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The Short Questions Thread (4)
Nice edit, but I am not "confused." I'm agreeing with you that "dioxide" by itself can be somewhat a ...
19-6-2017 at 03:29
by: Darkstar
The Short Questions Thread (4)
Right, but I am assuming that the context of his question was the difference between the anions in s ...
19-6-2017 at 02:11
by: Darkstar
The Short Questions Thread (4)
"Dioxide" is the correct IUPAC nomenclature for the superoxide anion. For example, if you check the ...
19-6-2017 at 01:31
by: Darkstar
The Short Questions Thread (4)
@JJay:

Dioxide and peroxide are both ions, and are formed through single-electron transfer to mol ...
19-6-2017 at 01:19
by: Darkstar
Birch reduction - why does it reduce OH from pseudoephedrine, rather than reducing the benzene ring?
[rquote=483528&tid=74079&author=Stibnut]But I’m not sure what happens if you had 1-phenyle ...
13-6-2017 at 07:30
by: Darkstar
abnormal nitration of styrene
[rquote=475797&tid=4868&author=Melgar]Why couldn't you use iodine instead of bromine or chlo ...
25-2-2017 at 16:01
by: Darkstar
Achtung baby: hasta la vista!
Glad to see you're back! With all the medical and legal issues you've been dealing with lately, many ...
18-2-2017 at 01:40
by: Darkstar
Oxidative decarboxylation with TCCA
@[b]Cryolite[/b]: As JJay pointed out, there are numerous examples in the literature of hypochlorite ...
16-2-2017 at 03:22
by: Darkstar
Where is Blogfast25 ?
[u]UPDATE[/u]: For anyone still worried about blogfast, I think I may have some good news. Not only ...
7-2-2017 at 20:21
by: Darkstar
Where is Blogfast25 ?
I hope he's alright. According to his profile, he hasn't even logged in now for nearly three months. ...
7-2-2017 at 14:01
by: Darkstar
Claisen Reaction
I wasn't saying that really strong bases won't work, I was saying that you may need to be more caref ...
12-12-2016 at 17:10
by: Darkstar
Claisen Reaction
You also need to take into consideration your target molecule when choosing a base, otherwise you ma ...
12-12-2016 at 12:22
by: Darkstar
4,7-phenanthroline-5,6-dione intermediate
[rquote=468751&tid=71219&author=Boffis]The question is therefore if I were to nitrate 2-anis ...
11-12-2016 at 15:55
by: Darkstar
Need help recovering alpha-phenylacetoacetonitrile
No offense, Iso, but you'd probably get better results if you'd just drop the whole "I have no inten ...
10-11-2016 at 04:40
by: Darkstar
naphthoyl indole grignard question.
[rquote=465037&tid=70405&author=zed]Keeping in mind, that Indoles are already extremely reac ...
31-10-2016 at 15:52
by: Darkstar
difference between forms of tocopherol
The difference between the four forms of tocopherol shown on Wikipedia are the number of methyl grou ...
16-10-2016 at 02:03
by: Darkstar
Hydrazine soln. + Time = ... Maple Syrup?!
[rquote=463024&tid=69723&author=chemplayer...]Could this be slow oxidation of the alcohol to ...
15-10-2016 at 22:09
by: Darkstar
How to make a buffer of a specific pH?
[rquote=463275&tid=69804&author=aga]Oh crap. Always read the question at least 5 times when ...
10-10-2016 at 03:49
by: Darkstar
Mercury-free Clemmensen reduction?
[rquote=463150&tid=69602&author=laserlisa]I never heard that Shulgin had this intention, and ...
8-10-2016 at 23:57
by: Darkstar
Chemical Bonds
[rquote=463035&tid=69742&author=NzForever]Anyway, some things he said were that [b]convalent ...
6-10-2016 at 23:15
by: Darkstar
Synthesis of malonic acid
[rquote=462694&tid=1600&author=wg48]I am still looking for the detailed mechanism.[/rquote]
...
5-10-2016 at 00:37
by: Darkstar
Mercury-free Clemmensen reduction?
[rquote=462574&tid=69602&author=Maroboduus]Never could figure out why a guy with access to L ...
2-10-2016 at 21:38
by: Darkstar
Seperating 2-phenylpropionaldehyde from phenyl-2-propanone
[rquote=462028&tid=69436&author=OBLONG]Also, I am aware that phenyl-2-propanone is a commonl ...
25-9-2016 at 07:06
by: Darkstar
Synthesis of tris(tert-butyl) alcohol
[rquote=461247&tid=69157&author=Romain]Ah I didn't know grignard reagents could reduce steri ...
16-9-2016 at 11:46
by: Darkstar
Can 2-chloroethanol be prepared with glycol + HCl(aq), rather than HCl gas?
[rquote=461165&tid=69158&author=buuun]By looking at the equation, there's no apparent reason ...
16-9-2016 at 09:58
by: Darkstar
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