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so much bubbles in glass
I'd really avoid putting much stress on that joint, and distillations where the vapor front moves sl ...
21-5-2021 at 06:23
by: njl
Orthosilicate esters from silica gel
Problem is EG is much less volatile than ethanol. So there's nothing driving the equilibrium towards ...
20-5-2021 at 10:05
by: njl
SO2 influence on nitration
Exactly that. I thought OP meant something more like a saturated solution of SO2 in H2SO4.
20-5-2021 at 05:56
by: njl
Is sodium dichloroisocyanurate an oxidiser?
Maybe, that's something that you will most likely have to try to get a good answer.

Edit: That's ...
20-5-2021 at 04:54
by: njl
Is sodium dichloroisocyanurate an oxidiser?
Yes?
20-5-2021 at 04:42
by: njl
SO2 influence on nitration
80 PPM of SO2 is about 0.00125 M

95 percent H2SO4 is around 17 M

This amount of SO2 is inconse ...
19-5-2021 at 07:25
by: njl
N-acetyl MDA from helional
If you can back up that formamide route then right on. However, if you have the acid and want the am ...
19-5-2021 at 05:32
by: njl
Aldehyde oxidation
Does the oxidation of aldehydes with hypochlorite require water, or is hypochlorite a good enough nu ...
17-5-2021 at 12:34
by: njl
Vilsmeier reagent/POCl3 formation
Where can P2O5 be easily purchased?
17-5-2021 at 09:43
by: njl
N-acetyl MDA from helional
Since it's back on my mind, maybe the Schmidt reaction can be optimized for the synthesis of formami ...
17-5-2021 at 07:36
by: njl
Ninja smoke/flash
Hold your breath and crack open some TiCl[sub]4[/sub]
17-5-2021 at 05:40
by: njl
Greek fire -- why not alum?
Which "organo-aluminum" species are you suggesting? And by thiolate do you mean the sulfur analogues ...
17-5-2021 at 04:43
by: njl
Salt amoniac sublimation, best method???
If it falls it will land on the watchglass!
14-5-2021 at 10:05
by: njl
Pyridine hydrogenation - methods?
I'm interested in the electroreduction garagechemist mentioned, where can I find more info on that?
14-5-2021 at 09:10
by: njl
Salt amoniac sublimation, best method???

[quote]
NH3(g) + Cl(g)
[/quote]

Should be NH3 + HCl
14-5-2021 at 04:44
by: njl
N-acetyl MDA from helional
Consider the schmidt reaction of HN3 with carbonyls, which under some conditions yields formamides f ...
13-5-2021 at 14:17
by: njl
Survey: Reagent Wish List
What reducing agents would those be?
12-5-2021 at 15:12
by: njl
Aldehyde oxidation
The colors in the first reaction ranged from purple, light pink, brown, to gray, honey, and red-oran ...
12-5-2021 at 11:16
by: njl
Anhydrous Aluminum Chloride
[url=https://onyxmet.com/index.php?route=product/product&path=70&product_id=1949]Onyxmet[/ur ...
12-5-2021 at 10:21
by: njl
Survey: Reagent Wish List
Definitely clean and undiluted H2SO4, HNO3, anhydrous alcohols, I'm always looking for NaBH4 - best ...
12-5-2021 at 10:13
by: njl
Aldehyde oxidation
Because that's how they do it in the paper I linked.
11-5-2021 at 12:03
by: njl
Aldehyde oxidation
Proposed reaction scheme, .1 M scale:

A 250 mL beaker is charged with 14 g Ca(OCl)2. 150 mL room ...
11-5-2021 at 11:53
by: njl
wall wart as power supply for electrolysis
Actually, I think 2 amp phone chargers require feedback from the load in order to operate. You proba ...
11-5-2021 at 05:36
by: njl
Aldehyde oxidation
Luckily enough I have some Me2CO3. However, it is mixed with 1,3 dioxolane and I am not in a positio ...
11-5-2021 at 05:34
by: njl
Aldehyde oxidation
Seems like hypochlorite doesn't form stable solutions with many common solvents, so I think I'll be ...
11-5-2021 at 05:14
by: njl
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