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Author: Subject: Ethyl Perchlorate
Davin
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[*] posted on 14-1-2014 at 21:26


Thanks Dany!
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BromicAcid
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[*] posted on 15-1-2014 at 04:31


Here are the first to pages of the Meyer&Spormann paper in English courtesy of the Wayback Archive. The rest of the images however were not archived as far as I can tell. I can also dig up the Hare&Boye paper transcribed into Word. It was difficult to read so once upon a time I copied it over.

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Shamelessly plugging my attempts at writing fiction: http://www.robvincent.org
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Davin
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[*] posted on 16-1-2014 at 16:57


Thanks Bromic!
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franklyn
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[*] posted on 1-1-2020 at 11:07
Perchlorate polymers


Reactions of Dichlorine Heptoxide with alcohols
J. Am. Chem. Soc. 1974, 96, 10, 3233-3237
https://pubs.acs.org/doi/pdf/10.1021/ja00817a033
https://doi.org/10.1021/ja00817a033

Reactions of dichlorine heptoxide with alcohols.jpg - 547kB


Dichlorine Heptoxide in Carbon Tetrachloride is a general reagent for the facile oxidation of alcohols to alkyl perchlorates.
It's preparation from Perchloric acid obviates subsequent handling of the acid itself.
Propargyl alcohol H-CΞC-CH2OH for example is thus made in situ into Propargyl Perchlorate. H-CΞC-CH2-ClO4 => 3 CO + H2O + HCl .
Propargyl alcohol polymerizes , presenting the prospect of producing a perchlorate polymer.

Chloroethene monomer commonly known as Vinyl Chloride , H2:C=CH.Cl polymerizes into the familiar PVC plastic ( Poly Vinyl Chloride ) [CH2.CHCl]n
Ethenol known as Hydroxylethylene commonly known as Vinyl alcohol H2:C=CH.OH
may suitably be made into Vinyl Perchlorate H2:C=CH.ClO4 => CO2 + CO + H2O + HCl
and subsequently polymerized in the same way ( barring steric hindrance ) into a Poly Vinyl Perchlorate [CH2CHClO4]n

The highest density of PVC plastic is ~ 1.45 . Higher density can be anticipated in the perchlorate variant.

1,3,5-Trihydroxybenzene also known as 1,3,5-Benzenetriol commonly known as Phloroglucinol C6H3(OH)3
should readily be liable to form the Perchlorate , C6H3(ClO4)3 => 6 CO2 + 3 HCl

IMPORTANT CRITICAL PRACTICE FOR INVESTIGATION
https://sites.google.com/site/energeticchemical/alkyl-perchl...


.

[Edited on 2-1-2020 by franklyn]




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