethyl carbonate as d ...
26-4-2021 at 09:46
by: clearly_not_atara
Dichromate overoxidation
It seems like activated manganese dioxide would be the first port of call for indole-3-carbinol, sin ...
24-4-2021 at 10:52
by: clearly_not_atara
Preparation of 2-hydroxybenzylamine
The trouble with salicyl alcohols is the tendency to eliminate to the o-quinone methide. This is a r ...
24-4-2021 at 10:46
by: clearly_not_atara
Preparation of 2-hydroxybenzylamine
[rquote=658726&tid=157328&author=kmno4]
Maybe good old Leuckart would make the day ?[/rquot ...
23-4-2021 at 15:56
by: clearly_not_atara
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