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Formation of S-alkylthiosulfates/Bunte's salts from Alkyl sulfates?
Wiki describes the reaction between alkyl halides and sodium thiosulfate, I was wondering whether th ...
5-3-2020 at 14:31
by: Merryp
How do Sodium Sulfide and Sodium Hydrogen Sulfide differ in aqueous solution?

Since the Sulfide anion shouldn't exist in solution, I'd assume both form HS-, and eventually, H2S ...
26-2-2020 at 04:41
by: Merryp
Looking for the most convenient preparation of ethyl mercaptan. Via ethyl chloride/sulfate?
The thiol formation seems pretty straightforward, making the adequate ethylating agent seems somewha ...
9-2-2020 at 13:23
by: Merryp
Why is sodium carbonate not used as starting point for hypochlorite/chlorate production?
Someone suggested this equation:

3 Na2CO3 + 3 Cl2 → 5 NaCl + NaClO3 + 3 CO2

Looks reasonable ...
21-1-2020 at 14:47
by: Merryp
From the Wiki: CaSO4 + SiO2 -> SO3 + CaSiO3. Does this actually work?
[rquote=629765&tid=154745&author=annaandherdad]This was done at Whitehaven in the UK, google ...
20-1-2020 at 17:43
by: Merryp
From the Wiki: CaSO4 + SiO2 -> SO3 + CaSiO3. Does this actually work?
[rquote=629767&tid=154745&author=rockyit98]
yes https://d28rz98at9flks.cloudfront.net/9554/ ...
20-1-2020 at 17:26
by: Merryp
From the Wiki: CaSO4 + SiO2 -> SO3 + CaSiO3. Does this actually work?

http://www.sciencemadness.org/smwiki/index.php/Sulfur_trioxide#Preparation

Temperatures aside, ...
20-1-2020 at 15:11
by: Merryp
Sensitivity of chlorate explosives/cheddite.
[rquote=629481&tid=154727&author=JohnDoe13]Another wiki bullshit. [/rquote]

Well, the che ...
14-1-2020 at 00:52
by: Merryp
Sensitivity of chlorate explosives/cheddite.
Now, I heard that cheddite was used as a shotgun primer, but I always assumed it contained some kind ...
13-1-2020 at 20:06
by: Merryp
Schematics for a H2SO4/H2O2 electrolytic cell?
[rquote=628770&tid=154646&author=mysteriusbhoice]well 3 problems
H2O2 decomposes [/rquote]
...
3-1-2020 at 04:12
by: Merryp
Making iron phosphide without elemental phosphorus?
[rquote=628792&tid=154655&author=Tellurium]Well it is possibe to reduce Calcium phosphate(ot ...
3-1-2020 at 04:11
by: Merryp
Making iron phosphide without elemental phosphorus?

I was wondering whether there's a convenient method.

Carbothermal reduction of iron phosphate? ...
29-12-2019 at 19:33
by: Merryp
Calcium Chlorate from TCCA
As far as I'm aware Calcium hypochlorite will only react very slowly to chlorate.
So, unless you in ...
29-12-2019 at 18:59
by: Merryp
Schematics for a H2SO4/H2O2 electrolytic cell?
I was wondering how that'd actually work, and whether you can get a reasonable yield of H2O2 at lab ...
28-12-2019 at 16:40
by: Merryp
Acetylide from NaOH + carbon - does this actually work?
There's an old patent claiming as much:

https://patents.google.com/patent/US2802723A/en?q=C01B32% ...
18-12-2019 at 17:02
by: Merryp
Sodium oxide via decomposition of Sodium sulfate - would it work?
I think it's fair to assume that sulfur dioxide would be the first thing to go upon heating to decom ...
6-10-2019 at 04:24
by: Merryp
Convenient route of reducing nitrate to nitrite?
[rquote=624001&tid=154132&author=rockyit98]you don't need reducing agents at all just need t ...
5-10-2019 at 03:38
by: Merryp
Convenient route of reducing nitrate to nitrite?
[rquote=623985&tid=154132&author=Alkoholvergiftung] here is the link i hope it works.
[/rqu ...
4-10-2019 at 17:27
by: Merryp
Convenient route of reducing nitrate to nitrite?
[rquote=623983&tid=154132&author=Alkoholvergiftung]I have this from an patent but if you don ...
4-10-2019 at 08:01
by: Merryp
Convenient route of reducing nitrate to nitrite?
[rquote=623979&tid=154132&author=Alkoholvergiftung]oh i ve forgotten my favorite is an wet M ...
4-10-2019 at 07:27
by: Merryp
Convenient route of reducing nitrate to nitrite?
There are various reducing agents listed for molten nitrate; ideally, I'd like to avoid lead or othe ...
4-10-2019 at 05:23
by: Merryp
Properties of (mono) Nitroethane, relative to Nitromethane?
I was wondering how well Nitroethane might hold up as energetic compound.

Apparently there's some ...
30-9-2019 at 14:06
by: Merryp
Convenient Formaldehyde/Paraform synthesis from Polyoxymethylene?
Wiki: "Acetal resins are sensitive to acid hydrolysis and oxidation by agents such as mineral acid a ...
28-8-2019 at 14:00
by: Merryp
Could a thermal lance with Aluminium fuel be operated with compressed air?
[rquote=621503&tid=153436&author=Ubya][rquote=621445&tid=153436&author=Merryp] to bu ...
28-8-2019 at 10:15
by: Merryp
Could a thermal lance with Aluminium fuel be operated with compressed air?
Given the fact that Al can maintain thermite reactions with weak oxidizers, like Fe2O3 or CaSO4, I w ...
27-8-2019 at 15:36
by: Merryp
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